Page 1 of 7
MATERIAL SAFETY DATA SHEET OP-018
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2006
1. PRODUCT IDENTIFICATION
1.1 Product Name:
OSIS SHAPE
1.2 Chemical Name:
NA
1.3 Synonyms:
NA
1.4 Trade Names:
NA
1.5 Product Use:
PROFESSIONAL OR SUNDRY USE ONLY
1.6 Distributor's Name:
SCHWARZKOPF, INC.
1.7 Distributor's Address:
6047 BRISTOL PARKWAY, SUITE 200, CULVER CITY, 90230 USA
1.8 Emergency Phone:
CHEMTREC: +1 (703) 527-3887 / +1 (800) 424-3887
1.9 Business Phone:
+1 (310) 641-4600
2. HAZARD IDENTIFICATION
2.1 Hazard Identification:
WARNING: Flammable. Do not place on hot water, or near radiators, stoves or other sources of heat. Do not use near open flame,
sparks or other sources of ignition. KEEP OUT OF REACH OF CHILDREN. Avoid getting into the eyes. Use only as directed.
2.2 Routes of Entry: Inhalation: YES Absorption: YES Ingestion: YES
2.3 Effects of Exposure:
INGESTION: If product is swallowed, may cause nausea, vomiting and/or diarrhea and central nervous system depression.
EYES: Moderately irritating to the eyes. Symptoms of overexposure may include redness, itching, irritation and watering.
SKIN: May be irritating to skin. The product can cause allergic skin reactions (e.g., rashes, welts, dermatitis) in some sensitive
individuals.
INHALATION: Vapors of this product may be moderately irritating to the nose, throat and other tissues of the respiratory system.
Symptoms of overexposure can include coughing, wheezing, nasal congestion, and difficulty breathing. Inhalation of
concentrated vapors can cause central nervous system depression (e.g., drowsiness, dizziness, headaches, nausea).
2.4 Symptoms of Overexposure:
Overexposure in eyes may cause redness, itching and watering. Symptoms of skin overexposure may include redness, itching, and
irritation of affected areas. The product can cause allergic skin reactions (e.g., rashes, welts, dermatitis) in some sensitive individuals.
2.5 Acute Health Effects:
Moderate irritation to eyes. Moderate irritation to skin near affected areas. Intentional inhalation of vapors may cause headache,
fatigue, weakness, mental confusion, mood disturbances and decreased coordination and judgment.
2.6 Chronic Health Effects:
No harmful or chronic health effects are expected to occur from a single accidental ingestion. Intentional and continuous ingestion
can cause serious effects on liver and kidneys. Contains denatured alcohol.
2.7 Target Organs:
Eyes
3. COMPOSITION & INGREDIENT INFORMATION
EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH ?ppm OSHA - ppm OTHER
%
CHEMICAL NAME(S) CAS No. RTECS No. EINECS No. TLV STEL PEL STEL IDLH
WATER 7732-18-5 ZC0110000 231-791-2 NA NE NE NE NE NE
DENATURED ALCOHOL 64-17-5 KQ6300000 200-578-6 24.0 1000 NA 1000 NA NA
PEG-25 HYDROGENATED
61788-85-0 NA NA NA NA NA NA NA NA
CASTOR OIL
NA NE NE NE NE
CAPRYLIC/CAPRIC TRIGLYCERIDE 65381-09-1 NA 265-724-3 NE
119415-85-3 NA NA NA NA NA NA NA NA
TRICETEARETH-4 PHOSPHATE
BUTYLENE GLYCOL 107-88-0 EK0440000 203-529-7 NA NA NA NA NA NA
NA = Not Available; ND = Not Determined; NE = Not Established; C = Ceiling Limit; See Section 16 for Additional Definitions of Terms Used
NOTE: All WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2004 format.
