Page 1 of 8 / V3
Date of Issue: May 2010
SAFETY DATA SHEET
Section 1: IDENTIFICATION OF THE MATERIAL AND SUPPLIER
TALON?Rodenticide Wax Blocks
Product Name:
Other Names: Product code: A12720B
Recommended Use: Rodenticide
Company Details: Syngenta Crop Protection Pty Limited
ABN 33 002 933 717
Address: Level 1, 2-4 Lyonpark Road
MACQUARIE PARK NSW 2113
AUSTRALIA
Telephone Number: (02) 8876 8444
Emergency Telephone Number: 24 hours - 1800 033 111
Section 2: HAZARDS IDENTIFICATION
Hazard Classification: Not classified as a hazardous chemical according to the
Australian criteria for the classification of chemicals
Risk Phrases: ?br>
Safety Phrases: ?br>
Section 3: COMPOSITION / INFORMATION ON INGREDIENTS
SUBSTANCE
Chemical Identity of Pure Substance: Brodifacoum
Synonym: PP581
CAS Number: 56073-10-0
MIXTURE
Chemical Identity of Ingredients CAS No Proportion
(% w/w
Brodifacoum 56073-10-0 0.005
Propane-1,2-diol 57-55-6 <0.5
Triethanolamine 102-71-6 <0.1
Bitrex (bittering agent) 3734-33-6 0.01
Other ingredients determined not to be hazardous - to 100
Syngenta Crop Protection Pty Ltd Page 2 of 8
TALON?Rodenticide Wax Blocks May 2010
Section 4: FIRST AID MEASURES
Description of Necessary In case of poisoning by any exposure route get to a doctor or hospital
First Aid Measures: quickly. Phone Poisons Information Centre on 131 126.
Have the product label or SDS with you when calling or going for
treatment. Vitamin K1 (Phytomenadione) is antidotal.
Ingestion: HUMANS: Rinse mouth with water. Give plenty of
water to drink. If vomiting occurs give further water.
Seek medical advice.
DOMESTIC ANIMALS: If severe signs of poisoning,
immediately transport to veterinarian.
For early signs of poisoning, transport to
veterinarian.
No signs but suspected bait consumption, induce
vomiting only if ingestion is recent (less than six
hours). Make up a solution of salty water (2-3
tablespoons salt in a cup of water), place in a soft
drink bottle and squirt down animal's throat.
Vomiting should take place in approximately 10
minutes. Seek veterinarian's advice.
Eye contact: Rinse immediately with plenty of water, also under
the eyelids, for at least 15 minutes. Remove contact
lenses. Immediate medical attention is required.
Skin contact: Take off all contaminated clothing immediately.
Wash off immediately with plenty of water.
If skin irritation persists, call a physician.
Wash contaminated clothing before re-use.
Inhalation: Remove to fresh air. Keep patient warm and at rest.
If breathing is irregular or stopped, administer
artificial respiration. Call a physician or Poison
Information Centre immediately.
Poisoning Symptoms: No adverse health effects expected if the product is handled in
accordance with this Safety Data Sheet and the product label.
Symptoms that may arise if the product is mishandled and
overexposure occurs are:
MILD EXPOSURE: reduction in the clotting power of blood,
detectable only by laboratory analysis.
MODERATE EXPOSURE: symptoms include bleeding gums,
increased tendency to bruise, blood in faeces and urine or excessive
bleeding from minor cuts or abrasions.
SEVERE EXPOSURE: severe gastrointestinal bleeding, massive
internal bleeding resulting in shock, coma and death in very severe
cases
Syngenta Crop Protection Pty Ltd Page 3 of 8
TALON?Rodenticide Wax Blocks May 2010
Medical Advice: NOTE TO PHYSICIANS AND VETERINARIANS:
Brodifacoum, the active constituent of TALON Rodenticide Wax
Blocks, is a long lasting anticoagulant chemical, which if ingested by
humans, domestic animals or pets, can reduce the clotting power of
the blood and haemorrhage may result. Vitamin K1
(Phytomenadione) should be administered urgently by medical,
appropriate para-medical personnel or veterinarians. If administered
intravenously the injection must be given slowly.
This product contains anticoagulants with an effect similar to warfarin
in that they act by interfering with the synthesis of prothrombin.
HUMANS: The specific measure of effect is the prothrombin time.
Note: this may not become prolonged until 12-18 hours after
ingestion. The specific antidote is vitamin K1 (Phytomenandione).
Antidote must be administered under medical supervision. Initially,
antidote should be given by injection (10-20 mg, or 0.25 mg/kg for
children, by slow intravenous infusion at a rate not exceeding
1mg/minute. In severe cases the use of fresh frozen plasma may be
required). Maintenance treatment is given orally (40 mg/day in
divided doses for adults; up to 20 mg/day in divided doses for
children). The prothrombin time and the haemoglobin should be
monitored. Patients should be kept under medical supervision until
the prothrombin time has been normal for 3 consecutive days. Oral
treatment may need continuing for several months (20 mg/day in
divided doses for adults and up to 20mg/day in divided doses for
children).
