M850-20704 DARK BROWN LEATHER MARKER
MATERIAL SAFETY DATA SHEET
RPM Wood Finishes Group
3194 Hickory Boulevard
Hudson, North Carolina 28638
828-728-8266
EMERGENCY PHONE (CHEM TREC): . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-800-424-9300
FOR ALL INTERNATIONAL TRANSPORTATION ACCIDENTS. . . . . . . . . . . . . . . . .1-703-527-3887 (collect)
Health: 2 Flammability: 0 Reactivity 0
PRODUCT NAME: M850-20704 DARK BROWN LEATHER MARKER
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
REVISION DATE: 28/04/06
SUPERCEDES: 22/07/03
MSDS NO. M850-20704
OSHA HAZ. CLASS: Lung toxin - may cause lung damage.
II. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME % CAS # PEL
resin solids 11-20 PROPRIETARY No PEL established
isopropanol 1-10 67-63-0 400 ppm TWA; 980 mg/m3 TWA
Dipropylene glycol monomethyl ether 1-10 34590-94-8 No PEL established
carbon black 1-10 1333-86-4 3.5 mg/m3 TWA
iron oxide yellow 1-10 51274-00-1 No PEL established
iron oxide red 1-10 1332-37-2 No PEL established
black iron oxide 1-10 1317-61-9 No PEL established
m-xylene <1 108-38-3 No PEL established
ethylbenzene <1 100-41-4 100 ppm TWA; 435 mg/m3 TWA
o-xylene <1 95-47-6 No PEL established
p-xylene <1 106-42-3 No PEL established
III. HAZARDS IDENTIFICATION
Absorption., Eyes, Skin, Inhalation, inhalation, ingestion.
Routes of Entry:
Eye disease. Respiratory disease including asthma and bronchitis. Skin disease
Medical Conditions Aggravated:
including eczema and sensitization. No medical conditions affected by exposure.
Digestive tract disease. Liver disease. Kidney disease.
Immediate (Acute) Health Effects
Irritation may be delayed for several hours. Can cause severe respiratory irritation,
Inhalation:
dizziness, weakness, fatigue, nausea, headache and possible unconsciousness.
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Moderately irritating to the skin. No hazard in normal industrial use. Can cause
Skin Contact:
moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent
damage.
Can cause irritation. Contact with the eyes may cause moderate to severe eye injury.
Eye Contact:
Eye contact may result in tearing and reddening, but not likely to permanently injure
eye tissue. Temporary vision impairment (cloudy or blurred vision) is possible. Can
cause moderate irritation, tearing and reddening, but not likely to permanently injure
eye tissue.
Toxic and may be harmful if absorbed through the skin; may produce target organ
Skin Absorption:
damage. Minimal hazard in normal industrial use. May cause gastrointestinal
discomfort.
Aspiration of material into the lungs can cause chemical pneumonitis which can be
Ingestion:
fatal. Irritating to mouth, throat, and stomach. Can cause abdominal discomfort,
nausea, vomiting and diarrhea.
Target Organ Acute Toxicity:
Isopropyl alcohol eyes, skin, respiratory system
Dipropylene glycol, methyl ether eyes, respiratory system, CNS
Carbon black respiratory system, eyes, lymphatic cancer
m-Xylene CNS, eyes, blood, liver, kidneys, skin, GI tract, respiratory system
Ethyl benzene eyes, respiratory system, skin, CNS
o-Xylene CNS, eyes, blood, liver, kidneys, skin, GI tract, respiratory system
p-Xylene CNS, eyes, blood, liver, kidneys, skin, GI tract, respiratory system
Long-Term (Chronic) Health Effects:
ACGIH. IARC. NIOSH. NTP. OSHA. Contains a substance that is a probable cancer
Carcinogenicity:
hazard based on human studies.
A component in this product has been shown to cause birth defects and reproductive
Reproductive and Developmental
Toxicity: disorders in laboratory animals at doses that could be encountered in the workplace.
No data available to indicate product or any components present at greater than 0.1%
Mutagenicity:
is mutagenic or genotoxic.
Upon prolonged and/or repeated exposure, can cause severe respiratory irritation,
Inhalation:
dizziness, weakness, fatigue, nausea, headache and possible unconsciousness.
Prolonged or repeated contact may cause irritation. Not generally an irritant and is
Skin Contact:
only mildly irritating to the skin upon prolonged or repeated contact. May cause
lingering affects but not likely to result in permanent damage if the exposure is
eliminated. Upon prolonged or repeated contact, can cause moderate skin irritation,
defatting, and dermatitis. Not likely to cause permanent damage.
Upon prolonged or repeated contact, can cause severe irritation. Eye contact may
Eye Contact:
result in corneal injury. Symptoms may include discomfort or pain, excess blinking
and tear production, with marked redness and swelling of the conjunctiva. Temporary
vision impairment (cloudy or blurred vision) is possible.
