M AT E R I A L S A F E T Y D ATA S H E E T
PRODUCT IDENTIFICATION REACTIVITY HAZARD DATA
Product Name: Spotrete F Stability: Stable
Cleary Product Code: 4322 Conditions to Avoid: Excessive heat
E.P.A. REG. NO.: 45728-26-1001 Incompatibility: Acids, oxidizers, copper
Chemical Name: Tetramethylthiuram disulfide Hazardous Polymerization: Will not occur.
Synonyms: Thiram Hazardous Decomposition Products: Decom-
posed by excessive heat and acids. Heating to de-
INGREDIENTS composition generates carbon disulfide and oxides
of carbon, nitrogen and sulfur. Acid decomposition
Ingredients (CAS#) Percent
may evolve carbon disulfide and hydrogen sulfide.
Tetramethylthiuram disulfide (137-26-8) . . . .42%
Inert Ingredients . . . . . . . . . . . . . . . . . . . . . .58%
HEALTH HAZARD DATA
Exposure Limits
Inhalation: Mist or vapor may cause mucous mem-
0.5 mg/m3 TWA-PEL
brane and respiratory irritation with coughing, chok-
ing, labored breathing and lethargy.
PHYSICAL DATA
Eye Contact: May cause irritation based on a study
Boiling Point: Approx. 220 F
in rabbits.
Melting Point: N/A
Skin Contact: May cause irritation and possible sen-
Freezing Point: Approx. 32 F sitization. May be absorbed through the skin based
Specific Gravity: 1. 15 on animal studies.
Vapor Pressure (@ 20 C mm Hg): Negligible Ingestion: May cause systemic poisoning with symp-
toms of weakness, nausea, diarrhea, confusion, dizzi-
% Volatile: Approx. 47%
ness, delirium, tremor, hallucinations, ataxia,
Evaporation Rate: N/A
ascending paralysis, hypothermia and peripheral
Solubility in Water: 30 mg/L at room temp. neuropathy (pain, numbness and weakness of ex-
tremities). Respiratory paralysis and death may occur.
Appearance and Odor: Opaque liquid suspension.
No specific odor. Chronic Effects of Overexposure: Thiram has been
found to be mutagenic in some test systems and to cause
FIRE & EXPLOSION DATA adverse reproductive effects in laboratory animals.
Flash Point (Method): N/A Other Toxic Effects: An antabuse-like reaction with
Flammable Limits (vol % in air): N/A flushing, sweating, headache, weakness and hyper-
tension may occur when ethyl alcohol (alcoholic bev-
Autoignition Temperature: N/A
erages) is ingested following exposure to this
Extinguishing Media: Carbon dioxide, dry chemi-
material.
cal, foam, water or water fog. Not defined as flam-
TOXICITY DATA:
mable or combustible.
ORAL (acute): LD50 2400 mg/kg (rat)
Special Firefighting Procedures: Evacuate area of
DERMAL (acute): LD50 5000 mg/kg (rat)
all non-emergency personnel. Firefighters should wear
INHALATION (acute): LD50 4.42 mg/L 4 Hr (rat)
full emergency equipment and NIOSH approved pos-
CHRONIC, SUBCHRONIC:This product is not listed as
itive pressure self-contained breathing apparatus.
a carcinogen or suspect carcinogen by NTP,
Fight fire from upwind and cool exposed intact con-
IARC, OSHA. This material may cause skin sensitiza-
tainers and structures with water spray or stream at
tion. Thiram is mutagenic in some test systems and
maximum range. Decontaminate all protective equip-
has been found to cause adverse reproductive ef-
ment after use, prevent skin contact. This product is
fects and teratogenic effects in laboratory animals.
toxic to fish. Contain all water run-off with diking.
