Spartan Chemical Company, Inc.
Material Safety Data Sheet
SECTION I: PRODUCT INFORMATION
Product Name or Number (as it appears on label): Product Division:
Janitorial
ORANGE TOUGH 40
Product Number: 2240
Spartan Chemical Company, Inc. Product/Technical Information: 1-(800)-537-8990
1110 Spartan Drive Medical Emergency: 1-(888)-314-6171 (24 hours)
Maumee OH 43537
Chemical Leak/Spil Emergency: CHEMTREC 1-(800) 424-9300 (24 hours)
Shipping Description: Cleaning compounds, liquid, n.o.s.
NFPA Ratings: HMIS Ratings:
Health: 2 - Moderate Health: 2 - Moderate
Fire: 2 - Moderate Fire: 2 - Moderate
Reactivity: 0 - Minimal Reactivity: 0 - Minimal
Pers. Prot. Equip.: See Section VIII
SECTION II: HAZARDOUS INGREDIENTS
(Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from
listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency.
Table Z-1-A
CAS
NTP, IARC
TWA STEL CEILING
Registry
or OSHA
3 3 3
mg/m mg/m mg/m
Chemical Name(s) %Wt No.
Carcinogen
d-limonene 35-40 5989-27-5 Not Established Not Established Not Established No
Nonyl phenol ethoxylate 10-15 127087-87-0 Not Established Not Established Not Established No
Triethanolamine 05-10 27323-41-7 Not Established Not Established Not Established No
dodecylbenzenesulfonate - - - - - -
Triethanolamine 05-10 102-71-6 5 (ACGIH) Not Established Not Established No
Hexylene glycol 01-05 107-41-5 Not Established Not Established 121 (NIOSH) No
Dicarboxylic fatty acid, 01-05 66375-37-9 Not Established Not Established Not Established No
dipotassium salt - - - - - -
Tetrasodium ethylene 01-05 64-02-8 Not Established Not Established Not Established No
diaminetetraacetate - - - - - -
SECTION III: PHYSICAL DATA
Boiling Point: >212 癋 Vapor Pressure: Unknown
Vapor Density (AIR = 1): Unknown Solubility in Water: Emulsifiable
pH: 9.0 Specific Gravity (H O=1): 0.96
2
Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: 20-25
Physical State: Liquid
Appearance & Odor: Clear, orange liquid. Orange citrus fragrance.
SECTION IV: FIRE & EXPLOSIVE HAZARD DATA
Flash Point: 124癋 Method Used: ASTM-D56
Flammable Limits: Unknown Flame Extension: N/A
Extinguishing Media: Foam, dry chemical, carbon dioxide, water fog or spray
Special Fire Fighting Procedures: Wear NIOSH approved self-contained breathing apparatus and protective clothing. Cool fire-exposed
containers with water spray.
Unusual Fire & Explosive Hazards: Combustible liquid and vapor. Keep away from heat, sparks or flame. Combustion products are toxic.
SECTION V: HEALTH HAZARD DATA
Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes and
Oral
Effects of Overexposure- Causes eye irritation: Symptoms may include pain, redness and swelling of the conjunctiva.
Conditions to Avoid: Causes skin irritation: Symptoms may include redness, pain and swelling.
Harmful if swallowed: Symptoms may include pain, nausea, vomiting and diarrhea.
Breathing product vapors or mist may cause respiratory irritation: Symptoms may include nasal
discomfort and coughing. Contains d-limonene, hexylene glycol and triethanolamine which may cause
skin sensitization with repeated contact. Repeated overexposure to triethanolamine may cause liver and
kidney damage.
Avoid contact with eyes, skin and clothing. Avoid breathing product vapors or mists. Do not
swallow. Use with adequate ventilation. Wash thoroughly after handling.
Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and
dermatitis.
Emergency & First Aid Procedures:
Eyes: Flush eyes with water for at least 15 minutes. Remove contact lenses. Get medical attention.
Skin: Remove contaminated clothing. Flush skin with water for at least 15 minutes. Get medical attention if
irritation persists. Wash contaminated clothing before reuse.
Ingestion: Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do
not give anything by mouth to an unconscious person.
Inhalation: Move person to fresh air. Get medical attention if irritation persists.
SECTION VI: REACTIVITY DATA
Stability: Stable Incompatible Materials: Strong oxidants
Hazardous Decomposition Products: CO, CO Hazardous Polymerization: Will Not Occur
2
SECTION VII: SPILL OR LEAK PROCEDURES
Steps to be Taken in Case
Material is Released or Spilled: Dike and contain spill with inert material (sand, earth, commercial absorbent, etc.) and transfer to
containers for disposal. Keep spill out of storm sewers and waterways.
Waste Disposal Method: Dispose of in compliance with all federal, state and local laws and regulations.
SECTION VIII: SPECIAL PROTECTION INFORMATION
Respiratory Protection: Not normally required when good general ventilation is provided. However if exposure limits are exceeded
(see Section II) or if respiratory irritation occurs, the use of a NIOSH approved respirator suitable for the
use-conditions and chemicals listed in Section II should be considered.
Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations.
Protective Gloves(Specify Type): Rubber or other impervious gloves.
Eye Protection(Specify Type): Splash goggles are recommended to prevent eye contact.
Other Protective Equipment: See 29 CFR 1910.132-138 for further guidance.
SECTION IX: SPECIAL PRECAUTIONS
Precautions; Handling & Storing: Combustible liquid and vapors. Flash Point 124癋. Keep away from heat, sparks, or open flame. Keep
container tightly closed. Store in a cool, dry area. Do not store above 120癋.
Other Precautions: Keep out of reach of children.
?SCC 06/30/2005 Name: Title:
Ronald T. Cook Manager, Regulatory Affairs
Effective Date: 06/30/2005 Supercedes: 01/01/2005
ORANGE TOUGH 40
Ref: 29 CFR 1910.1200 (OSHA) Changes: Update Section IX
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as
to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to
evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations.
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