MATERIAL SAFETY DATA SHEET
SECTION I:
Manufacturer's Name: Refinish Solutions
Address: 850 Ladd Road, Bldg. E
Walled Lake, MI 48390-3020
Product: Isocyanate Activators, Hardeners and ISOCYANATE ACTIVATORS
Additives
HARDENERS AND ADDITIVES
Emergency Phone #: Chemtrec (800) 424-9300, (800) 735-0303
D.O.T. Hazard Class Paint, Flammable Liquids UN 1263
SECTION II - Hazardous Ingredients. (See Section X for specific products' codes.)
ACGIH OSHA
N FLASH VAPOR
STEL** NFPA
CODE EMERG O POINT PRESSURE
HAZARDOUS INGREDIENT CAS NO TLV PEL
NO. PLAN* T
PPM H-F-R
TCC/?F mm Hg.
E PPM PPM
10 @20?C
1 n-BUTYL ACETATE YES 123-86-4 150 150 200 2-3-0 81
47 @20?C
2 TOLUENE YES 4 108-88-3 50 100 150 2-3-0 45
1.5 @20?C
3 ethyl 3-ethoxypropionate YES 763-69-9 N/E N/E 100 1-2-0 136
9.5 @20?C
4 XYLENES YES 3 1330-20-7 100 100 150 2-3-0 77
[N120] hexamethylene
5 NO 1 822-06-0 0.05 0.02 N/E 3-0-0 N/E N/E
diisocyanate
[N120] isophorone
6 NO 2 4098-71-9 N/E N/E N/E 2-1-0 N/E N/E
diisocyanate
16 @20?C
7 METHYL ISOBUTYL KETONE YES 108-10-1 50 50 75 2-3-0 60
7.10@68?F
8 ETHYL BENZENE YES 100-41-4 100 100 150 2-3-0 77
9 hexamethylene diisocyanate
NO 28182-81-2 N/E N/E N/E 2-2-1 N/E N/E
polymer
10 isocyanate polymer NO 53880-05-0 N/E N/E N/E 2-1-1 N/E N/E
11 1.58 @
pseudocumene YES 95-63-6 25 25 N/E 0-2-0 118.4
68?F
RS-SD2 Page 1 of 5 Printed: 9/14/2006
MATERIAL SAFETY DATA SHEET
SECTION II - Hazardous Ingredients. (See Section X for specific products' codes.)
ACGIH OSHA
N FLASH VAPOR
STEL** NFPA
CODE EMERG O POINT PRESSURE
HAZARDOUS INGREDIENT CAS NO TLV PEL
NO. PLAN* T
PPM H-F-R
TCC/?F mm Hg.
E PPM PPM
12 FORMALDEHYDE YES 50-00-0 0.3 CEILING 0.75 2.00 2*-2-0 N/E N/E
13 n-AMYL ACETATE NO 628-63-7 50 100 100 2-3-0 77 4.88 @ 77?F
14 o-xylene YES 95-47-6 100 100 150 2-3-0 80 5.20 @ 68?F
15 m-xylene YES 108-38-3 100 100 150 2-3-0 80 8.3 @ 68?F
16 PROPYL BENZENE NO 103-65-1 N/E N/E N/E 0-2-0 N/E N/E
17 p-xylene YES 106-42-3 100 100 150 2-3-1 80 8.00 @ 68?F
18 naphthalene YES 91-20-3 N/E N/E N/E 0-2-0 N/E N/E
19 METHYL ACETATE NO 79-20-9 200 200 250 1-3-0 9 171.3 @ 68?F
300?F
20 hexamethylene diisocyanate NO 3779-63-3 N/E N/E N/E 2-1-1 N/E
ASTM
D93
3
2.5 mg/m3
2.5 mg/m
21 p-chloro-a,a,a-trifluorotoluene NO 98-56-6 TWA as TWA as N/E 1*-2-1 116.6 N/E
FLOURIDES FLOURIDES
22 ethyl acetate NO 141-78-6 400 400 N/E 1-3-0 24 86
23 isobutyl isobutyrate NO 97-85-8 N/E N/E N/E 1-2-0 104 0.11812
acetic acid, 2-ethylhexyl
24 NO 103-09-3 N/E N/E N/E 2-2-0 159.8 0.4
acetate
25 1-methoxy-2propanol acetate NO 108-65-6 N/E N/E N/E 1-2-0 107.6 3.58
TRADE 249.98
26 NJTSR# 05995500-(MT120) NO N/E N/E N/E 2-1-0 N/E
SECRET PMCC
* Subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.
