Product Name: PS-100 WB/PRIMER-SEALER WB PTB MSDS No: AS905H
View MSDS : 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Product Name: PS-100 WB/PRIMER-SEALER WB PTB
HMIS
MSDS Manufacturer AS905H
Number: Health Hazard 2*
Manufacturer Name: ITW Polymer Technologies
Fire Hazard 1
Address: 130 Commerce Drive
Montgomeryville, PA 18936
REACTIVITY 1
General Phone Number: (215) 855-8450
Emergency Phone (215) 855-8450 Personal X
Number: Protection
CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424-9300
* Chronic Health
Canutec: In Canada, call CANUTEC: (613) 996-6666 (call collect)
Effects:
MSDS Revision Date: 06/15/2009
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS# Ingredient Percent
1-methoxy-2-propanol 107-98-2 10 - 30 by weight
Poly(oxy(methyl-1,2-ethanedlyl)), 9046-10-0 1 - 5 by weight
alpha-(2-aminomethylethyl)omega-(2-aminomethylethoxy)-
Tetraethylenepentamine 112-57-2 1 - 5 by weight
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview: DANGER! Severe Irritant. Potential Sensitizer Harmful.
Route of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
Eye: Can cause severe eye irritation and burns. Eye contact may cause permanent
damage or blindness.
Skin: Causes severe skin irritation. May cause permanent skin damage. Allergic
reactions are possible.
May cause skin sensitization, an allergic reaction, which becomes evident on
reexposure to this material.
Inhalation: Vapor or mist may cause severe respiratory system irritation. May cause
respiratory sensitization with asthma-like symptoms in susceptible
individuals.
Ingestion: Toxic if swallowed. Causes irritation, a burning sensation of the mouth,
throat and gastrointestinal tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe
reddening, swelling, and possible tissue destruction.
Signs/Symptoms: Overexposure may cause eye watering or discomfort, redness and swelling.
Target Organs: Eyes. Skin. Respiratory system. Digestive system.
Aggravation of Pre-Existing Individuals with pre-existing skin disorders, asthma, allergies or known
Page 1 of 6
Product Name: PS-100 WB/PRIMER-SEALER WB PTB MSDS No: AS905H
Aggravation of Pre-Existing Individuals with pre-existing skin disorders, asthma, allergies or known
Conditions: sensitization may be more susceptible to the effects of this product.
SECTION 4 - FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes.
Ensure adequate flushing of the eyes by separating the eyelids with fingers.
Get immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes,
while removing contaminated clothing and shoes.
Get medical attention if irritation develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or
give oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious person.
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: >200 癋
Auto Ignition Temperature: Not determined.
Lower Flammable/Explosive Not determined.
Limit:
Upper Flammable/Explosive Not determined.
Limit:
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire
exposed containers to minimize risk of rupture. Do not enter confined fire
space without full protective gear. If possible, contain fire run-off water.
Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this
material.
Protective Equipment: As in any fire, wear Self-Contained Breathing Apparatus (SCBA),
MSHA/NIOSH (approved or equivalent) and full protective gear.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personnel Precautions: Evacuate area and keep unnecessary and unprotected personnel from
entering the spill area.
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a
chemical waste container. Provide ventilation. Clean up spills immediately
observing precautions in the protective equipment section. After removal,
flush spill area with soap and water to remove trace residue.
Avoid personal contact and breathing vapors or mists. Ventilate area. Use
proper personal protective equipment as listed in section 8.
Other Precautions: Pump or shovel to storage/salvage vessels.
SECTION 7 - HANDLING and STORAGE
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist.
Storage: Store in a cool, dry, well ventilated area away from sources of heat and
incompatible materials. Keep container tightly closed when not in use. Do not
store in reactive metal containers. Keep away from acids, oxidizers.
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition
Page 2 of 6
Product Name: PS-100 WB/PRIMER-SEALER WB PTB MSDS No: AS905H
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition
products (see Section 10) during welding/flame cutting operations and to
protect against dust during sanding/grinding of cured product.
