MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION
HAZARD RATINGS
Manufacturer/Supplier SCHENECTADY CANADA LTD.
2* 1
Health
319 Comstock Road
3 3
Scarborough, ON M1L 2H3 Canada Flammability
0 0
Reactivity
Telephone Numbers - 24 Hour Emergency Assistance
B
PPE
CANUTEC (613)-996-6666
In Canada
NFPA Special Hazards
CHEMTREC (800)-424-9300
In United States
Telephone Numbers - General Assistance
In Canada (416)-615-4700
In United States (518)-887-2400
SA-1040
Trade Name
127
NAERG #
B3, D2A, D2B
WHMIS Classifications
N/A
CAS Number
MODIFIED ALKYD RESIN SOLUTION
Chemical Name / Class
Coatings
Product Use
The material, or components, is either on the TSCA inventory list or is exempt from the requirement to be listed.
TSCA Status
on DSL
CEPA/DSL Status
This information is not considered to represent confidential business information to SII / SCL
Trade Secret
2. HAZARDS IDENTIFICATION
Emergency Overview
Hazard Statements
ANSI signal word for this material is: DANGER
Per SARA 312 regulations this material represents the following health hazard(s): acute chronic
Per SARA 312 regulations this material represents the physical hazard(s) of: fire
Per SARA 312 regulations this material is classified as a mixture.
Physical Dangers
FLAMMABLE
General Fire Hazards
Vapors may form explosive mixture with air. Vapors are heavier than air and may travel along the ground to some distant source of
ignition and flash back.
Appearance
Liquid
Overview
Each person who could potentially be exposed to this material, via any route of entry, while performing their assignments, routine and
non-routine; from piping; and/or during an emergency situation, should review this MSDS in order to better understand the hazards
associated with the material. To work safely with this material: keep away from heat and ignition sources avoid contact with eyes, skin,
or clothing avoid breathing material's vapors, dust, or fumes keep container closed use with adequate ventilation -- do not enter any
confined spaces without first verifying air quality wash thoroughly after handling
Potential Health Effects
Health Dangers
potential cancer hazard may cause reproductive system effects
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N/AP = Not Applicable N/A = Not Available
Health Warnings
lung irritant may affect the liver may affect the kidneys may be a teratogen may cause respiratory sensitization may cause skin
sensitization may effect the circulatory system may effect the female's reproductive capabilities may effect the male's reproductive
capabilities may effect the endocrine system
Health Cautions
may cause nervous system effects may cause blood chemistry changes may cause eye irritation may cause skin irritation may
affect mucous membranes may cause gastrointestinal disturbances may alter the body's biochemistry may affect the urinary tract
Environmental Concerns
Information for this material is not available. However, limited ingredient data, if available, is presented.
BENZENE: Aquatic Toxicity: fathead minnow LC50 = 15.1 mg/l/96h; sunfish TLM = 20 ppm/24h; low bioconcentration.
ETHYL BENZENE: Aquatic Toxicity: bluegill TLm = 29 ppm/96h; fathead minnow LC50 = 12.1 mg/l/96h; shrimp LC50 = 8736 mg/l/96h;
may bioconcentrate.
TOLUENE: Aquatic Toxicity: bluegill, LC50 = 17 mg/L/24 hours & 13 mg/L/96 hours; grass shrimp, LC50 = 9.5 ppm/96 hours.
MINERAL SPIRITS: Aquatic Toxicity: may bioconcentrate.
XYLENE: Aquatic Toxicity: bluegill TLm = 22 ppm/96h; rainbow trout LC50 = 13.5 mg/l/96h; low bioconcentration.
N-PROPANOL: Aquatic Toxicity: goldfish TLM = 500 ppm/24 hr; low bioconcentration.
