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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : CAULK 149 COMP. B
IDENTIFICATION NUMBER: CLK149THB00B PREPARE/REVISED: 08/07/06
PRODUCT USE/CLASS : POLYSULFIDE CURING COMPOUND
SUPPLIER: MANUFACTURER:
Dudick, Inc. Dudick, Inc.
1818 Miller Parkway 1818 Miller Parkway
Streetsboro, Ohio 44241 Streetsboro, Ohio 44241
CHEM-TEL: 800-255-3924 CHEM-TEL: 800-255-3924
24 HOURS A DAY 24 HOURS A DAY
PREPARER: DUDICK, INC., PHONE: 800-322-1970
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
01 MANGANESE DIOXIDE 1313-13-9 50.0 %
02 TETRAMETHYLTHIOPEROXYDICARBONIC DIA 137-26-8 5.0 %
03 SODIUM HYDROXIDE 1310-73-2 5.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 .2MG/m3 DUST NO INFO NO INFO NO INFO NE NO
02 1mg/M3 NO INFO 5mg/m3 NO INFO NE YES
03 2mg/M3 DUST NO INFO NO INFO NO INFO NE YES
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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*** EMERGENCY OVERVIEW ***: CAUTION!...MAY CAUSE EYE AND SKIN IRRITATION.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: MILD EYE IRRITANT.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: MILD SKIN IRRITANT.
EFFECTS OF OVEREXPOSURE - INHALATION: LOW VOLITILITY. PRODUCT IS NOT
EXPECTED TO BE A MAJOR INHALATION HAZARD. BECAUSE OF THIS PRODUCT'S
PHYSICAL FORM, THE RELEASE OR GENERATION OF DUST AND FUMES SHOULD NOT OCCUR
UNDER NORMAL CONDITIONS OF USE.
(Continued on Page 2)
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Product: CLK149THB00B PREPARE / REVISED: 08/07/06 Page 2
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EFFECTS OF OVEREXPOSURE - INGESTION: THIS PRODUCT HAS A LOW ORDER ORAL
TOXICITY.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: CHRONIC HAZARDS HAVE NOT BEEN
ESTABLISHED. IN STUDIES WITH ANIMALS, THIRAM CAUSED MATERNAL AND
FETOTOXICITY, AND MALE INFERTILITY. THIRAM WAS FOUND TO BE MUTAGENIC TO TWO
STRAINS OF BACTERIA.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION INGESTION EYE
CONTACT
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| SECTION 4 - FIRST AID MEASURES |
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FIRST AID - EYE CONTACT: HOLD OPEN EYE LIDS AND FLUSH WITH COPIOUS AMOUNTS
OF FLOWING WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION.
FIRST AID - SKIN CONTACT: WASH AFFECTED AREAS THOROUGHLY WITH SOAP AND
WATER. IF SYMPTOMS PERSIST,SEEK MEDICAL ATTENTION.
FIRST AID - INHALATION: REMOVE VICTIM TO FRESH AIR. IF VICTIM IS NOT
BREATHING, ARTIFICIAL RESPIRATION SHOULD BE ADMINISTERED BY QUALIFIED
PERSONNEL.
FIRST AID - INGESTION: DO NOT INDUCE VOMITING.SEEK MEDICAL ATTENTION. IF
GASTROINTESTINAL IRRITATION OCCURS, SEEK MEDICAL ATTENTION.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 201 F LOWER EXPLOSIVE LIMIT: N.A.
(PENSKY-MARTENS C.C.) UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE: NE
EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS: MAY PRODUCE TOXIC CARBON MONOXIDE AND
NITROGEN OXIDES UPON COMBUSTION.
SPECIAL FIREFIGHTING PROCEDURES: FIGHT FIRE FROM A SAFE DISTANCE. WEAR
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: DIKE AREA TO
CONTAIN SPILLAGE. ABSORB EXCESS WITH SAND, EARTH, OR VERMICULITE. SCRAPE
UP AND PLACE IN SUITABLE CONTAINER FOR DISPOSAL. WEAR ALL APPROPRIATE
SAFETY EQUIPMENT WHILE HANDLING SPILLS.
(Continued on Page 3)
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Product: CLK149THB00B PREPARE / REVISED: 08/07/06 Page 3
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: FOR INDUSTRIAL USE ONLY. WEAR APPROPRIATE SAFETY EQUIPMENT WHEN
HANDLING.