Upon prolonged or repeated exposure, minimal hazard in normal industrial use. May
Skin Absorption:
cause gastrointestinal discomfort.
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Skin. Respiratory Tract. Eyes. Nervous System. Lungs. Digestive Tract. Liver.
Target Organ Chronic Toxicity:
Kidneys. Blood.
No additional health information available.
Supplemental Health Hazard
Information:
IV. FIRST AID
Remove to fresh air. If not breathing, give artificial respiration. If breathing is
Inhalation:
difficult, give oxygen. Get immediate medical attention. Remove to fresh air. Get
medical attention.
Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids
Eyes:
often. Tilt the head to prevent chemical from transferring to the uncontaminated eye.
Get immediate medical attention and monitor the eye daily as advised by your
physician.
Wash with mild soap and water. If irritation occurs get medical attention. If clothing
Skin Contact:
is contaminated, remove and wash before reuse. Wash with soap and water. Remove
contaminated clothing and launder. Get medical attention if irritation develops or
persists.
If swallowed, do NOT induce vomiting. Give victim 1-2 glasses of water. Call a
Ingestion:
physician or poison control center immediately. Never give anything by mouth to an
unconscious person. Get medical attention. No hazard in normal industrial use. Do
not induce vomiting. Seek medical attention if symptoms develop. Provide medical
care provider with this MSDS.
No additional first aid information available.
Notes to MD:
V. FIRE FIGHTING MEASURES
Flammability Summary:
o
>200 (CALC.) F
Flash Point:
Flammable Liquid. Can release vapors that form explosive mixtures at temperatures at
Fire Hazards:
or above the flash point. If product is heated above its flash point it will release
flammable vapors which can burn in the open or be explosive in confined spaces if
exposed to ignition source. Vapors may be ignited by sparks, flames or other sources
of ignition if material is above the flash point giving rise to a fire (Class B). Vapors
are heavier than air and may travel to a source of ignition and flash back.
Use methods suitable to fight surrounding fire. Water spray Dry chemical Carbon
Extinguishing Media:
dioxide Alcohol foam Use alcohol resistant foam, carbon dioxide, or dry chemical
extinguishing agents. Water may be ineffective but water spray can be used extinguish
a fire if swept across the base of the flames. Water can absorb heat and keep exposed
material from being damaged by fire.
As in any fire, wear self-contained breathing apparatus pressure-demand,
Fire Fighting Instructions:
MSHA/NIOSH (approved or equivalent) and full protective gear. Use methods for
the surrounding fire.Do not enter fire area without proper protection including self-
contained breathing apparatus and full protective equipment. Fight fire from a safe
distance and a protected location due to the potential of hazardous vapors and
decomposition products.
Hazardous Combustion Products: Carbon dioxide, Carbon monoxide
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VI. ACCIDENTAL RELEASE MEASURES
Exposure to the spilled material may be irritating or harmful. Follow personal
Health Consideration for Spill
Response: protective equipment recommendations found in Section VIII of this MSDS.
Additional precautions may be necessary based on special circumstances created by
the spill including; the material spilled, the quantity of the spill, the area in which the
spill occurred. Also consider the expertise of employees in the area responding to the
spill.
Prevent the spread of any spill to minimize harm to human health and the
Spill Mitigation Procedures
General Methods: environment if safe to do so. Wear complete and proper personal protective
equipment following the recommendation of Section VIII at a minimum. Dike with
suitable absorbent material like granulated clay. Gather and store in a sealed container
pending a waste disposal evaluation.
VII. HANDLING AND STORAGE
"Empty" containers retain product residue (liquid and/or vapor) and can be dangerous.
Handling:
Follow all MSDS/label precautions even after container is emptied because it may
retain product residues. Wash thoroughly after handling. Avoid breathing material.
Use spark-proof tools and explosion-proof equipment. Harmful or irritating material.
Avoid contact and avoid breathing the material. Use only in a well ventilated area.
Keep away from heat, sparks, and flame. Avoid exposure to sunlight or ultraviolet
Storage:
(UV) light sources. Keep container closed when not in use. Keep away from sources
of ignition. No special requirements.
VIII. ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
Local exhaust. Local exhaust ventilation or other engineering controls are normally
Engineering Controls:
required when handling or using this product to avoid overexposure.
Protective Equipment
Respirators should be selected by and used under the direction of a trained health and
Respiratory Tract:
safety professional following requirements found in OSHA's respirator standard (29
CFR 1910.134) and ANSI's standard for respiratory protection (Z88.2-1992). A
written respiratory protection program, including provisions for medical certification,
training, fit testing, exposure assessments, maintenance, inspection, cleaning, and
convenient, sanitary storage should be implemented.
Wear chemically resistant safety glasses with side shields when handling this product.
Eyes:
Wear additional eye protection such as chemical splash goggles and/or face shield
when the possibility exists for eye contact with splashing or spraying liquid, or
airborne material. Do not wear contact lenses. Have an eye wash station available.
