LUBRIZOL?9570CM
Material Safety Data Sheet
LUBRIZOL?9570CM
Prepared according to 29CFR 1910.1200.
1 Chemical Product and Company Identification
The Lubrizol Corporation
29400 Lakeland Boulevard
Wickliffe, Ohio 44092
Tel: (440) 943-4200
LUBRIZOL?9570CM
Product Trade Name
Not applicable for mixtures.
CAS Number
None.
Synonyms
Mixture.
Generic Chemical Name
Miscellaneous fuel additive.
Product Type
24 June 2009
Preparation/Revision Date
FOR TRANSPORT EMERGENCY call CHEMTREC: (+1) 703-527-3887 (outside the
Transportation Emergency
U.S.), 1-800-424-9300 (in the U.S.)
Phone No.
37485189-2026626-3021910-102103
MSDS No.
2 Hazards Identification
Amber colored liquid.
Appearance
Pungent
Odor
Danger.
Principal Hazards
Causes severe skin irritation.
Harmful if inhaled.
Causes respiratory tract irritation.
Harmful if absorbed through skin.
Combustible liquid.
Suspected of damaging the unborn child.
May cause eye irritation.
May cause chronic health effects.
Central nervous system Kidney Liver Lung
Target Organs:
See Section 11 for complete health hazard information.
3 Composition/Information on Ingredients
Hazardous Ingredients
Comp CAS No. Percentage (by wt.) Carcinogen
2-Ethylhexyl nitrate 27247-96-7 From 60 to 69.9 percent N/E
Petroleum naphtha 64742-95-6 From 5 to 9.9 percent N/E
Propylene glycol ether 107-98-2 From 1 to 4.9 percent N/E
Trimethylbenzene 25551-13-7 From 1 to 4.9 percent N/E
1,2,4-Trimethylbenzene 95-63-6 2.9% N/E
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LUBRIZOL?9570CM
Ethylbenzene 100-41-4 0.2% IARC Suspect Carcinogen
(N/E) - None established
4 First Aid Measures
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
Eyes
to do. Continue rinsing. If eye irritation persists, get medical attention.
Wash with plenty of soap and water. Immediately remove contaminated clothing. If skin
Skin
irritation occurs, seek medical attention. Launder contaminated clothing before reuse.
Remove exposed person to fresh air. If breathing is labored, administer oxygen. If breathing
Inhalation
has stopped, apply artificial respiration. Call a poison center or doctor if you feel unwell.
DO NOT INDUCE VOMITING. Aspiration of material due to vomiting can cause chemical
Oral
pneumonitis which can be fatal. Get immediate medical attention. If vomiting occurs
naturally, the casualty should lean forward to reduce the risk of aspiration. Do NOT induce
vomiting. Immediately call a poison center or doctor.
If exposed or concerned: Get medical attention.
Additional Information
5 Fire Fighting Measures
53 癈, 127.4 癋 PMCC (Typical)
Flash Point
CO2, dry chemical, or foam. Water can be used to cool and protect exposed material.
Extinguishing Media
Recommend wearing self-contained breathing apparatus. Water may cause splattering.
Firefighting Procedures
Toxic fumes, gases or vapors may evolve on burning. Vapors may be heavier than air and
Unusual Fire & Explosion
may travel along the ground to a distant ignition source and flash back. Container may
Hazards
rupture on heating. Toxic nitrogen oxides may evolve when burning. The alkyl nitrate
contained in this product may decompose exothermicly if heated above 100?C. Studies in
the Koenen Tube Test indicate that the reaction is non-explosive even when the alkyl nitrate
is present at levels up to 70%.
6 Accidental Release Measures
May form explosive mixtures with air. Immediately evacuate all personnel from danger area.
Spill Procedures
Personal Protective Equipment must be worn, see Personal Protection Section for PPE
recommendations. Eliminate all sources of heat, sparks pilot lights, static electricity and open
flames. Ventilate spill area. Prevent entry into sewers and waterways, dispose of in
accordance with all federal, state and local environmental regulation. Pick up free liquid for
recycle and/or disposal if can be accomplished safely with explosion proof equipment.
