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MSDS  
:
 Potassium pyrosulfate, p.a.
CAS  
:
 7790-62-7
SYNONYMS  
:
 

Section 1 - Chemical Product and Company Identification

MSDS Name: Potassium pyrosulfate, p.a.
Catalog Numbers: AC207910000, AC207910250, AC207915000, P195-3, P195-500
Synonyms:
Potassium disulfate; Potassium hydrogen sulfate, anhydrous; Potassium pyrosulfate
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7790-62-7 Potassium pyrosulfate 99.0% 232-216-8

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: white powder.
Danger! Corrosive. Causes eye and skin burns. Causes digestive and respiratory tract burns. Moisture sensitive.
Target Organs: Respiratory system, eyes, skin, mucous membranes.


Potential Health Effects
Eye: Causes eye burns. May cause permanent visual impairment. Risk of serious damage to eyes.
Skin: Contact with skin causes irritation and possible burns, especially if the skin is wet or moist.
Ingestion: May cause corrosion and permanent tissue destruction of the esophagus and digestive tract.
Inhalation: Causes chemical burns to the respiratory tract.
Chronic: Chronic exposure may cause effects similar to those of acute exposure.

Section 4 - First Aid Measures


Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Do not allow contact with water. Keep from contact with moist air and steam.
Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed. Store protected from moisture.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Potassium pyrosulfate none listed none listed none listed

OSHA Vacated PELs: Potassium pyrosulfate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear a chemical apron.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Powder
Appearance: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not applicable.
Vapor Density: Not applicable.
Evaporation Rate:Not applicable.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:325 deg C
Decomposition Temperature:Not available.
Solubility: may decompose
Specific Gravity/Density:2.5120g/cm3
Molecular Formula:K2O7S2
Molecular Weight:254.31

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures. Moisture sensitive. Readily hydrolyzed by moisture. Decomposes in the presence of water or acids to form sulfuric acid.
Conditions to Avoid: Incompatible materials, dust generation, moisture.
Incompatibilities with Other Materials: Oxidizing agents, reducing agents, acids, bases, alkalis.
Hazardous Decomposition Products: Oxides of potassium, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 7790-62-7 unlisted.
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 7790-62-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: Fish: Pseudomonas putida:Fish: Pseudomonas putida:

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. POTASSIUM HYDROGEN SULFATE
Hazard Class: 8 8
UN Number: UN3260 UN2509
Packing Group: III II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7790-62-7 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7790-62-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     C
Risk Phrases:

     R 34 Causes burns.
     R 41 Risk of serious damage to eyes.

Safety Phrases:

     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 28A After contact with skin, wash immediately with plenty of water
     .

WGK (Water Danger/Protection)

     CAS# 7790-62-7: No information available.
Canada - DSL/NDSL
     CAS# 7790-62-7 is listed on Canada's DSL List.
Canada - WHMIS
     not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 2/24/1999
Revision #8 Date: 6/22/2006

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

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