MATERIAL SAFETY DATA SHEET

                          Nuturf TMTD 600

Emergency Response: 1800 631 008                                                   Phone:          (02) 9395 1200

Nuturf Pty Ltd                                                                     Fax             (02) 9395 1241

                    ABN 30 000 425 927

Unit B2 Lidcombe Business Park                                              Toll Free (B/H):         1800 631 008

3-9 Birnie Ave Lidcombe, NSW 2141                                                     (A/H)          1800 033 498

AUSTRALIA

Hazardous according to the criteria of NOHSC Australia.



                                               l IDENTIFICATION

Product Name: TMTD 600 Flowable Herbicide

Other Names: None.

Product Code: None.

UN No: None allocated                                      Hazchem Code: None allocated

Dangerous Goods Class: None allocated

Sub Risk Class: None allocated

Packaging Group: None allocated

Poison Schedule: S6

Chemical Family: Blend of ingredients (see below). Active ingredient is a dithiocarbamate derivative.

Uses: For the control of certain fungus diseases as directed on product label.

 ______________________________________________________________________________________________

Physical Appearance & Properties

Appearance & Odour: Off-white viscous liquid. Characteristic odour.

Melting/softening point: No specific data. Liquid at normal temperatures.

Boiling point and vapour pressure: Boils at about 100?at 100kPa.

                                                        C

Volatile materials: Water component.

Flashpoint: Does not burn.

Flammability limits: Not applicable. This product does not burn.

Specific gravity: 1.18 - 1.19

Solubility in water: Forms suspensions in water.

Corrosiveness: Not corrosive.

Vapour Pressure: 18mm Hg at 20?(water vapour pressure).

                                    C

 ______________________________________________________________________________________________

Ingredients                                                                             Worksafe Exposure Limits

                                                                                                      3                  3

Chemical Entity                               CAS No             Proportion, %          TWA, mg/m         STEL, mg/m

thiram                                        137-26-8           60                     1                 not set

Other non hazardous ingredients               secret             12                     not set           not set

Water                                         7732-18-5          to 100                 not set           not set



This is a commercial product whose exact ratio of components may vary. Trace quantities of impurities are also likely.



                                         ll HEALTH HAZARD DATA

Health Effects:

No specific data is available for the product for chronic exposure symptoms. The ingredients are not listed as

carcinogenic in Worksafe's document "Exposure Standards for Atmospheric Contaminants in the Occupational

Environment" (May 1995), nor in NOHSC's "List of Designated Hazardous Substances" (April 1999). This material

contains at least one ingredient classified by NOHSC Australia criteria as a sensitiser. Exposure to a sensitiser, once

sensitisation has occurred, may manifest itself as a skin rash or inflammation or as an asthmatic condition, and in some

individuals this reaction can be extremely severe.

Chronic toxicity: Symptoms of chronic exposure to thiram in humans include drowsiness, confusion, loss of sex drive,

incoordination, slurred speech, and weakness, in addition to those due to acute exposure. Repeated or prolonged

exposure to thiram can also cause allergic reactions such as dermatitis, watery eyes, sensitivity to light, and

conjuntivitis. Except for the occurrence of allergic reactions, harmful chronic effects from thiram have been observed in

test animals only at very high doses. In one study, a dietary dose of 125 mg/kg/day thiram was fatal to all rats within 17

weeks. Oral doses of about 49 mg/kg/day to rats for 2 years produced weakness, muscle incoordination, and paralysis

of the hind legs. Rats fed 52 to 67 mg/kg/day for 80 weeks exhibited hair loss, and paralysis and atrophy of the hind



Issued by: Nuturf Pty Ltd                                                    Product: TMTD 600 Flowable Herbicide

Phone: 1800631008                                      Page 1 of 4                           Issued: January 2008

                                      MATERIAL SAFETY DATA SHEET

legs. Symptoms of muscle incoordination and paralysis from thiram poisoning have been shown to be associated with

degeneration of nerves in the lower lumbar and pelvic regions. Day-old white leghorn chicks fed 30 and 60 ppm for 6

weeks exhibited bone malformations. At doses of about 10% of the LD50 for 15 days, thiram reduced blood platelet and

white blood cell counts, suppressed blood formation, and slowed blood coagulation in rabbits.

Reproductive effects: Very high oral doses of approximately 1200 mg/kg/day thiram to mice on days 6 to 17 of

pregnancy caused resorption of embryos and retarded fetal development. In another study, doses of 132 mg/kg/day for

13 weeks produced infertility in male mice, while doses of 96 mg/kg/day for 14 days delayed the estrous cycle in

females. The feeding of 50 mg/kg/day thiram from day 16 of pregnancy to 21 days after birth caused reduced growth

and survival of the pups. Pups that were transferred to untreated dams at birth remained healthy, while pups transferred

from untreated to treated dams showed toxic effects. These data suggest that reproductive effects occur at high doses

not likely to be experienced by humans.