3. COMPOSITION / INFORMATION ON INGREDIENTS
CAS Weight Trade OSHA Capable of
Number Range Secret Hazardous Release
Ingredient Name
AMIDE-IMIDE RESIN N/A 59 - 61 %
MINERAL SPIRITS 64742-47-8 35 - 39 %
XYLENE 1330-20-7 1-5%
N-PROPANOL 71-23-8 <3%
ETHYL BENZENE 100-41-4 <1% *
TOLUENE 108-88-3 < 250 PPM *
BENZENE 71-43-2 < 15 PPM *
* [NOTE: An * in the Capable of Release field indicates the substance(s) so marked represent either: processing by/co-products and/or
residuals. Such may be capable of being released during storage, handling, and/or processing but should not represent a physical, or
health, hazard during normal operations. The user of this material has the responsibility to provide a safe work place and, as necessary via
job-task analysis: develop appropriate work practices, assign personal protective equipment, and provide instructional programs.]
4. FIRST AID MEASURES
Skin
Immediately take off all contaminated clothing. For skin contact, flush with large amounts of water. If any adverse effects persist, get medical
attention. The signs and symptoms that may result from an emergency or an unexpected acute overexposure include: rash to irritation to burns
Eyes
For eye contact, rinse immediately with plenty of water. Seek medical advice. The signs and symptoms that may result from an
emergency or an unexpected acute overexposure include: irritation to burns
Inhalation
Move person to non-contaminated air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give
oxygen. Seek medical attention. The signs and symptoms that may result from an emergency or an unexpected acute overexposure
include: irritation to burns; respiratory depression
Ingestion
If the material is swallowed, get immediate medical attention or advice. Never give anything by mouth to a victim who is unconscious or is
having convulsions. If patient has a good gag reflex, you can consider giving several ounces of water for dilution. The signs and
symptoms that may result from an emergency or an unexpected acute overexposure include: nausea; vomiting; diarrhea; abdominal pain;
gastrointestinal tract irritation to burns
Cardiovascular
The signs and symptoms that may result from an emergency or an unexpected acute overexposure include: arrhythmia
Central Nervous System
Monitor for shock; anticipate seizures and treat accordingly. The signs and symptoms that may result from an emergency or an
unexpected acute overexposure include: headache; CNS depression; coma
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N/AP = Not Applicable N/A = Not Available
5. FIRE FIGHTING MEASURES
Flammable Properties
Substance Name % LEL % UEL
NA NA
SA-1040
Sensitivity to Static Discharge
Material can accumulate static charges from material handling management. Bond and ground as appropriate. For additional recommendations,
consult an applicable guideline such as National Fire Protection Association [NFPA] 77, "Recommended Practices on Static Electricity". NOTE:
The Lower Explosive Limit [LEL] for organic liquids can range from as low as 0.5 - 1%.
Extinguishing Media
Dry chemical, foam, carbon dioxide, water fog. Do not direct a solid stream of water or foam into hot, burning pools; this may result in frothing and
increase fire intensity.
Unsuitable Extinguishing Media
Do not use a solid water stream as it may scatter and spread fire.
Protection of Firefighters/Specific Hazards Arising from the Chemical
Exclude air; treat like a gasoline or oil fire. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand
breathing apparatus, protective clothing and face mask.
6. ACCIDENTAL RELEASE, SPILL, LEAK PROCEDURES
Personal Precautions
Follow facility/company's emergency plans.
Environmental Precautions
Stop the flow of material, if this is without risk. Eliminate sources of ignition. Ventilate the contaminated area. Contain the spill and
prevent the material from obtaining access to any confined spaces, public sewers, or waterways.
Methods for Clean-Up
Ventilate the contaminated area. Eliminate ignition sources including sources of electrical, static or frictional sparks. Collect the material
using absorbents, non-sparking tools, explosion-proof vacuums or other equipment required by the size of the release. Decontaminate
the area, collecting any cleaning and rinsing media for proper reclamation or disposal.
Other Information
Wear appropriate protective equipment and clothing during clean-up. Determine appropriate course of action for the collected material.
Regulations vary. Consult local authorities before disposal.
Exposure Guidelines
All PPE use is to be determined by a qualified person. Protect from eye and skin contact.