** Short Term Exposure Limit
Note 1 - Free Hexamethylene Diisocyanate monomer (HDI) is less than 0.7% by weight of total HDI
Note 2 - Free Isophrone Diisocyanate monomer (IPDI) is less than 0.7% by weight of total IPDI
Note 3 - Xylene contains 18-20% Ethyl Benzene (CAS#100-41-4) having PEL of 100 ppm, TLV of 100 ppm & STEL of 125 ppm.
Note 4 - Toluene is known to the state of California to cause birth defects or other reproductive harm.
N/E - Not established as reported by manufacturer.
RS-SD2 Page 2 of 5 Printed: 9/14/2006
MATERIAL SAFETY DATA SHEET
SECTION III - PHYSICAL DATA
Slower than ether Heavier than air
Evaporation Rate: Vapor Density:
Miscible Volume % volatile: 40.12 ?79.31%
Solubility in water:
132-390.2?F 33.00 ?74.21%
Boiling range: Weight % volatile:
Gallon weight (lbs. per gal.): 7.84 ?9.22 V.O.C. (lbs. per gal.): 0.48 ?5.95
SECTION IV - FIRE & EXPLOSION DATA
Flash point (Closed cup): 9 - 78?F.
Approximate flammable limits: 0.8% - 16.0%.
Extinguishing media: Foam, carbon dioxide, dry chemical.
Special fire fighting procedures: Full protective equipment, including self-contained breathing apparatus, is recommended. Water from fog nozzles may be used to cool closed
containers to prevent pressure build up.
Unusual fire & explosion hazards: When heated above the flash point, emits flammable vapors which, when mixed with air, can burn or be explosive. Fine mists or sprays may be
flammable at temperatures below the flash point.
SECTION V - HEALTH HAZARD DATA
GENERAL EFFECTS
Ingestion: Gastro-intestinal distress. In the unlikely event of ingestion, call a physician immediately and have the names of the ingredients available.
Inhalation: May cause nose and throat irritation. Repeated and prolonged overexposure to solvents may lead to permanent brain and nervous system damage. Eye watering,
headaches, nausea, dizziness and loss of coordination are signs that solvent levels are too high. Exposure to isocyanates may cause respiratory sensitization. This effect may be
permanent. Symptoms include and asthma-like reaction with shortness of breath, wheezing or coughing which may be permanent. This effect may be delayed for several hours after
exposure. Repeated overexposure to isocyanates may cause a decrease in lung function which may be permanent. Individuals with lung or breathing problems or prior reaction to
isocyanates must not be exposed to the vapors or spray mist of this product. If affected by inhalation of vapor or spray mist, remove to fresh air. If breathing difficulty persists, or occurs
later, consult a physician.
Skin or eye contact: May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and dermatitis. In case of eye contact,
immediately flush with plenty of water for at least 15 minutes; call a physician. In case of skin contact, wash with soap and water. If irritation occurs, contact a physician.
SPECIFIC EFFECTS
Butyl acetate: Recurrent overexposure may result in liver and kidney injury. Tests for embryotoxic activity in animals have been inconclusive. Toluene: Recurrent overexposure may
result in liver and kidney injury. High airborne levels have produced irregular heartbeats in animals and occasional palpitations in humans. Rats exposed to very high airborne levels
have exhibited high frequency hearing deficits. Toluene has been found in the state of California to cause birth defects or other reproductive harm. Diethylene Glycol- Monobutyl Ether:
Contact may cause skin irritation with discomfort or rash. Can be absorbed through the skin in harmful amounts. Recurrent overexposure may result in liver and kidney injury. High
doses in laboratory animals have shown n on specific effects such as irritation, weight loss, and moderate blood changes. Tests for mutagenic activity in bacterial or mammalian cell
cultures have been inconclusive. Ethyl acetate: Prolonged and repeated high exposures of laboratory animals resulted in secondary anemia with an increase in white blood cells; fatty
degeneration, cloudy swelling, and an excess of blood in various organs. Aromatic hydrocarbon: Recurrent overexposure may result in liver and kidney injury. Has been toxic to the
fetus in laboratory animals at doses that are toxic to the mother. Aliphatic Polyisocyanate or Polymeric Isophorone Diisocyanate or Polyisocyanate: Repeated exposure may cause
allergic skin rash, itching, and swelling. Repeated overexposure to isocyanates may cause lung injury, including a decrease in lung function, which may be permanent. Over exposure
may cause asthma-like reactions with shortness of breath, wheezing, and cough which may be permanent or permanent lung sensitization. This effect may be delayed for several hours
after exposure. Individuals with pre-existing lung disease, asthma, or breathing difficulties may have increased susceptibility to the toxicity of excessive exposures. 1,6 Hexamethylene
Diisocyanate: May cause temporary upper respiratory and/or lung irritation with cough, difficult breathing, or shortness of breath. Over exposure may cause asthma-like reactions with
shortness of breath, wheezing, cough, or permanent lung sensitization. This effect may be delayed for several hours after exposure. Prolonged skin contact may cause chemical burns.
