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MSDS  
:
 Basic Stain Set, Water Solutions
CAS  
:
 17372-87-1
SYNONYMS  
:
 

Section 1 - Chemical Product and Company Identification

MSDS Name: Basic Stain Set, Water Solutions
Catalog Numbers: S70111-2
Synonyms:
Biological stains kit
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7732-18-5 Water 99.0 231-791-2
61-73-4 Methylene blue 0-1.0 200-515-2
477-73-6 C.I. Basic Red 2 0-1.0 207-518-8
548-62-9 Gentian violet 0-1.0 208-953-6
553-24-2 Neutral red 0-1.0 209-035-8
569-64-2 Malachite Green 0-1.0 209-322-8
10114-58-6 Bismark Brown 0-1.0 233-314-3
17372-87-1 Eosin yellow 0-1.0 241-409-6

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: various liquid.
Caution! May cause irritation. This is expected to be a low hazard for usual industrial handling.
Target Organs: None.


Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation.
Ingestion: May cause irritation of the digestive tract.
Inhalation: May cause respiratory tract irritation. Low hazard for usual industrial handling.
Chronic: Not available.

Section 4 - First Aid Measures


Eyes: Get medical aid. Gently lift eyelids and flush continuously with wate r.
Skin: Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.
Antidote: None reported.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: Not published.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - Handling and Storage


Handling: Use with adequate ventilation. Avoid contact with eyes. Keep container tightly closed.
Storage: Store in a cool, dry place.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Good general ventilation should be sufficient to control airborne levels.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Water none listed none listed none listed
Methylene blue none listed none listed none listed
C.I. Basic Red 2 none listed none listed none listed
Gentian violet none listed none listed none listed
Neutral red none listed none listed none listed
Malachite Green none listed none listed none listed
Bismark Brown none listed none listed none listed
Eosin yellow none listed none listed none listed

OSHA Vacated PELs: Water: No OSHA Vacated PELs are listed for this chemical. Methylene blue: No OSHA Vacated PELs are listed for this chemical. C.I. Basic Red 2: No OSHA Vacated PELs are listed for this chemical. Gentian violet: No OSHA Vacated PELs are listed for this chemical. Neutral red: No OSHA Vacated PELs are listed for this chemical. Malachite Green: No OSHA Vacated PELs are listed for this chemical. Bismark Brown: No OSHA Vacated PELs are listed for this chemical. Eosin yellow: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: various
Odor: odorless
pH: Not available.
Vapor Pressure: 1442 mm Hg @20 deg C
Vapor Density: 0.7-1.6
Evaporation Rate:>1.0 (ether=1)
Viscosity: Not available.
Boiling Point: 100 deg C
Freezing/Melting Point:0 deg C
Decomposition Temperature:Not available.
Solubility: Completely soluble in water.
Specific Gravity/Density:0.95-1.0
Molecular Formula:Mixture
Molecular Weight:Not available

Section 10 - Stability and Reactivity


Chemical Stability: Stable.
Conditions to Avoid: None reported.
Incompatibilities with Other Materials: None reported.
Hazardous Decomposition Products: None.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 7732-18-5: ZC0110000      
CAS# 61-73-4: SO5600000      
CAS# 477-73-6: SG1623000      
CAS# 548-62-9: BO9000000      
CAS# 553-24-2: SG1400000      
CAS# 569-64-2: BQ1180000      
CAS# 10114-58-6 unlisted.      
CAS# 17372-87-1: LM5850000
LD50/LC50:
CAS# 7732-18-5:
     Oral, rat: LD50 = >90 mL/kg;
.

CAS# 61-73-4:
     Oral, mouse: LD50 = 3500 mg/kg;
     Oral, rat: LD50 = 1180 mg/kg;
.

CAS# 477-73-6:
.

CAS# 548-62-9:
     Oral, mouse: LD50 = 96 mg/kg;
     Oral, rabbit: LD50 = 150 mg/kg;
     Oral, rat: LD50 = 420 mg/kg;
.

CAS# 553-24-2:
.

CAS# 569-64-2:
     Oral, mouse: LD50 = 80 mg/kg;
.

CAS# 10114-58-6:
.

CAS# 17372-87-1:
     Oral, mouse: LD50 = 2344 mg/kg;
.

