Page 1 of 6
MATERIAL SAFETY DATA SHEET
COATINGS AND RESINS GROUP
PPG Industries, Inc.
SECTION I - CHEMICAL, PRODUCT, ~qD COMPANY INFORMATION
PRODUCT CODE/IDENTITY: 6-208
REVISION DATE: 07/28/98 (000) 0814
CUSTOMER PART #/NAME: Not applicable
PRODUCT TRADE NAME: RED INHIBITIVE PRIMER
CHEMICAL FAMILY: Alkyd
WHMIS HAZARD CLASS:
Class B, Dlvision 6 Class D, Division 2, Subdivision A Class D, Division 2,
Subdivision B
EMERGENCY MEDICAL/SPILL INFO: (514) 645-1320 91-800-00-214 (MEXICO)
TECHNICAL INFORMATION: 1-800-441-9695
PRODUCT SAFETY/MSDS INFORMATION: 4325 ROSANNA DRIVE, P.O. BOX 9 ALLISON PARK, PA
15101 (412) 492-5555
DATE OF MSDS PREPARATION: 08/19/99
PRIMARY HAZARD WARNING
Combustible. Keep away from heat, sparks, flames, and other sources of ignition.
Do not smoke. Harmful or fatal if swallowed. Causes primary skin irritation.-
Causes eye irritation. May be absorbed through the skin. Vapor and/or spray mist
may be harmful if inhaled. Vapor irritates eyes, nose, and throat.
IN ACCORD~qCE WITH CANADA'S
THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM.
SECTION 2 - HAZARDOUS INGREDIENTS
REF HAZARDOUS INGREDIENTS PERCENT CAS NUMBER CARCINOGEN*
01 ETHYL BENZENE 0.i-I.0 100-41-4
02 P-XYLENE 0.i-i.0 106-42-3
03 M-XYLENE 0.1-1.0 108-38-3
04 IRON OXIDE 1-5 1332-37-2
05 CARBON BLACK 0.I-I.0 1333-86-4
06 SODIUM ALUMINUM SILICATE i0 - 30 1344-00-9
07 BARIUM METABORATE 5 - i0 13701-59-2
08 TALC 5 - l0 14807-96-6
09 PETROLEUM DISTILLATES I-5 64741-92-0
l0 NAPHTHA I0 - 30 8052-41-3
ii O-XYLENE 0.I-i.0 95-47-6
96-29-7
12 METHYL ETHYL KETOXIME 0.i-i.0
* Carcinogens: O=OSHA; A=ACGIH; N=NTP; I=IARC
OCCUPATIONAL EXPOSURE LIMITS HAVE BEEN ESTABLISHED FOR THE FOLLOWING MATERIALS:
http://ppg.web.ppg.coln/CllIlsds%2DdatWe0058164,txt 9/10/1999
PPG Industries, Inc.
SEP 10 '99 10:31 PAGE.002
Page 2 of 6
ACGIH ONTARIO
REF TLV-TWA TLV-STEL PEL-TWA PEL-STEL
01 i00 ppm 125 ppm I00 ppm 125 ppm
02 i00 PPM 150 PPM NOT ESTAB NOT ESTAB
03 i00 ppm 150 ppm I00 ppm 150 ppm
04 5 mg/m3 NOT ESTAB I0 mg/m3 NOT ESTAB
05 3.5 mg/m3 NOT ESTAB 3.5 mg/m3 NOT ESTAB
06 NOT ESTAB. NOT ESTAB NOT ESTAB. NOT ESTAB
07 0.5 MG/M3 NOT ESTAB NOT ESTAB. NOT ESTAB
08 R- 2 mg/m3 NOT ESTAB R- 2 mg/m3 NOT ESTAB
09 NOT ESTAB. NOT ESTAB NOT ESTAB. NOT ESTAB
i0 i00 ppm NOT ESTAB 525 mg/m3 NOT ESTAB
ii I00 PPM 150 PPM NOT ESTAB NOT ESTAB
12 NOT ESTAB. NOT ESTAB. NOT ESTAB. NOT ESTAB.
12 IPEL-TWA: 3 PPM IPEL-STEL: I0 PPM
[C- Ceiling Limit; S- Potential Skin Absorption; R- Respirable Dust] [NOT ESTAB.
