Material Safety Data Sheet
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : PSC-1000 2K CLEARCOAT
Product Use Description : Solvent-borne coatings, Primers
Company : PRO-SPRAY
An Alco Industries Company
600 Nova Drive, S.E.
Massillon, Ohio 44646
Phone : 330-830-6000
Fax : 330-830-6005
For Chemical Emergency : CHEMTREC: 1-800-424-9300
CANUTEC: 1-613-996-6666 (For Canada Call Collect)
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Regulatory status : This material is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
Signal Word : DANGER
Form : aerosol
Odour : characteristic
Odour - Control parameters : no data available
Hazard Summary : Sensitizer
May cause fire.
Flammable Aerosol
Pressurized container. Protect from sunlight and do not expose to
temperatures exceeding 50癈 / 122 癋.
Irritant
Potential Health Effects
Eyes : Causes eye irritation.
Skin : May cause skin irritation.
Inhalation : May cause allergic respiratory reaction. Causes respiratory tract irritation.
Target Organs: Skin, Central nervous system, Eyes
Carcinogenicity:
ACGIH: ethylbenzene (CAS-No.: 100-41-4)
NTP: No component of this product present at levels greater than or equal to
0.1% is identified as a known or anticipated carcinogen by NTP.
IARC: ethylbenzene (CAS-No.: 100-41-4)
OSHA: No component of this product present at levels greater than or equal to
0.1% is identified as a carcinogen or potential carcinogen by OSHA.
CA Prop 65: WARNING! This product contains a chemical known in the State of
California to cause cancer.
ethylbenzene (CAS-No.: 100-41-4)
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SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS-No. Weight %
dimethyl ether 115-10-6 >= 45 - < 50
acetone; propan-2-one; propanone 67-64-1 >= 25 - < 35
Hexane, 1,6-diisocyanato-, homopolymer 28182-81-2 >= 7 - < 10
n-butyl acetate 123-86-4 >= 5 - < 7
2-methoxy-1-methylethyl acetate 108-65-6 >= 2 - < 3
heptan-2-one; methyl amyl ketone 110-43-0 >= 1 - < 1.5
xylene 1330-20-7 >= 1 - < 1.5
ethylbenzene 100-41-4 >= 1 - < 1.5
SECTION 4. FIRST AID MEASURES
General advice: Move out of dangerous area. Never give anything by mouth to an
unconscious person. In the case of accident or if you feel unwell, seek
medical advice immediately (show the label where possible). When
symptoms persist or in all cases of doubt seek medical advice. Take off all
contaminated clothing immediately.
Inhalation: Remove to fresh air. Keep patient warm and at rest. If breathing
is irregular or stopped, administer artificial respiration. If symptoms
persist, call a physician.
Skin contact: Wash off immediately with soap and plenty of water. Do
NOT use solvents or thinners.
Eye contact: Remove contact lenses. In the case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. Irrigate
copiously with clean, fresh water for at least 10 minutes, holding the
eyelids apart.
Ingestion:If a person vomits when lying on his back, place him in the
recovery position. Clean mouth with water and drink afterwards plenty of
water. Ingest activated charcoal. If swallowed, seek medical advice
immediately and show this container or label.
SECTION 5. FIRE-FIGHTING MEASURES
Form Aerosol
Flashpoint <0癈 (<32癋)
Ignition temperature 365癈 (689癋)
Lower explosion limit 1.4% (V)
Upper explosion limit 8.5% (V)
Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide
Extinguishing media which must High volume water jet
not be used for safety reasons
Specific hazards during fire fighting Fire will produce dense black smoke containing hazardous
combustion products (see heading 10). Do not use a solid water
stream as it may scatter and spread fire.
Special protective equipment for Use personal protective equipment. Wear self-contained fire-
fighters breathing apparatus for fire fighting if necessary.
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Further information:
Use water spray to cool unopened containers. Exposure to decomposition products may be a hazard to
helth. Standard procedure for chemical fires. use extinguishing measures that are appropriate to local
circumstances and the surrounding environment. Fire residues and contaminated fire extinguishing water
must be disposed of in accordance with local regulations.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions Ventilate the area. Remove all sources of ignition. Avoid inhalation of
vapour or mist. Refer to protective measures listed in sections 7 and 8.
Environmental precautions Should not be released into the environment. Avoid subsoil penetration. If
the product contaminates rivers and lakes or drains, inform respective
authorities.