Carcinogenicity:
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 61-73-4: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 477-73-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 548-62-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 553-24-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 569-64-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 10114-58-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 17372-87-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: No information reported.
Physical: No information available.
Other: None.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: FLAMMABLE LIQUIDS, N.O.S. No information available.
Hazard Class: 3
UN Number: UN1993
Packing Group: II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7732-18-5 is listed on the TSCA inventory.
     CAS# 61-73-4 is listed on the TSCA inventory.
     CAS# 477-73-6 is listed on the TSCA inventory.
     CAS# 548-62-9 is listed on the TSCA inventory.
     CAS# 553-24-2 is listed on the TSCA inventory.
     CAS# 569-64-2 is listed on the TSCA inventory.
     CAS# 10114-58-6 is listed on the TSCA inventory.
     CAS# 17372-87-1 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 61-73-4: immediate, delayed.
     CAS # 477-73-6: immediate, reactive.
     CAS # 548-62-9: immediate.
     CAS # 569-64-2: immediate.
     CAS # 17372-87-1: immediate.
Section 313
     This material contains Malachite Green (CAS# 569-64-2, 0-1.0%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 61-73-4 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 477-73-6 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 548-62-9 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 553-24-2 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 569-64-2 can be found on the following state right to know lists: New Jersey, Pennsylvania, Massachusetts.
     CAS# 10114-58-6 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 17372-87-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:


Safety Phrases:


WGK (Water Danger/Protection)

     CAS# 7732-18-5: No information available.
     CAS# 61-73-4: 2
     CAS# 477-73-6: No information available.
     CAS# 548-62-9: 2
     CAS# 553-24-2: 1
     CAS# 569-64-2: No information available.
     CAS# 10114-58-6: 1
     CAS# 17372-87-1: 1
Canada - DSL/NDSL
     CAS# 7732-18-5 is listed on Canada's DSL List.
     CAS# 61-73-4 is listed on Canada's DSL List.
     CAS# 477-73-6 is listed on Canada's DSL List.
     CAS# 548-62-9 is listed on Canada's DSL List.
     CAS# 553-24-2 is listed on Canada's DSL List.
     CAS# 569-64-2 is listed on Canada's DSL List.
     CAS# 10114-58-6 is listed on Canada's DSL List.
     CAS# 17372-87-1 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 61-73-4 is listed on the Canadian Ingredient Disclosure List.
     CAS# 548-62-9 is listed on the Canadian Ingredient Disclosure List.
     CAS# 569-64-2 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #5 Date: 11/07/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
Bromocresol Purple Solution 115-40-2
2-Chloroacrylonitrile, 99% (stabilized with ca. 500 ppm hydroquinone) 123-31-9
L-Adrenaline Hydrochloride Solution (1:10,000) 51-43-4L-Adrenaline<-td>
Chloramine-T trihydrate 7080-50-4
alpha-D-(+)-Lactose monohydrate 5989-81-1
Calcium Stearate 1592-23-0
Zinc Metal (Shot, Sticks, Pieces and Sheet) 7440-66-6
Phenolphthalein Solution 1% 77-09-8
Ammonia Combination Electrode: pH Ionic Strength Adjustor 1310-73-2
Iodine Solution 0.1 N 7553-56-2
Crystal Violet 0.1 and 1.0% Solutions 532-32-1
FisherBrand Cytoprep 75-28-5
FisherBrand Traceable Conductivity Calibration Standards 7447-40-7
Fisherbrand? Versa-Clean? 68603-42-9
Common 20 Stain Kit, Alcoholic 67-56-1
Basic Stain Set, Water Solutions 17372-87-1
Vital Stain Set, Alcoholic 67-56-1
Bile Salts 83-44-3
Ethyl alcohol, denatured (S71297 Part A) Not available
Methyl Violet 2B 8004-87-3
Thermit Black 7429-90-5
TCLP Extraction Fluid 1 1310-73-2
Bromine Water (EMD) 7726-95-6
Potassium pyrosulfate, p.a. 7790-62-7
Fehling's Solution, Part B 1310-58-3
Silica Gel Desiccant Grade 7646-79-9
1,3-Dibromo-5-fluorobenzene, 98% 1435-51-4
Quercetin hydrate 849061-97-8
Bouin's solution 7732-18-5
Aitch-tu-ess Cartridge 57455-37-5
Aceto-Orcein Solution 1400-62-0
Aceto-Carmine Solution 1390-65-4
Ethanol, denat. with mek 78-93-3
Carnoy's Solution
Methyl Cellulose Solution and Paste 9004-67-5
Sulfuric acid solution, 0.02 N (N/50) 50-00-0
Iodine Solution, Tincture 7553-56-2
Iodine-Potassium Iodide Solution 7681-11-0
1,3-Diphenylacetone-p-tosylhydrazone, 98% 19816-88-7
Ferric Sulfate Monohydrate 10028-22-5
Buffer Concentrate, pH 7.00 64-02-8
Crystal Violet Solution 548-62-9
Tri-p-tolyl phosphate 78-32-0
Universal Indicator Solution (S75017) 845-10-3
Formic acid 7732-18-5
Hexanes (Technical and Certified Grades) 0-01-1Methylpentanes<-td>
Methyl Red Indicator Solution 493-52-7
Nitric Acid 6M-9M Solution 7697-37-2Nitric acid<-td>
Ethidium Bromide Solution 1239-45-8
Tris Glycine, 10X Powder 77-86-1



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