Schering-Plough HealthCare Products Canada,
a division of Schering-Plough Canada Inc.
3535 Trans-Canada
Pointe-Claire, Quebec
Canada H9R 1B4
MATERIAL SAFETY DATA SHEET
Schering-Plough urges each user or recipient of this MSDS to read the entire data sheet to become aware of the hazards associated with this
material.
SECTION 1. IDENTIFICATION OF SUBSTANCE AND CONTACT INFORMATION
MSDS NAME: Coppertone Emulsion Lotions
SYNONYM(S): Coppertone Kids Colorblock Lotion (Blue, Purple) SPF 30-40
Coppertone Kids Lotion SPF 30-50
Coppertone Kids Lotion SPF 30 w ith Parsol-1789
Coppertone Kids Sunblock Lotion SPF 45
Coppertone Kids UVA Guard Lotion SPF 30
Coppertone Lotion Spray (Waterproof) SPF 30
Coppertone Shade UVA Guard Lotion SPF 30-45
Coppertone Shade Waterproof Lotion SPF 45
Coppertone Sport Trigger Spray Lotion SPF 30
Coppertone Waterbabies Broad Spectrum UVA/UVB Sunblock Lotion SPF 45
Coppertone Waterbabies Lotion SPF 30-50
Coppertone Waterbabies Spray Lotion SPF 50
Coppertone UltraGuard Lotion SPF 15-50
MSDS NUMBER: SP000039
EMERGENCY NUMBER(S): Schering-Plough Security Control Center (908) 820-6921 (24 Hours)
Transportation Emergencies - CANUTEC:
(613) 996-6666 (Canada)
INFORMATION: Schering-Plough HealthCare Products Canada
Customer Service (English): 1-800-361-6550
Service ?la client鑜e (French): 1-800-361-2431
SCHERING-PLOUGH MSDS HELPLINE: (800) 770-8878 (US and Canada)
(908) 473-3371 (Worldw ide)
Monday to Friday, 9am to 5pm (US Eastern Time)
SECTION 2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Lotion
Color according to product specification
Product-specific odor
Consumers: Refer to the package insert or product label for appropriate consumer-specific information about this product w hen used according to
manufacturer's directions.
POTENTIAL HEALTH EFFECTS:
Although some ingredients used in the manufacture of this product are considered hazardous on an individual basis, the final formulation of this
product is considered non-hazardous w hen used according to manufacturer's directions.
The health hazard information presented is based on studies conducted using the maximum concentrations of the active ingredients in formulations
similar to that of this product. Any health effects w ould be expected to be similar to or less than those observed in those studies.
These products have been show n to be not sensitizing to human skin. These products may cause slight skin irritation under occulsive conditions.
Eye contact may cause slight eye irritation w ith temporary stinging, redness, tearing, and increased blinking.
Coppertone Emulsion Lotions MSDS NUMBER: SP000039
Latest Revision Date: 07-May-2009 Page 1 of 6
LISTED CARCINOGENS
Triethanolamine is classified by IARC as a Group 3 carcinogen (unclassifiable as to carcinogenicity in humans).
SECTION 3. COMPOSITION AND INFORMATION ON INGREDIENTS
PRODUCT USE: Consumer product
CHEMICAL FORMULA: Mixture.
The formulations for these products are proprietary information. These formulations have the same hazardous profile; how ever, the presence of
hazardous ingredients may vary by formulation. Only hazardous ingredients in concentrations of 1% or greater and/or carcinogenic ingredients in
concentrations of 0.1% or greater are listed in the Chemical Composition table. Active ingredients in any concentration are listed.
CHEMICAL COMPOSITION
INGREDIENT CAS NUMBER PERCENT
Homosalate 118-56-9 0-15
Octocrylene 6197-30-4 0-10
Octinoxate 5466-77-3 0-7.5
Oxybenzone 131-57-7 0-6
Octisalate 118-60-5 0-5
Avobenzone 70356-09-1 0-3
Sorbitol 50-70-4 <10
Sorbitan Isostearate 71902-01-7 <10
Octadecene/MA Copolymer 25266-02-8 <10
Triethanolamine 102-71-6 <10
Stearic Acid 57-11-4 <10
Isopropyl Myristate 110-27-0 <10
Aluminum Starch Octenylsuccinate 9087-61-0 <10
Barium Sulfate 7727-43-7 <10
Benzyl Alcohol 100-51-6 <10
ADDITIONAL INFORMATION: This MSDS is w ritten to provide health and safety information for individuals w ho w ill be handling the
final product formulation during research, manufacturing, and distribution. For health and safety
information for individual ingredients used during manufacturing, refer to the appropriate MSDS for each
ingredient. Refer to the package insert or product label for handling guidance for the consumer.
