Material Safety Data Sheet
Self-Cross-Linking Waterborne Urethane/Acrylic
1. Product and company identification
Product name Self-Cross-Linking Waterborne In case of emergency 1-800-843-6174
Urethane/Acrylic
Code R6030 Validation date 1/22/2009.
Responsible name Regulatory Affairs Department
Manufacturer Essential Industries, Inc.
P.O. Box 12
Merton, WI 53056-0012
Phone: 262-538-1122
2. Hazards identification
Potential acute health effects do to overexposure
Inhalation No known significant effects or critical hazards.
Ingestion No known significant effects or critical hazards.
Skin No known significant effects or critical hazards.
Eyes No known significant effects or critical hazards.
Hazardous Material Information System (U.S.A.)
0 HAZARD RATING
Health
4 = Extreme
3 = High
0
Flammability 2 = Moderate
1 = Slight
0
Physical hazards 0 = Insignificant
B
Personal protection
A = Goggles B = Goggles & Gloves C = Goggles, Gloves & Apron
3. Composition/information on ingredients
There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as
hazardous to health or the environment and hence require reporting in this section.
4. First aid measures
Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical attention if symptoms occur.
Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get
medical attention if symptoms occur.
Inhalation Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs,
provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or
waistband. Get medical attention if symptoms occur.
Ingestion Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Get medical attention if symptoms occur.
Notes to physician No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
5. Fire-fighting measures
Flammability of the product In a fire or if heated, a pressure increase will occur and the container may burst.
Extinguishing media
Suitable Use an extinguishing agent suitable for the surrounding fire.
Special exposure hazards Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action
shall be taken involving any personal risk or without suitable training.
Special protective equipment for Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA)
with a full face-piece operated in positive pressure mode.
fire-fighters
6. Accidental release measures
Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep
unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate
personal protective equipment (see section 8).
Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant
authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods for cleaning up
Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material
and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Self-Cross-Linking Waterborne Urethane/Acrylic
6. Accidental release measures
Large spill Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g.
sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Dispose
of via a licensed waste disposal contractor. Note: see section 1 for emergency contact information and section 13 for waste disposal.
7. Handling and storage
Handling Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking.
Storage Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
8. Exposure controls/personal protection
Engineering No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure
to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures,
measures
local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or
statutory limits.
Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and
using the lavatory and at the end of the working period. Appropriate techniques should be used to remove
potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash
stations and safety showers are close to the workstation location.
Personal protection
Respiratory Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Hands Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times
when handling chemical products if a risk assessment indicates this is necessary.
Eyes Safety eyewear complying with an approved standard should be used when a risk assessment indicates this
is necessary to avoid exposure to liquid splashes, mists or dusts.
Skin Personal protective equipment for the body should be selected based on the task being performed and the
risks involved and should be approved by a specialist before handling this product.
9. Physical and chemical properties
Physical state Liquid
Color Off-white
VOC <0.4 Lbs./Gal.
pH 7.8 Specific Gravity: Not available
10 . Stability and reactivity
Chemical stability The product is stable.
Hazardous polymerization Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to avoid No specific data.
Materials to avoid No specific data.
Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Hazardous thermal decomposition Decomposition products may include the following materials:
carbon dioxide
products
carbon monoxide
11 . Toxicological information
Acute toxicity
Conclusion/Summary Not available
Chronic toxicity
Conclusion/Summary Not available
Potential chronic health effects do to overexposure
Carcinogenicity No known significant effects or critical hazards.
Mutagenicity No known significant effects or critical hazards.
Teratogenicity No known significant effects or critical hazards.
Developmental effects No known significant effects or critical hazards.
Self-Cross-Linking Waterborne Urethane/Acrylic
11 . Toxicological information
Fertility effects No known significant effects or critical hazards.
12 . Ecological information
Environmental effects No known significant effects or critical hazards.
Aquatic ecotoxicity
Conclusion/Summary Not available
Biodegradability
Conclusion/Summary Not available
13 . Disposal considerations
Waste disposal The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may
retain some product residues. This material and its container must be disposed of in a safe way. Dispose of
surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product,
solutions and any by-products should at all times comply with the requirements of environmental protection and
waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling
information and protection of employees.
14 . Transport information
Regulatory information UN number Proper shipping name Classes PG* Label Additional information
DOT Classification Not regulated - - - -
IMDG Class Not available Not available Not available - -
IATA-DGR Class Not available Not available Not available - -
PG* : Packing group
15 . Regulatory information
HCS Classification Not regulated
U.S. Federal regulations TSCA 5(a)2 final significant rules: Propane, oxybis[methoxy-
United States inventory (TSCA 8b): Not determined.
TSCA 12(b) annual export notification: Propane, oxybis[methoxy-
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: n-butyl acrylate; methacrylic acid; methyl methacrylate; styrene
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: n-butyl acrylate: Fire hazard,
reactive, Immediate (acute) health hazard, Delayed (chronic) health hazard; methacrylic acid: Fire hazard,
reactive, Immediate (acute) health hazard, Delayed (chronic) health hazard; methyl methacrylate: Fire hazard,
reactive, Immediate (acute) health hazard, Delayed (chronic) health hazard; styrene: Fire hazard, reactive,
Immediate (acute) health hazard, Delayed (chronic) health hazard
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: methyl methacrylate; styrene; sodium hydroxide; ethylenediamine; triethylamine;
ammonia
Clean Air Act (CAA) 112 accidental release prevention: ethylenediamine
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: ethylenediamine
Clean Air Act Section 112(b)
Hazardous Air Pollutants (HAPs)
Clean Air Act Section 602 Class I
Substances
Clean Air Act Section 602 Class II
Substances
DEA List I Chemicals (Precursor
Chemicals)
DEA List II Chemicals (Essential
Chemicals)
SARA 313
Product name CAS number Concentration
Self-Cross-Linking Waterborne Urethane/Acrylic
15 . Regulatory information
Form R - Reporting requirements n-butyl acrylate 141-32-2 14.099
methyl methacrylate 80-62-6 6.6107
styrene 100-42-5 6.6107
Supplier notification n-butyl acrylate 141-32-2 14.099
methyl methacrylate 80-62-6 6.6107
styrene 100-42-5 6.6107
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution
of the notice attached to copies of the MSDS subsequently redistributed.
State regulations Connecticut Carcinogen Reporting: None of the components are listed.
Connecticut Hazardous Material Survey: None of the components are listed.
Florida substances: None of the components are listed.
Illinois Chemical Safety Act: None of the components are listed.
Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed.
Louisiana Reporting: None of the components are listed.
Louisiana Spill: None of the components are listed.
Massachusetts Spill: None of the components are listed.
Massachusetts Substances: None of the components are listed.
Michigan Critical Material: None of the components are listed.
Minnesota Hazardous Substances: None of the components are listed.
New Jersey Hazardous Substances: None of the components are listed.
New Jersey Spill: None of the components are listed.
New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.
New York Acutely Hazardous Substances: None of the components are listed.
New York Toxic Chemical Release Reporting: None of the components are listed.
Pennsylvania RTK Hazardous Substances: None of the components are listed.
Rhode Island Hazardous Substances: None of the components are listed.
United States inventory (TSCA 8b) Not determined.
16 . Other information
Date of issue 1/22/2009.
Date of previous issue 1/22/2009.
Version 2
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be
used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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