Page 1/7
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 28.07.2006 Reviewed On: 28.07.2006
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY
PRODUCT DETAILS
Trade name: Vertiseal CE Standard Part A
Manufacturer/supplier:
Grace Construction Products
Ajax Avenue,
Slough,
Berks.
SL1 4BH
Tel: ++44 (0)1753 692929
Fax: ++44 (0)1753 691623
www.graceconstruction.com
Information in case of emergency: ++ 44 (0)208 762 8322
2 COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL CHARACTERIZATION
Description:
Mixture of substances listed below with non-hazardous additions.
For further information, please refer to the product technical data sheet.
Dangerous components:
Xn, N; R 40-50/53
CAS: 85535-84-8 Alkanes, C10-13, chloro 20-30%
EINECS: 287-476-5
CAS: 1313-13-9 Manganese dioxide Xn; R 20/22 20-30%
EINECS: 215-202-6
Xn, N; R 20/22-36/38-43-48/22-50/53 1.0-2.0%
CAS: 137-26-8 Thiram
EINECS: 205-286-2
CAS: 1310-73-2 Sodium hydroxide C; R 35 0.0-1.0%
EINECS: 215-185-5
Additional information: For the wording of the listed risk phrases refer to section 16.
3 HAZARDS IDENTIFICATION
Hazard description:
Xn Harmful
N Dangerous for the environment
Information concerning particular hazards for human and environment:
The product has to be labelled in accordance with applicable regulations.
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
R 40 Limited evidence of a carcinogenic effect.
(Contd. on page 2)
GB
DR
Page 2/7
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 28.07.2006 Reviewed On: 28.07.2006
Trade name: Vertiseal CE Standard Part A
(Contd. of page 1)
R 43 May cause sensitisation by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 68 Possible risk of irreversible effects.
4 FIRST-AID MEASURES
General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after
the accident.
After inhalation:
Take affected persons into fresh air and keep quiet.
Seek immediate medical advice.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact:
Rinse opened eye for several minutes under running water.
Seek immediate medical advice.
After swallowing:
Wash out mouth with water.
Do not induce vomiting; call for medical help immediately.
Never give anything by mouth to an unconscious person.
5 FIRE-FIGHTING MEASURES
Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray.
Protective equipment: Wear self-contained respiratory protective device.
Additional information:
Collect contaminated fire fighting water separately. It must not enter the sewage system.
6 ACCIDENTAL RELEASE MEASURES
Person-related safety precautions:
Ensure adequate ventilation.
Wear protective equipment. Keep unprotected persons away.
Measures for environmental protection: Do not allow to enter sewers/surface or ground water.
Measures for cleaning/collecting:
Ensure adequate ventilation.
Send for recovery or disposal in suitable receptacles.
(Contd. on page 3)
GB
DR
Page 3/7
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 28.07.2006 Reviewed On: 28.07.2006
Trade name: Vertiseal CE Standard Part A
(Contd. of page 2)
Dispose contaminated material as waste according to item 13.
7 HANDLING AND STORAGE
HANDLING
Information for safe handling:
Store in original containers.
Open and handle receptacle with care.
Information about fire - and explosion protection: No special measures required.
STORAGE
Information about storage in one common storage facility: No special measures required.
Further information about storage conditions:
Protect from frost.
Store in cool, dry conditions in well sealed receptacles.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with limit values that require monitoring at the workplace:
1313-13-9 Manganese dioxide
WEL Long-term value: 5 mg/m?br>
1310-73-2 Sodium hydroxide
WEL Short-term value: 2 mg/m?br>
Additional information: Based on the lists valid at the date of MSDS creation.
PERSONAL PROTECTIVE EQUIPMENT
General protective and hygienic measures:
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-
contained respiratory protective device.
Protection of hands: Protective gloves.
Material of gloves: Rubber gloves.
Eye protection:
Tightly sealed goggles.
Face protection.
(Contd. on page 4)
GB
DR
Page 4/7
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 28.07.2006 Reviewed On: 28.07.2006
Trade name: Vertiseal CE Standard Part A
(Contd. of page 3)
Body protection: Protective work clothing.
9 PHYSICAL AND CHEMICAL PROPERTIES
GENERAL INFORMATION
Paste.
Form:
According to product specification.
Colour:
Characteristic.
Odour:
Change in conditions:-
Undetermined.
Melting point/Melting range:
> 100癈
Boiling point/Boiling range:
Flash point: > 100癈
Self-igniting: Product is not self-igniting.
Danger of explosion: Product does not present an explosion hazard.
Density: Not determined.
Solubility in/Miscibility with:-
Not miscible or difficult to mix.
Water:
Additional information: These are typical values and do not constitute a specification.
10 STABILITY AND REACTIVITY
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Dangerous reactions:
Reacts with acids.
Reacts with strong oxidizing agents.
Dangerous decomposition products:
Carbon monoxide and carbon dioxide.
Hydrogen chloride (HCl).
Sulphur oxides (SOx).
