MATERIAL SAFETY DATA SHEET
100 Challenger Road
Ridgefield Park, NJ 07660
USA
TRANSPORTATION EMERGENCY NON-TRANSPORTATION
CALL CHEMTREC: 800-424-9300 HEALTH EMERGENCY PHONE..: (303) 623-5716
INTERNATIONAL: 703-527-3887 AGFA INFORMATION PHONE..: (201) 440-2500
1. Product and Company Identification
Lithostar Copyrapid Correction Pen Plus
Product Name:
Corrector Pen Containing Propylene Glycol Monomethyl Ether
Chemical Family:
FN8YV000 FR8TK000 LAY4M000
Product Code:
Quicksilver Correction Pens, Supermaster Corrector Addition Pen, Lithostar Copyrapid
Synonyms:
Correction Pen Plus + Correction Pen
Graphic Systems
Business Group:
569g.002
Agfa MSDS Number:
2. Hazards Identification
Emergency Overview
CAUTION! Color: Red Form: Liquid Pen Odor: ether-like.
May cause eye, skin, and respiratory tract irritation. Use cold water spray to cool fire-exposed containers
to minimize the risk of rupture. May cause conjunctivitis. May affect nervous system. May cause
kidney damage. May cause liver damage.
Potential Health Effects
Skin Contact, Eye Contact, Ingestion, Inhalation
Primary Routes of Entry:
Skin disorders, Respiratory disorders, Eye disorders
Medical Conditions Aggravated by Exposure:
HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE
Acute Inhalation
For Component: Propylene Glycol Methyl Ether
Overexposure to vapor may produce dizziness, drowsiness, or nausea. May cause respiratory tract irritation with symptoms
of coughing, sore throat and runny nose.
For Component: C.I. Basic Red 1
May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose.
Chronic Inhalation
For Component: Propylene Glycol Methyl Ether
Repeated or prolonged exposure may cause effects as described in chronic ingestion.
Acute Skin
For Component: Propylene Glycol Methyl Ether
May cause slight irritation.
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For Component: C.I. Basic Red 1
Not expected to be irritating.
Chronic Skin
For Component: Propylene Glycol Methyl Ether
Prolonged or repeated skin contact may cause dermatitis with symptoms of red, itchy, dry skin.
Acute Eye
For Component: Propylene Glycol Methyl Ether
May cause slight irritation.
For Component: C.I. Basic Red 1
Causes irritation with symptoms of reddening, tearing, stinging, and swelling.
Chronic Eye
For Component: Propylene Glycol Methyl Ether
Prolonged vapor contact may cause conjuntivitis.
Acute Ingestion
For Component: Propylene Glycol Methyl Ether
May cause nervous system effects which can include symptoms of dizziness, incoordination, headache, numbness, and/or
confusion.
For Component: C.I. Basic Red 1
Harmful if swallowed.
Chronic Ingestion
For Component: Propylene Glycol Methyl Ether
Repeated or prolonged exposure may cause injury to the nervous system, kidneys, and liver.
General Effects of Exposure
Chronic Effects of Exposure
For Product: Lithostar Copyrapid Correction Pen Plus
No applicable information was found concerning any adverse chronic health effects from overexposure to this product.
Carcinogenicity:
No Carcinogenic substances as defined by IARC, NTP and/or OSHA
3. Composition/Information on Ingredients
Hazardous Components
Weight % Components CAS-No.
60 - 100% Propylene Glycol Methyl Ether 107-98-2
1 - 5% C.I. Basic Red 1 989-38-8
4. First Aid Measures
Eye Contact
In case of contact, flush eyes with plenty of lukewarm water. Get medical attention if irritation develops.
Skin Contact
In case of skin contact, wash affected areas with soap and water. Immediately remove contaminated
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clothing and shoes. Get medical attention if irritation develops and persists.
Inhalation
If inhaled, remove to fresh air. Get medical attention if irritation develops.
Ingestion
If ingested, do not induce vomiting unless directed to do so by medical personnel. Get medical attention.
5. Fire-Fighting Measures
Not Available
Conditions of Flammability
All extinguishing media are suitable.
Suitable Extinguishing Media:
Special Fire Fighting Procedures
Firefighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating
fumes. Use cold water spray to cool fire-exposed containers to minimize risk of rupture.
Unusual Fire/Explosion Hazards
Toxic and irritating gases/fumes may be given off during burning or thermal decomposition.