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MATERIAL SAFETY DATA SHEET OP-018
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2006
3. COMPOSITION & INGREDIENT INFORMATION ?cont'd
EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH ?ppm OSHA - ppm OTHER
%
CHEMICAL NAME(S) CAS No. RTECS No. EINECS No. TLV STEL PEL STEL IDLH
PEG-200 HYDROGENATED
67784-88-7 NA NA NA NA NA NA NA NA
GYLCERYL PALMITATE
PEG-7 GLYCERYL COCOATE 68201-46-7 NA NA NA NA NA NA NA NA
FRAGRANCE NA NA NA NA NA NA NA NA NA
METHYLPARABEN 99-76-3 DH2450000 NA NA NE NE NE NE NE
DMDM HYDANTOIN 6440-58-0 YT7365000 NA NA NA NA NA NA NA
CI 60730 (ACID VIOLET 43) 4430-18-6 NA NA NA NA NA NA NA NA
4. FIRST AID MEASURES
4.1 First Aid:
INGESTION: DO NOT INDUCE VOMITING. Contact ChemTrec at 703-527-3887 or the nearest Poison Control Center or local
emergency telephone number for assistance and instructions. Seek immediate medical attention. If vomiting occurs
spontaneously, keep victim's head lowered (forward) to reduce the risk of aspiration.
EYES: If product gets in the eyes, flush eyes thoroughly with copious amounts of water for at least 15 minutes, holding
eyelid(s) open to ensure complete flushing. If irritation persists, seek medical attention.
SKIN: Remove contaminated clothing and wash affected areas with soap and water. If irritation persists, seek prompt
medical attention. Do not wear contaminated clothing until after it has been properly cleaned.
INHALATION: Remove victim to fresh air at once. Under extreme conditions, if breathing stops, perform artificial respiration. Seek
immediate medical attention.
HEALTH 1
4.2 Medical Conditions Aggravated by Exposure:
Pre-existing dermatitis, other skin conditions, and disorders of the target organs (eyes,
FLAMMABILITY 2
skin, and respiratory system).
REACTIVITY 0
PROTECTIVE EQUIPMENT A
EYES
5. FIREFIGHTING MEASURES
5.1 Flashpoint & Method:
NA
5.2 Autoignition Temperature:
NA
5.3 Flammability Limits: Lower Explosive Limit (LEL): 3.3 Upper Explosive Limit (UEL): 19.0
5.4 Fire & Explosion Hazards:
This product is a flammable liquid. When involved in a fire, this product may ignite and decompose to
form toxic gases (e.g., CO, CO2, and NOx).
5.5 Extinguishing Methods:
Water Fog, Foam, Dry Chemical, CO2
5.6 Firefighting Procedures:
As in any fire, wear MSHA/NIOSH approved self-contained breathing apparatus (pressure-demand) and
full protective gear. Keep containers cool until well after the fire is out. Use water spray to cool fire-
exposed surfaces and to protect personal. Fight fire upwind. Avoid spraying water directly into storage
containers because of danger of boilover. Prevent runoff from fire control or dilution from entering
sewers, drains, drinking water supply, or any natural waterway. Firefighters must use full bunker gear
including NIOSH-approved positive pressure self-contained breathing apparatus to protect against
potential hazardous combustion or decomposition products and oxygen deficiencies.
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MATERIAL SAFETY DATA SHEET OP-018
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2006
6. ACCIDENTAL RELEASE MEASURES
6.1 Spills:
Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective Equipment.
For small spills (e.g., <1 gallon) wear appropriate personal protective equipment (e.g., goggles, gloves). Maximize ventilation (open
doors and windows) and secure all sources of ignition. Remove spilled material with absorbent material and place into appropriate
closed container(s) for disposal. Dispose of properly in accordance with local, state and federal regulations. Wash all affected areas
and outside of container with plenty of warm water and soap. Remove any contaminated clothing and wash thoroughly before
reuse.
For spills 1 gallon, deny entry to all unprotected individuals. Dike and contain spill with inert material (e.g., sand or earth). Use ONLY
non-sparking tools for recovery and cleanup. Transfer liquid to containers for recovery or disposal and solid diking material to
separate containers for proper disposal. Remove contaminated clothing promptly and wash affected skin areas with soap and water.