Teratogenic effects: Cleft palate, wavy ribs, and curved long leg bones were observed in the offspring of mice that

ingested very high thiram doses of 1200 mg/kg/day on days 6 to 17 of pregnancy. Maternal doses of 125 mg/kg/day

thiram were teratogenic in hamsters, causing incomplete formation of the skull and spine, fused ribs, abnormalities of

the legs, heart, great vessels, and kidneys. Developmental toxicity was observed in a three-generation study of rats fed

5.0 mg/kg/day. These data suggest that high doses are required to cause teratatogenic effects.

Mutagenic effects: Thiram has been found to be mutagenic in some test organisms but not in others. Thus, the

evidence is inconclusive.

Carcinogenic effects: When administered to mice at the highest dose possible, thiram was not carcinogenic. Dietary

levels as high as 125 mg/kg/day for 2 years did not cause tumors in rats. These data indicate that thiram is not

carcinogenic.

Organ toxicity: Studies have shown evidence of damage to the liver by thiram in the form of decreased liver enzyme

activity and increased liver weight. Thiram may also cause damage to the nervous system, blood, and kidneys.

Fate in humans and animals: In the body, carbon disulfide is formed from the breakdown of thiram and does

contribute to the toxicity of thiram to the liver. Thiram is not a member of the ethylene(bis)dithiocarbamate (EBDC)

chemical family, and thus it should not generate ethylene thiourea (ETU).

Acute Effects:

Acute toxicity: Thiram is slightly toxic by ingestion and inhalation, but it is moderately toxic by dermal absorption. Acute

exposure in humans may cause headaches, dizziness, fatigue, nausea, diarrhea, and other gastrointestinal complaints.

In rats and mice, large doses of thiram produced muscle incoordination, hyperactivity followed by inactivity, loss of

muscular tone, labored breathing, and convulsions. Most animals died within 2 to 7 days. Thiram is irritating to the eyes,

skin, and respiratory tract. It is a skin sensitizer. Symptoms of acute inhalation exposure to thiram include itching,

scratchy throat, hoarseness, sneezing, coughing, inflammation of the nose or throat, bronchitis, dizzines, headache,

fatigue, nausea, diarrhea, and other gastrointestinal complaints. Persons with chronic respiratory or skin disease are at

increased risk from exposure to thiram. Ingestion of thiram and alcohol together may cause stomach pains, nausea,

vomiting, headache, slight fever, and possible dermatitis. Workers exposed to thiram during application or mixing

operations within 24 hours of moderate alcohol consumption have been hospitalized with symptoms. The 4-hour

inhalation LC50 for thiram is greater than 500 mg/L in rats. Reported oral LD50 values for thiram are 620 to over 1900

mg/kg in rats; 1500 to 2000 mg/kg in mice; and 210 mg/kg in rabbits. The dermal LD50 is greater than 1000 mg/kg in

rabbits and in rats.

First Aid:

If poisoning occurs, contact a Doctor or Poisons Information Centre. Phone 13 1126 from anywhere in Australia. If

possible have this MSDS or product label with you.

Swallowed: If swallowed, do NOT induce vomiting. Wash mouth with water and give a glass of water to drink. Avoid

giving alcohol. Seek medical attention.

Eyes: If this product comes into contact with eyes, hold open and wash with running water for at least 15 minutes.

Ensure irrigation under eyelids by occasionally lifting them. Do not try to remove contact lenses unless trained. Seek

medical attention.

Skin: If product gets on skin, immediately remove contaminated clothing and wash skin thoroughly with soap and water

to remove material. If you begin to feel unwell, seek medical attention.

Inhalation: If vapours or mists have been inhaled, and irritation or unusual symptoms have developed, remove to fresh

air and observe until recovered. If irritation or symptoms persists more than about 30 minutes, seek medical advice.

Advice to Doctor: Treat symptomatically. However, note the sensitising nature of this product. Observe for signs of

sensitisation, and treat appropriately if evident. We suggest contact with the Poisons Information Centre for expert

advice.



                                        lll PRECAUTIONS FOR USE

Risk Phrases are: R43, R40, R20/22, R36/37. May cause sensitisation by skin contact. Harmful: possible risk of

irreversible effects. Harmful through inhalation, and if swallowed. Irritating to eyes and respiratory system.





Issued by: Nuturf Pty Ltd                                                      Product: TMTD 600 Flowable Herbicide

Phone: 1800631008                                       Page 2 of 4                            Issued: January-2008

                                      MATERIAL SAFETY DATA SHEET

Exposure Standards:

A time weighted average (TWA) has been established for thiram. This value is 1mg/m3. The corresponding STEL level

is "not set". The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15

minutes and should not be repeated for more than 4 times per day. There should be at least 60 minutes between

successive exposures at the STEL. The exposure value at the TWA is the average airborne concentration of a

particular substance when calculated over a normal 8 hour working day for a 5 day working week. See ingredients

section on page 1 of this data sheet. The ADI (Acceptable Daily Intake) for thiram is set at 0.004mg/kg/day. The

corresponding NOEL (No-observable-effect-level) is set at 0.4mg/kg/day. Values taken from Australian ADI List,

January 2001.