= NOT ESTABLISHED = NOT APPLICABLE]
Consult local authorities for acceptable provincial values.
SECTION 3 - TOXICOLOGICAL PROPERTIES
REF LD50 ORAL (rat) LD50 DERMAL (rabbit) LC50 INHALATION (rat)
01 3.50 g/kg 17.80 g/kg Not available
5.00 g/kg
02 Not available 19.73 mg/L. 4 h
03 5.00 g/kg 5.00 g/kg Not available
04 Not available Not available Not available
05 Not available Not available Not available
06 Not available Not available Not available
07 .85 g/kg Not available 3.54 mg/L. 4 h
08 Not available Not available Not available
09 Not available Not available Not available
I0 Not available Not available Not available
ii Not available Not available Not available
12 1.69 g/kg Not available Not available
THE FOLLOWING INFORMATION IS REQUIRED UNDER CANADA'S WORKPLACE HAZARDOUS
MATERIALS INFORMATION SYSTEM
REF ACUTE TOXICITY
01 NO SEVERE HAZARDS
02 NO SEVERE HAZARDS
03 EYE IRRITANT
04 NO SEVERE HAZARDS
O5 NO SEVERE HAZARDS
O6 NO SEVERE HAZARDS
07 NO SEVERE HAZARDS
08 NO SEVERE HAZARDS
09 SKIN IRRITANT
i0 NO SEVERE HAZARDS
ii NO SEVERE HAZARDS
12 SKIN SENSITIZER/EYE CORROSIVE
REF CHRONIC TOXICITY
Ol CARCINOGEN/KIDNEY/LIVER/LUNG
O2 EMBRYOTOXIN
03 EMBRYOTOXIN
04 NO LONG-TERM EFFECTS IDENTIFIED
O5 CARCINOGEN
06 NO LONG-TERM EFFECTS IDENTIFIED
http :#ppg.web .ppg. colrgcrmsds%2Ddam/e0058164,
tx't 9/10/1999
SEP 10 '99 10:32 PPG Industries, Inc. PAGE.003
Page 3 of 6
07 NO LONG-TERM EFFECTS IDENTIFIED
O8 CARCINOGEN/LUNG
O9 NO LONG-TERM EFFECTS IDENTIFIED
I0 NO LONG-TERM EFFECTS IDENTIFIED
EMBRYOTOXIN
ii
BLOOD/CARCINOGEN/CATARACT EFFECTS~KIDNEY~LIVER~LUNG~SPLEEN
12
HAZARDS IDENTIFICATION
EFFECTS OF OVEREXPOSURE FROM:
INGESTION: Harmful or fatal if swallowed.
EYE CONTACT: Causes eye irritation.
SKIN CONTACT: Causes primary skin irritation. May be absorbedthrough the skin.
INHALATION: Vapor and/or spray mist may be harmful if inhaled. Vapor irritates
eyes, nose, and throat. Repeated exposure to high vapor concentrations may cause
irritation of the respiratory system and permanent brain and nervous system
damage.
CHRONIC OVEREXPOSURE: Avoid long-term and repeated contact. This product
contains methyl ethyl ketoxime (MEKO). Studies in animals indicate that
overexposure can cause adverse effects in spleen and kidney, anemla, liver
cancer and cataracts. This product contains talc. In a lifetime inhalation study
female rats exposed to an elevated respirable concentration (9 times the
Permissible Exposure Limit) of cosmetic grade talc developed lung cancer. To
date, no U.S. regulatory agency has classified talc as a carcinogen based on
this data. This product contains carbon black which has been rated an IARC 2B
carcinogen due to animal data. Ethylbenzene has been reported by NTP to cause
cancer in laboratory animals following a chronic (2 year) inhalation exposure.
Dose levels of 75, 250 and 750 ppm were used, with evidence of carcinogenicity
found in the kidneys of rats and the lung and liver of mice at 750 ppm. The No
Observed Effect Level (NOEL) was 75 ppm. The relevance of these findings
humans is uncertain, but appropriate safeguards should be employed to reduce or
eliminate inhalation exposure to ethylbenzene. High exposures to xylenes in some
animal studies have been reported to cause health effects on the developing
embryo and fetus. These effects were often at levels toxic to the mother. The
significance of these findings to humans has not been determined.