Keep spills and cleaning runoffs out of municipal sewers and open bodies of water.
7. HANDLING & STORAGE INFORMATION
7.1 Work & Hygiene Practices:
Avoid breathing the vapors generated by this product. If necessary, apply a moisturizer after using product. Do not eat, drink, or
smoke while handling this product.
7.2 Storage & Handling:
Use and store in a cool, dry, well-ventilated location (e.g., local exhaust ventilation, fans). Keep away from excessive heat, open
flames, sparks, and other possible sources of ignition. Keep away from incompatible materials listed in Section 10. Do not store in
damaged or unmarked containers or storage devices. Empty containers may contain residual amounts of this product; therefore,
empty containers should be handled with care. Keep away from children at all times!
7.3 Special Precautions:
Spilled material may present a slipping hazard if left unattended. Clean all spills promptly.
8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1 Ventilation & Engineering Controls:
Use with adequate ventilation (e.g., open doors and windows, local exhaust ventilation). Ensure appropriate decontamination
equipment is available (e.g., sink, safety shower, eye-wash station). Use in a chemical fume hood when working with large quantities
of product and provide adequate ventilation (e.g., local exhaust ventilation, fans).
8.2 Respiratory Protection:
No special respiratory protection is required under typical circumstances of use or handling. In instances where vapors or sprays of
this product are generated, and respiratory protection is needed, use only protection authorized by 29 CFR ?910.134, applicable U.S.
State regulations, or the Canadian CAS Standard Z94.4-93 and applicable standards of Canadian Provinces, EC member States, or
Australia.
8.3 Eye Protection:
Avoid eye contact. Safety glasses with side shields should be used when handling large quantities (e.g., 1 gallon) of this product.
8.4 Hand Protection:
None required under normal conditions of use. However, may cause skin irritation in some sensitive individuals. When handling large
quantities (e.g., 1 gallon), wear rubber or impervious plastic gloves.
8.5 Body Protection:
No apron required when handling small quantities. When handling large quantities (e.g., 1 gallon), eye wash stations and deluge
showers should be available. Upon completion of work activities involving large quantities of this product, wash any exposed areas
thoroughly with soap and water.
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MATERIAL SAFETY DATA SHEET OP-018
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2006
9. PHYSICAL & CHEMICAL PROPERTIES
NA
9.1 Density:
9.2 Boiling Point: NA
9.3 Melting Point: NA
9.4 Evaporation Rate: NA
9.5 Vapor Pressure: NA
9.6 Molecular Weight: NA
9.7 Appearance & Color: Opaque, colored gel with a fresh odor.
9.8 Odor Threshold: NE
9.9 Solubility: Soluble.
9.10 pH NA
9.11 Viscosity: NA
9.12 Other Information: NA
10. STABILITY & REACTIVITY
10.1 Stability:
This product is stable.
10.2 Hazardous Decomposition Products:
Oxides of carbon (CO, CO2) and sulfur (SO2)
10.3 Hazardous Polymerization:
Will not occur.
10.4 Conditions to Avoid:
Open flames, sparks, high heat and direct sunlight.
10.5 Incompatible Substances:
None known.
11. TOXICOLOGICAL INFORMATION
11.1 Toxicity Data:
The product has not been tested for specific toxicity data.
11.2 Acute Toxicity:
See section 2.5
11.3 Chronic Toxicity:
See section 2.6
11.4 Suspected Carcinogen:
No
11.5 Reproductive Toxicity:
This product is not reported to produce reproductive toxicity in humans.
Mutagenicity:
This product is not reported to produce mutagenic effects in humans.
Embryotoxicity:
This product is not reported to produce embryotoxic effects in humans.
Teratogenicity:
This product is not reported to produce teratogenic effects in humans.
Reproductive Toxicity:
This product is not reported to produce reproductive effects in humans.
11.6 Irritancy of Product:
See Section 2.3
11.7 Biological Exposure Indices:
NE
11.8 Physician Recommendations:
Treat symptomatically.