Methods for cleaning up Contain and collect spillage with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and place in container for
disposal according to local/national regulations.
CERCLA Hazardous 115-10-6 100 lbs final RQ
substances and
corresponding RQs 67-64-1 5,000 lbs final RQ
123-86-4 5,000 lbs final RQ
1330-20-7 100 lbs final RQ
100-41-4 1000 lbs final RQ
SECTION 7. HANDLING AND STORAGE
Handling Do not breathe vapours or spray mist. Avoid contact with skins and eyes.
Take precautionary measures against static discharges. Prevent the creation
of flammable or explosive concentrations of vapour in air and avoid
vapour concentration higher than the occupational exposure limits. Limit
the stock at work place.Do nt spray on a naked flame or any other
incandescent material. Use only in well-ventilated areas. For personal
protection see section 8.
Advice on protection Keep away from heat and sources of ignition. Do not smoke. Vapours
against fire and explosion may form explosive mixtures with air. Vapours are heavier than air and
may spread along floors. Electrical equipment should be protected to the
appropriate standard.
Dust explosion class Not applicable.
Storage
Requirements for storage BEWARE: Aerosol is pressurized. Keep away from direct sun exposure
areas and containers and temperatures over 50癈/122癋. Do not open by force or throw into fire
even after use. Do not spray on flames or red-hot objects. Please observe
the storage instructions for aerosols.
Advice on common storage Keep away from food, drink, and animal feeding stuffs. Keep away from
oxidising agents and strongly acid or alkaline materials.
Storage period 24 months
Storage temperature 5 ?30癈 (41 ?86癋)
Other data No decomposition if stored and applied as directed.
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SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Components CAS-No. List Type: Value
dimethyl ether 115-10-6 WEEL TWA 1,000 ppm 1,880 mg/m3
acetone; propan-2-one; 67-64-1 ACGIH TWA 500 ppm
propanone ACGIH STEL 750 ppm
NIOSH REL 250 ppm 590 mg/m3
OSHA Z1 PEL 1,000 ppm 2,400 mg/m3
OSHA Z1A TWA 750 ppm 1,800 mg/m3
OSHA Z1A STEL 1,000 ppm 2,400 mg/m3
US CA OEL TWA PEL 750 ppm1,780 mg/m3
US CA OEL Ceiling 3,000 ppm
US CA OEL STEL 1,000 ppm 2,400 mg/m3
n-butyl acetate 123-86-4 ACGIH TWA 150 ppm
ACGIH STEL 200 ppm
NIOSH REL 150 ppm710 mg/m3
NIOSH STEL 200 ppm950 mg/m3
OSHA Z1 PEL 150 ppm710 mg/m3
OSHA Z1A TWA 150 ppm710 mg/m3
OSHA Z1A STEL 200 ppm950 mg/m3
US CA OEL TWA PEL 150 ppm710 mg/m3
US CA OEL STEL 200 ppm950 mg/m3
2-methoxy-1-methylethyl 108-65-6 WEEL TWA 50 ppm
acetate
US CA OEL TWA PEL 100 ppm541 mg/m3
US CA OEL STEL 150 ppm811 mg/m3
heptan-2-one; methyl amyl 110-43-0 ACGIH TWA 50 ppm
ketone
NIOSH REL 100 ppm465 mg/m3
OSHA Z1 PEL 100 ppm465 mg/m3
OSHA Z1A TWA 100 ppm465 mg/m3
US CA OEL TWA PEL 50 ppm 235 mg/m3
xylene 1330-20-7 ACGIH TWA 100 ppm
ACGIH STEL 150 ppm
OSHA Z1 PEL 100 ppm435 mg/m3
OSHA Z1A TWA 100 ppm435 mg/m3
OSHA Z1A STEL 150 ppm655 mg/m3
US CA OEL TWA PEL 100 ppm435 mg/m3
US CA OEL Ceiling 300 ppm
US CA OEL STEL 150 ppm655 mg/m3
ethylbenzene 100-41-4 ACGIH TWA 100 ppm
ACGIH STEL 125 ppm
NIOSH REL 100 ppm435 mg/m3
NIOSH STEL 125 ppm545 mg/m3
OSHA Z1 PEL 100 ppm435 mg/m3
OSHA Z1A TWA 100 ppm435 mg/m3
OSHA Z1A STEL 125 ppm545 mg/m3
US CA OEL TWA PEL 100 ppm435 mg/m3
US CA OEL STEL 125 ppm545 mg/m3
Engineering measures : Provide adequate ventilation.