Hygiene Practices: Wash thoroughly after handling.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES
Engineering Controls: Use appropriate engineering control such as process enclosures, local
exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits. Good general ventilation should be
sufficient to control airborne levels. Where such systems are not effective
wear suitable personal protective equipment, which performs satisfactorily
and meets OSHA or other recognized standards. Consult with local
procedures for selection, training, inspection and maintenance of the personal
protective equipment.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29
CFR 1910.133, OSHA eye and face protection regulation, or the European
standard EN 166.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent
skin contact. Consult manufacturer's data for permeability data.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided
by air purifying respirators is limited. Use a positive pressure air supplied
respirator if there is any potential for an uncontrolled release, exposure
levels are not known, or any other circumstances where air purifying
respirators may not provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an
eyewash and a deluge shower safety station.
EXPOSURE GUIDELINES
1-methoxy-2-propanol :
Guideline ACGIH: 100 ppm
TLV-STEL: 150 ppm
TLV-TWA: 100 ppm
Notes : Only established PEL and TLV values for the ingredients are listed.
SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES
Physical State Appearance: Liquid.
Color: amber
Boiling Point: 275 癋
Melting Point: 32 癋 Freezing
Vapor Density: Heavier than air.
Vapor Pressure: 3.8 mmHg
Evaporation Rate: 1
pH: Not determined.
Molecular Formula: Mixture
Molecular Weight: Mixture
Flash Point: >200 癋
Auto Ignition Temperature: Not determined.
VOC Content: 1lb/gal (120 g/l) mixed components
Percent Solids by Weight
SECTION 10 - STABILITY and REACTIVITY
Page 3 of 6
Product Name: PS-100 WB/PRIMER-SEALER WB PTB MSDS No: AS905H
Chemical Stability: Stable under normal temperatures and pressures.
Hazardous Polymerization: Not reported.
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and
oxidizing conditions.
Incompatible Materials: Oxidizers, acids, and chlorinated organic compounds. Reactive metals (e.g.
sodium, calcium, zinc). Sodium/calcium hypochlorite. Nitrous acid/ oxide,
nitrites. Peroxides. Materials reactive with hydroxyl compounds.
SECTION 11 - TOXICOLOGICAL INFORMATION
1-methoxy-2-propanol :
RTECS Number: UB7700000
Eye: Eye - Rabbit Standard Draize Test.: 500 mg/24H
Skin: Intraperitoneal. - Rat LD50: 3720 mg/kg [Details of toxic effects not reported
other than lethal dose value.]
Subcutaneous - Rat LD50: 7800 mg/kg [Behavioral - Convulsions or effect on
seizure threshold Behavioral - Ataxia Lungs, Thorax, or Respiration -
Dyspnea]
Intravenous. - Rat LD50: 4200 mg/kg [Behavioral - Convulsions or effect on
seizure threshold Behavioral - Ataxia Lungs, Thorax, or Respiration -
Dyspnea]
Oral - Mouse LD50: 11700 mg/kg [Behavioral - Convulsions or effect on
seizure threshold Behavioral - Ataxia Lungs, Thorax, or Respiration -
Dyspnea]
Intravenous. - Mouse LD50: 5300 mg/kg [Behavioral - Convulsions or effect
on seizure threshold Behavioral - Ataxia Lungs, Thorax, or Respiration -
Dyspnea]
Oral - Rabbit LD50: 5700 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
Administration onto the skin - Rabbit LD50: 13 gm/kg [Details of toxic effects
not reported other than lethal dose value.]
Subcutaneous - Rabbit LD50: 5 gm/kg [Details of toxic effects not reported
other than lethal dose value.]
Intravenous. - Rabbit LD50: 1200 mg/kg [Details of toxic effects not reported
other than lethal dose value.]
Oral - Rat LD50: 6600 mg/kg [Brain and Coverings - Other degenerative
changes Behavioral - General anesthetic Lungs, Thorax, or Respiration -
Dyspnea]
Administration onto the skin - Rabbit Open irritation test: 500 mg
Inhalation: Inhalation. - Rat LC50: 10000 ppm/5H [Details of toxic effects not reported
other than lethal dose value.]
