Page 1/6
Safety Data Sheet
According to 91/155 EEC
Printing date 24.06.2009 Revision: 23.06.2009
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: butyl acrylate
?Manufacturer/Supplier:
Petrochem Middle East FZE
PO Box 17028,
Jebel Ali Free Zone
Dubai, UAE
Ph +971 4 8839222; Fax +971 4 8834133
?Further information obtainable from: Product safety department.
?Information in case of Emergency Product safety department.
?Information concerning particular hazards for human and environment:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 43 May cause sensitisation by skin contact.
4 First aid measures
?After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: If symptoms persist consult doctor.
5 Fire-fighting measures
?Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?For safety reasons unsuitable extinguishing agents: Water with full jet
(Contd. on page 2)
UAE
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Safety Data Sheet
According to 91/155 EEC
Printing date 24.06.2009 Revision: 23.06.2009
Trade name: butyl acrylate
(Contd. of page 1)
?Protective equipment: No special measures required.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Dilute with plenty of water.
Ensure adequate ventilation.
7 Handling and storage
?Handling:
?Information for safe handling: No special requirement
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep container tightly sealed.
8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
141-32-2 n-butyl acrylate
REL (USA) 55 mg/m? 10 ppm
TLV (USA) 11 mg/m? 2 ppm
SEN
IOELV (EU) Short-term value: 53 mg/m? 10 ppm
Long-term value: 11 mg/m? 2 ppm
WEL (Great Britain) Short-term value: 26 mg/m? 5 ppm
Long-term value: 5 mg/m? 1 ppm
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
?Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
self-contained respiratory protective device.
?Protection of hands:
Protective gloves
(Contd. on page 3)
UAE
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Safety Data Sheet
According to 91/155 EEC
Printing date 24.06.2009 Revision: 23.06.2009
Trade name: butyl acrylate
(Contd. of page 2)
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Fluid
Form:
Colourless
Colour:
Fruit-like
Odour:
?Change in condition
Melting point/Melting range: -64.6癈
Boiling point/Boiling range: 145癈
37癈
?Flash point:
275癈
?Ignition temperature:
Product is not explosive. However, formation of explosive air/vapour mixtures
?Danger of explosion:
are possible.
?Explosion limits:
1.2 Vol %
Lower:
8 Vol %
Upper:
5.3 hPa
?Vapour pressure at 20癈:
0.8898 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
1.4 g/l
water at 20癈:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products: No dangerous decomposition products known.
UAE
(Contd. on page 4)
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Safety Data Sheet
According to 91/155 EEC
Printing date 24.06.2009 Revision: 23.06.2009
Trade name: butyl acrylate
(Contd. of page 3)
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
Oral LD50 900 mg/kg (rat)
Dermal LD50 2000 mg/kg (rabbit)
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritating effect.
?Sensitization: Sensitization possible through skin contact.
12 Ecological information
?General notes:
Water hazard class 1 (German Regulation) (Assessment by list): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
3 Flammable liquids.
?ADR/RID class:
?Danger code (Kemler): 39
2348
?UN-Number:
III
?Packaging group:
3
?Hazard label:
?Description of goods: 2348 BUTYL ACRYLATES, STABILIZED
?Maritime transport IMDG:
3
?IMDG Class:
2348
?UN Number:
3
?Label
III
?Packaging group:
(Contd. on page 5)
UAE
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Safety Data Sheet
According to 91/155 EEC
Printing date 24.06.2009 Revision: 23.06.2009
Trade name: butyl acrylate
(Contd. of page 4)
F-E,S-D
?EMS Number:
No
?Marine pollutant:
?Proper shipping name: BUTYL ACRYLATES, STABILIZED
?Air transport ICAO-TI and IATA-DGR:
15 Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
?Code letter and hazard designation of product:
Xi Irritant
?Risk phrases:
10 Flammable.
36/37/38 Irritating to eyes, respiratory system and skin.
43 May cause sensitisation by skin contact.
?Safety phrases:
2 Keep out of the reach of children.
9 Keep container in a well-ventilated place.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Department issuing MSDS: Product safety department
?Contact:
Mr. Menon
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
(Contd. on page 6)
UAE
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Safety Data Sheet
According to 91/155 EEC
Printing date 24.06.2009 Revision: 23.06.2009