Residual liquid can be absorbed on inert material. Check under Transportation and Labeling
(DOT/CERCLA) and Other Regulatory Information Section (SARA) for hazardous
substances to determine regulatory reporting requirements for spills.
7 Handling and Storage
Not determined.
Pumping Temperature
Maximum Handling
Not determined.
Temperature
Handling Procedures
Keep away from ignition sources such as heat, sparks and open flame. No smoking. Keep
containers closed when not in use. Do not discharge into drains or the environment, dispose
to an authorized waste collection point. Use appropriate containment to avoid environmental
contamination. DO NOT HEAT. Avoid breathing dust, fume, gas, mist, vapors or spray.
Ground / bond container and receiving equipment. Use explosion-proof equipment. Use only
non-sparking tools. Wash thoroughly after handling. Empty containers retain material
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LUBRIZOL?9570CM
residue. Do not cut, weld, braze, solder, drill, grind or expose containers to heat, flame, spark
or other sources of ignition.
Maximum Storage
Not determined.
Temperature
Do not store near potential sources of ignition. Isolated outside storage is preferred. Inside
Storage Procedures
storage area should be in a flammable liquids cabinet or storage area. Take precautions to
avoid release to the environment. Store in a cool, dry, well-ventilated area. Keep container
tightly closed.
Not determined.
Loading Temperature
8 Exposure Controls/Personal Protection
Exposure Limits
Exposure Guidelines
OSHA ACGIH Other
Comp TWA STEL TWA STEL TWA STEL
2-Ethylhexyl
N/E N/E N/E N/E 1 ppm (l) N/E
nitrate
Petroleum
N/E N/E N/E N/E 100 ppm (u) N/E
naphtha
Propylene glycol
N/E N/E 100 ppm 150 ppm N/E N/E
ether
Trimethylbenzene N/E N/E 25 ppm N/E N/E N/E
Ethylbenzene 100 ppm N/E 100 ppm 125 ppm N/E N/E
(s) - Skin exposure
(p) - Proposed limit
(c) - Ceiling exposure
(l) - Recommended exposure limit
(u) - Supplier recommended exposure limit
(N/E) - None established
The recommended TWA for 2-Ethylhexyl nitrate is 1 PPM.
Other Exposure Limits
Use local exhaust ventilation to control mists or vapors. Additional ventilation or exhaust
Engineering Controls
may be required to maintain air concentrations below recommended exposure limits. Use
explosion proof equipment.
Nitrile.
Gloves Procedures
Chemical goggles or faceshield.
Eye Protection
Use NIOSH/MSHA approved disposable dust/mist mask if the recommended exposure limit
Respiratory Protection
is exceeded. Use self-contained breathing apparatus for entry into confined space, for other
poorly ventilated areas and for large spill clean-up sites. Consult with an industrial hygienist
to determine the appropriate respiratory protection for your specific use of this material. A
respiratory protection program compliant with all applicable regulations must be followed
whenever workplace conditions require the use of a respirator.
Clothing Recommendation Gloves, coveralls, apron, boots as necessary to minimize contact. Wear either a chemical
protective suit or apron when potential for contact with material exists. Use chemically
protective boots when necessary to avoid contaminating shoes. Do not wear rings, watches or
similar apparel that could entrap the material and cause a burn. Launder contaminated
clothing before reuse.
9 Physical and Chemical Properties
53 癈, 127.4 癋 PMCC (Typical)
Flash Point
Not determined.
Upper Flammable Limit
Not determined.
Lower Flammable Limit
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LUBRIZOL?9570CM
Not determined.
Autoignition Point
Material does not have explosive properties in the liquid state, but vapors may form
Explosion Data
explosive mixtures with air.
Not determined.
Vapor Pressure
Not determined.
pH
0.95 (15.6 癈)
Specific Gravity
Not determined.
Bulk Density
Insoluble.
Water Solubility
Not determined.
Percent Solid
Not determined.
Percent Volatile
Volatile Organic Compound Not determined.
Not determined.
Vapor Density
Not determined.