Page 5 of 7
MATERIAL SAFETY DATA SHEET OP-018
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2006
12. ECOLOGICAL INFORMATION
12.1 Environmental Stability:
There is no specific data available for this product.
12.2 Effects on Plants & Animals:
There is no specific data available for this product.
12.3 Effects on Aquatic Life:
There is no specific data available for this product.
13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal:
Dispose of in accordance with federal, state and local regulations.
13.2 Special Considerations:
U.S. EPA Characteristic Waste: D001 (characteristic - ignitable)
14. TRANSPORTATION INFORMATION
The basic description (proper shipping name, hazard class & division, ID Number, packing group) is shown for each mode of transportation.
Additional descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND):
NOT REGULATED PER 49 CFR ?73.150 (e)
14.2 IATA (AIR):
NOT REGULATED PER IATA ?4.4, SPECIAL PROVISION A58
14.3 IMDG (OCN):
NOT REGULATED PER IMDG ?3.3, SPECIAL PROVISION 144
14.4 TDGR (Canadian GND):
NOT REGULATED PER TDGR, SCHEDULE I
14.5 ADR/RID (EU):
NOT REGULATED PER ADR ?3.3, SPECIAL PROVISION 144
14.6 SCT (MEXICO):
NOT REGULATED PER SCT-NOM-002, TABLA 3 (DISPOSICIONES ESPECIALES), NO. 144
15. REGULATORY INFORMATION
15.1 SARA Reporting Requirements:
NA
15.2 SARA Threshold Planning Quantity:
NA
15.3 TSCA Inventory Status:
All chemical substances of this product are listed on the TSCA inventory or are otherwise exempted from inventory status.
15.4 CERCLA Reportable Quantity (RQ):
NA
15.5 Other Federal Requirements:
This product complies with the appropriate sections of the Food and Drug Administration's 21 CFR subchapter G (Cosmetics).
15.6 Other Canadian Regulations:
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of
the information required by the CPR. The components of this product are listed on the DSL/NDSL. None
of the components of this product are listed on the Priorities Substances List.
15.7 State Regulatory Information:
Ethanol is covered under specific state criteria. No components of this product are listed on the California Proposition 65 lists.
15.8 67/548/EEC (European Union) Requirements:
The primary component of this product is listed in Annex I of EU Directive 67/548/EEC:
Ethanol: Flammable (F): R: 11-20/21/22-36/37/38 - Highly flammable. Harmful by inhalation, in contact
with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 7-16-24/25-36/37/39-45 -
Keep container tightly closed. Keep away from sources of ignition -- No smoking. Avoid contact with
skin and eyes. Wear suitable protective clothing, gloves and eye/face protection. In case of accident
or if you feel unwell, seek medical advice immediately.
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MATERIAL SAFETY DATA SHEET OP-018
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2006
16. OTHER INFORMATION
16.1 Other Information:
For external use only. Use only as directed. Discontinue use immediately if irritation develops.
16.2 Terms & Definitions:
See page 7 of this MSDS.
16.3 Disclaimer:
This Material Safety Data Sheet is offered pursuant to OSHA's Hazard Communication Standard, 29 CFR ?910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & Schwarzkopf's knowledge, the
information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness are not
guaranteed and no warranties of any type, either expressed or implied, are provided. The information contained herein relates only
to the specific product(s). If this product(s) is combined with other materials, all component properties must be considered. Data
may be changed from time to time. Be sure to consult the latest edition.
16.4 Prepared for:
Schwarzkopf, Inc.
6047 Bristol Parkway, Suite 200
Culver City, CA 90230 USA
Tel: +1 (310) 641-4600
Fax: +1 (310) 641-4601
http://www.schwarzkopf.com
16.5 Prepared by:
ShipMate, Inc.
