MATERIAL SAFETY DATA SHEET
Review Date: 11/28/2006
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
SHELL METALINA?B 3650
PRODUCT:
MSDS NUMBER: 403192L - 0
PRODUCT CODE(S): 5072698
PRODUCT USE: Metal Working Fluid
MANUFACTURER TELEPHONE NUMBERS
SOPUS Products Spill Information: (877) 242-7400
P.O. Box 4427 Health Information: (877) 504-9351
Houston, TX. 77210-4427 MSDS Assistance Number: (877) 276-7285
SECTION 2 PRODUCT/INGREDIENTS
INGREDIENTS CAS# CONCENTRATION
Metal Working Fluid
Deionized water and Biocide Mixture 40 - 60 %weight
2-Amino ethanol 141-43-5 3-9 %weight
Triethanolamine 102-71-6 10 - 20 %weight
Proprietary polymer additives Mixture 15 - 25 %weight
SECTION 3 HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Appearance & Odor: Amber liquid. Mild odor.
Health Hazards: May be harmful if absorbed through the skin. Causes severe eye irritation. May be harmful or
fatal if swallowed. May cause skin irritation. Toxic and harmful if inhaled.
NFPA Rating (Health, Fire, Reactivity): 1, 1, 0
Hazard Rating: Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4
Route(s) of Exposure: Eye, Inhalation, Skin
Inhalation:
Toxic and harmful if inhaled.
Eye Irritation:
Severely irritating to the eyes causing pain, redness, swelling and blurred vision.
Skin Contact:
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May be irritating to the skin causing a burning sensation, redness and/or swelling. Slightly toxic and may be harmful if
absorbed through the skin.
Ingestion:
May be harmful or fatal if swallowed. Developmental Toxicity, Genotoxicity
Primary Target Organs:
The following organs and/or organ systems may be damaged by overexposure to this material and/or its components:
Kidney, Lungs
Signs and Symptoms:
Lung damage (scarring, bronchitis, emphysema) may be indicated by shortness of breath, especially on exertion and may
be accompanied by chronic cough. Kidney damage may be indicated by changes in urine output or appearance, pain
upon urination or in the lower back or general edema (swelling from fluid retention).
For additional health information, refer to section 11.
SECTION 4 FIRST AID MEASURES
Inhalation:
If the victim has difficulty breathing or tightness of the chest, is dizzy, vomiting or unresponsive, give 100% oxygen with
rescue breathing or CPR as required and transport to the nearest medical facility.
Skin:
Flush exposed area with water and follow by washing with soap if available. Remove contaminated clothing. If redness,
swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment.
Eye:
Immediately flush eyes with large amounts of water for at least 30 minutes, by the clock, while holding eyelids open.
Transport to nearest medical facility for additional treatment.
Ingestion:
DO NOT induce vomiting. DO NOT take internally. Have victim rinse mouth out with water, then drink sips of water to
remove taste from mouth. If the victim is coughing, choking, has shortness of breath, or difficulty breathing, transport to
the nearest medical facility for additional treatment. If any of the following delayed signs and symptoms appear within the
next 6 hours, transport to the nearest medical facility: fever greater than 101?F, shortness of breath, chest congestion or
continued coughing or wheezing. If vomiting occurs spontaneously, keep head below hips to prevent aspiration.
SECTION 5 FIRE FIGHTING MEASURES
Flash Point [Method]: >500 篎/>260 篊
Upper Flammability Limit: Not Determined
Lower Flammability Limit: Not Determined
Extinguishing Media:
Use water fog, 'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use a direct stream of
water.
Fire Fighting Instructions:
Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coats, gloves and rubber boots),
including a positive pressure, NIOSH approved, self-contained breathing apparatus. This material is non-flammable.
SHELL METALINA?B 3650 MSDS# 403192L
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Unusual Fire Hazards:
Material may ignite when preheated.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Protective Measures:
May burn although not readily ignitable.
Wear appropriate personal protective equipment when cleaning up spills. Refer to Section 8.
Spill Management:
Flush area with water to remove trace residue; place flush solution in proper container for recycle or disposal. Shut off
source of leak if safe to do so. Dike and contain spill.
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place in
non-leaking container and seal tightly for proper disposal.
SECTION 7 HANDLING AND STORAGE
Precautionary Measures:
Wash with soap and water before eating, drinking, smoking, applying cosmetics, or using toilet. Launder contaminated
clothing before reuse. Properly dispose of contaminated leather articles such as shoes or belts that cannot be
decontaminated. Do not take internally. Do not taste or swallow. Avoid heat, open flames, including pilot lights, and
strong oxidizing agents. Use explosion-proof ventilation to prevent vapor accumulation. Ground all handling equipment to
prevent sparking. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling.