> 93.33 癈 (> 200 癋)
Flash Point:
Not Available
Lower Flammable Limit
Not Available
Upper Flammable Limit
Not Available
Autoignition Temperature
Not Available
Hazardous Combustion Products
Not Available
Sensitivity to Mechanical Impact
Not Available
Sensitivity to Static Discharge
6. Accidental release measures
Spill and Leak Procedures
Cleanup personnel must use appropriate personal protective equipment. Cover spill with inert material (e. g., dry sand or
earth) and collect for proper disposal.
7. Handling and Storage
Handling/Storage Precautions
Avoid breathing dust, vapor, or mist. Avoid contact with skin or clothing. Avoid contact with eyes. Use only with adequate
ventilation/personal protection. Wash thoroughly after handling. Keep container closed when not in use. Protect from
freezing.
Further Info on Storage Conditions
Keep out of the reach of children.
8. Exposure Controls / Personal Protection
Propylene Glycol Methyl Ether (107-98-2)
US. ACGIH Threshold Limit Values
Time Weighted Average (TWA): 100 ppm
US. ACGIH Threshold Limit Values
Short Term Exposure Limit (STEL): 150 ppm
Industrial Hygiene/Ventilation Measures
General dilution and local exhaust as necessary to control airborne vapors, mists, dusts and thermal decomposition products
below appropriate airborne concentration standards/guidelines.
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Respiratory Protection
In case of insufficient ventilation wear suitable respiratory equipment.
Hand Protection
Permeation resistant gloves.
Eye Protection
Chemical safety goggles or safety glasses with side-shields.
Skin and body protection
Wear cloth work clothing including long pants and long-sleeved shirts.
Additional Protective Measures
Employees should wash their hands and face before eating, drinking, or using tobacco products. Educate and train
employees in the safe use and handling of this product. Emergency showers and eye wash stations should be available.
9. Physical and chemical properties
Liquid
Form:
Pen
Appearance:
Red
Color:
ether-like
Odor:
Not Available
Odor Threshold:
Not Available
pH
Not Available
Freezing Point
Not Available
Boiling Point/Range
Not Available
Evaporation Rate
Not Available
Vapor Pressure
Not Available
Vapor Density:
1
Specific Gravity:
Partition Coefficient (n-octanol/water) Not Available
Approximately 69.78 %
VOC Content:
10. Stability and Reactivity
Hazardous Reactions
Hazardous polymerization does not occur.
Stability
Stable
11. Toxicological Information
Toxicity Data for Propylene Glycol Methyl Ether
Acute Oral Toxicity
LD50: > 5,000 mg/kg (Rat)
Acute Inhalation Toxicity
LC50: 36.4 mg/l, 6 hrs (Rat)
Acute dermal toxicity
LD50: > 5,000 mg/kg (rabbit)
Skin Irritation
rabbit, Draize, Slightly irritating
rabbit, Draize, Exposure Time: 24 hrs, Non-irritating
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Eye Irritation
rabbit, Draize, Exposure Time: 24 hrs, Slightly irritating
Sensitization
dermal: non-sensitizer (Guinea pig, Other method)
Repeated Dose Toxicity
90 Days, inhalation: NOAEL: 1000 ppm, (Rat)
90 Days, oral: NOAEL: < 459.5 mg/kg, (Rat)
Toxicity to Reproduction/Fertility
One generation study, inhalation, 6 hrs/day 7 days/week, (Rat, Female) NOAEL (F2): 600 ppm
No effects on Reproductive parameters observed at doses tested.
Developmental Toxicity/Teratogenicity
Rat, Female, inhalation, 6 hrs/day 7 days/week, NOAEL (teratogenicity): 1,500 ppm,
Fetotoxicity seen only with maternal toxicity.
Toxicity Data for Phenolformaldehyde Resin
Acute Oral Toxicity
LD50: > 5,000 mg/kg (rat)
Acute dermal toxicity
LD50: > 2,000 mg/kg (rat)
Skin Irritation
rabbit, Non-irritating
Eye Irritation
rabbit, Slightly irritating
Toxicity Data for C.I. Basic Red 1
Acute Oral Toxicity
LD50: 250 mg/kg (rat)
Acute dermal toxicity
LD50: > 2,500 mg/kg (Rat)
Skin Irritation
rabbit, Slightly irritating
Eye Irritation
rabbit, Severely irritating
Mutagenicity
Genetic Toxicity in Vitro:
Ames: negative (Salmonella typhimurium, Metabolic Activation: with/without)
Positive and negative results were seen in various in vitro studies.
