4001 W Sam Houston Parkway N, Suite 100 Houston, Texas 77043-1226 U.S.A.
Toll- Free: 1-800-539-5283 Tel: 713-461-1493 Fax: 713-461-4467 stoller@stollerusa.com
Material Safety Data Sheet (rev.04/07/10)
WHITE LABELTM Manganese
SECTION I PRODUCT IDENTIFICATION
NFPA HAZARD RATINGS
HEALTH HAZARD 1 FIRE HAZARD 0 REACTIVITY 0
Based on the National Fire Protection Association rating system
(0 = Minimal; 1 = Slight; 2 = Moderate; 3 = High; 4 = Severe)
SARA/ TITLE III HAZARD CATEGORIES (See Section IX)
Immediate (ACUTE) Health: Yes Reactive Hazard: None
Delayed (Chronic) Health: None Fire Hazard: None Sudden Release of Pressure: not applic
Company Name: STOLLER USA, INC.
Address: 4001 W. Sam Houston Parkway, N., Suite 100
Houston, Texas 77043-1226 U.S.A.
Emergency Phone Number: CHEMTREC: In the U.S. and Canada call Toll- free: 1 (800) 424-9300
From other countries call collect: 1 (703) 527-3887
Phone Number for Information: 1 (800) 539-5283 or 1 (713) 461-1493
Chemical Family: Solution of organic acid with manganese.
Chemical Name & Synonyms: Liquid fertilizer containing manganese and sulfur.
Formula: Proprietary
Trade name & Synonyms: WHITE LABELTM MANGANESE (4% S, 5% Mn)
SECTION II COMPOSITION/ INFORMATION ON INGREDIENTS
INGREDIENTS: CAS# Approx. % TLV
Manganese Sulfate 10034-96-5 18 N/ E
Lignosulfonic Acid, Sodium Salf 68512-34-5 5 - 10
INGREDIENTS: RTECS No. Haz- Mat
Manganese Sulfate N/ E
SECTION III HAZARD IDENTIFICATION
A. EXPOSURE LIMITS:
1. OSHA Permissible Exposure Limit (PEL): NOT ESTABLISHED
2. Threshold Limit Value (TLV): NOT ESTABLISHED
B. CARCINOGEN OR POTENTIAL CARCINOGEN:
C. EFFECTS OF OVEREXPOSURE:
1. ACUTE:
EYES: Contact with product may cause severe irritation and possibly irreversible damage.
SKIN: Harmful if absorbed through broken skin. Large doses may cause liver and kidney damage. May cause,
discomfort, irritation, injury and death unless treated promptly.
INHALATION: Prolonged exposure to low concentrations of vapors may cause sore throat and headache, which are
temporary.
INGESTION: May cause malaise, nausea, gastrointestinal damage, or even death unless treated promptly.
2. CHRONIC: Not known.
D. ADDITIONAL INFORMATION:Manganese sulfate LD50 (oral/ mouse) 980 mg/ kg.
SECTION IV FIRST- AID MEASURES
A. EMERGENCY FIRST AID PROCEDURES:
EYES: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Call a physician.
SKIN: Remove product and immediately wash affected area with soap and water for 15 minutes. Do not apply greases
or ointments. Launder contaminated clothing.
INHALATION: Move patient to fresh air. Supplemental oxygen may be indicated if patient has difficulty breathing.
Assure mucous does not obstruct airway. Call a physician immediately. Do not induce vomiting.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting..
B. ANIMAL TOXICITY DATA: Note to physician: symptomatic treatment.
C. ADDITIONAL INFORMATION: Manganese sulfate LD50 (oral/ mouse) 980 mg/ kg.
C. ADDITIONAL INFORMATION: Manganese sulfate LD50 (oral/ mouse) 980 mg/ kg.
SECTION V FIRE AND EXPLOSION DATA
FLASH POINT: NOT ESTABLISHED
FLAMMABLE LIMITS: NOT ESTABLISHED LEL: UEL:
EXTINGUISHER MEDIA: Use any means suitable to fight surrounding fire.
SPECIAL FIRE FIGHTING PROCEDURES: NONE
UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE
SECTION VI ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED: It is necessary to contain spill into the smallest area possible by
diking, enclosing, etc.; replace liquid into plastic container. If liquid is absorbed onto dry carrier such as soil or absorbent
material, then this material should be put in covered labeled containers and dispose of as a dry waste.
SECTION VII HANDLING AND STORAGE
Keep containers closed and away from oxidizing agents. Store only in shipping container: Bulk material can be stored in
polyethylene, aluminum or stainless steel tanks.
SECTION VIII SPECIAL PROTECTION / CONTROL MEASURES
RESPIRATORY PROTECTION: Not specifically required. Use of a NIOSH/ OSHA approved respirator is suggested.
LOCAL EXHAUST: Provide general or local exhaust ventilation.
SPECIAL VENTILATION: Not applicable.
PROTECTIVE GLOVES: Wear protective gloves and clothing impervious to this material.
OTHER SPECIAL CLOTHING/ EQUIPMENT: Eye wash fountain should be located in immediate work area.
WORK/ HYGIENIC PRACTICES: Wash hands thoroughly after using product.
SECTION IX PHYSICAL AND CHEMICAL CHARACTERISTICS
BOILING POINT: 220癋 VAPOR PRESSURE (mm/ <1mm @
(104癈) Hg): 68癋 (20癈)
MELTING POINT: N/ A VAPOR DENSITY (air = 1): 2.1
SPECIFIC GRAVITY: 1.2 REACTIVITY IN WATER: N/ A
SOLUBILITY IN WATER: 100% EVAPORATION RATE: 0.1
APPEARANCE AND ODOR: Dark brown solution, characteristic mild odor.
PERCENT VOLATILE BY VOLUME: N/ A
SECTION X PHYSICAL HAZARDS (REACTIVITY DATA)
STABILITY: Stable: Yes Unstable:
CONDITIONS TO AVOID: Stable under normal conditions.
INCOMPATIBILITY, MATERIALS TO AVOID: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Sulfur dioxide, carbon dioxide.
MAY OCCUR: WILL NOT OCCUR: X
SECTION XI TOXICOLOGICAL INFORMATION
A. TOXICITY DATA:
B. CARCINOGENICITY:
C. MUTAGENICITY:
D. REPRODUCTIVE TOXICITY:
SECTION XII ENVIRONMENTAL EFFECTS DATA
No environmental impact studies have been performed with this product. The available data on the ingredients of this plant
nutrient product does not indicate any undue hazard to the environment under anticipated use and storage. Any waste due to
spillage or leakage should be contained and disposed of as a Fertilizer (see above under Waste Disposal Methods). Due to its
nutrient value, may contribute to eutrophication in bodies of water.
SECTION XIII DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHODS: Follow all applicable federal, state and local regulations regarding liquid fertilizers.
SECTION XIV TRANSPORTATION DATA
PROPER SHIPPING NAME: Not Applicable (WHITE LABELTM MANGANESE)
DOT HAZARD CLASS: Not - Regulated Material; Non - Hazardous Material
PLACARD: N/ A