- - - - - - - - - - - - - - - - MATERIAL SAFETY DATA SHEET - - - - - - - - - - - - - - -
Uniroyal Chemical ARREST(R) 75W
----------------------------------------------------------- ANIMAL DATA:
PRODUCT IDENTIFICATION THIRAM:
----------------------------------------------------------- ORAL LD50 (Rat): 2600 mg/kg
TRADE NAME: ARREST(R) 75W DERMAL LD50 (Rabbit): >2000 mg/kg
----------------------------------------------------------- INHALATION LC50 (Rat): 4.42 mg/L/4 hr.
CHEMICAL IDENTITY: CAS No: EYE IRRITATION (Rabbit): Moderate.
----------------------------------------------------------- SKIN IRRITATION (Rabbit): Slight.
Thiram 50% 137-26-8 SKIN SENSITIZATION (Guinea Pig): Moderate.
Carbathiin 20% 5234-68-4 CARBATHIIN:
Oxycarboxin 5% 5259-88-1 ORAL LD50 (Rat): 2864 mg/kg
----------------------------------------------------------- DERMAL LD50 (Rabbit): >4000 mg/kg
USES: Agricultural turf fungicide. INHALATION LC50 (Rat): >4.7 mg/L/4 hr.
PCP REGISTRATION NUMBER: 13431 EYE IRRITATION (Rabbit): Mild.
MANUFACTURER/SUPPLIER: UNIROYAL CHEMICAL CO. SKIN IRRITATION (Rabbit): Negative.
25 ERB STREET SKIN SENSITIZATION (Guinea Pig): Negative.
ELMIRA, ONTARIO OXYCARBOXIN:
N3B 3A3 ORAL LD50 (Rat): >1500 mg/kg
EMERGENCY PHONE NUMBERS: DERMAL LD50 (Rabbit): >5000 mg/kg
HEALTH (24 Hr.): (519) 744-3060 INHALATION LC50 (Rat): >5 mg/L/4 hr.
TRANSPORT (CANUTEC): (613) 996-6666 EYE IRRITATION (Rabbit): Mild.
----------------------------------------------------------- SKIN IRRITATION (Rabbit): Negative.
HAZARDOUS INGREDIENTS SKIN SENSITIZATION (Guinea Pig): Negative.
----------------------------------------------------------- CHRONIC: In long-term feeding studies conducted on rats and
ACGIH 1999 dogs the following were seen:
TLV-TWA STEL % (w/w) CARBATHIIN: effects on survival, body weight, hematocrit
----------------------------------------------------------- and kidney histopathology;
Thiram 1 mg/m3 50 OXYCARBOXIN: effects on body weight, food intake and
CAS No.: 137-26-8 thyroid histopathology;
Crystalline silica 0.1 mg/m3 <0.5 THIRAM: effects on body weight, liver, hematocrit, and
CAS No.: 14808-60-7 stomach, kidney and pancreas bile duct histopathology.
NOTE: Consult local authorities for acceptable provincial CARCINOGENICITY:
exposure limits. ACGIH: A4 (Thiram)
----------------------------------------------------------- IARC: 2A (Silica)
PHYSICAL DATA No increase in tumour incidence was noted in mice fed
----------------------------------------------------------- carbathiin or thiram for eighteen months. Effects were
PHYSICAL STATE: Solid. seen on liver histopathology (carbathiin) and body
BOILING POINT: Not applicable. weight (thiram).
FREEZING POINT: Not applicable. TERATOGENICITY / REPRODUCTIVE EFFECTS:
SPECIFIC GRAVITY (H2O = 1): Not available. TERATOGENICITY:
VAPOUR DENSITY (AIR = 1): Not available. CARBATHIIN: No treatment related effects were seen in a
SOLUBILITY IN WATER (% wt.): Not available. rabbit study. In a rat study maternal toxicity, as
OTHER SOLUBILITY: Not available. evidenced by decreased weight gain, was seen along
APPEARANCE: White powder. with a reduction in fetal body weight. No teratogenic
ODOUR: Faint, musty. effects were seen.