STORAGE: DO NOT STORE NEAR INCOMPATIBLES. DO NOT STORE NEAR EXCESSIVE
HEAT OR NEAR SOURCES OF IGNITION. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT
IN USE.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: GENERAL MECHANICAL VENTILATION MAY BE SUFFICIENT TO
MINIMIZE VAPOR CONCENTRATIONS. LOCAL EXHAUST MAY BE REQUIRED.
RESPIRATORY PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS.
SKIN PROTECTION: CONSULT GLOVE MANUFACTURER FOR RECOMMENDATIONS.
POLYVINYL CHLORIDE.
EYE PROTECTION: SAFETY GLASSES RECOMMENDED. IF USED WITH OTHER MORE
HAZARDOUS MATERIALS, FOLLOW THE RECOMMENDATIONS OF THE MOST SEVERE
COMPONENT.
OTHER PROTECTIVE EQUIPMENT: CLEAN, FULL BODY COVERING TO MINIMIZE SKIN
CONTACT WITH MATERIAL. AN EYEWASH STATION AND SAFETY SHOWER IS RECOMMENDED
NEAR WORK AREA.
HYGIENIC PRACTICES: SMOKING OR EATING IN THE WORK AREA SHOULD NOT BE
PERMITTED. WASH THOROUGHLY AFTER HANDLING MATERIAL.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : N.A. VAPOR DENSITY : Is heavier than air
ODOR : SLIGHT AMINE ODOR THRESHOLD : NE
APPEARANCE : BLACK PASTE EVAPORATION RATE: Is slower than Ether
SOLUBILITY IN H2O : INSOLUBLE
FREEZE POINT : NE SPECIFIC GRAVITY: 1.78
VAPOR PRESSURE : NE pH @ 0.0 % : NE
PHYSICAL STATE : LIQUID VISCOSITY : NE
COEFFICIENT OF WATER/OIL DISTRIBUTION: NE
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: HEAT, FLAME, CONTAMINANTS.
INCOMPATIBILITY: STRONG OXIDANTS. STRONG ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE TOXIC FUMES.
OXIDES OF CARBON. OXIDES OF SULFUR.
(Continued on Page 4)
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Product: CLK149THB00B PREPARE / REVISED: 08/07/06 Page 4
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| SECTION 10 - STABILITY AND REACTIVITY |
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HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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No product or component toxicological information is available.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL INFORMATION: DO NOT CONTAMINATE PONDS, STREAMS, OR UNDERGROUND
WATER SUPPLY. PREVENT FROM ENTERING SEWERS.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: FOLLOW ALL RELEVANT LOCAL, STATE, AND FEDERAL
REGULATIONS.
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: PLASTIC LIQUID MATERIAL NOI
DOT TECHNICAL NAME: NA
DOT HAZARD CLASS: NON-REGULATED HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: NA PACKING GROUP: NA RESP. GUIDE PAGE:
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| SECTION 15 - REGULATORY INFORMATION |
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THE FOLLOWING COMPONENTS ARE NOT SUBJECT TO REPORTING IN SECTION 2:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
INERT SOLIDS NO INFO 50.0 %
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
(Continued on Page 5)
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Product: CLK149THB00B PREPARE / REVISED: 08/07/06 Page 5
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| SECTION 15 - REGULATORY INFORMATION |
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CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
MANGANESE DIOXIDE 1313-13-9 50.0 %
TETRAMETHYLTHIOPEROXYDICARBONIC DIA 137-26-8 5.0 %
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No information is available.
U.S. STATE REGULATIONS: AS FOLLOWS -
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
INERT SOLIDS NO INFO
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
INERT SOLIDS NO INFO
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------- CAS NUMBER
No Proposition 65 chemicals exist in this product.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
(Continued on Page 6)
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Product: CLK149THB00B PREPARE / REVISED: 08/07/06 Page 6
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| SECTION 15 - REGULATORY INFORMATION |
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CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: D2
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0
VOLATILE ORGANIC COMPOUNDS (VOCS): 0.00 lbs/gal, 0 grams/ltr
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
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The information contained on this MSDS has been compiled from information
obtained from raw material suppliers and is believed to be accurate. It is
the responsibility of the user to comply with all Federal, State and Local
Regulations.
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