Avoid skin contact by wearing chemically resistant gloves, an apron and other
Skin:
protective equipment depending upon conditions of use. Inspect gloves for chemical
break-through and replace at regular intervals. Clean protective equipment regularly.
Wash hands and other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
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IX. PHYSICAL DATA
COLORED LIQUID
Physical State:
MILD AMINE
Odor:
18.6866
Solids Vol %:
24.5264
Solids Wt %:
1.0044
Material VOC lbs/gal:
120.624
Material VOC gms/l:
3.0757
Coatings VOC lbs/gal:
369.3706
Coatings VOC gms/l:
8.8834
Weight per gallon lbs:
VOC data per US EPA guidelines. State and local variations may apply.
X. STABILITY AND REACTIVITY
Stable. Stable under normal conditions.
Stability Information:
Contact with air. Visible light. High temperatures. Temperatures above 140F (60 C)
Conditions to Avoid:
Avoid: heat, sparks, flame and oxidizing agents. None known.
Strong oxidizing agents. Strong acids.
Chemical Incompatibility:
Hazardous Polymerization will not occur.
Hazardous Polymerization:
XI. TOXICOLOGICAL INFORMATION
Chemical Name CAS Number LD50/LC50
Isopropyl alcohol 67-63-0 Inhalation LC50 Rat : 16000 ppm/8H; Oral LD50 Rat : 5045 mg/kg; Oral
LD50 Mouse : 3600 mg/kg; Dermal LD50 Rabbit : 12800 mg/kg
Dipropylene glycol, monomethyl ether 34590-94-8 Oral LD50 Rat : 5400 uL/kg; Dermal LD50 Rabbit : 10 mL/kg
Carbon black 1333-86-4 Oral LD50 Rat : >15400 mg/kg; Dermal LD50 Rabbit : >3 gm/kg
m-Xylene 108-38-3 Oral LD50 Rat : 5 gm/kg; Dermal LD50 Rabbit : 14100 uL/kg
Benzene, ethyl- 100-41-4 Oral LD50 Rat : 3500 mg/kg; Dermal LD50 Rabbit : 17800 uL/kg
p-Xylene 106-42-3 Inhalation LC50 Rat : 4550 ppm/4H; Oral LD50 Rat : 5 gm/kg
XII. ECOLOGICAL INFORMATION
No data available. This material is not expected to be harmful to the ecology.
Overview (for ingredients):
XIII. DISPOSAL CONSIDERATIONS
Spent or discarded material is a hazardous waste.
Waste Description for Spent
Product:
Perform waste water treatment. Dispose of in a landfill. Disposal is not likely to be
Disposal Methods:
regulated.
If discarded, this product is considered a RCRA ignitable waste, D001.
Potential EPA Waste Codes:
Components Subject to USEPA Land Disposal Restrictions:
Ethyl benzene 100-41-4 0.03 %
XIV. TRANSPORTATION INFORMATION
NON REGULATED
DOT
See 49CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations.
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XV. REGULATORY INFORMATION
Chemical Name Regulation CASRN %
Isopropyl alcohol SARA 313 Reportable: 67-63-0 6.22
m-Xylene SARA 313 Reportable: 108-38-3 0.08
Ethyl benzene SARA 313 Reportable: 100-41-4 0.03
o-Xylene SARA 313 Reportable: 95-47-6 0.03
p-Xylene SARA 313 Reportable: 106-42-3 0.02
Formaldehyde SARA 313 Reportable: 50-00-0 0.00
Toluene SARA 313 Reportable: 108-88-3 0.00
Benzene SARA 313 Reportable: 71-43-2 0.00
1333-86-4 2.45
Carbon Black California Proposition 65 Cancer List:
100-41-4 0.03
Benzene, ethyl- California Proposition 65 Cancer List:
50-00-0 0.00
Formaldehyde (gas) California Proposition 65 Cancer List:
108-88-3 0.00
Benzene, methyl- California Proposition 65 Cancer List:
71-43-2 0.00
Benzene California Proposition 65 Cancer List:
14808-60-7 0.00
Quartz California Proposition 65 Cancer List:
108-88-3 0.00
Toluene California Proposition 65
Developmental Toxicity:
71-43-2 0.00
Benzene California Proposition 65
Developmental Toxicity:
71-43-2 0.00
Benzene California Proposition 65 Reproductive -
Female:
PROPRIETARY 14.48
resin solids New Jersey Right To Know:
67-63-0 6.22
isopropanol New Jersey Right To Know:
34590-94-8 3.98
Dipropylene glycol monomethyl ether New Jersey Right To Know:
1333-86-4 2.45
carbon black New Jersey Right To Know:
51274-00-1 2.07
iron oxide yellow New Jersey Right To Know:
XVI. ADDITIONAL INFORMATION
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION
Other Information:
CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE
ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY
FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND
THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A
PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES
OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA
OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS,
INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS
AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND
INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION
OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE
ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
MSDS glossary.
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