COEFFICIENT OF WATER / OIL DISTRIBUTION: Not available. OXYCARBOXIN: In rabbit and rat studies maternal
ODOUR THRESHOLD: Not available. toxicity, as evidenced by decreased weight gain, was
VAPOUR PRESSURE: Not available. seen along with reduced pup body weights. No
% VOLATILE: Essentially non-volatile. teratogenic effects were seen.
EVAPORATION RATE: Not applicable. THIRAM: No developmental or teratogenic effects were
pH: Not available. seen in a rabbit study. In a rat study maternal
----------------------------------------------------------- toxicity, as evidenced by decreased weight gain, was
HEALTH HAZARD INFORMATION seen along with an increased incidence of fetuses
----------------------------------------------------------- with small ribs.
ROUTE(S) OF EXPOSURE: Inhalation, skin contact, eye REPRODUCTION:
contact, skin absorption, ingestion. CARBATHIIN: In a rat study a decrease in adult weight
EFFECTS OF ACUTE EXPOSURE: Thiram may cause skin, eyes and gain and pup growth weight during lactation was seen.
respiratory tract irritation. Potential skin sensitizer. No effects on reproduction were seen.
If absorbed into the body it may affect the liver, OXYCARBOXIN: In a rat study effects were seen on litter
kidneys and central nervous system. Symptoms may include size and pup growth weight rate. No effects on
headache, insomnia, nervous disorders and in severe cases reproduction were seen.
kidney pain, dizziness, loss of memory and tremours. THIRAM: In a rat study a decrease in maternal and
Alcohol intolerance may result on exposure; symptoms offspring body weights was seen. No effects on
include flushing of face and neck, followed by rapid reproduction were seen.
heart beat, nausea, vomiting, headache and low blood MUTAGENICITY: Carbathiin, oxycarboxin and thiram have been
pressure. evaluated in several short-term mutagenicity assays.
Carbathiin produced positive results in the CHO
chromosome aberration and rat hepatocyte UDS assays.
Oxycarboxin produced positive results in the L5178Y mouse
lymphoma assay with activation. Thiram produced positive
results in the Ames reverse mutation assay.
TOXICOLOGICALLY SYNERGISTIC MATERIALS: Alcohol.
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Uniroyal Chemical ARREST(R) 75W
----------------------------------------------------------- WASTE DISPOSAL METHOD: In accordance with local, provincial
FIRST AID and federal regulations. Contact regional environmental
----------------------------------------------------------- agency.
EYES: Immediately flush with plenty of water for at least RESPIRATORY PROTECTION: NIOSH approved for particulate and
15 minutes. Get immediate medical attention. organic vapours.
SKIN: Wash thoroughly with soap and water. Remove PROTECTIVE GLOVES: Impervious rubber - neoprene or nitrile
contaminated clothing and wash before re-use. Get medical may be adequate.
attention if irritation persists or dermatitis develops. EYE PROTECTION: Chemical safety goggles.
INHALATION: Remove to fresh air. Aid or restore breathing VENTILATION: Local exhaust strongly recommended. Wear
if necessary. Get medical attention. respiratory protection in the absence of good
INGESTION: If conscious, give 1-2 glasses of water and ventilation.
induce vomiting. Contact physician immediately. Do NOT OTHER: Emergency eye wash and shower. Separate street and
give milk, oils or fats which enhance absorption. Do NOT work clothing recommended. Avoid lanolin or petroleum
give anything by mouth or induce vomiting if person is based protective creams.
unconscious. -----------------------------------------------------------
SPECIAL PRECAUTIONS: Consumption of alcohol should be REGULATORY INFORMATION
avoided before and after exposure. -----------------------------------------------------------
----------------------------------------------------------- WHMIS CLASSIFICATION: This product is registered under the
FIRE AND EXPLOSION Pest Control Products Act, thus it is exempt from the
----------------------------------------------------------- material safety data sheet (MSDS) and labelling
FLASH POINT (method): >110 deg C (SCC) requirements of WHMIS.