Storage:
Do not store in open or unlabeled containers. Store in a cool, dry place with adequate ventilation. Keep away from open
flames and high temperatures.
Container Warnings:
Keep containers closed when not in use. Containers, even those that have been emptied, can contain explosive vapors.
Do not cut, drill, grind, weld or perform similar operations on or near containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Chemical Limit TWA STEL Ceiling Notation
2-Amino-Ethanol ACGIH TLV 3 ppmv 6 ppmv
OSHA PEL -
2-Amino-Ethanol 3 ppmv 6 mg/m3
1989(revoked)
Triethanolamine ACGIH TLV 5 mg/m3
Exposure Controls
Provide adequate ventilation to control airborne concentrations below the exposure guidelines/limits. Eye washes
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and showers for emergency use.
Personal Protection
Personal protective equipment (PPE) selections vary based on potential exposure conditions such as handling practices,
concentration and ventilation. Information on the selection of eye, skin and respiratory protection for use with this material
is provided below.
Eye Protection:
Chemical Goggles / Face Shield
Skin Protection:
Use protective clothing which is chemically resistant to this material. Selection of protective clothing depends on potential
exposure conditions and may include gloves, boots, suits and other items. The selection(s) should take into account such
factors as job task, type of exposure and durability requirements.
Published literature, test data and/or glove and clothing manufacturers indicate the best protection is provided by:
Neoprene, or Nitrile Rubber
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an
approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the
requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134.
Types of respirator(s) to be considered in the selection process include:
For Mist: Air Purifying, R or P style NIOSH approved respirator.
For Vapors: Air Purifying, R or P style prefilter & organic cartridge, NIOSH approved respirator. Self-contained
breathing apparatus for use in environments with unknown concentrations or emergency situations.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance & Odor: Amber liquid. Mild odor.
Physical State: Liquid
Density 9.05 lb/gal Flash Point > 500 篎
Solubility (in Water) Completely Soluble Specific Gravity 1.05
Stability Stable
Odor Threshold: Not Determined
Partition Coefficient: Not Determined
pH: 9.5 - 10.4
SECTION 10 REACTIVITY AND STABILITY
Stability:
Material is stable under normal conditions.
Hazardous Decomposition Products:
Thermal decomposition products are highly dependent on combustion conditions. A complex mixture of airborne solids,
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liquids and gases will evolve when this material undergoes pyrolysis or combustion. Carbon Monoxide, Carbon Dioxide,
Formaldehyde, Nitrogen Oxides and other unidentified organic compounds may be formed upon combustion.
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity
TEST Result OSHA Material Tested
Classification
Dermal LD50 1000 mg/kg(Rabbit) Non-Toxic Based on components(s)
Oral LD50 1720 mg/kg(Rat) Non-Toxic Based on components(s)
Carcinogenicity Classification
Chemical Name NTP IARC ACGIH OSHA
Metal Working Fluid No No No No
Toxic Effects - Metalina B 3650
Oral exposures of pregnant rats to maternally toxic doses of a product component have
Developmental
been embryotoxic.
Toxicity
A component of this product was mutagenic in in-vitro (test tube) testing. It was not
Genotoxicity
mutagenic in animal tests.
Prolonged and repeated exposure to one or more components has produced kidney and
Kidney
liver damage in animal tests.
Rats and mice exposed to vapor or mist of a component for an unspecified length of time
Lungs
developed pulmonary, liver and kidney lesions.
May cause skin sensitization. Based on components.
Sensitization
SECTION 12 ECOLOGICAL INFORMATION
Environmental Impact Summary:
There is no ecological data available for this product.
SECTION 13 DISPOSAL CONSIDERATIONS
RCRA Information:
Under RCRA, it is the responsibility of the user of the material to determine, at the time of the disposal, whether the
material meets RCRA criteria for hazardous waste. This is because material uses, transformations, mixtures, processes,
etc. may affect the classification. Refer to the latest EPA, state and local regulations regarding proper disposal.
SECTION 14 TRANSPORT INFORMATION
SHELL METALINA?B 3650 MSDS# 403192L
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US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
International Air Transport Association
Not regulated under IATA rules.
International Maritime Organization Classification
Not regulated under International Maritime Organization rules.
SECTION 15 REGULATORY INFORMATION
Federal Regulatory Status
OSHA Classification:
Product is hazardous according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
WHMIS Classification: Not a controlled substance.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
Clean Air Act (CAA):
This material is classified as a Hazardous Air Pollutant under the Clean Air Act (CAA).
Ozone Depleting Substances (40 CFR 82 Clean Air Act):
This material does not contain nor was it directly manufactured with any Class I or Class II ozone depleting substances.
Superfund Amendment & Reauthorization Act (SARA) Title III:
There are no components in this product on the SARA 302 list.