7. HANDLING & STORAGE
Handling Procedures
Organics can obtain an electrostatic charge during processing activities including: mixing, filtering, or pumping which may represent a spark hazard
and, therefore, a fire hazard. Also, a sudden release of such materials from process equipment at elevated temperatures, and/or pressures, can
result in ignitions from static absent any apparent ignition source. Flashpoint and autoignition values obtained from standard test conditions may
not be applicable to other situations and, thus, the safe use of this material in any process should be reviewed by one familiar with both the
processing conditions and this material. As with all chemicals, good industrial hygiene practices should be followed when handling this material.
When the container(s) is empty it may retain product residue including vapors which could accumulate. Therefore, do not cut, drill, grind, or weld
empty containers. Additionally, do not conduct such activity(ies) near full, partially full, or empty product containers without appropriate workplace
safety authorization(s) or permit(s).
Storage Procedures
Protect container from physical abuse. Keep the container tightly closed. Keep this material in a cool, well-ventilated place. Eliminate all
sources of ignition. Keep separate from incompatibles. Bond and ground containers when transferring material. Do not handle or store
near an open flame, heat or other sources of ignition. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or
other sources of ignition. Empty product containers may contain product residue. Do not reuse empty containers.
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N/AP = Not Applicable N/A = Not Available
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
All PPE use is to be determined by a qualified person. Protect from eye and skin contact.
ACGIH - Occupational Exposure Limits - Skin Absorbers
BENZENE 71-43-2 skin - potential for cutaneous absorption
N-PROPANOL 71-23-8 skin - potential for cutaneous absorption
TOLUENE 108-88-3 skin - potential for cutaneous absorption
ACGIH - Occupational Exposure Limits - STELs
BENZENE 71-43-2 2.5 ppm STEL
ETHYL BENZENE 100-41-4 125 ppm STEL
N-PROPANOL 71-23-8 250 ppm STEL
XYLENE 1330-20-7 150 ppm STEL
ACGIH - Occupational Exposure Limits - TWAs
BENZENE 71-43-2 0.5 ppm TWA
ETHYL BENZENE 100-41-4 100 ppm TWA
N-PROPANOL 71-23-8 200 ppm TWA
TOLUENE 108-88-3 50 ppm TWA
XYLENE 1330-20-7 100 ppm TWA
AEL/REL [Acceptable/Recommended Exposure Limit]
MINERAL SPIRITS 64742-47-8 REL = 5 mg/m3; TWA [Exxon]
Canada - Ontario - OHSA - CEVs
BENZENE 71-43-2 15 ppm CEV; 48 mg/m3 CEV (designated substance
regulation)
Canada - Ontario - OHSA - Designated Substances
BENZENE 71-43-2 5 ppm TWAEV; 16 mg/m3 TWAEV 15 ppm CEV; 48 mg/m3
CEV; See Ontario Reg. 839 for full information.
Canada - Ontario - OHSA - Skin Notations
N-PROPANOL 71-23-8 absorption through skin, eyes, or mucous membranes
Canada - Ontario - OHSA - STEVs
BENZENE 71-43-2 5 ppm STEV; 48 mg/m3 STEV (designated substance
regulations)
ETHYL BENZENE 100-41-4 125 ppm STEV; 540 mg/m3 STEV
N-PROPANOL 71-23-8 250 ppm STEV; 615 mg/m3 STEV
TOLUENE 108-88-3 150 ppm STEV; 564 mg/m3 STEV
XYLENE 1330-20-7 150 ppm STEV; 650 mg/m3 STEV
Canada - Ontario - OHSA - TWAEVs
BENZENE 71-43-2 1 ppm TWAEV; 3.2 mg/m3 TWAEV (designated substance
regulation); 5 ppm TWAEV; 16 mg/m3 TWAEV (These
values apply to work places in which the designated
substance regulation does not apply.)
