SAFETY DATA SHEET
IN COMPLIANCE WITH DIRECTIVE 91/155/EEU
301 / Date of issue: 07.06.2006
1. NAME OF THE PRODUCT AND THE COMPANY
Trade name of the product:
DEKO PROFESSIONAL 2K COLD PLASTIC FOR HORISONTAL ROAD MARKING
General use of the product:
The cold plastic is used for horizontal road marking of roads, streets and tracks with asphalt and
concrete coatings. It is applied only with marking equipment. Immediately prior to use of plastic
add from 2-4 % of Hardener.
It is produced in following colours: white and yellow.
Name of the company:
"ORGACHIM" JSC
Republic of Bulgaria
7000 Rousse
21, "Treti mart" blvd.
Tel. +359/82/ 886-275
Fax: +359/82/ 822-490
Emergency phone:
Company Fire brigade: +359/82/886-333
2. CONTENT OF THE PRODUCT
The product is homogenous suspension of pigments and fillers in special acrylate resins.
According to the EU-Directives 67/548, 88/379 and 92/32 the product is classified as a
dangerous substance.
DEKO PROFESSIONAL 2K COLD PLASTIC FOR HORISONTAL ROAD MARKING -
WHITE CONTAINS THE FOLLOWING COMPONENTS, DANGEROUS TO THE
HUMAN HEALTH:
CAS INECS Chemical name conc.% Symbol R ?phrases
141-32-2 205-480-7 n-butyl acrylate 5 ?10 Xi 10-36/37/38-43
80-62-6 201-297-1 Methyl metacrylate 8 ?15 F, Xi 11-37/38-43
103-11-7 203-080-7 2-etyl hexil acrylate max 5 Xi 37/38-43
DEKO PROFESSIONAL 2K COLD PLASTIC FOR HORISONTAL ROAD MARKING
WITH LEAD CONTENT 璝ELLOW COLOR CONTAINS THE FOLLOWING
COMPONENTS, DANGEROUS TO THE HUMAN HEALTH:
CAS INECS Chemical name conc.% Symbol R ?phrases
141-32-2 205-480-7 n-butyl acrylate 5 ?10 Xi 10-36/37/38-43
80-62-6 201-297-1 Methyl metacrylate 8 ?15 F, Xi 11-37/38-43
103-11-7 203-080-7 2-etyl hexil acrylate max 5 Xi 37/38-43
Lead sulphate-chrome 61-33-40-50/53-
12656-85-8 235-759-9 4-5 T, N
molybdate 62
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3. HAZARDS IDENTIFICATION
The product is flammable.Keep away from open fire when handling it. It may form dangerous
explosive mixtures with the air. It's harmful by inhalation and in contact with skin. The vapours
of the organic solvents in it act as narcotic at high concentrations.
4. FIRST AID MEASURES
Symptoms arisen from prolonged expose: dizziness, headache, respiratory problems, skin
irritation and eye irritation.
Medical attention should be obtained in case of symptoms connected with respiration and skin/eye
contact.
Inhalation:
Remove the casualty immediately to fresh air. In case of complaints, seek medical help.
Casual ingestion:
Do not give drinks and do not induce vomiting, if the patient is unconscious or with convulsions.
In case of prolonged complaints, consult with a doctor.
Skin or clothes contact:
Immediately change the contaminated clothing, wash the contact skin with water and soap and
rinse well. Don't use organic solvents! If the skin has inflammation consult with the doctor.
Eye contact:
Wash the eyes with plenty of fresh water for several minutes, holding eyelids open.
Remove contact lenses. Call an eye-doctor.
Notes to the doctor:
There is no specific antidote. The treatment from the overexposure should be directed to control
of the symptoms and clinical treatment of the patient.
5. FIRE FIGHTING MEASURES
General directions:
Remove all sources of fire: e.g. open fire, lit cigarettes, sparks from tools/equipment.
Always keep packages closed.
Suitable extinguishing agents:
Alkali resistant foam, dry chemical powder, CO2.
Unsuitable extinguishing agents:
Lavish water spray.