SIGNS AND SYMPTOMS OF OVEREXPOSURE: Eye watering, headaches, nausea, dizziness,
and loss of coordination are indications that solvent levels are too high.
Intentional misuse by deliberately concentrating and inhaling the contents can
be harmful or fatal. Redness, itching, burning sensation and visual disturbances
may indicate excessive eye contact. Dryness, itching, cracking, burning,
redness, and swelling are conditions associated with excessive skin contact.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not applicable.
TOXICOLOGICALLY SYNERGISTIC PRODUCTS: blot available
SECTION 4 - FIRST AID MEASURES
INGESTION: If swallowed, do not induce vomiting. Gently wipe out inside mouth to
remove any residual material.
EYE CONTACT: In case of eye contact, remove contact lenses and flush eyes
immediately with a gentle stream of luke warm water for at least 15 minutes.
SKIN CONTACT: In case of skin contact, flush i~aediately with plenty of water
for at least 15 minutes followed by washing with soap and water.
o 9/10/1999
http'#ppg.web.ppg, com/cmasds ~2Ddat~e0058164.txt
PAGIE.004
Inc.
SEP 18 '99 18:33 PPG Industrles,
1-'age4 ot 0
INHALATION: If affected by inhalation of vapor or spray mist, remove to fresh
air. Apply artificial respiration and other support measures as required.
OTHER: If ingestion, any type of overexposure or symptoms of overexposure occur
during or following the use of this product, contact a poison control center,
emergency room or physician immediately; have Material Safety Data Sheet
information available.
SECTION 5 - FIRE OR EXPLOSION DATA
FLASHPOINT: 106 Degrees F ( 41 Degrees C) (PENSKY-MARTENS CLOSED CUP)
FLAMMABLE LIMITS: Lower explosion limit (LEL): 1.2
Upper explosion limit (UEL): Not available
EXTINGUISHING MEDIA: Use National Fire Protection Association (NFPA) Class
extinguishers (carbon dioxide, dry chemical, or universal aqueous film forming
foam) designed to extinguish NFPA Class II combustible liquid fires.
UNUSUAL FIRE AND EXPLOSION HAZARDS: When this product is used, the overspray and
other combustible materials such as paint booth filters, rags, masking
materials, etc., contaminated by coating material are subject to spontaneous
combustion. Wetting the contaminated materials and not packing them tightly
together in refuse containers will minimize the potential for this to occur.
Keep this product away from heat, sparks, flame, and other sources of ignition
(i.e., pilot lights, electric motors, static electricity). Invisible vapors can
travel to a source of ignition and flash back. Do not smoke while using this
product. Keep containers tightly closed when not in use. Closed containers may
explode when overheated. Do not apply to hot surfaces. Toxic gases may form when
this product comes in contact with extreme heat.
SPECIAL FIRE FIGHTING PROCEDURES: Water spray may be ineffective. Water spray
may be used to cool closed containers to prevent pressure build-up and posbible
autoignition or explosion when exposed to extreme heat. If water is used, fog
nozzles are preferable. Fire-fighters should wear self-contained breathing
apparatus and full protective clothing.
AUTOIGNITION TEMPERATURE: Not available
SECTION 6 - PREVENTIVE MEASURES
ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Provide maximum
ventilation. Only personnel equipped with proper respiratory, skin, and eye
protection should be permitted in the area. Remove all sources of ignition. Take
up spilled material with sand, vermiculite, or other noncombustible absorbent
material and place in clean, empty containers for disposal. Only the spilled
material and the absorbant should be placed in this conta!ner.
WASTE DISPOSAL METHOD: Waste material must be disposed of in accordance with
federal, state, provincial, and local environmental control regulations. Empty
containers should be recycled or disposed of through an approved waste
management facility.
HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS: Do not store above 120 degrees F. (48 degrees
C.) . Store large quantities in buildings designed and protected for storage of
NFPA Class II combustible liquids.
hRp://ppg.web.ppg.com/crmsds%2Ddata/e0058164.tx~ 9/10/1999
PPG Industrtes, Inc.
SEP 18 '99 18:33 PAGE.005
Page 5 of 6
OTHER PRECAUTIONS: Vapors may collect in low areas. If this material is part of
a multiple component system, read the Material Safety Data Sheet(s) for the
other component or components before blending as the resulting mixture may have
the hazards of all of its parts. Containers should be grounded when pouring.