18436 Hawthorne Boulevard, Suite 201
Torrance, CA 90504
310-370-3600 phone
310-370-5700 fax
http://www.shipmate.com
Page 7 of 7
MATERIAL SAFETY DATA SHEET OP-018
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2006
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:
GENERAL INFORMATION: OTHER STANDARD ABBREVIATIONS:
CAS No. Chemical Abstract Service Number NA Not Available
NR No Results
EXPOSURE LIMITS IN AIR: NE Not Established
ND Not Determined
ACGIH American Conference on Governmental Industrial Hygienists ML Maximum Limit
TLV Threshold Limit Value SCBA Self-Contained Breathing Apparatus
OSHA U.S. Occupational Safety and Health Administration
NATIONAL FIRE PROTECTION ASSOCIATION: NFPA HAZARD RATINGS:
PEL Permissible Exposure Limit
IDLH Immediately Dangerous to Life and Health
0 Minimal Hazard
1 Slight Hazard
FIRST AID MEASURES: FLAMMABILITY
REACTIVITY
2 Moderate Hazard
3 Severe Hazard
Cardiopulmonary resuscitation - method in which a person
whose heart has stopped receives manual chest compressions 4 Extreme Hazard
CPR
and breathing to circulate blood and provide oxygen to the ACD Acidic
body. ALK Alkaline
COR Corrosive
HMIS?br>
HAZARDOUS MATERIALS IDENTIFICATION W Use No Water SPECIAL
HEALTH
SYSTEM: HMIS PRECAUTIONS
OX Oxidizer
HEALTH
HEALTH, FLAMMABILITY & REACTIVITY RATINGS: TOXICOLOGICAL INFORMATION:
FLAMMABILITY
0 Minimal Hazard Lethal Dose (solids & liquids) which kills 50% of the
LD50
1 Slight Hazard exposed animals s
2 Moderate Hazard REACTIVITY Lethal concentration (gases) which kills 50% of the
LC50
3 Severe Hazard exposed animal
4 Extreme Hazard PERSONAL PROTECTION Concentration expressed in parts of material per million
ppm
parts
NCCHL44T ?NPCA Printed by Labelmaster, A, American Labelmark Co., Chicago, IL 60646 (800) 621-5808
PERSONAL PROTECTION RATINGS: TDlo Lowest dose to cause a symptom
TCLo Lowest concentration to cause a symptom
TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or toxic
A G
TC, TCo, LClo, & LCo effects
IARC International Agency for Research on Cancer
NTP National Toxicology Program
B H
RTECS Registry of Toxic Effects of Chemical Substances
BCF Bioconcentration Factor
C I
TLm Median threshold limit
log KOW or log KOC Coefficient of Oil/Water Distribution
D J
REGULATORY INFORMATION:
WHMIS Canadian Workplace Hazardous Material Information System
E K
DOT U.S. Department of Transportation
TC Transport Canada
Consult your supervisor or S.O.P.
F X
EPA U.S. Environmental Protection Agency
for special handling directions.
DSL Canadian Domestic Substance List
NDSL Canadian Non-Domestic Substance List
PSL Canadian Priority Substances List
TSCA U.S. Toxic Substance Control Act
Face Shield &
EU European Union (European Union Directive 67/548/EEC)
Safety Glasses Splash Goggles Gloves
Eye Protection
CPR Canada's Controlled Product Regulations
EC INFORMATION:
Boots Synthetic Apron Dust Respirator
Full Suit
Full Face
Dust & Vapor Airline
Vapor Respirator Respirator
Respirator Hood/Mask or
C E F N O T+ Xi Xn
Note: the dotted circle indicates that this respiratory
Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful
protective equipment is required for high concentrations
or for large volume spills or releases of product.
WHMIS INFORMATION:
FLAMMABILITY LIMITS IN AIR:
Autoignition Minimum temperature required to initiate combustion in air
Temperature with no other source of ignition
Lower Explosive Limit - lowest percent of vapor in air, by
A B C D1 D2 D3 E F
LEL volume, that will explode or ignite in the presence of an
ignition source Compressed Flammable Oxidizing Toxic Irritation Infectious Corrosive Reactive
Upper Explosive Limit - highest percent of vapor in air, by
UEL volume, that will explode or ignite in the presence of an
ignition source
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