ETHYL BENZENE 100-41-4 100 ppm TWAEV; 435 mg/m3 TWAEV
N-PROPANOL 71-23-8 200 ppm TWAEV; 490 mg/m3 TWAEV
TOLUENE 108-88-3 50 ppm TWAEV; 376 mg/m3 TWAEV
XYLENE 1330-20-7 100 ppm TWAEV; 435 mg/m3 TWAEV
NIOSH - Health Standards - Carcinogenic Chemicals
BENZENE 71-43-2 potential human carcinogen
NIOSH - Health Standards - Exposure Limits
BENZENE 71-43-2 0.1 ppm TWA (8 hr); 0.32 mg/m3 TWA (8 hr); C (15 min) 1
ppm; C (15 min) 3.2 mg/m3
ETHYL BENZENE 100-41-4 100 ppm TWA; 435 mg/m3 TWA; 125 ppm STEL; 545
mg/m3 STEL
N-PROPANOL 71-23-8 200 ppm TWA (skin); 500 mg/m3 TWA (skin); 250 ppm
STEL (skin); 625 mg/m3 STEL (skin)
TOLUENE 108-88-3 100 ppm TWA; 375 mg/m3 TWA; 150 ppm STEL; 560
mg/m3 STEL
XYLENE 1330-20-7 100 ppm TWA; 434 mg/m3 TWA; 150 ppm STEL; 655
mg/m3 STEL
OSHA - 29 CFR 1910 Specifically Regulated Chemicals
BENZENE 71-43-2 1 ppm TWA; 5 ppm STEL; 0.5 ppm TWA action limit;
Cancer hazard; Flammable (see 29 CFR 1910.1028)
OSHA - Final PELs - Ceiling Limits
BENZENE 71-43-2 25 ppm Ceiling
TOLUENE 108-88-3 300 ppm Ceiling
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N/AP = Not Applicable N/A = Not Available
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
OSHA - Final PELs - Time Weighted Averages (TWAs)
BENZENE 71-43-2 10 ppm TWA (apply only to exempt industry segments)
ETHYL BENZENE 100-41-4 100 ppm TWA; 435 mg/m3 TWA
N-PROPANOL 71-23-8 200 ppm TWA; 500 mg/m3 TWA
TOLUENE 108-88-3 200 ppm TWA
XYLENE 1330-20-7 100 ppm TWA; 435 mg/m3 TWA
Engineering Controls
Ventilation should be sufficient to effectively remove, and prevent buildup of, any vapors, dusts, or fumes that may be generated during
handling or thermal processing. In order to ensure appropriate electrical safety practices are followed, consult applicable standards.
These may include guidelines such as the National Fire Protection Association [NFPA] 70, "The National Electrical Code" and NFPA 499,
"Recommended Practice for the Classification of Combustible Dusts and of Hazardous (Classified) Locations for Electrical Installations in
Chemical Process Areas ". NOTE: since this material's vapors, dust or fumes can form explosive mixtures in air, ensure that any
potential areas where explosions may occur are designed to minimize potential damage. For recommendations to prevent such
explosions and associated damage, consult applicable guidelines such as National Fire Protection Association [NFPA] 69, "Standard on
Explosion Prevention Systems" and/or NFPA 68, "Guide for Venting Deflagrations".
Personal Protective Equipment
Eye Protection
Wear safety glasses with side shields; chemical goggles (if splashing is possible). Wear a face shield if a splash hazard exists. Select & use eye
protection per a competent health & safety professional using: OSHA [29 CFR 1910.133] or Europe's [EN166].
Skin Protection
Use appropriate hand protection. Wear impervious gloves for prolonged contact.
Respiratory Protection
Maintain material's vapors, fumes, or particulate levels below any levels of concern including, for solids, considering the material as a
particulate not otherwise classified [nuisance dust] @ 10 mg/m3. Select & use respirators per a competent health & safety professional
using: OSHA (29 CFR 1910.134); ANSI (Z88.2-1992); or Europe's [EN 149].
9. PHYSICAL & CHEMICAL PROPERTIES
Liquid
Physical State
300 - 410 癋
Boiling Point ( 149 - 210 癈 )
105 癋 Tag Closed Cup
Flash Point ( 41 癈 )
< Ether
Evaporation Rate
Combustible II
Flammability Class
N/A
Vapor Pressure
> Air
Vapor Density
0.95 - 1
Specific Gravity
4%
Solubility in Water
7.9 -8.3
lbs/Gal
10. STABILITY & REACTIVITY
Chemical Stability
Stable under normal conditions [e.g., 70癋 (21癈) & 14.7 psig (760 mmHg)].