FLAMMABLE LIMITS IN AIR (% by volume): Not available. TDG CLASSIFICATION: Regulated Limit Applies (Thiram -
AUTOIGNITION TEMPERATURE: Not available. 0.5 kg): Environmentally Hazardous Substance, Solid,
EXTINGUISHING MEDIA: Water spray/fog, foam, carbon dioxide N.O.S. (Thiram), Class 9.2, UN 3077, Pkg. Gr. III
(CO2), dry chemical. DOMESTIC SUBSTANCES LIST (DSL): All substances in this
SPECIAL FIRE FIGHTING EQUIPMENT AND PROCEDURES: product are exempt as the product is registered under the
Firefighters should wear self-contained breathing Pest Control Products Act.
apparatus to prevent inhalation of combustion products. -----------------------------------------------------------
Use minimum amounts of extinguishing agent and contain PREPARATION INFORMATION
run-off. May form explosive dust mixture in air. -----------------------------------------------------------
EXPLOSION DATA: DATE: December 1, 1999
SENSITIVITY TO MECHANICAL IMPACT: Not available. ISSUE #: 010
SENSITIVITY TO STATIC DISCHARGE: Not available. SUPERSEDES: August 1, 1998
----------------------------------------------------------- ISSUE #: 009
REACTIVITY DATA PREPARED BY: Industrial Hygiene Department
----------------------------------------------------------- (519) 669-1671
STABILITY: Thiram decomposes at elevated temperatures. MSDS CODE: AG0260E
HAZARDOUS POLYMERIZATION: Will not occur. -----------------------------------------------------------
INCOMPATIBILITY: Strong oxidizing agents, alkalis and To the best of UNIROYAL CHEMICAL Co.'s knowledge, the above
acids. information is true and accurate as of the date of
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon disulphide, preparation of this material safety data sheet. The above
hydrogen sulfide on contact with strong acids. Oxides of information is not intended to be exhaustive. Additional or
carbon, nitrogen and sulphur on combustion. other information may be required depending on actual
----------------------------------------------------------- conditions of use and handling. UNIROYAL CHEMICAL Co. makes
PREVENTIVE MEASURES no warranties, expressed or implied and shall not be liable
----------------------------------------------------------- for any damages or injury, howsoever caused, arising out of
STORAGE AND HANDLING: Store in a cool, dry location. Do not the use of this data sheet.
store near food, feed or fertilizers. Do not contaminate -----------------------------------------------------------
ponds, lakes, streams or any source of water. Handle in a (R) Registered Trade Mark of Uniroyal Chemical Co.
well ventilated area. Local exhaust recommended. Use -----------------------------------------------------------
personal protective equipment to prevent contact with DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: although
skin and eyes. preparer and owner have taken reasonable care in the
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: preparation of this document, we extend no warranties and
Cleanup personnel should wear personal protective make no representation as to the accuracy or completeness
equipment. Contain large spills. Vacuum or shovel powder of the information contained herein, and assume no
into suitable containers. Avoid creating dust. Absorb responsibility regarding the suitability of this
liquid spills containing this product on an inert, information for the user's intended purposes or for the
non-combustible absorbent. Put into containers for consequences of its use. Each user should make a
disposal. determination as to the suitability of the information for
ENVIRONMENTAL TOXICITY DATA: Thiram Technical their particular purpose(s). A request has been made to the
LC50 96 HR, RAINBOW TROUT: 0.128 mg/l LC50 8-day, manufacturer to approve the contents of this material
Bobwhite Quail: ~3950 ppm safety data sheet. Upon receipt of any changes a new MSDS
LC50 96 HR, BLUEGILL SUNFISH: 0.0445 mg/l LC50 8-day, will be made available.
Mallard Duck: >5000 ppm -----------------------------------------------------------
LC50 48 HR, DAPHNIA MAGNA: 0.021 ppm LC50 8-day, Ring- COMPAS Code: 11220012
neck Pheasant: >5000 ppm
LD50 MALLARD DUCK: >2800 mg/kg LC50 8-day, Japanese
Quail: >5000 ppm
LD50 RING-NECK PHEASANT: 673 mg/kg LD50 Red-winged
Blackbird: >100 mg/kg
LD50 STARLING: >100 mg/kg LD50 Honeybee: 73.7 ug/bee (75%
formulation)
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