Avoid free fall of liquids in excess of a few inches.
EXPOSURE CONTROLS AND PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT FOR:
EYE PROTECTION: Wear chemical-type splash goggles when possibility exists for
eye contact due to splashing or spraying liquid, airborne particles, or vapors.
SKIN PROTECTION: Wear protective clothing to prevent skin contact. Apron and
gloves should be constructed of: impermeable material. No specific
permeation/degradation testing have been done on protective clothing for this
product. Recommendations for skin protection are based on infrequent contact
with this product. For frequent contact or total imlersion, contact a
manufacturer of protective clothing for appropriate chemical imperv眔us
equipment.
RESPIRATORY PROTECTION: Overexposure to vapors may be prevented by ensuring
proper ventilation controls, vapor exhaust or fresh air entry. A NIOSH- approved
air purifying respirator with the appropriate chemical cartridges or a
positive-pressure, air-supplied respirator may also reduce exposure. Read the
respirator manufacturer's instructions and literature carefully to determine the
type of airborne contaminants against which the respirator is effective, its
limitations, and how it is to be properly fitted and used.
OTHER EQUIPMENT: Clean contaminated clothing and shoes.
VENTILATION REQUIREMENTS: Provide general dilution or local exhaust ventilation
in volume and pattern to keep the concentration of ingredients listed in Section
2 below the lowest suggested exposure limits, the LEL below the stated limit,
and to remove decomposition products during welding or flame cutting.
SECTION 7 - PHYSICAL AND CHEMICAL PROPERTIES
[FORMULA VALUES, NOT SALES SPECIFICATIONS]
BOILING RANGE: 280- 468Degrees F
SOLUBILITY IN WATER: .2 %
VAPOR PRESSURE: i. 9 nmd
WEIGHT/GALLON (LBS): 13.6 (IMPERIAL)
VAPOR DENSITY: Heavier than air
pH: Not applicable
% VOLATILE/VOLUME: 44.910
% SOLIDS BY WEIGHT: 74.34
SPECIFIC GRAVITY: 1.362
EVAPORATION RATE(BuOAc=I00):
PHYSICAL STATE: LIQUID
http://ppg.web.ppg.colrdcn~sds%2Ddata/e0058164.tx~ 9/10/1999
PPG Industries, Inc.
SEP 18 '99 18:34 PAGE.006
Page 6 of 6
FREEZING POINT: Not available
ODOR THRESHHOLD: Not available
COEFFICIENT OF OIL/WATER DISTRIBUTION: Not available
ODOR/APPEARANCE: Viscous liquid with an odor characteristic of the solvents
listed in Section 2.
SECTION 8 - STABILITY AND REACTIVITY DATA
This product is normally stable and will not undergo hazardous reactions.
INCOMPATIBILITY (MATERIALS AND CONDITIONS TO AVOID): Avoid contact with strong
alkalies, strong mineral acids, or strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: May produce the following hazardous
decomposition products when exposed to extreme heat: carbon monoxide ; carbon
dioxide ; lower molecular weight polymer fractions; Extreme heat includes, but
is not limited to, flame cutting, brazing, and welding.
SECTION 9 - PREPARATION INFORMATION PREPARED BY: Product Safety Department PHONE
NUMBER: (412)492-5555 DATE OF MSDS PREPARATION: 08/19/99
Hazardous Materials Identification System (HMIS) and National Fire Protection
Association (NFPA) Ratings:
HMIS Rating NFPA Rating
2* HEALTH
HEALTH 2
FLAMMABILITY 2 FLAMMABILITY 2
REACTIVITY 0 INSTABILITY 0
Rating System:0=Minimal, l=Slight, 2=Moderate, 3=Serious, 4=Severe, *=Chronic
Effects.
Safe handling of this product requires that all of the information on the MSDS
be evaluated for specific work environments and conditions of use.
THIS IS THE END OF THE MSDS FOR: 6-208 (00150901.0016-208 )
Manufactured and Supplied by:
PPG INDUSTRIES, EAST POINT
1377 OAKLEIGH DRIVE
EAST POINT, GA 30344
C"
http :#ppg.web. ppg. com/crmsds
O ~2Ddata/e0058164.tx~ 9/10/1999
PPG Indumtrles, Inc. PAGE.007
SEP 10 '99 10:35
|