Ingestion: Oral - Mouse LD50: 11700 mg/kg [Behavioral - Convulsions or effect on
seizure threshold Behavioral - Ataxia Lungs, Thorax, or Respiration -
Dyspnea]
Oral - Rat LD50: 6600 mg/kg [Brain and Coverings - Other degenerative
changes Behavioral - General anesthetic Lungs, Thorax, or Respiration -
Dyspnea]
Poly(oxy(methyl-1,2-ethanedlyl)), alpha-(2-aminomethylethyl)omega-(2-aminomethylethoxy)- :
RTECS Number: TR3702500
Eye: Eye - Rabbit Standard Draize Test.: 100 mg [severe]
Skin: Oral - Rat LD50 : 242 mg/kg [Behavioral - Convulsions or effect on seizure
threshold Gastrointestinal - Ulceration or bleeding from stomach Blood -
Hemorrhage]
Administration onto the skin - Rabbit LD50 : 360 mg/kg [Lungs, Thorax, or
Respiration - Other changes Blood - Hemorrhage Skin and Appendages -
Dermatitis, other (After systemic exposure)]
Ingestion: Oral - Rat LD50 : 242 mg/kg [Behavioral - Convulsions or effect on seizure
threshold Gastrointestinal - Ulceration or bleeding from stomach Blood -
Hemorrhage]
Tetraethylenepentamine :
RTECS Number: KH8585000
Eye: Eye - Rabbit Standard Draize Test.: 5 mg [Moderate]
Eye - Rabbit Standard Draize Test.: 100 mg/24H [Moderate]
Skin: Oral - Rat LD50 : 3990 mg/kg [Details of toxic effects not reported other than
Page 4 of 6
Product Name: PS-100 WB/PRIMER-SEALER WB PTB MSDS No: AS905H
Skin: Oral - Rat LD50 : 3990 mg/kg [Details of toxic effects not reported other than
lethal dose value.]
Intraperitoneal. - Rat LD50 : 205 mg/kg [Details of toxic effects not reported
other than lethal dose value.]
Intravenous. - Mouse LD50 : 320 mg/kg [Details of toxic effects not reported
other than lethal dose value.]
Administration onto the skin - Rabbit LD50 : 660 uL/kg [Details of toxic
effects not reported other than lethal dose value.]
Administration onto the skin - Rabbit Open irritation test: 495 mg [severe]
Ingestion: Oral - Rat LD50 : 3990 mg/kg [Details of toxic effects not reported other than
lethal dose value.]
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.
SECTION 14 - TRANSPORT INFORMATION
DOT Shipping Name: Non regulated.
DOT UN Number: Non regulated.
DOT Hazard Class: Non regulated.
DOT Packing Group: Non regulated.
SECTION 15 - REGULATORY INFORMATION
1-methoxy-2-propanol :
TSCA Inventory Status: Listed
Massachussetts: Listed: Massachusetts Oil and Hazardous List
Pennsylvania: Listed
Canada DSL: Listed
Poly(oxy(methyl-1,2-ethanedlyl)), alpha-(2-aminomethylethyl)omega-(2-aminomethylethoxy)- :
TSCA Inventory Status: Listed
Canada DSL: Listed
Tetraethylenepentamine :
TSCA Inventory Status: Listed
Massachussetts: Listed
Pennsylvania: Listed
Canada DSL: Listed
Page 5 of 6
Product Name: PS-100 WB/PRIMER-SEALER WB PTB MSDS No: AS905H
Canadian Regulations. WHMIS Hazard Class(es): D2A, D2B
All components of this product are on the Canadian Domestic Substances List.
WHMIS Pictograms
SECTION 16 - ADDITIONAL INFORMATION
HMIS Fire Hazard: 1
HMIS Health Hazard: 2*
HMIS Reactivity: 1
HMIS Personal Protection: X
MSDS Revision Date: 06/15/2009
MSDS Author: Actio Corporation
Disclaimer: This Health and Safety Information is correct to the best of our knowledge
and belief at the date of its publication but we cannot accept liability for any
loss, injury or damage which may result from its use. The information given
in the Data Sheet is designed only as a guidance for safe handling, storage
and the use of the substance. It is not a specification nor does it guarantee
any specific properties. All chemicals should be handled only by competent
personnel, within a controlled environment.
Copyright?1996-2008 Actio Software Corporation. All Rights Reserved.
Page 6 of 6
|