Conditions to Avoid
Avoid excessive heat and ignition sources.
Incompatible Materials
This material may react with: strong oxidizing agents
XYLENES may react with: strong oxidizing agents; concentrated acids [acetic, nitric, sulfuric]; halogens [bromine, chlorine, fluorine]; molten sulfur.
Hazardous Decomposition Products
Upon decomposition this product emits carbon monoxide, carbon dioxide, and/or low molecular weight hydrocarbons.
Possibility of Hazardous Reactions
Will not occur under normal conditions [e.g., 70癋 (21癈) & 14.7 psig (760 mmHg)].
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N/AP = Not Applicable N/A = Not Available
11. TOXICOLOGICAL INFORMATION
Overview
While OSHA 29 CFR 1910.1200 emphasizes the use of industrial -- human -- data for workplace hazard evaluations, relatively few materials have
such data available as toxicological information is primarily obtained from tests conducted on, or with, animals used as surrogates for humans.
Therefore, the effects and symptoms represented, and/or summarized, may not reflect actual workplace exposures. All materials used in a given
work area should be evaluated by a competent person who can then advise involved workers of health effects, or symptoms, if any, they may
experience from their assigned tasks.
MINERAL SPIRITS
MINERAL SPIRITS, medium aliphatic solvent naphtha, is a petroleum distillate fraction primarily comprised of paraffins in the C9 - C16
range with a boiling point between 140 - 290癈. Other major components include naphthenes and aromatics.
XYLENE
XYLENE is commercially a mixture. It primarily consists of three xylene isomers along with ethyl benzene. The approximate concentrations
are: 3-xylene [45 - 70%]; 2-xylene [10 - 25%]; 4-xylene [6 - 15%], and ethyl benzene [<15%].
Routes of Entry
inhalation ingestion eye contact skin contact
Target Organs
liver kidneys blood heart female reproductive system male reproductive system endocrine system respiratory system central
nervous system urinary tract
Skin Contact
Dermal LD50s
BENZENE 71-43-2 Dermal LD50 [rabbit]: >9400 ul/kg
ETHYL BENZENE 100-41-4 Dermal LD50 [rabbit]: 4100 mg/kg
MINERAL SPIRITS 64742-47-8 Dermal LD50 [rabbit]: >3000 mg/kg [estimate]
N-PROPANOL 71-23-8 Dermal LD50 [rabbit]: 5040 mg/kg
TOLUENE 108-88-3 Dermal LD50 [rabbit]: 14100 ul/kg
XYLENE 1330-20-7 Dermal LD50 [rabbit]: >1700 mg/kg
Ingestion
Oral LD50
BENZENE 71-43-2 Oral LD50 [rat]: 930 mg/kg
ETHYL BENZENE 100-41-4 Oral LD50 [rat]: 3500 mg/kg
MINERAL SPIRITS 64742-47-8 Oral LD50 [rat]: >5000 mg/kg [vendor]
N-PROPANOL 71-23-8 Oral LD50 [rat]: 1870 mg/kg
TOLUENE 108-88-3 Oral LD50 [rat]: 636 mg/kg
XYLENE 1330-20-7 Oral LD50 [rat]: 4300 mg/kg
Inhalation
Inhalation LC50s
BENZENE 71-43-2 Inhalation LC50 [rat]: 10000 ppm/7h
MINERAL SPIRITS 64742-47-8 Inhalation LC50 [rat]: >2500 ppm/4h [vendor]
TOLUENE 108-88-3 Inhalation LC50 [rat]: 13000 ppm/4h
XYLENE 1330-20-7 Inhalation LC50 [rat]: 5000 ppm/24h
Inhalation LCLo
ETHYL BENZENE 100-41-4 Inhalation LCLo [rat]: 4000 ppm/4h
N-PROPANOL 71-23-8 Inhalation LCLo [rat]: 4000 ppm/4h
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N/AP = Not Applicable N/A = Not Available
Carcinogenicity
ACGIH - Occupational Exposure Limits - Carcinogens
BENZENE 71-43-2 A1 - Confirmed Human Carcinogen
ETHYL BENZENE 100-41-4 A3 - Animal Carcinogen
TOLUENE 108-88-3 A4 - Not Classifiable as a Human Carcinogen
XYLENE 1330-20-7 A4 - Not Classifiable as a Human Carcinogen
IARC - Group 1 (carcinogenic to humans)
BENZENE 71-43-2 Supplement 7, 1987; Monograph 29, 1982
IARC - Group 2B (Possibly carcinogenic to humans)
ETHYL BENZENE 100-41-4 Monograph 77, 2000
IARC - Group 3 (not classifiable)
TOLUENE 108-88-3 Monograph 71, 1999; Monograph 47, 1989
XYLENE 1330-20-7 Monograph 71, 1999; Monograph 47, 1989
NTP - Report on Carcinogens - Known Carcinogens
BENZENE 71-43-2 Known Carcinogen
OSHA - Regulated Carcinogens
BENZENE 71-43-2 Present
12. ECOLOGICAL INFORMATION
Persistence and Degradability
Information for this material is not available. However, limited ingredient data, if available, is presented.