Evaporation Rate
Pungent
Odor
Amber colored liquid.
Appearance
12 Centistokes (0 癈)
Viscosity
5 Centistokes (25 癈)
3.7 Centistokes (40 癈)
Not determined.
Odor Threshold
Not determined.
Boiling Point
-57 癈, -71 癋
Pour Point Temperature
Not determined.
Melting / Freezing Point
The above data are typical values and do not constitute a specification. Vapor pressure
data are calculated unless otherwise noted.
10 Stability and Reactivity
Material can become unstable at elevated temperatures and pressures.
Stability
Not determined.
Decomposition Temperature
Strong oxidizing agents. Nitriles.
Incompatibility
Will not occur.
Polymerization
Smoke, carbon monoxide, carbon dioxide, aldehydes and other products of incomplete
Thermal Decomposition
combustion. Under combustion conditions, oxides of the following elements will be formed:
nitrogen.
Not determined.
Conditions to Avoid
11 Toxicological Information
-- ACUTE EXPOSURE --
Weak to moderate eye irritant. Does not meet EU R36 criteria. Based on data from similar
Eye Irritation
materials.
Severe skin irritant. Based on data from similar materials. Prolonged or repeated skin contact
Skin Irritation
as from clothing wet with material may cause dermatitis. Symptoms may include redness,
edema, drying, and cracking of the skin.
Nose, throat and lung irritant. Based on data from similar materials. Exposure to a high
Respiratory Irritation
concentration of vapor or mist is irritating to the respiratory tract. Breathing of vapor or mist
may aggravate asthma and inflammatory or fibrotic pulmonary disease. If fatty acids are
over-heated, vapors or entrained mist may cause respiratory irritation.
Dermal Toxicity
The LD50 in rabbits is > 2000 mg/Kg. Based on data from components or similar materials.
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LUBRIZOL?9570CM
Skin absorption of components of this material may cause systemic effects; note toxicity
from other sections. Overexposure to organic nitrates by skin contact may cause headache,
nausea and decreased blood pressure.
The LC50 (1 hr.) in rats for dust or mist of this material is 20 - 200 mg/l. Based on data from
Inhalation Toxicity
components or similar materials. High concentrations may cause headaches, dizziness,
nausea, stupor, and other central nervous system effects leading to visual impairment,
difficulty breathing and convulsions. Overexposure to organic nitrates by inhalation may
cause headache, nausea and decreased blood pressure.
The LD50 in rats is > 10,000 mg/Kg. Based on data from components or similar materials.
Oral Toxicity
Ingestion can cause cyanosis, collapse, and coma.
No data available to indicate product or components may be a skin sensitizer.
Dermal Sensitization
No data available to indicate product or components may be respiratory sensitizers.
Inhalation Sensitization
-- CHRONIC EXPOSURE --
Repeated overexposure to propylene glycol ether may cause lung, liver and kidney damage.
Chronic Toxicity
Prolonged or repeated overexposure to petroleum naphtha may cause liver and kidney
damage.
A National Toxicology Program (NTP) study found an increased incidence of renal tubule
Carcinogenicity
neoplasms in male and female rats exposed to ethylbenzene by inhalation for two years. In
male and female mice similarly exposed, increased incidences of alveolar/bronchiolar
neoplasms, and hepatocellular neoplasms, respectively, were observed. Ethylbenzene has
been classified by IARC as a possible human carcinogen (Group 2B) on the basis of
sufficient evidence of carcinogenicity in experimental animals but inadequate evidence in
exposed humans.
No data available to indicate product or any components present at greater than 0.1% are
Mutagenicity
mutagenic or genotoxic.
No data available to indicate either product or components present at greater than 0.1% that
Reproductive Toxicity
may cause reproductive toxicity.