Special hazards arising from the product itself, products formed as a result of its
incineration or gasses formed:
Take into consideration that dangerous gas products and thick soot can be formed during its
burning.
Special protective equipment:
Using a gas mask and protective firemen clothing is recommended.
Additional instructions:
Extinguish fire in the wind direction. Cool the non-burning packages by spraying water. Prevent
spillage and remove the packages to a safety place.
6. ACCIDENTAL RELEASE MEASUERS
Personal precautions:
Remove all sources of ignition. Provide adequate ventilation. Keep away from sources of ignition.
Wear suitable protective cloths and personal precautions (see item.8). Use independent
respiratory equipment, if you are exposed on vapor/dust/mist/aerosols.
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Environment precautions:
Avoid dust formation. Prevent spillage in water basins, tanks, basements, drains and sewerage.
If the spilled product has penetrated into water basins, sewerage, the soil or plants, advise the Fire
brigade and the Police. Avoid collecting of vapour in closed premises.
Methods for cleaning up:
Large quantities of spillages shall be transferred mechanically. Use explosion-protected
equipment.
Small spilled quantities can be collected with sand, dust or other similar absorbents..
Safely dispose to special areas, according to local regulations or incinerate under controlled
conditions.
7. HANDLING AND STORAGE OF THE PRODUCT
Safe handling:
General precautions of product handling:
Ensure adequate ventilation for handling and storage of the product. Do not exceed the value of
admissible concentration limits stated in item 8. Don't eat or drink at the working place. Don't
smoke. Observe the fire prevention measures.
Don't pollute the environment.
Storage:
Keep only in original, tightly closed containers, out of the reach of children or any other
unauthorized employees, in covered and dry storehouses, at temperature up to 25oC, away from
direct sunlight. Vapors may form flammable, explosive mixes with the air
The storehouses should be equipped in compliance with the local Regulations for storage of
flammable materials. Don't keep the product together with foodstuff, drinks or fodder. Don't
smoke. Packages should be marked with original labels stuck by the producer.
Observe the storage requirements indicated on the label.
8. EXPOSURE CONTROL AND PERSONAL PROTECTION
Technical measures for supervising the safety labour requirement observance:
Provide adequate ventilation in the working premises to ensure that the defined admissible
concentration limit of the hazardous compounds in the air of the working environment does not
exceed norms according to Ordinance No.13( State Gazette 8/2004):
n-butyl acrylate- 11 mg/m3
methyl metacrylate - 50 mg/m3
N,N-di-methyl aniline ?2 mg/m3
lead and non-organic compounds -0,05 mg/m3
Use only non-sparking tools/equipment.
Ensure safe static electricity discharge.
Do not breath vapors. Avoid contact with skin and eyes.
Personal precautions:
Use materials, which are resistant to organic solvents like rubber or special plastics.
Respiratory protection:
In case the admissible concentration limit has been exceeded for a long time or the product is
handled in small, closed premises, it is recommended to use a gas mask.
Hand protection:
Always wear protective gloves.
Eye protection:
It is recommended to use a face protective mask or goggles.
Body protection:
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Wear non-static protective clothing and gum-boots.
Other protective equipment:
The storage and handling places should be equipped with devices for washing/ eye rinsing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Homogenous flowing mass
Physical form:
White, yellow
Colour:
Specific for Esther
Odour:
2,14 ?0,1 kg/L
Density:
Max 21篊
Flash point :
Approx. 230 0
Auto-ignition temperature:
Lower 2.1 % vol. upper 12.5 % vol.
Explosion limits:
> 1 at 20
Vapour pressure:
Insoluble
Solubility in water:
Not applicable
value:
10. CHEMICAL STABILITY AND REACTIVITY
The product is stable under normal storage conditions.
Conditions to avoid:
High temperature.
Substances to avoid:
Polymerization with release of heat may start in presence of peroxides, reducers an/or ions of
heavy metals.
Hazardous decomposition products:
The product is non-reactive.
11. TOXICOLOGICAL INFORMATION
The product is classified as health hazardous ?see item 2 and 3 of the present data sheet.