MINERAL SPIRITS: Terrestrial Fate: may leach; may volatilize; biodegrades. Aquatic Fate: volatizes [half-lives: river ~ 3 hours; lake ~4 days];
biodegrades [BOD5 >70%]. Atmospheric Fate: photochemically degrades [half-life = 4 - 8 days].
XYLENE: Terrestrial Fate: leaches; slow biodegradation. Aquatic Fate: slow biodegradation [BOD5: 40 - 80%]; volatilizes [half-lives: river ~ 3
hours; lake ~ 100 hours]. Atmospheric Fate: photochemically degrades [half-life: 1 - 2 days].
N-PROPANOL: Terrestrial Fate: evaporates; leaches; low soil adsorption. Aquatic Fate: volatizes [half-life ~7 days]; biodegrades [BOD5 ~60 %].
Atmospheric Fate: photochemically degrades [half-life ~7 days].
BENZENE: Terrestrial Fate: volatilizes; biodegrades. Aquatic Fate: volatilizes [half-life: river ~3 hours].
ETHYL BENZENE: Terrestrial Fate: volatilizes; leaches; biodegrades slowly. Aquatic Fate: volatilizes [half-lives: river ~ 2 hours; lake ~4 days];
biodegrades slowly [BOD5 ~3%; BOD7 = as high as 85%]. Atmospheric Fate: photochemically degrades [half-life ~55 hours].
TOLUENE: Terrestrial Fate: evaporates; may leach; biodegrades slowly. Aquatic Fate: volatilizes; biodegrades [BOD8 ~ 40% ]. Atmospheric
Fate: photochemically degrades [half-life = 3 - 24 hours].
13. DISPOSAL CONSIDERATIONS
Disposal Instructions
Any wastes generated must be managed in accordance with local, state and federal regulations.
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
BENZENE 71-43-2 10 lb final RQ (receives an adjustable RQ of 10 lbs based
on potential carcinogenicity in August 14, 1989 final rule);
4.54 kg final RQ (receives an adjustable RQ of 10 lbs based
on potential carcinogenicity in August 14, 1989 final rule)
ETHYL BENZENE 100-41-4 1000 lb final RQ; 454 kg final RQ
TOLUENE 108-88-3 1000 lb final RQ; 454 kg final RQ
XYLENE 1330-20-7 100 lb final RQ; 45.4 kg final RQ
New York - Reporting of Releases Part 597 - List of Hazardous Substances
BENZENE 71-43-2 Air RQ = 10 lbs; Land/Water RQ = 1 lb.
ETHYL BENZENE 100-41-4 Air RQ = 1,000 lbs; Land/Water RQ = 1 lb.
TOLUENE 108-88-3 Air RQ = 1,000 lbs; Land/Water RQ = 1 lb.
XYLENE 1330-20-7 Air RQ = 1,000 lbs; Land/Water RQ = 1 lb.