SECTION 4. FIRST AID MEASURES
INHALATION: Remove to fresh air. If any trouble breathing, get immediate medical attention. Administer artificial
respiration if breathing has ceased. If irritation or symptoms occur or persist, consult a physician.
SKIN CONTACT: In keeping w ith good hygienic practices, w ash exposed areas thoroughly w ith soap and w ater.
EYE CONTACT: As w ith any material contacting the eye, it is recommended to rinse eyes w ith w ater.
INGESTION: Rinse mouth w ith w ater. If symptoms develop, consult a physician.
SECTION 5. FIRE FIGHTING MEASURES
FLAMMABILITY DATA:
Flash Point: >93 deg C ( >199.4 deg F )
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing and self-contained breathing apparatus (SCBA).
SUITABLE EXTINGUISHING MEDIA:
Carbon dioxide (CO2), extinguishing pow der or w ater spray.
Coppertone Emulsion Lotions MSDS NUMBER: SP000039
Latest Revision Date: 07-May-2009 Page 2 of 6
SECTION 5. FIRE FIGHTING MEASURES
See Section 9 for Physical and Chemical Properties.
SECTION 6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS:
Wear appropriate personal protective equipment as specified in Section 8. Keep personnel aw ay from the clean-up area.
SPILL RESPONSE / CLEANUP:
All spills should be handled according to site requirements and based on precautions cited in the MSDS. In the case of liquids, use proper absorbent
materials. For laboratories and small-scale operations, incidental spills w ithin a hood or enclosure should be cleaned by using a HEPA filtered vacuum
or w et cleaning methods as appropriate. For large dry or liquid spills or those spills outside enclosure or hood, appropriate emergency response
personnel should be notified. In manufacturing and large-scale operations, HEPA vacuuming prior to w et mopping or cleaning is required.
See Sections 9 and 10 for additional physical, chemical, and hazard information.
SECTION 7. HANDLING AND STORAGE
HANDLING:
Keep containers adequately sealed during material transfer, transport, or w hen not in use.
Appropriate handling of this material is dependent on many factors, including physical form, duration and frequency of process or task, and
effectiveness of engineering controls. Site-specific risk assessments should be conducted to determine the feasibility and the appropriateness of all
exposure control measures. See Section 8 (Exposure Controls) for additional guidance.
STORAGE:
Store in a cool, dry, w ell ventilated area.
See Section 8 for exposure controls and additional safe handling information.
SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
EXPOSURE CONTROLS:
The health hazard risks of handling this material are dependent on many factors, including physical form, duration and frequency of process or task,
and effectiveness of engineering controls. Site-specific risk assessments should be conducted to determine the feasibility and the appropriateness
of all exposure control measures. Exposure controls for normal operating or routine procedures follow a tiered strategy. Engineering controls are
the preferred means of long-term or permanent exposure control. If engineering controls are not feasible, appropriate use of personal protective
equipment (PPE) may be considered as alternative control measures. Exposure controls for non-routine operations must be evaluated and
addressed as part of the site-specific risk assessment.
RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE):
Respiratory Protection: None required for consumer use of this product.
Respiratory protective equipment (RPE) may be required for certain laboratory and large-scale
manufacturing tasks if potential airborne breathing zone concentrations of substances exceed the
relevant exposure limit(s). Workplace risk assessment should be completed before specifying and
implementing RPE usage. Potential exposure points and pathw ays, task duration and frequency,
potential employee contact w ith the substance, and the ability of the substance to be rendered airborne
during specific tasks should be evaluated. Initial and ongoing strategies of quantitative exposure
measurement should be obtained as required by the w orkplace risk assessment. All RPE must conform
to local and regional specifications for efficacy and performance. Consult your site or corporate health
and safety professional for additional guidance.
Skin Protection: None required for consumer use of this product.
Gloves that provide an appropriate barrier to the skin are recommended if there is potential for contact
w ith this material. Consult your site safety staff for guidance.
Eye Protection: None required for consumer use of this product.
Safety glasses w ith side shields. Use of goggles or full face protection may be required based on
hazard, potential for contact, or level of exposure. Consult your site safety staff for guidance.
Coppertone Emulsion Lotions MSDS NUMBER: SP000039
Latest Revision Date: 07-May-2009 Page 3 of 6
Body Protection: None required for consumer use of this product.
In small-scale or laboratory operations, lab coats or equivalent protection is required. Disposable Tyvek
or other dust impermeable suit should be considered based on procedure or level of exposure. Use of
additional PPE such as shoe coverings, gauntlets, hood, or head covering may be necessary. Consult
your site safety staff for guidance.