Carcinogenicity
Rat, Male/Female, oral, 2 years, daily
ambiguous
Toxicity to Reproduction/Fertility
intraperitoneal, (mouse)
Reproductive effects have been observed in animal studies.
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12. Ecological Information
Ecological Data for Propylene Glycol Methyl Ether
Biodegradation
Aerobic, > 70 %, Exposure time: 29 Days
Readily biodegradable.
Acute and Prolonged Toxicity to Fish
LC50: 4,600 - 10,000 mg/l (Golden orfe (Leuciscus idus), 96 hrs)
LC50: 20,800 mg/l (Fathead minnow (Pimephales promelas), 96 hrs)
Acute Toxicity to Aquatic Invertebrates
EC50: > 500 mg/l (Water flea (Daphnia magna), 24 hrs)
Toxicity to Aquatic Plants
EC50: > 1,000 mg/l, End Point: growth (Green algae (Selenastrum capricornutum), 7 Days)
Toxicity to Microorganisms
EC0: > 5,000 mg/l, (Other bacteria, 48 hrs)
Ecological Data for C.I. Basic Red 1
Acute and Prolonged Toxicity to Fish
LC50: 1 - 10 mg/l (Golden orfe (Leuciscus idus), 96 hrs)
Toxicity to Microorganisms
IC50: 1 - 10 mg/l,
13. Disposal considerations
Waste Disposal Method
Waste disposal should be in accordance with existing federal, state and local environmental control laws.
Empty Container Precautions
Recondition or dispose of empty container in accordance with governmental regulations. Do not reuse empty container
without proper cleaning.
14. Transportation information
Land transport (TDG)
Non-Regulated
Land transport (DOT)
Non-Regulated
Sea transport (IMDG)
Non-Regulated
Air transport (ICAO/IATA)
Non-Regulated
15. Regulatory Information
United States Federal Regulations
Hazardous
OSHA Hazcom Standard Rating:
Listed on the TSCA Inventory.
US. Toxic Substances Control Act:
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US. EPA CERCLA Hazardous Substances (40 CFR 302):
Components
C.I. Basic Red 1 Included in the regulation but with no data values. See regulation for further details
SARA Section 311/312 Hazard Categories:
Acute Health Hazard
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302
Extremely Hazardous Substance (40 CFR 355, Appendix A):
Components: None
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic
Chemicals (40 CFR 372.65) - Supplier Notification Required:
Components
C.I. Basic Red 1
State Right-To-Know Information
The following chemicals are specifically listed by individual states; other product specific health and safety data in other
sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you
should contact the appropriate agency in your state.
Massachusetts, New Jersey or Pennsylvania Right to Know Substance Lists:
Weight % Components CAS-No.
60 - 100% Propylene Glycol Methyl Ether 107-98-2
>=1% Phenolformaldehyde Resin 9003-35-4
1 - 5% C.I. Basic Red 1 989-38-8
New Jersey Environmental Hazardous Substances List and/or New Jersey RTK Special Hazardous Substances
Lists:
Weight % Components CAS-No.
60 - 100% Propylene Glycol Methyl Ether 107-98-2
1 - 5% C.I. Basic Red 1 989-38-8
California Prop. 65:
To the best of our knowledge, this product does not contain any of the listed chemicals, which the state of California has
found to cause cancer, birth defects or other reproductive harm.
Canadian Regulations
WHMIS Classification:
D2B, Toxic Material Causing Other Toxic Effects
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the MSDS contains all the information required by the Controlled Products Regulations.
Foreign Chemical Inventory List(s):
Canada DSL Inventory List - All components of this product are listed
16. Other Information
NFPA 704M Rating HMIS Rating
1
Health 1
Health
1
Flammability 1
Flammability
0
Reactivity 0
Physical Hazard
Other
0=Insignificant 1=Slight 2=Moderate 0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe
3=High 4=Extreme * = Chronic Health Hazard
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AGFA Corporation's method of hazard communication is comprised of Product Labels and Material Safety Data Sheets.
HMIS and NFPA ratings are provided by AGFA Corporation as a customer service.
Contact Person: Product Safety Department
Telephone: (201) 440-2500
MSDS Number: A01030
Version Date: 03/08/2005
Report Version: 1.0
This information is furnished without warranty, express or implied. This information is believed to be accurate to the best
knowledge of AGFA Corporation. The information in this MSDS relates only to the specific material designated herein.
AGFA Corporation assumes no legal responsibility for use of or reliance upon the information in this MSDS.
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