Code Name DOT RQ EPA RQ
Waste Flammable material with a flash point <140癋
D001 100 100
Waste Benzene
D018 10 10
14. TRANSPORT INFORMATION
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N/AP = Not Applicable N/A = Not Available
Comments
NOTE: This section's data are provided as a guide to the overall classification of the product. However, transportation classifications may
be subject to change as, for example, with changes in package size. Consult shipper requirements under IMO, ICAO (IATA), TDG and
49 CFR to assure regulatory compliance. Additionally, please contact the Transportation & Regulatory Affairs Specialist with SII/SCL @
(518)-370-4200 if there are questions regarding the cleaning of containers, or vessels. Remember that the reuse, treatment, or disposal,
of any related residuals or wastes must be in accordance with all federal, state, and local environmental regulations.
SURFACE TRANSPORTATION (HIGHWAY/RAIL)
BULK-- TANK TRUCK/TANK
CAR
Resin solution
Shipping Name
class 3
Hazard Class
UN1866
Identification Number
III
Packing Group
DRUM(s)/BAG(s)
Resin, coal tar or petroleum, non-dangerous goods
Shipping Name
INTERMEDIATE BULK
CONTAINER
Resin solution
Shipping Name
class 3
Hazard Class
UN 1866
Identification Number
III
Packing Group
PAIL(s)/CAN(s)
Resin, coal tar or petroleum, non-dangerous goods
Shipping Name
IMDG CODE (WATER)
DRUM(s)/BAG(s)
RESIN SOLUTION
Shipping Name
class 3
Hazard Class
UN1866
Identification Number
PG III
Packing Group
PAIL(s)/CAN(s)
RESIN SOLUTION
Shipping Name
class 3
Hazard Class
UN1866
Identification Number
PG III
Packing Group
ICAO/IATA (AIR)
DRUM(s)/BAG(s)
Resin solution
Shipping Name
3
Hazard Class
UN1866
Identification Number
II
Packing Group
PAIL(s)/CAN(s)
Resin solution
Shipping Name
3
Hazard Class
UN1866
Identification Number
II
Packing Group
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N/AP = Not Applicable N/A = Not Available
15. REGULATORY INFORMATION
CAA - 1990 Hazardous Air Pollutants
BENZENE 71-43-2 [present] (includes Benzene from gasoline)
ETHYL BENZENE 100-41-4 [present]
TOLUENE 108-88-3 [present]
XYLENE 1330-20-7 [present]
CAA - High Risk Pollutants
BENZENE 71-43-2 Weighting factor: 10
CAA - HON Rule - Organic HAPs
BENZENE 71-43-2 [present]
ETHYL BENZENE 100-41-4 [present]
TOLUENE 108-88-3 [present]
XYLENE 1330-20-7 [present]
CAA - HON Rule - SOCMI Chemicals
BENZENE 71-43-2 compliance by Oct. 24, 1994
ETHYL BENZENE 100-41-4 compliance by Oct. 24, 1994
TOLUENE 108-88-3 compliance by Oct. 24, 1994
XYLENE 1330-20-7 compliance by Oct. 24, 1994
CAA - Volatile Organic Compounds (VOCs) in SOCMI
BENZENE 71-43-2 Present
ETHYL BENZENE 100-41-4 Present
N-PROPANOL 71-23-8 Present
TOLUENE 108-88-3 Present
XYLENE 1330-20-7 Present
FDA - 21 CFR - Total Food Additives
BENZENE 71-43-2 172.560, 175.105
N-PROPANOL 71-23-8 172.515, 573.880
FDA - Controlled Substances Act - Essential Chemicals (List II)
TOLUENE 108-88-3 Import/Export threshold volume = 500 gallons; weight =
1,591 kilograms; Domestic threshold volume = 50 gallons;
weight = 159 kilograms
OSHA Materials that May be Capable of Release (29 CFR 1910.1200(d)(5)(i)(iv))
Depending on the concentrations that may be released from this material, vapors may be heavier than air, may concentrate; and may travel along
the ground to some source of ignition including static electricity. The composite potential health hazards of the substance(s) marked as capable of
release include: potential cancer hazard lung irritant has tested positive as a mutagen may cause reproductive system effects may affect
the liver may affect the kidneys may be a teratogen may effect the nervous system may cause blood chemistry changes may cause eye
irritation may cause skin irritation may affect mucous membranes may influence, or cause, tumor(s) growth may cause gastrointestinal
disturbances may affect the heart may affect the female's reproductive capabilities may affect the male's reproductive capabilities may
effect the endocrine system may alter the body's biochemistry may affect the spleen may affect muscular response may affect the urinary
tract
Superfund Amendments & Reauthorization Act of 1986
This material may be applicable to the SARA regulations. Thus, it may require you to file appropriate governmental reports if the total amount of
this material, or any of the listed constituents, in your possession ever exceeds the regulations' threshold values.