Eye protection : Safety glasses
Hand protection : Choose gloves to protect hands against chemicals depending on the
concentration and quantity of the hazardous substance and specific to place of work. For
special applications, we recommend clarifying the resistance to
chemicals of the aforementioned protective gloves with the glove
manufacturer.
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Skin and body protection : impervious clothing
Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment.
respirator with ABEK filter
Hygiene measures : Do not inhale aerosol. When using, do not eat, drink or smoke. Avoid
contact with skin, eyes and clothing. Wash hands before breaks and at the end of workday.
Wash contaminated clothing before re-use. Handle in accordance with good
industrial hygiene and safety practice. General industrial hygiene practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Form : aerosol
Odour : characteristic
Flash point : < 0 癈 (< 32 癋)
Ignition temperature : 365 癈 (689 癋)
Thermal decomposition : Heating can release hazardous gases. Fire or intense heat may cause
violent rupture of packages.
Lower explosion limit : 1.4 %(V)
Upper explosion limit : 8.5 %(V)
Vapour pressure : 3.6 hPa at 20 癈 (68 癋)
Density : 0.85 g/cm3 at ca.20 癈 (68 癋)
Volatile organic compounds : 61.83 %
(VOC) content
SECTION 10. STABILITY AND REACTIVITY
Conditions to avoid : Heat, flames and sparks.
Materials to avoid : Strong acids and strong bases
Oxidizing agents
Hazardous decomposition : Carbon dioxide (CO2), carbon monoxide (CO), oxides of products
nitrogen (NOx), dense black smoke.
Thermal decomposition : Heating can release hazardous gases. Fire or intense heat may cause
violent rupture of packages.
Hazardous reactions : Vapours may form explosive mixture with air.
Note: No decomposition if used as directed.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute inhalation toxicity: Irritating to respiratory system.
Skin irritation: Repeated or prolonged contact with the preparation may cause removal of
natural fat from the skin resulting in desiccation of the skin.
Eye irritation: The liquid splashed in the eyes may cause irritation and reversible damage.
Strong lachrymation can make it difficult to escape
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Carcinogenicity : No data is available on the product itself.
Toxicity to reproduction : No data is available on the product itself.
Teratogenicity : No data is available on the product itself.
Further information : Symptoms of overexposure may be headache, dizziness, tiredness,
nausea and vomiting. Ingestion may cause gastrointestinal irritation,
nausea, vomiting and diarrhoea.
Liver and kidney injuries may occur.
Even the smallest quantities that enter into the lung due to swallowing or
subsequent vomiting can lead to a pulmonary oedema or pneumonia.
Component Acute oral toxicity: LD50 rat
acetone; propan-2-one; 67-64-1
propanone
Hexane, 1,6- 28182-81-2 Acute oral toxicity: LD50 rat
diisocyanato-, Dose: 5,800 mg/kg
homopolymer Acute dermal toxicity: LD50 rabbit
Dose: 20,000 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 70 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Repeated or prolonged contact with the preparation may
cause removal of natural fat from the skin resulting in
desiccation of the skin.
Eye irritation: Classification: Irritating to eyes.
Result: Moderate eye irritation
Acute oral toxicity: LD50 rat
Dose: > 10,000 mg/kg
Acute inhalation toxicity: LD50 rat
Dose: 137 - 1,150 mg/m3
Exposure time: 4 h
Isocyanates may cause acute irritation and/or sensitisation of
the respiratory system leading to tightness of the chest,
wheeziness and an asthmatic condition.
Sensitization: May cause sensitization by inhalation.
n-butyl acetate 123-86-4 Acute oral toxicity: LD50 rat Dose: 13,100 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: > 14,100 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 21 mg/l
Exposure time: 4 h
Skin irritation:
Result: Mild skin irritation
Eye irritation:
Result: Mild eye irritation
2-methoxy-1-methylethyl 108-65-6 Acute oral toxicity: LD50 mouse
acetate Dose: 8,532 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 7,500 mg/kg
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
heptan-2-one; methyl amyl 110-43-0 Acute dermal toxicity: LD50 rabbit
ketone Dose: 12,600 mg/kg
xylene 1330-20-7 Acute oral toxicity: LD50 rat
Dose: 2,840 mg/kg
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Acute dermal toxicity: LD50 rabbit
Dose: ca. 4,500 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 6,350 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Repeated or prolonged exposure may cause skin
irritation and dermatitis, due to degreasing
properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
ethylbenzene 100-41-4 Acute oral toxicity: LD50 rat
Dose: 3,500 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 15,500 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 18 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Risk of serious damage to eyes.
