MATERIAL SAFETY DATA SHEET
Emergency Telephone (262) 251-4977
Section 1 ?Company Name and Product Information
Company Name: Alliance Group, Inc.
Address: N114 W18621 Clinton Drive City: Germantown
State: Wisconsin Zip Code: 53022
Product name: Oxytrol S
Product code: 0143
Chemical Family: Bisulfite Solution Revised MSDS: 9/5/08
Replaces MSDS: 7/31/91
Section 2 ?Hazards Identification
EMERGENCY OVERVIEW: DANGER! CORROSIVE. Harmful or fatal if swallowed. Harmful if inhaled.
May cause an allergic reaction to skin, respiratory tract or if swallowed.
Physical State: Liquid.
Color: Clear. Light pink.
Odor: Sharp, pungent odor.
POTENTIAL HEALTH EFFECTS
Routes of Exposure: Eyes. Skin. Inhalation. Ingestion.
Target Organs: Eyes. Skin. Respiratory System. Mucous Membranes.
Eyes: May be corrosive to the eyes. Severe irritation and burns may result. Liquid or mist may cause:
discomfort. tearing. redness. pain. blurred vision. If left untreated, may cause: burns. corneal damage.
blindness.
Skin: May be corrosive to skin. Severe irritation and possible burns may result. Contact may cause:
discomfort. rash. redness. swelling. scaling. blistering. allergic reaction in some individuals.
Ingestion: May be corrosive to the digestive tract. Severe irritation and burns may result. Large amounts
may cause: nausea. stomach upset. vomiting. diarrhea. abdominal pain. central nervous system
depression. violent colic. death. Effects may be delayed. Estimated fatal dose for Sodium Bisulfite is 10
grams.
Inhalation: May be corrosive to the respiratory tract. Severe irritation and burns may result. May irritate or
damage: nose. throat. mucous membranes. respiratory tract. May cause: coughing. shortness of breath.
allergic reaction in some individuals. Effects may be delayed.
Medical Conditions Aggravated By Exposure To Product: Asthma. Lung disorders. Some individuals
are said to be dangerously sensitive to minute amounts of sufites in foods. Symptoms may include
broncho constriction, shock, gastrointestinal disturbances, angio edema, flushing, and tingling sensations.
Once allergy develops, future exposures can cause asthma attacks with shortness of breath, wheezing,
and cough.
Other: The potential for exposure to sulfur dioxide must always be considered as well, particularly when
the solution may become overheated. SULFUR DIOXIDE GIVEN OFF BY THIS PRODUCT HAS BEEN
SHOWN TO CAUSE BREATHING DIFFICULTIES IN ASTHMATICS.
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Cancer Information: This product does not contain greater than 0.1% of the known or potential
carcinogens listed in NTP, IARC, or OSHA
Section 3 ?Composition / Hazardous Ingredients
CAS Number Chemical Component % by Weight OSHA Hazard
7631-90-5 Sodium Bisulfite <50 % YES
Section 4 ?First Aid Measures
Eye Contact: Immediately flush eyes with plenty of cool water for at least 15 minutes while holding eyelids
open. Tilt head to avoid contaminating unaffected eye. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Do not reuse clothing or shoes until cleaned. If irritation persists, get
medical attention. Wipe off excess. Discard footwear which cannot be decontaminated.
Ingestion: If swallowed, call a physician immediately. DO NOT induce vomiting unless directed to do so
by a physician. Never give anything by mouth to an unconscious person. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration of liquid into lungs. Keep airway clean. Give
water or milk to dilute.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If
breathing is difficult, administer oxygen. Get medical attention immediately.
Note to Physicians: The decision of whether or not to induce vomiting should be made by a physician.
Section 5 - Fire Fighting Measures
Flash Point: None. Lower Explosion Limit: N.A.
Upper Explosion Limit: N.A.
Extinguishing Media: For fires in area use appropriate media. For example: Water Spray. Dry chemical.
Carbon dioxide. Foam.
Fire Fighting Methods: Evacuate area of unprotected personnel.Wear protective clothing including a
NIOSH-Approved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors
and decomposition products. Cool fire exposed containers with water until fire is out. Do not use solid
water streams near ruptured tanks or spills. Neutralize runoff with lime, soda ash, or other suitable
neutralizing agent. Run-off from fire control may cause pollution.
Fire and Explosion Hazards: Toxic fumes, gases or vapors may evolve on burning. Sulfur dioxide gas will
be released at a rate increasing with temperature.
Hazardous Combustion Products: Toxic vapors. Sulfur oxides. Sulfur dioxide. Sodium sulfide may be
formed after dried solution residues are heated. This is an explosive hazard and strongly alkaline in
contact with water.
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Section 6 ?Accidental Release Measures
Steps to be taken in case of spills: Corrosive Material. Evacuate unprotected personnel from area.
Maintain adequate ventilation. Use proper safety equipment. Never exceed any occupational exposure
limit. Eliminate all sources of ignition. Shut off source of leak if safe to do so. Contain spill, place into
drums for proper disposal. Neutralize with an alkali (sodium carbonate, lime, etc). Sulfur dioxide and
carbon dioxide may be released during neutralization. Flush remaining area with water to remove trace
residue and dispose of properly. Avoid direct discharge to sewers and surface waters. Notify authorities if
entry occurs.
Section 7 - Handling and Storage
Handling: Avoid contact with eyes, skin, clothing. Use with adequate ventilation. Avoid breathing vapors,
mists, or dust. Do not swallow. Do not eat, drink or smoke in work area. Wash thoroughly after handling.
Empty containers retain product residues; observe all warnings and precautions listed for the product.