Unusual Fire and Explosion Hazards:
Decomposition products are toxic. CLEARY CHEMICAL CORPORATION
178 RIDGE ROAD
DAYTON, NJ 08810-1501
EMERGENCY PHONE NUMBERS:
M-F 9AM-5PM ET
800-524-1662 ?732-329-8399
24 Hour CHEMTREC
800-424-9300
M AT E R I A L S A F E T Y D ATA S H E E T
EMERGENCY AND SPECIAL PRECAUTIONS
FIRST AID PROCEDURES Precautions to be Taken in Handling and
Storing: Store in a well ventilated area with origi-
Ingestion: If conscious, give 1-2 glasses of water to
nal containers closed. Do not store in a manner
dilute and induce vomiting. Get immediate medical
where cross-contamination with other pesticides,
attention.
food or feed could occur.
Skin Contact: Wash contact area thoroughly with
soap and water until no traces of the chemical re-
ADDITIONAL REGULATORY
main. Remove contaminated clothing, immediately
INFORMATION
and launder before reuse. Seek medical attention if
DOT Shipping Name: Environmentally hazardous
irritation develops.
substance, Liquid, NOS, (Thiraim)
Eye Contact: Immediately flush eye with water for
DOT Hazard Classification: Class 9 (miscellaneous
at least 15 minutes while lifting the upper and lower
hazard)
lids. Get immediate medical attention.
DOT Label Requirements: Class 9
Inhalation: Remove to fresh air. If breathing is dif-
ficult or has stopped seek medical attention imme- UN Identification Number: UN 3082
diately, start necessary resuscitation procedures.
Hazardous Substance: Thiram
Reportable Quantity: 10 lbs. active material (13.3
SPECIAL PROTECTION
lbs. product)
INFORMATION
OSHA Hazard Classification: Irritant, toxic, target
Protective Clothing: Wear protective clothing, in-
organ effect, sensitizer
cluding resistant boots and socks. Chemical resistant
gloves are required for all operations where contact EPA SARA Title III Data:
with Spotrete is possible. ACUTE: Yes
CHRONIC: Yes
Eye Protection: Non-venting chemical safety gog-
FIRE: No
gles or face shield are required if full face-piece res-
REACTIVE: No
pirator is not worn. Do not wear contact lenses
during use of product.
Ventilation: Use in a well ventilated area.
Respiratory Protection: Use approved OSHA
and/or NIOSH full-face respirator in confined spaces
where ventilation is limited. A half-face device is
acceptable provided eye protection measures indi-
cated above are followed.
SPILL OR LEAK PROCEDURES
Steps to be Taken in Case Material is Released or
Spilled: Wear appropriate protective clothing to pre-
vent eye and skin contact and appropriate respirator
to prevent overexposure. Contain and absorb with inert
material, carefully sweep up spilled material and col-
lect into closeable container for proper disposal. This
material is toxic to fish. Prevent runoff to storm sew-
ers and ditches leading to natural waterways.
Waste Disposal Methods: Improper disposal of ex-
cess pesticide, spray mixture or rinsate is a violation
of federal law. If these wastes cannot be disposed of
by intended use according to label instructions, con-
CLEARY CHEMICAL CORPORATION
tact the appropriate agency in your state or the near-
178 RIDGE ROAD
est EPA Regional office for guidance.
DAYTON, NJ 08810-1501
EMERGENCY PHONE NUMBERS: Preparation and distribution of this Material Safety Data Sheet done by Cleary Chemical Corporation, 178 Ridge Road, Dayton, New Jersey 08810,
pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). The information contained herein is based on available data. However,
M-F 9AM-5PM ET no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof, and you should make your
800-524-1662 ?732-329-8399 investigation to determine safety for the use you contemplated. Cleary Chemical Corporation assumes no responsibility or liability for any inciden-
tal or consequential damages whether related to personal injury or property damage, to vendors, users or third parties, caused by the material and
24 Hour CHEMTREC Cleary Chemical Corporation's responsibility is limited to replacement of, or repayment of, the purchase price for the materials with respect to which
800-424-9300 any damages are claimed. All vendors or users assume all risk associated with the use of the material(s). Effective Date 2/17/95
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