2-Methoxy-1-propanol caused dose related developmental effects in rabbits following
Teratogenicity
inhalation exposure. The effects included increased fetal resorption, incidence of fetal
visceral and skeletal malformations/variations, and reduced fetal body weights in the absence
of maternal toxicity. In addition, when pregnant rats and rabbits were exposed to 2-
methoxypropanol acetate (which rapidly hydrolyzes to 2-Methoxy-1-propanol in the body)
via inhalation similar developmental effects were observed. The effects in rats included fetal
resorption, thoracic vertebral incision, and split vertebrae while malformations of the
sternum, paws, major blood vessels and heart were observed in rabbits.
-- ADDITIONAL INFORMATION --
No other health hazards known.
Other
12 Ecological Information
-- ENVIRONMENTAL TOXICITY --
The acute LC50 is 10 - 100 mg/L based on component data.
Freshwater Fish Toxicity
Freshwater Invertebrates
The acute EC50 is 1 - 10 mg/L based on component data.
Toxicity
The acute EC50 is 10 - 100 mg/L based on component data.
Algal Inhibition
Not determined.
Saltwater Fish Toxicity
Saltwater Invertebrates
Not determined.
Toxicity
The acute EC50 is 10 - 100 ppm based on component data.
Bacteria Toxicity
Not determined.
Miscellaneous Toxicity
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LUBRIZOL?9570CM
-- ENVIRONMENTAL FATE --
At least 25% of the components in this product show limited biodegradation based on OECD
Biodegradation
301-type test data.
25% or greater of the components potentially bioconcentrate, based on octanol/water
Bioaccumulation
coefficients.
Not determined.
Soil Mobility
13 Disposal Considerations
This material, if discarded, is a hazardous waste under RCRA Regulation 40 CFR 261.
Waste Disposal
Material, if discarded, is expected to be hazardous waste under RCRA due to ignitability
(D001). 0.00008% Benzene, CAS no. 71-43-2, D018. Treatment, storage, transportation, and
disposal must be in accordance with applicable Federal, State/Provincial, and Local
regulations.
14 Transport Information
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Propylene glycol ether), Class 3, PG
ICAO/IATA I
III
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Propylene glycol ether), Class 3, PG
ICAO/IATA II
III, Marine Pollutant (Alkyl C7-C9 nitrates)
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Propylene glycol ether), Class 3, PG
IMDG
III, Marine Pollutant (Alkyl C7-C9 nitrates)
F-E
IMDG EMS Fire
S-E
IMDG EMS Spill
*Subsection 4.2
IMDG MFAG
Not determined.
MARPOL Annex II
Not determined.
USCG Compatibility
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Propylene glycol ether) Class 3, PG
U.S. DOT Bulk
III, Marine Pollutant (Alkyl C7-C9 nitrates), RQ (Xylene)
Not regulated.
U.S. DOT Non-Bulk
128
DOT NAERG
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Propylene glycol ether), Class 3, PG
TDG Bulk
III, Marine Pollutant (Alkyl C7-C9 nitrates)
Not regulated.
TDG Non-Bulk
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Propylene glycol ether), Class 3, PG
Mexico
III, Marine Pollutant (Alkyl C7-C9 nitrates)
Not regulated.
Mexico Non-Bulk
85000 liters, 22457 gal.
Bulk Quantity
207.8 liters, 55 gal.
Non-Bulk Quantity
Review classification requirements before shipping materials at elevated temperatures.
15 Regulatory Information
-- Global Chemical Inventories --
All components of this material are on the US TSCA Inventory or are exempt.
USA
Section 8D (2-Propanol, 1-methoxy-).Section 8D (Benzene, ethyl-).Section 8D (Benzene,
Other TSCA Reg.
trimethyl-).Section 8D (Solvent naphtha (petroleum), light aromatic).
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LUBRIZOL?9570CM
All components are in compliance with the EC Seventh amendment Directive 92 /32/EEC.
EU
This product requires notification in Japan.
Japan
May require notification before sale under Australian regulations.
Australia
May require notification before sale under New Zealand regulations.
New Zealand
All components are in compliance with the Canadian Environmental Protection Act and are
Canada
present on the Domestic Substances List.
All components are in compliance with the Environmentally Hazardous Substances
Switzerland
Ordinance in Switzerland.
This product requires notification before sale in Korea.
Korea
May require notification before sale under Philippines Republic Act 6969.