In large-scale or manufacturing operations, disposable Tyvek or other dust impermeable suit is
recommended and based on level of exposure. Use of additional PPE such as shoe coverings,
gauntlets, hood, or head covering may be necessary. Consult your site safety staff for guidance.
EXPOSURE LIMIT VALUES
INGREDIENT CAS NUMBER ACGIH TLV (TWA) OSHA PEL (TWA)
Triethanolamine 102-71-6 5 mg/m3
Barium Sulfate 7727-43-7 10 mg/m3 5 mg/m3
Fields in the above table(s) that do not contain data indicate that exposure limits are not available for those endpoints.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
FORM: Lotion
COLOR: Color according to product specification
ODOR: Product-specific odor
pH: 6.5-8.8
BOILING POINT / RANGE: >93 deg C
SPECIFIC GRAVITY: 1.01-1.05
SOLUBILITY:
Water: Slightly soluble
See Section 5 for flammability/explosivity information.
SECTION 10. STABILITY AND REACTIVITY
STABILITY/ REACTIVITY:
Stable under normal conditions.
INCOMPATIBLE MATERIALS / CONDITIONS TO AVOID:
Strong acids and bases.
SECTION 11. TOXICOLOGICAL INFORMATION
These data are from studies using the maximum concentrations of the active ingredients in the final formulation.
ACUTE TOXICITY DATA
SKIN:
Slightly irritating.
EYE:
Slightly irritating.
ORAL:
Practically not toxic.
SENSITIZATION:
Not sensitizing.
REPEAT DOSE TOXICITY DATA
CARCINOGENICITY:
This material or product has not been evaluated for carcinogenicity.
Coppertone Emulsion Lotions MSDS NUMBER: SP000039
Latest Revision Date: 07-May-2009 Page 4 of 6
SECTION 12. ECOLOGICAL INFORMATION
ECOTOXICITY DATA
This product has not been tested for ecotoxicity.
ENVIRONMENTAL DATA
There are no environmental data available for this product.
SECTION 13. DISPOSAL CONSIDERATIONS
MATERIAL WASTE:
Disposal must be in accordance w ith applicable federal, state/provincial, and/or local regulations. Incineration is the preferred method of disposal,
w hen appropriate. Operations that involve the crushing or shredding of w aste materials or returned goods must be handled to meet the
recommended exposure limit(s).
PACKAGING AND CONTAINERS:
Disposal must be in accordance w ith applicable federal, state/provincial, and/or local regulations.
SECTION 14. TRANSPORT INFORMATION
This material is not subject to the transportation regulations of DOT, IATA, IMO, and the ADR.
SECTION 15. REGULATORY INFORMATION
WHMIS CLASSIFICATIONS:
This product has been classified in accordance w ith the hazard criteria on the Controlled Products Regulations and the MSDS contains all the
information required by the Controlled Products Regulations. The final packaged product is not subject to WHMIS classification. The follow ing
classification applies to the bulk formulation handled in the w orkplace.
This product does not meet classification requirements according to WHMIS criteria.
TSCA LISTING
INGREDIENT TSCA
Homosalate X
Octocrylene X
Octinoxate X
Oxybenzone X
Octisalate X
Avobenzone X
Sorbitol X
Sorbitan Isostearate X
Octadecene/MA Copolymer X
Triethanolamine X
Stearic Acid X
Isopropyl Myristate X
Aluminum Starch Octenylsuccinate X
Barium Sulfate X
Benzyl Alcohol X
Coppertone Emulsion Lotions MSDS NUMBER: SP000039
Latest Revision Date: 07-May-2009 Page 5 of 6
SECTION 16. OTHER INFORMATION
Although reasonable care has been taken in the preparation of this document, w e extend no w arranties and make no representations as to the
accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's
intended purposes or for the consequence of its use. Each individual should make a determination as to the suitability of the information for their
particular purpose(s).
DEPARTMENT ISSUING MSDS: Global Safety and Environmental Affairs
Occupational and Environmental Toxicology
Schering-Plough Corporation
556 Morris Avenue
Summit, NJ 07901 USA
SCHERING-PLOUGH MSDS HELPLINE: (800) 770-8878 (US and Canada)
(908) 473-3371 (Worldw ide)
Monday to Friday, 9am to 5pm (US Eastern Time)
MSDS CREATION DATE: 18-Aug-1999
SUPERSEDES DATE: 02-Sep-2008
SECTIONS CHANGED (CAN SUBFORMAT): 1, 5, 9
SIGNIFICANT CHANGES (CAN SUBFORMAT): Synonyms
Coppertone Emulsion Lotions MSDS NUMBER: SP000039
Latest Revision Date: 07-May-2009 Page 6 of 6
|