DOMESTIC ANIMALS EXHIBITING SIGNS OF INTOXICATION:
1. Carry out a prothrombin test. Administer parentally 2-5mg/kg of
Vitamin K1. Use the smallest diameter needle feasible and avoid
the intravenous route in severely haemorrhagic animals.
2. Repeat prothrombin test about four hours after injection. Provided
that the prothrombin time has normalised start daily oral vitamin
K1 treatment and continue for three to four weeks.
3. Carry out a prothrombin test 24-48 hours after end of treatment.
Continue treatment if signs of poisoning reappear or if
prothrombin time is still abnormal.
DOMESTIC ANIMALS SUSPECTED OF CONSUMING BAIT:
1. Test prothrombin time daily for up to three days after suspected
date of ingestion.
2. Treat with Vitamin K1 if signs of poisoning appear or if
prothrombin time increases.
3. Prophylactic oral Vitamin K1 treatment could be carried out.
Refer to the document "The Treatment of Anticoagulant Rodenticide
Poisoning" (1998 or later edition) available at most major treatment
hospitals, Poisons Information Centre or Syngenta Crop Protection
Pty Ltd.
Syngenta Crop Protection Pty Ltd Page 4 of 8
TALON?Rodenticide Wax Blocks May 2010
Section 5: FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Small fires
Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide. Do not use a solid water stream as it may scatter and
spread fire.
Large fires
Use alcohol-resistant foam or water spray. Do not use a solid
water stream as it may scatter and spread fire.
Hazards from Combustion As the product contains combustible organic components, fire
Products: will produce dense black smoke containing hazardous products
of combustion (see Section 10). Combustion or thermal
decomposition will evolve toxic and irritant vapours. Exposure
to decomposition products may be a hazard to health.
Special Protective Precautions Wear full protective clothing and self-contained breathing
and Equipment for Fire Fighters: apparatus.
Do not allow run-off from fire fighting to enter drains or water
courses. Cool closed containers exposed to fire with water
spray.
Section 6: ACCIDENTAL RELEASE MEASURES
Emergency Procedures: In case of spillage it is important to take all steps necessary to
?Avoid eye and skin contact
?Avoid contamination of waterways
Methods and Materials for Procedure for spill
Containment and Clean Up: (1) Keep all bystanders away
(2) Wear full length clothing and PVC gloves
(3) Reposition any leaking containers so as to minimise
leakage
(4) Sweep spilt material into a pile
(5) Shovel into drums
(6) Disposal of the material will depend upon the extent of the
spill
?For quantities up to 50 kg of product bury in a secure
landfill site
?For quantities greater than 50 kg seek advice from the
manufacturer (use emergency contact number below)
before attempting disposal. Contain in a secure location
until disposal method is established
(7) Decontaminate spill area with detergent and water and
rinse with the smallest volume of water practicable
Section 7: HANDLING AND STORAGE
Precautions for Safe Handling: MANUFACTURE, PACKAGING AND TRANSPORT: Avoid skin
and eye contact. Wear overalls, safety glasses and impervious
gloves. Always wash hands before smoking, eating, drinking or
using the toilet.
PREPARATION AND USE OF THE PRODUCT: Do not inhale
dust. Do not touch the bait, use scoop or measure. If on skin and
after each baiting, wash thoroughly with soap and water.
Only use protective equipment bearing the mark of the
Standards Association of Australia.
Syngenta Crop Protection Pty Ltd Page 5 of 8
TALON?Rodenticide Wax Blocks May 2010
Conditions for Safe Storage: Containers which have held bait should not be used for any
other purpose. Store in tightly sealed original containers in a dry
secure place away from fertilisers, seed, feed and food. Store
out of direct sunlight. Keep out of reach of children,
unauthorised persons and animals.
Store and transport according to the requirements for a
Schedule 6 poison. Not classified as Dangerous Goods by the
criteria of the Australian Dangerous Goods Code (ADG Code)
for transport by Road and Rail.
Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
ALWAYS READ AND FOLLOW THE LABEL INSTRUCTIONS AND WARNINGS
Component Exposure limit Value type
3
National Exposure Standards: propane-1,2-diol 10 mg/m 8h TWA
(particulates)
3
Syngenta Exposure Standards: brodifacoum 0.002 mg/m 8h TWA
Biological Limit Values: No biological limits allocated
Engineering Controls: IN THE WORKPLACE: Natural ventilation should be adequate
under normal conditions. Keep containers closed when not in
use.
Personal Protective Equipment: MANUFACTURE, PACKAGING AND TRANSPORT: Avoid skin
and eye contact. Wear overalls, safety glasses and impervious
gloves. Always wash hands before smoking, eating, drinking or
using the toilet.
PREPARATION AND USE OF THE PRODUCT: Do not inhale
dust. Do not touch the bait, use scoop or measure. If on skin and
after each baiting, wash thoroughly with soap and water.