Philippines
This product requires notification in China.
China
-- Other U.S. Federal Regulations --
This product does not contain greater than 1.0% of any chemical substance on the SARA
SARA Ext. Haz. Subst.
Extremely Hazardous Substances list.
2.9% 1,2,4-Trimethylbenzene, CAS no. 95-63-6; 0.2% Ethylbenzene, CAS no. 100-41-4
SARA Section 313
SARA 311 Classifications Acute Hazard Yes
Chronic Hazard Yes
Fire Hazard Yes
Reactivity Hazard No
CERCLA Hazardous
Substances Transit Reportable Quantities
Reportable Reportable
Component Units Units
Quantity RQ Quantity RQ
Xylene 1523 gal. 5764 liters
Not applicable.
FDA Approval
-- State Regulations --
This product contains the following chemical(s) known to the state of California to cause
Cal. Prop. 65
cancer and/or birth defects: < 1 ppm Benzene, CAS no. 71-43-2 0.002% Toluene, CAS no.
108-88-3 0.005% Naphthalene, CAS no. 91-20-3 0.184% Ethylbenzene, CAS no. 100-41-4
-- Product Registrations --
This fuel additive is registered in the United States.
U.S. Fuel Registration
This product has not been filed with the USDA to support H2 approvals.
U.S. Dept of Agriculture
NSF Nonfood Compounds
This product has not been filed with the NSF to support H1 or H2 approvals.
Registration
Finnish Registration
Not Registered
Number
Swedish Registration
Not Registered
Number
Norwegian Registration
Not Registered
Number
Danish Registration
Not Registered
Number
Not Registered
Swiss Registration Number
Not Registered
Italian Registration Number
Korean Registration
Not Registered
Number
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LUBRIZOL?9570CM
-- Other / International --
None known.
TDG Regulated Limit.
16 Other Information
US NFPA Codes Health Fire Reactivity Special
3 2 1 N/E
(N/E) - None established
HMIS Codes Health Fire Reactivity
3* 2 1
Danger.
Precautionary Labels
Causes severe skin irritation.
Harmful if inhaled.
Causes respiratory tract irritation.
Harmful if absorbed through skin.
Combustible liquid.
Suspected of damaging the unborn child.
May cause eye irritation.
May cause chronic health effects.
Revision Indicators Section: 2 Principal hazards. Changed: 31 March 2009
Section: 3 Hazardous ingredients. Changed: 29 March 2009
Section: 4 Additional first aid measures. Changed: 29 March 2009
Section: 4 Inhalation first aid. Changed: 29 March 2009
Section: 4 Oral first aid. Changed: 29 March 2009
Section: 4 Skin first aid. Changed: 29 March 2009
Section: 7 Handling procedures. Changed: 29 March 2009
Section: 7 Storage procedures. Changed: 19 July 2008
Section: 8 Clothing recommendations. Changed: 29 March 2009
Section: 8 Eye protection. Changed: 29 March 2009
Section: 8 Hazardous ingredients. Changed: 29 March 2009
Section: 8 Respiratory protection. Changed: 29 March 2009
Section: 8 Ventilation procedures. Changed: 27 May 2009
Section: 9 Odor threshold. Changed: 1 April 2009
Section: 9 Percent volatile. Changed: 11 December 2008
Section: 11 Inhalation toxicity. Changed: 27 May 2009
Section: 11 Oral toxicity. Changed: 27 May 2009
Section: 11 Teratogenicity. Changed: 11 December 2008
Section: 13 Waste disposal. Changed: 27 May 2009
Section: 15 MISC. Regulatory info. Changed: 19 July 2008
Section: 16 HMIS codes. Changed: 29 March 2009
Section: 16 Miscellaneous information. Changed: 19 July 2008
Section: 16 NFPA Codes. Changed: 29 March 2009
Section: 16 Principal hazards. Changed: 31 March 2009
As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim
any liability for any use of this product. Information contained herein is believed to be true and accurate but all
statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the
hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all
applicable federal, state, and local regulations remains the responsibility of the user.
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