Engineering Controls:

In industrial situations, concentration values below the TWA value should be maintained. Values may be reduced by

process modification, use of local exhaust ventilation, capturing substances at the source, or other methods. If you

believe air borne concentrations of mists, dusts or vapours are high, you are advised to modify the process or

environment to reduce the problem.

Personal Protection:

Respiratory Protection: If there is a significant chance of dusts, vapours or mists accumulating in the area where this

product is being used, a mask or respirator should be used. For help in selecting suitable equipment, consult AS/NZS

1715.

Protective Gloves: Protective gloves are recommended when using this product. For help in selecting suitable

equipment, consult AS 2161.

Eye Protection: Protective eyewear should be worn when using this product. Eye contact may prove painful and

dangerous and should be avoided. Consult AS1336 and AS/NZS 1337 for advice on Industrial Eye Protection.

Clothing: Clean overalls or protective clothing should be worn, preferably with an apron. Consult AS2919 for advice on

Industrial Clothing.

Safety Boots: Wearing safety boots in industrial situations is advisory. Consult AS/NZS2210 for advice on Occupational

Protective Footwear.

Always wash hands before smoking, eating or using the toilet. Wash contaminated clothing and other protective

equipment before storing or re-using.



                                  lV SAFE HANDLING INFORMATION

Safety Phrases are: S20, S23, S38, S24/25. When using, do not eat or drink. Do not breathe mists. In case of

insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin and eyes.

Storage & Transport

No special storage and transport requirements. This product has no UN classification. This product is a S6 Poison.

Observe all relevant regulations regarding sale, transport and storage of this class of product. Containers should be

kept closed in order to minimise contamination. Keep from extreme heat and open flames, and make sure that the

product does not come into contact with substances listed under "Materials to avoid" below.

Spills & Disposals

In the event of a major spill, prevent spillage from entering drains or water courses. Immediately call the Fire Brigade.

Wear full protective chemically resistant clothing including face mask, face shield, gauntlets and self contained

breathing apparatus. See above under Personal Protection regarding Australian Standards relating to personal

protective equipment. Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable

absorbent material. Sweep up and shovel or collect recoverable product into labelled containers for recycling or

salvage, and dispose of promptly. After spills, wash area preventing runoff from entering drains. If a significant quantity

of material enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and

unused material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the

label prevail. Dispose of only in accord with all regulations. Advise laundry of nature of contamination when sending

contaminated clothing to laundry.

Fire & Explosion Hazard

There is no risk of an explosion from this product under normal circumstances if it is involved in a fire.

Flashpoint: Does not burn.

Flammability limits: Not applicable. This product does not burn.

Extinguishing Media: This product does not burn. Use extinguishing media suited to the materials that are burning.

Special Fire Fighting procedures: When fighting fires involving significant quantities of this product, wear safety boots,

non-flammable overalls, gloves, hat, goggles and respirator. All skin areas should be covered.

Unusual Fire & Explosion Hazards: Fire decomposition products from this product may form toxic and corrosive

mixtures in confined spaces.

Stability: This product is unlikely to spontaneously decompose.

Issued by: Nuturf Pty Ltd                                                      Product: TMTD 600 Flowable Herbicide

Phone: 1800631008                                       Page 3 of 4                            Issued: January-2008

                                   MATERIAL SAFETY DATA SHEET

Polymerisation: This product is unlikely to spontaneously polymerise.

Decomposition Products: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and

its compounds, and under some circumstances, oxides of nitrogen. Oxides of sulfur (sulfur dioxide is a respiratory

hazard) and other sulfur compounds. Water.

Materials to avoid: strong acids, strong bases, strong oxidising agents.



                                        V OTHER INFORMATION

This MSDS is prepared in accord with the Worksafe Australia document "National Code of Practice for the Preparation

of Material Safety Data Sheets", 1994.



Contact Points:                                                            AUSTRALIA

Police and Fire Brigade:                           Dial                        000

If ineffective:                                    Dial                    1100 (Exchange)

For emergency response: B/H                        Dial                    1800 631 008

For emergency response: A/H                        Dial                    1800 033 498

National Poisons Information Centre:               Dial      13 1126 (from anywhere in Australia)

THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE

PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER SHOULD READ

THIS MSDS AND CONSIDER THE INFORMATION IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED

IN THE WORKPLACE INCLUDING IN CONJUNCTION WITH OTHER PRODUCTS. IF CLARIFICATION OR FURTHER

INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD

CONTACT THIS COMPANY. THE RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND

CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.



Please read all labels carefully before using product.

        This MSDS copyright ?Kilford & Kilford Pty Ltd,January 2005. Revised January 2008

                          http://www.kilford.com.au/ Phone (02)9516 2079









Issued by: Nuturf Pty Ltd                                                 Product: TMTD 600 Flowable Herbicide

Phone: 1800631008                                   Page 4 of 4                           Issued: January-2008