Only use protective equipment bearing the mark of the
Standards Association of Australia.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Boiling Point/Range:
Blue wax blocks Not available
Odour: Freezing/Melting Point:
Odourless Not available
pH: Solubility:
Not applicable Not soluble in water
3
Vapour Pressure: Density:
Not available 1.2 g/cm
Vapour Density: Not available
Flash Point: Explosive Properties:
>61癈 Not explosive
Upper and Lower Oxidising Properties:
Not available Not oxidising
Flammable (Explosive)
Combustibility: Combustible
Limits in Air:
Ignition Temperature: Corrosiveness:
Not available Not corrosive
Syngenta Crop Protection Pty Ltd Page 6 of 8
TALON?Rodenticide Wax Blocks May 2010
Section 10: STABILITY AND REACTIVITY
Chemical Stability: Stable under standard conditions.
Conditions to Avoid: Not available
Incompatible Materials: Not available
Hazardous Decomposition Combustion or thermal decomposition will evolve toxic and
Products: irritant vapours
Hazardous Reactions: unknown
Section 11: TOXICOLOGICAL INFORMATION
Health Effects from Likely Routes of Exposure:
Acute: Oral toxicity: LOW TOXICITY
Tests on rats indicate this product has a low toxicity following
single doses of undiluted product.
(LD50 > 5,000 mg/kg)
Dermal toxicity: LOW TOXICITY
Tests on rats indicate this product has a low toxicity following
skin contact with undiluted product.
(LD50 > 5,000 mg/kg)
Inhalation: Due to the form of this product (solid preparation), inhalation is
not considered to be a relevant route of exposure.
Skin irritation: NON IRRITANT
Eye irritation: NON IRRITANT
Sensitisation: NOT A SENSITISER
Chronic: Brodifacoum technical has been extensively tested on laboratory mammals and in
test-tube systems. No evidence was obtained of mutagenic, carcinogenic, teratogenic
neurotoxic or reproductive effects.
Excessive exposure slows blood clotting time and can cause bleeding, shock and
death.
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity: Toxicity to fish: Practically non-toxic to fish
Oncorhynchus mykiss (Rainbow trout):
LC50 > 100 mg/L, 96 h
(Derived from components)
Toxicity to daphnia Practically non-toxic to aquatic invertebrates
and other aquatic Daphnia magna (Water flea):
invertebrates: EC50 > 100 mg/L, 48 h
(Derived from components)
Persistence and Brodifacoum is persistent in soil and water.
Degradability:
Mobility Brodifacoum has low mobility in soil.
Bioaccumulative Brodifacoum has high potential to bioaccumulate.
Potential:
Syngenta Crop Protection Pty Ltd Page 7 of 8
TALON?Rodenticide Wax Blocks May 2010
Section 13: DISPOSAL CONSIDERATIONS
Disposal Methods and Break, crush, puncture and bury empty containers and dispose of unused
Containers: bait in a local authority landfill. If no landfill is available, bury the containers
or unused bait below 500 mm in a disposal pit specifically marked and set
up for this purpose clear of waterways, desirable vegetation and tree roots.
Empty containers and product should not be burnt.
Special Precautions Not applicable
for Landfill or
Incineration:
Section 14: TRANSPORT INFORMATION
LAND TRANSPORT Not a dangerous good in Australia
ADG
UN Number: Packing Group:
None allocated None allocated
UN Proper Shipping Special Precautions
None allocated None allocated
Name: for User:
Class: Hazchem Code:
None allocated None allocated
Subsidiary Risk: None allocated
SEA TRANSPORT Not a dangerous good
IMDG
UN Number: Subsidiary Risk:
None allocated None allocated
UN Proper Shipping Packing Group:
None allocated None allocated
Name:
Class: Marine Pollutant:
None allocated
AIR TRANSPORT Not a dangerous good
IATA - DGR
UN Number: Subsidiary Risk:
None allocated None allocated
UN Proper Shipping Packing Group:
None allocated None allocated
Name:
Class: None allocated
Section 15: REGULATORY INFORMATION
APVMA Product Number: 52675
Poisons Schedule (SUSDP): 6
Syngenta Crop Protection Pty Ltd Page 8 of 8
TALON?Rodenticide Wax Blocks May 2010
Section 16: OTHER INFORMATION
Date of preparation or last revision: May 2010
Source of Data: The information provided in this SDS is sourced from Syngenta internal studies
which have been conducted according to Regulatory requirements including OECD and CIPAC
Guidelines and EC Directives. A comprehensive package of toxicological and environmental data for
the active ingredients of this product has been submitted to the government health and environment
authorities and has been evaluated by expert toxicologists and environmental scientists.
Note: This product is a registered agricultural chemical and must, therefore, be used in
accordance with the container label directions
CONTACT POINT: Regulatory Affairs Manager, Syngenta Crop Protection Pty Limited
(02) 8876 8444
24 HOURS EMERGENCY CONTACT: 1800 033 111
This Material Safety Data Sheet summarises our best knowledge of the health and safety hazard
information of the product and how to safely handle and use the product in the workplace. Each user
should read this SDS and consider the information in the context of how the product will be handled
and used in the workplace including in conjunction with other products.
If clarification or further information is needed to ensure that an appropriate risk assessment can be
made, the user should contact this company.
?br>
Registered trademark of a Syngenta Group Company
|