Its classification is determined by a conventional method (given in EU-Directive No. 88/379),
based on the health hazardous characteristics of the individual components of the product.
General information;
No available toxicological data for the product. Avoid contact with the eyes and skin and vapour
inhalation.
Inhalation:
Prolonged inhalation of concentrated organic solvents, present in the product, which exceed the
admissible concentration limit (see item 8) may cause irritation of the mucous tissue of the
respiratory system.
Ingestion:
It may injure the digestive system tissue.
Skin contact:
Prolonged and intensive contact with the skin may cause sensitisizing.
Eye contact:
Drops from the product or high concentration product vapours may cause eye irritation.
12. ECOLOGICAL INFORMATION
Volatile compounds:
The product contains totally 20% volatile organic compounds.
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Bio-decomposition:
This product doesn't decompose biologically.
Additional information
Prevent spillage penetration into the soil, watercourses, tanks, drains and purifying equipment.
It is recommended to incinerate the unnecessary product at a high temperature.
13. DISPOSAL CONSIDERATIONS
Any remainder of the product or waste material left from its application, as well as the used
packages should be disposed according to the local Regulations for processing of special and
dangerous waste products.
Recommended disposal methods:
Incinerate the remainder and waste material at high temperatures under control.
Disposal of waste material in special places approved for disposal of dangerous materials.
Recycling of the solvents by distillation, if possible, in case you can manage the problem with the
distillation residua.
Metal packages should be recycled in steelworks or disposed in specially intended places, if it's
not possible to be recycled for reuse.
14. TRANSPORT INFORMATION
Road transport ADR/RID
Class: 3,II
Code: 310()
UN 1263
Hazard identification 30
Hazard symbol: FIRE HAZARDOUS
15. REGULATORY INFORMATION
The following marking is required according to the regulations/directives for dangerous products
marking:
DEKO PROFESSIONAL 2K COLD PLASTIC FOR HORISONTAL ROAD MARKING -
WHITE
Marking of the hazard with F and labeling "Easy flammable".
Marking of the hazard with Xi and labeling "Irrittating".
R ?phrases
R 11 ?Easy flammable
R 36/38 ?Irritant to respiratory system and skin.
R 43 ?May cause sensitisation by skin contact.
S ?phrases
S2- keep away from children.
S9- Keep container in a well-ventilated place.
S 16 ?Keep away from sources of ignition - No smoking.
S 24 ?Avoid contact with skin.
S 37 ?Wear suitable gloves.
DEKO PROFESSIONAL 2K COLD PLASTIC FOR HORISONTAL ROAD MARKING -
YELLOW
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Marking of the hazard with F and labeling "Easy flammable".
Marking of the hazard with T and labeling "Toxic".
Marking of the hazard with N and labeling "Hazardous to the environment".
R ?phrases
R 11 ?Easy flammable
R 61 ?May cause harm to the unborn child.
R 62 ?Risk of impaired fertility.
R 33 ?Danger of cumulative effects.
R 40 ?Limited evidence of a carcinogenic effect.
R 50/53 ?Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.
S ?phrases
S 2 ?Keep out of the reach of children.
S 16 ?Keep away from sources of ignition - No smoking.
S 53 ?Avoid exposure - obtain special instructions before use.
S 45 ?In case of accident or if you feel unwell, seek medical advice immediately. (Show the label
where possible.)
S 60 ?This material and its container must be disposed of as hazardous waste.
S 61 ?Avoid release to the environment. Refer to special instructions / Safety data sheets.
16. OTHER INFORMATION
The recommendations and information given in the present publication are to the producer's best
knowledge, great experience in handling these materials, as well as the rules for trading.
The present information and recommendations were prepared in accordance with the Bulgarian
regulations, the EU-directives and the International agreements, relevant to transportation of
dangerous materials.
The present information provides directions for health and environment protection measures and
should not be construed as a warranty for technical characteristics or proper specific application.
7000 Rousse, 21 "Treti mart" blvd., tel. +359/ 82 / 886 303; fax +359/ 82 / 886 257
www.orgachim.bg
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