Storage: CORROSIVE MATERIAL. Store in a cool, well ventilated area, out of direct sunlight. Store in a
dry location away from heat. Store away from incompatible materials. Keep containers tightly closed. Do
not store in unlabeled or mislabeled containers. Keep away from all sources of heat and ignition to prevent
decomposition and release of sulfur dioxide gas. Do not freeze. Store above 50癋 to avoid crystallization.
Section 8 ?Exposure Control / Personal Protection
Exposure Guidelines:
Component OSHA PEL OSHA STEL/C ACGIH TWA ACGIH STEL/C
3 3
Sodium Bisulfite 5 mg/m + Not Estab. 5 mg/m Not Estab
Note: + Vacated 1989 OSHA PEL(s). Sulfur dioxide gas may be released. The Exposure Limits for Sulfur Dioxide are: 5 ppm-
TWA (OSHA); 2 ppm-TWA, 5 ppm-STEL (ACGIH).
Engineering Controls: Local exhaust ventilation, process enclosures, or other engineering controls are
imperative when handling or using this product to avoid overexposure. Maintain adequate ventilation. Do
not use in closed or confined spaces. Keep levels below exposure limits. To determine exposure,
monitoring should be performed regularly.
Eye / Face Protection: Chemical safety goggles. Do not wear contact lenses.
Skin Protection: Prevent contact with this product. Wear gloves. Protective gloves: Impervious.
Neoprene. Rubber. Polyvinyl chloride.
Other Protective Equipment: Eye wash station. Safety shower. Rubber boots. Chemical safety shoes.
Respiratory Protection: Maintain adequate ventilation. Local exhaust permissable if misty conditions
prevail the Threshold Limits. Do not use in closed or confined space. If recommended exposure limits are
exceeded wear NIOSH Approved self-contained breathing apparatus for sulfur dioxide. DO NOT exceed
limits established by the respirator manufacturer.
General Hygiene Conditions: Wash with soap and water before meal times and at the end of each work
shift.
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Section 9 ?Physical and Chemical Properties.
Physical State: Liquid
Color: Clear. Light pink.
Odor: Sharp, pungent odor
Specific Gravity: 1.18 at 25癈
Solubility in water: Complete
pH: 6.1
Freezing Point: N.D.
% Volatiles: N.D.
Vapor Pressure: N.D.
Vapor Density: N.D.
Autoignition Temperature: No Data
Section 10 ?Stability and Reactivity
Stability: Stable under normal conditions.
Conditions To Avoid: Avoid contact with heat, sparks, electric arcs, other hot surfaces, and open flames.
Incompatible Materials: Acids. Mineral acids. Oxidizing agents.
Hazardous Decomposition Products: Sulfur dioxide gas. Sulfur oxides. Toxic vapors.
Possibility of Hazardous Reactions: Hazardous polymerization will not occur under normal conditions.
Oxidizing agents may cause exothermic reactions. Acidification will accelerate the releaseof Sulfur dioxide
fumes.
Section 11 ?Toxicological Information
LD50 Oral: No data
LD50 Skin: No data
LC50 Inhalation: No data
Section 12 ?Ecological Information
Ecotoxicological Information: No data available
Chemical Fate Information: No data available
Section 13 璂isposal Considerations
Hazardous Waste Number: N.A.
Waste disposal methods: Dispose of in accordance with all local, state, and federal regulations.
Regulations may vary in different locations. Waste characterizations and compliance with applicable laws
are the responsibility solely of the waste generator. Since emptied containers retain product residue,
follow label warnings even after container is emptied.
Section 14 ?Transportation Information
Proper Shipping Name: Corrosive liquid, acidic, inorganic, n.o.s. (contains sodium bisulfite)
Hazard Class: 8
UN Number: UN3264 Packing Group: III
Label required: Corrosive
Reportable Quantity: 5000# (Sodium Bisulfite)
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Section 15 ?Regulatory Information
U.S. FEDERAL REGULATIONS
TSCA Inventory Status: This product or all components of this product are listed on the Inventory of Chemical
Substances.
SARA Title III Section 311/312 Category:
Immediate (Acute) Health Hazard: Y
Delayed (Chronic) Health Hazard: N
Fire Hazard: N
Sudden Release of Pressure Hazard: N
Reactive Hazard: N
SARA Section 302/304/313HAP:
Component CERCLA RQ SARA RQ SARA TPQ SARA 313 U.S. HAP
Sodium Bisulfite 5000 N.A. N.A. NO NO
CLEAN WATER ACT: This product contains one or more components designated as hazardous substances or toxic
pollutants pursuant to the Federal Clean Water Act (40 CFR 116.4 Table A; 40 CFR 401.15) Any unpermitted
introduction of this product into a facility stormwater or wastewater discharge may constitute a violation of the Clean
Water Act. Facilities must notify the appropriate permitting agency prior to discharge.
U.S. STATE REGULATIONS
CALIFORNIA - The following components are listed under Proposition 65:
Cobalt Sulfate Heptahydrate (CAS# 10026-24-1) < 0.1%
WISCONSIN ?The following components are listed as a Wisconsin HAP:
Sodium Bisulfite.
Section 16 瑼dditional Information
HMIS/NFPA Label Information
HMIS NFPA KEY
Health 2 2 0 = Minimal
Flammability 0 0 1 = Slight
Reactivity 1 1 2 = Moderate
Special Hazard: None 3 = Serious
4 = Severe
Complies with CFR Title 21 Section 173.310 for boiler water and steam which may contact dairy
products.
The above information is believed to be accurate and discloses the known hazards for this product as of
this date. Since conditions of use are outside our control it should not be taken as a warranty or
representation for which Alliance Group, Inc. assumes legal responsibility. This information is provided
solely for your consideration, investigation, and verification.
Date: September 5, 2008 By: P. May
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