11 TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
LD/LC50 values relevant for classification:
137-26-8 Thiram
Oral LD50 560 mg/kg (rat)
Dermal LD50 2000 mg/kg (rat)
Primary irritant effect:-
on the skin: May be irritating to the skin on prolonged contact.
on the eye: May be irritating to the eyes.
(Contd. on page 5)
GB
DR
Page 5/7
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 28.07.2006 Reviewed On: 28.07.2006
Trade name: Vertiseal CE Standard Part A
(Contd. of page 4)
Sensitization: Sensitization possible through skin contact.
12 ECOLOGICAL INFORMATION
General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms.
13 DISPOSAL CONSIDERATIONS
PRODUCT
European waste catalogue:
08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF
COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND
PRINTING INKS
08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products)
08 04 09 waste adhesives and sealants containing organic solvents or other dangerous substances
UNCLEANED PACKAGING
Recommendation: Disposal must be made according to official regulations.
14 TRANSPORT INFORMATION
LAND TRANSPORT ADR/RID (cross-border)
9 Miscellaneous dangerous substances and articles.
ADR/RID class:
3077
UN-Number:
III
Packaging group:
3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Alkanes,
Description of goods:
C10-13, chloro)
MARITIME TRANSPORT IMDG
-
IMDG Class:
3077
UN Number:
III
Packaging group:
Yes
Marine pollutant:
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Alkanes, C10-13,
chloro)
AIR TRANSPORT ICAO-TI AND IATA-DGR
9
ICAO/IATA Class:
3077
UN/ID Number:
(Contd. on page 6)
GB
DR
Page 6/7
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 28.07.2006 Reviewed On: 28.07.2006
Trade name: Vertiseal CE Standard Part A
(Contd. of page 5)
III
Packaging group:
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Alkanes, C10-13,
chloro)
15 REGULATORY INFORMATION
Labelling according to EU guidelines:
Observe the general safety regulations when handling chemicals.
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials.
Code letter and hazard designation of product:
Xn Harmful
N Dangerous for the environment
Hazard-determining components of labelling:
Alkanes, C10-13, chloro
Thiram
Manganese dioxide
Risk phrases:
22 Harmful if swallowed.
36/38 Irritating to eyes and skin.
40 Limited evidence of a carcinogenic effect.
43 May cause sensitisation by skin contact.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
68 Possible risk of irreversible effects.
Safety phrases:
2 Keep out of the reach of children.
9 Keep container in a well-ventilated place.
13 Keep away from food, drink and animal feedingstuffs.
23 Do not breathe fumes.
25 Avoid contact with eyes.
29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection
point.
36/37 Wear suitable protective clothing and gloves.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
51 Use only in well-ventilated areas.
52 Not recommended for interior use on large surface areas.
57 Use appropriate container to avoid environmental contamination.
60 This material and its container must be disposed of as hazardous waste.
61 Avoid release to the environment. Refer to special instructions/safety data sheets.
Waterhazard class: WGK 3 (VwVwS Anhang 4 vom 19.05.1999): extremely hazardous for water.
Other regulations, limitations and prohibitive regulations: All components EINECS listed.
GB
(Contd. on page 7)
DR
Page 7/7
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 28.07.2006 Reviewed On: 28.07.2006
Trade name: Vertiseal CE Standard Part A
(Contd. of page 6)
16 OTHER INFORMATION
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
Relevant R-phrases:
20/22 Harmful by inhalation and if swallowed.
35 Causes severe burns.
36/38 Irritating to eyes and skin.
40 Limited evidence of a carcinogenic effect.
43 May cause sensitisation by skin contact.
48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Department issuing MSDS:
EHS Department, EMEA Region, Grace Performance Chemicals, Ajax Avenue, Slough, Berks. SL1 4BH
Tel: ++44 (0)1753 692929 Fax: ++44(0)1753 637659
GB
DR
Page 1/5
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 04.05.2006 Reviewed On: 04.05.2006
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY
PRODUCT DETAILS
Trade name: Vertiseal CE Standard Part B
Manufacturer/supplier:
Grace Construction Products
Ajax Avenue,
Slough,
Berks.
SL1 4BH
Tel: ++44 (0)1753 692929
Fax: ++44 (0)1753 691623
Information in case of emergency: ++ 44 (0)208 762 8322
2 COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL CHARACTERIZATION
Description:
Mixture of substances listed below with non-hazardous additions.
For further information, please refer to the product technical data sheet.
Dangerous components:
68611-50-7 Polysulphide polymer R 52/53 30-50%
Additional information: For the wording of the listed risk phrases refer to section 16.
3 HAZARDS IDENTIFICATION
Hazard description: Not applicable.
Information concerning particular hazards for human and environment:
The product has to be labelled in accordance with applicable regulations.
R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4 FIRST-AID MEASURES
After inhalation:
Take affected persons into fresh air and keep quiet.
Seek immediate medical advice.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact:
Rinse opened eye for several minutes under running water.
(Contd. on page 2)
GB
DR
Page 2/5
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 04.05.2006 Reviewed On: 04.05.2006
Trade name: Vertiseal CE Standard Part B
(Contd. of page 1)
Seek immediate medical advice.