SARA Hazard Categories (311/312):
Immediate Health Delayed Health Fire Pressure Reactivity
YES NO NO NO NO
SARA Toxic Release Inventory (TRI) (313):
There are no components in this product on the SARA 313 list.
Toxic Substances Control Act (TSCA) Status:
All component(s) of this material is(are) listed on the EPA/TSCA Inventory of Chemical Substances.
Other Chemical Inventories:
Component(s) of this material is (are) listed on the Australian AICS, Canadian DSL, Chinese Inventory, European
EINECS, Korean Inventory, Philippines PICCS,
State Regulation
The following chemicals are specifically listed by individual states; other product specific health and safety data in other
sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you
should contact the appropriate agency in your state.
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New Jersey Right-To-Know Chemical List:
2-Amino-Ethanol 3 - 9 %weight
2-Amino-Ethanol 3 - 9 %weight Special Hazard
Pennsylvania Right-To-Know Chemical List:
2-Amino-Ethanol 3 - 9 %weight
Triethanolamine 10 - 20 %weight
SECTION 16 OTHER INFORMATION
Revision#: 0
Revision Date: 11/28/2006
Review Date: 11/28/2006
Revisions since last change (discussion): This Material Safety Data Sheet (MSDS) has been created to fully
comply with the guidance contained in the ANSI MSDS standard (ANSI Z400.1-2003). We encourage you to
take the opportunity to read the MSDS and review the information contained therein.
SECTION 17 LABEL INFORMATION
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT.
THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29
CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING
INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE
CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS.
PRODUCT CODE(S): 5072698
SHELL METALINA?B 3650
WARNING!
May be harmful if absorbed through the skin. MAYBE HARMFUL IF SWALLOWED. CAUSES SEVERE EYE
IRRITATION. MAY CAUSE SKIN IRRITATION. PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE OIL
ACNE OR DERMATITIS. The following organs and/or organ systems may be damaged by overexposure to this
material and/or its components.
MAY CAUSE DAMAGE TO: Kidney, LungsDevelopmental Toxicity, Genotoxicity
Precautionary Measures:
Avoid contact with skin and clothing. Avoid breathing of vapors, fumes, or mist. Do not take internally. Use only
with adequate ventilation. Keep container closed when not in use. Wash thoroughly after handling.
FIRST AID
Inhalation: DO NOT attempt to rescue victim unless proper respiratory protection is worn. If the victim has difficulty
breathing or tightness of the chest, is dizzy, vomiting or unresponsive, give 100% oxygen with rescue breathing or CPR as
required and transport to the nearest medical facility.
SHELL METALINA?B 3650 MSDS# 403192L
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Skin Contact: Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if
available. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment.
Eye Contact: Immediately flush eyes with large amounts of water for at least 30 minutes, by the clock, while holding
eyelids open. Transport to nearest medical facility for additional treatment.
Ingestion: DO NOT induce vomiting. DO NOT take internally. If vomiting occurs spontaneously, keep head below hips
to prevent aspiration. Have victim rinse mouth out with water, then drink sips of water to remove taste from mouth. If the
victim is coughing, choking, has shortness of breath, or difficulty breathing, transport to the nearest medical facility for
additional treatment. If any of the following delayed signs and symptoms appear within the next 6 hours, transport to the
nearest medical facility: fever greater than 101?F, shortness of breath, chest congestion or continued coughing or
wheezing.
FIRE
In case of fire, Use water fog, 'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use a
direct stream of water.
SPILL OR LEAK
Dike and contain spill.
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place in
non-leaking container and seal tightly for proper disposal.
CONTAINS: Deionized water and Biocide, Mixture; 2-Amino ethanol, 141-43-5; Triethanolamine, 102-71-6; Proprietary
polymer additives, Mixture
NFPA Rating (Health, Fire, Reactivity): 1, 1, 0
TRANSPORTATION
US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
Name and Address
SOPUS Products
P.O. Box 4427
Houston, TX 77210-4427
ADMINISTRATIVE INFORMATION
MANUFACTURER ADDRESS: SOPUS Products, P.O. Box 4427, Houston, TX. 77210-4427
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO US AT THIS TIME,
AND IS BELIEVED TO BE ACCURATE BASED UPON THAT : IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF
THE PRODUCT, FOR PURPOSE OF HAZARD COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE
PRODUCT PERFORMANCE INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE
WITH RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN. YOU ARE
URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE, AND ARE
ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE
INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE
PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT
SHELL METALINA?B 3650 MSDS# 403192L
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AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM
THE USE OF THE PRODUCT DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED
HEREIN AS A RESULT OF THAT DATA, IS THE PROPERTY OF SOPUS PRODUCTS AND IS NOT TO BE THE
SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF SOPUS PRODUCTS.
44774-12792-100R-11/28/2006
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