Liquid splashes in the eye may result in chemical burns. Individuals with pre-existing lung disease, asthma, or breathing difficulties may have increased susceptibility to the toxicity of
excessive exposures. Ethylene Glycol Monobutyl Ether Acetate: Can be absorbed through the skin in harmful amounts. May destroy red blood cells. May cause abnormal kidney
function.
RS-SD2 Page 3 of 5 Printed: 9/14/2006
MATERIAL SAFETY DATA SHEET
SECTION VI - REACTIVITY DATA
Stability: Stable
Incompatibility (materials to avoid): None, reasonably foreseeable
Hazardous decomposition products: CO, CO2, and smoke
Hazardous polymerization: Will not occur
SECTION VII - SPILL or LEAK PROCEDURES
Steps to be taken in case material is released or spilled: DO NOT breathe vapors. DO NOT get in eyes or on skin. Wear a positive pressure supplied air vapor/particulate respirator
(NIOSH/MSHA TC-19C), eye protection, gloves, and protective clothing. Remove sources of ignition. Absorb with inert material. Ventilate area. Pour liquid decontaminate solution over
the spill and allow to sit 10 minutes, minimum.
Typical decontamination solutions are: 20% surfactant (Tergitol TMN 10), 80% Water OR 0-10% Ammonia, 2-5% Detergent, Balance Water
Waste disposal method: DO NOT allow material to contaminate ground water systems. Incinerate absorbed material in accordance with federal, state, and local requirements. DO
NOT incinerate in closed containers.
SECTION VIII - SPECIAL PROTECTION INFORMATION
Respiratory: DO NOT breathe vapors or mists. Wear a positive pressure supplied air respirator (NIOSH/MSHA TC-19C) while mixing activator with any paint or clear enamel, during
application and until all vapors and spray mists are exhausted. Individuals with a history or lung or breathing problems or prior reaction to isocyanates should not use or be exposed to
this product. DO NOT permit anyone without protection in the painting area. Follow the respirator manufacturer's directions for respirator use.
Ventilation: Provide sufficient ventilation in volume and pattern to keep contaminants below applicable OSHA requirements.
Protective clothing: Neoprene gloves and coveralls are recommended.
Eye protection: Desirable in all industrial situations. Include splash guards or side shields.
SECTION IX - SPECIAL PRECAUTIONS
Precautions to be taken in handling and storing: Observe label precautions. Keep away from heat, sparks, and flame. Close container after each use. Ground containers when
pouring. Wash thoroughly after handling and before eating or smoking. Do not store above 120?F.
Other precautions: DO NOT sand, flame cut, braze, or weld dry coating without a NIOSH/MSHA approved respirator or appropriate ventilation.