After swallowing:
Wash out mouth with water.
Do not induce vomiting; call for medical help immediately.
Never give anything by mouth to an unconscious person.
5 FIRE-FIGHTING MEASURES
Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray.
Protective equipment: Wear self-contained respiratory protective device.
Additional information:
Collect contaminated fire fighting water separately. It must not enter the sewage system.
6 ACCIDENTAL RELEASE MEASURES
Person-related safety precautions:
Ensure adequate ventilation.
Wear protective equipment. Keep unprotected persons away.
Measures for environmental protection: Do not allow to enter sewers/surface or ground water.
Measures for cleaning/collecting:
Ensure adequate ventilation.
Absorb with liquid-binding material (sand, diatomite, universal binders).
Send for recovery or disposal in suitable receptacles.
Dispose contaminated material as waste according to item 13.
7 HANDLING AND STORAGE
HANDLING
Information for safe handling:
Store in original containers.
Open and handle receptacle with care.
Information about fire - and explosion protection: No special measures required.
STORAGE
Information about storage in one common storage facility: No special measures required.
Further information about storage conditions:
Protect from frost.
Store in cool, dry conditions in well sealed receptacles.
GB
(Contd. on page 3)
DR
Page 3/5
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 04.05.2006 Reviewed On: 04.05.2006
Trade name: Vertiseal CE Standard Part B
(Contd. of page 2)
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the
workplace.
Additional information: Based on the lists valid at the date of MSDS creation.
PERSONAL PROTECTIVE EQUIPMENT
General protective and hygienic measures: Avoid contact with the eyes and skin.
Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-
contained respiratory protective device.
Protection of hands: Protective gloves.
Material of gloves: Rubber gloves.
Eye protection:
Tightly sealed goggles.
Face protection.
Body protection: Protective work clothing.
9 PHYSICAL AND CHEMICAL PROPERTIES
GENERAL INFORMATION
Paste.
Form:
According to product specification.
Colour:
Characteristic.
Odour:
Change in conditions:-
Undetermined.
Melting point/Melting range:
> 100癈
Boiling point/Boiling range:
Flash point: > 100癈
Self-igniting: Product is not self-igniting.
Danger of explosion: Product does not present an explosion hazard.
Density at 20癈: 1.64000 g/cm?br>
Solubility in/Miscibility with:-
Not miscible or difficult to mix.
Water:
Additional information: These are typical values and do not constitute a specification.
10 STABILITY AND REACTIVITY
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
(Contd. on page 4)
GB
DR
Page 4/5
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 04.05.2006 Reviewed On: 04.05.2006
Trade name: Vertiseal CE Standard Part B
(Contd. of page 3)
Dangerous decomposition products:
Carbon monoxide and carbon dioxide.
Hydrogen sulphide
Sulphur oxides (SOx).
11 TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
LD/LC50 values relevant for classification:
13463-67-7 Titanium dioxide
Oral LD50 > 10 000 mg/kg (rat)
Dermal LD50 > 10 000 mg/kg (rabbit)
Inhalative LC50/4 h > 6.82 mg/l (rat)
Primary irritant effect:-
on the skin: May be irritating to the skin on prolonged contact.
on the eye: May be irritating to the eyes.
12 ECOLOGICAL INFORMATION
ECOTOXICAL EFFECTS
Remark: Harmful to fish
General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Harmful to aquatic organisms.
13 DISPOSAL CONSIDERATIONS
PRODUCT
European waste catalogue:
08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF
COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND
PRINTING INKS
08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products)
08 04 09 waste adhesives and sealants containing organic solvents or other dangerous substances
UNCLEANED PACKAGING
Recommendation: Disposal must be made according to official regulations.
GB
(Contd. on page 5)
DR
Page 5/5
Material Safety Data Sheet
According to 91/155 EEC
Printing Date: 04.05.2006 Reviewed On: 04.05.2006
Trade name: Vertiseal CE Standard Part B
(Contd. of page 4)
14 TRANSPORT INFORMATION
LAND TRANSPORT ADR/RID (cross-border)
-
ADR/RID class:
MARITIME TRANSPORT IMDG
-
IMDG Class:
Marine pollutant: No.
AIR TRANSPORT ICAO-TI AND IATA-DGR
ICAO/IATA Class: -
15 REGULATORY INFORMATION
Labelling according to EU guidelines:
Observe the general safety regulations when handling chemicals.
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials.
Risk phrases:
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety phrases:
29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection
point.
60 This material and its container must be disposed of as hazardous waste.
Waterhazard class: WGK 3 (VwVwS Anhang 4 vom 19.05.1999): extremely hazardous for water.
Other regulations, limitations and prohibitive regulations: All components EINECS listed.
16 OTHER INFORMATION
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
Relevant R-phrases:
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Department issuing MSDS:
EHS Department, EMEA Region, Grace Performance Chemicals, Ajax Avenue, Slough, Berks. SL1 4BH
Tel: ++44 (0)1753 692929 Fax: ++44(0)1753 637659
GB
DR
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