SECTION 12. ECOLOGICAL INFORMATION
Adsorbed organic bound not included
halogens (AOX)
Volatile organic 61.83 %
compounds
(VOC) content
Additional The product should not be allowed to enter drains,
ecological water courses or the soil.
information
SECTION 13. DISPOSAL CONSIDERATIONS
Adequate disposal : In accordance with local and national regulations.
Please ensure aerosol cans are sprayed completely
empty (including propellant)
Containers that have not been emptied in
compliance with regulations are regarded as
hazardous waste.
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SECTION 14. TRANSPORT INFORMATION
DOT 49 CFR
Proper shipping name : AEROSOLS
UN-No. : 1950
Class : 2.1
Packing group :
Emergency Response : 126
Guidebook Number
TDGR
Proper shipping name : AEROSOLS
UN-No. : 1950
Class : 2.1
Packing group :
Emergency Response : 126
Guidebook Number
ICAO / IATA-DGR
UN UN-No. : 1950
Description of the goods : AEROSOLS
Class : 2.1
ICAO-Labels : 2.1
Packing instruction (cargo : 203
aircraft)
Packing instruction : 203
(passenger aircraft)
Packing instruction : Y203
(passenger aircraft)
IMDG-Code
UN-No. : UN 1950
Description of the goods : AEROSOLS
Class : 2.1
IMDG-Labels : 2.1
EmS Number : F-D S-U
Marine pollutant : no
SECTION 15. REGULATORY INFORMATION
OSHA Hazards : Flammable Aerosol
Moderate respiratory irritant
Respiratory sensitizer
Moderate skin irritant
Severe eye irritant
Possible carcinogen.
TSCA Status : On TSCA Inventory
DSL Status : All components of this product are on the Canadian DSL list.
SARA 311/312 Hazards : Fire Hazard/Acute Health Hazard/Chronic Health Hazard
SARA III US. EPA Emergency Planning and Community Right-To-Know Act
(EPCRA) SARA
Title III Section 313 Toxic Chemicals (40 CFR 372.65) - Supplier
Notification Required
Page 8 of 9
Components CAS-No.
xylene 1330-20-7
ethylbenzene 100-41-4
PENN RTK US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323)
Components CAS-No.
ethylbenzene 100-41-4
xylene 1330-20-7
heptan-2-one; methyl amyl ketone 110-43-0
n-butyl acetate 123-86-4
Hexane, 1,6-diisocyanato-, homopolymer 28182-81-2
acetone; propan-2-one; propanone 67-64-1
dimethyl ether 115-10-6
MASS RTK US. Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of
Massachusetts Regulations Section 670.000)
Components CAS-No.
ethylbenzene 100-41-4
xylene 1330-20-7
heptan-2-one; methyl amyl ketone 110-43-0
n-butyl acetate 123-86-4
acetone; propan-2-one; propanone 67-64-1
dimethyl ether 115-10-6
NJ RTK US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated
Section 34:5A-5)
Components CAS-No.
ethylbenzene 100-41-4
xylene 1330-20-7
heptan-2-one; methyl amyl ketone 110-43-0
2-methoxy-1-methylethyl acetate 108-65-6
n-butyl acetate 123-86-4
Hexane, 1,6-diisocyanato-, homopolymer 28182-81-2
acetone; propan-2-one; propanone 67-64-1
dimethyl ether 115-10-6
California Prop. 65: WARNING! This product contains a chemical known in the State of California to
cause cancer: ethylbenzene 100-41-4
SECTION 16. OTHER INFORMATION
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and
belief at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in the text.
Prepared by PRO-SPRAY
An Alco Industries Company
600 Nova Drive, S.E.
Massillon, Ohio 44646
Phone : 330-830-6000
Fax : 330-830-6005
Date Revised: November 7, 2007
Date Reviewed: November 7, 2007
Revision: Format
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