CERCLA/SARA - Section 313 - Emission Reporting
BENZENE 71-43-2 form R reporting required for 0.1% de minimis concentration
ETHYL BENZENE 100-41-4 form R reporting required for 1.0% de minimis concentration
TOLUENE 108-88-3 form R reporting required for 1.0% de minimis concentration
XYLENE 1330-20-7 form R reporting required for 1.0% de minimis concentration
International Regulations
Canada - Accelerated Reduction/Elimination of Toxics (ARET)
BENZENE 71-43-2 B-3 (meets or exceeds toxicity criterion) (Listed under
'Aromatics') B-3 (meets or exceeds toxicity criterion)
(Listed under 'Aromatics')
Canada - NPRI (National Pollutant Release Inventory) for 2001
BENZENE 71-43-2 Part 1 reporting required
ETHYL BENZENE 100-41-4 Part 1 reporting required
TOLUENE 108-88-3 Part 1 reporting required
XYLENE 1330-20-7 Part 1 reporting required
Canada - WHMIS: Ingredient Disclosure
ETHYL BENZENE 100-41-4 0.1%; English Item 697; French Item 854
N-PROPANOL 71-23-8 1%; English Item 1355; French Item 187
B3, D2A, D2B
WHMIS Ratings
Trade Name | SA-1040 MSDS ANSI2
9 / 10
Short # | Printed On | 5/18/2005
N/AP = Not Applicable N/A = Not Available
European Classifications
This substance is considered hazardous per The Safety Data Sheets Directive (91/155/EC) as amended
EU Risk Phrases
R10 Flammable.
R36/37/38 Irritating to eyes, respiratory system and skin.
EU Safety Phrases
Keep away from sources of ignition - No smoking.
S16
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S26
Take precautionary measures against static discharges.
S33
Wear suitable protective clothing and gloves.
S36/37
EU Symbol(s)
Xn - Harmful
16. OTHER INFORMATION
Disclaimer
The health and safety information is that available to SII/SCL as of the date published and SII/SCL makes no representation of the
information's completeness or accuracy. Any data provided is based on either: reference sources, testing performed on a representative
sample(s), or professional judgement. The physical data should not be construed as either representing specifications or a guaranteed
analysis. This material has been classified in accordance with the hazard criteria of the Controlled Products Regulation and the MSDS
contains information required by Controlled Products Regulation. SII/SCL provides its MSDS in several languages using English as the
primary language. While SII/SCL uses reasonable efforts to provide accurate translations, SII/SCL assumes no liability, or responsibility,
for errors, omissions or ambiguities in any translations. SII/SCL expects those persons who receive this MSDS to exercise their
independent professional judgement, or consult with a competent health/safety professional, to determine how to utilize this material
safely. This includes, but is not exclusive to, the material's appropriateness for a specific use, the type of personal protection equipment
necessary, and the use of engineering controls. In no event is SII/SCL liable for any damages whatsoever arising out of your use of this
material based upon information obtained from this MSDS including: direct, indirect, incidental, consequential or punitive claims or
damages.
5/18/2005 5/12/2005
Completed On Replaces Sheet Dated
HGW
Completed By
Trade Name | SA-1040 MSDS ANSI2
10 / 10
Short # | Printed On | 5/18/2005
N/AP = Not Applicable N/A = Not Available
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