SECTION X - PRODUCT CODES AND INFORMATION
OSHA
COMPOSITION % BY WEIGHT NFPA
FLASH POINT
PRODUCT EMERG. VOC BOILING
FLAM
TCC/?F
(HAZARDOUS INGREDIENTS) POINT 癋
NUMBER PLAN* LBS/GL
H-F-R
CLASS
1) 11.83%; 2) 28.19%; 4) 9.4%; 5) <1%; 8) 1.66%;
45
RSA-165 YES IB 2*-3-0 5.95 201.2 ?365
9) 20-30%; 25) 15-25%; 26) 0-10%
1) 1.04%; 5) <1%; 9) 20-30%; 10) 0-10%; 11) 0.73%;
9
RSA-214 YES IB 2*-3-0 0.49 132 ?334.4
19) 31.73%; 20) 15-25%
RS-SD2 Page 4 of 5 Printed: 9/14/2006
MATERIAL SAFETY DATA SHEET
SECTION X - PRODUCT CODES AND INFORMATION
OSHA
COMPOSITION % BY WEIGHT NFPA
FLASH POINT
PRODUCT EMERG. VOC BOILING
FLAM
TCC/?F
(HAZARDOUS INGREDIENTS) POINT 癋
NUMBER PLAN* LBS/GL
H-F-R
CLASS
1) 1.04%; 5) <1%; 9) 20-30%; 11) 0.73%; 19) 29.68%;
9
RSA-215 YES IB 2*-3-0 0.48 132 ?334.4
20) 15-25%; 21) 0-10%
1) 1.03%; 5) <1%; 9) 20-30%; 11) 0.72%; 19) 27.67%;
9
RSA-216 YES IB 2*-3-0 0.48 132 ?334.4
20) 15-25%; 21) 0-10%
1) 28.86%; 2) 0-5%; 3) 0-10%; 4) 2.14%; 5) <1%;
6) 0.5644%; 7) 1.65%; 8) 0.4%; 9) 25-35%; 10) 20-30%;
45
RSA-225 YES IB 2*-3-0 3.35 201.2 - 334.4
11) 0.65%; 12) 0.0003%; 13) 1.35%; 14) 0.11%; 15) 0.11%;
16) 0.07%; 17) 0.03%; 18) 0-5%
1) 28.84%; 2) 0-5%; 3) 0-10%; 4) 2.14%; 5) <1%;
6) 0.5651%; 7) 1.65%; 8) 0.4%; 9) 25-35%; 10) 20-30%;
45
RSA-226 YES IB 2*-3-0 3.35 201.2 - 334.4
11) 0.65%; 12) 0.0003%; 13) 1.35%; 14) 0.11%; 15) 0.11%;
16) 0.07%; 17) 0.03%; 18) 0-5%
1) 4.27%; 2) 0-5%; 3) 0-10%; 4) 2.17%; 5) <1%;
6) 0.5717%; 7) 24.94%; 8) 0.41%; 9) 25-35%; 10) 20-30%;
RSA-227 YES IB 2*-3-0 3.20 201.2 - 334.4
45
11) 0.65%; 12) 0.0003%; 13) 1.37%; 14) 0.11%; 15) 0.11%;
16) 0.07%; 17) 0.03%; 18) 0-5%
1) 12.45%; 2) 0-5%: 4) 1.84%; 5) <1%; 6) 0.5854%;
7) 1.42%; 8) 0.35%; 9) 20-30%; 10) 15-25%; 11) 0.595%;
RSH-610 YES IB 2*-3-0 3.99 172 ?390.2
24
12) 0.0003%; 13) 1.16%; 14) 0.09%; 15) 0.09%; 16) 0.06%;
17) 0.02%; 18) 0-5%; 22) 14.97%; 23) 0-10%; 24) 0-10%
1) 29.07%; 2) 0-5%: 4) 1.20%; 5) <1%; 6) 0.3175%;
201.2 ?br>
7) 0.73%; 8) 0.28%; 9) 10-20%; 10) 15-25%; 11) 1.7%;
RSH-612 YES IB 2*-3-0 4.84
45 334.4
12) 0.0002%; 13) 0.76%; 14) 0.27%; 15) 0.27%; 16) 0.17%;
17) 0.07%; 18) 0-5%; 25) 10-20%
1) 4.3%; 2) 23.8%; 4) 20.23%; 8) 3.57%; 10) 25-35%;
RSH-620 YES IB 2*-3-0 5.48 231 ?390.2
45
11) 3.01%; 23) 0-10%; 24) 0-10%
RSH-3056 YES IB 2-3-0 2.95 201.2 - 252
1) 33%; 5) <1%; 9) 60-70% 78
* Products indicated are subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.
~ NFPA ratings for individual products have not been established. The ratings given are the highest rating of any ingredient contained in that product.
NOTICE: The data in this Material Safety Data Sheet relate only to the specific material designated herein and do not relate to use in
combination with another material or in any process.
Revised on: September 14, 2006
RS-SD2 Page 5 of 5 Printed: 9/14/2006
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