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MSDS  
:
 Bromine Water (EMD)
CAS  
:
 7726-95-6
SYNONYMS  
:
 

Section 1 - Chemical Product and Company Identification

MSDS Name: Bromine Water (EMD)
Catalog Numbers: S79926-3, S799263A, S79926-1MFD, S79926-1MFDH, S79926-3MFD, S79926-3MFDH, S79926-4MFD, S79926-4MFDH
Synonyms:
Bromine Solution; Bromine
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7732-18-5 Water 97 231-791-2
7726-95-6 Bromine 3.0 231-778-1

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: dark amber to orange liquid.
Danger! Corrosive. Causes eye and skin burns. Causes digestive and respiratory tract burns.
Target Organs: None.


Potential Health Effects
Eye: May cause irreversible eye injury. Vapor or mist may cause irritation and severe burns. Contact with liquid is corrosive to the eyes and causes severe burns.
Skin: Contact with liquid is corrosive and causes severe burns and ulceration.
Ingestion: Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract.
Inhalation: Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. May cause pulmonary edema and severe respiratory disturbances.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.
Antidote: No specific antidote exists.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Not flammable, but reacts with most metals to form flammable hydrogen gas.
Extinguishing Media: Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: Not published.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Large spills may be neutralized with dilute alkaline solutions of soda ash (sodium carbonate, Na2CO3), or lime (calcium oxide, CaO). Clean up spills immediately, observing precautions in the Protective Equipment section.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get on skin or in eyes. Do not ingest or inhale. Discard contaminated shoes.
Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Water none listed none listed none listed
Bromine 0.1 ppm TWA; 0.2 ppm STEL 0.1 ppm TWA; 0.7 mg/m3 TWA 3 ppm IDLH 0.1 ppm TWA; 0.7 mg/m3 TWA

OSHA Vacated PELs: Water: No OSHA Vacated PELs are listed for this chemical. Bromine: 0.1 ppm TWA; 0.7 mg/m3 TWA
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: dark amber to orange
Odor: characteristic odor
pH: 2.6
Vapor Pressure: 175 mm Hg
Vapor Density: 5.5
Evaporation Rate:>1
Viscosity: Not available.
Boiling Point: 100 deg C
Freezing/Melting Point:0 deg C
Decomposition Temperature:Not available.
Solubility: Slightly soluble in water.
Specific Gravity/Density:1.0
Molecular Formula:Mixture
Molecular Weight:Not available.

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Reacts explosively with diethylzinc, germane, disilane, dimethylformaldehyde, hydrogen, isobutyrophenone, metal azides, potassium, silane and homologs, praseodymium, antimony, drimethylamine, ammonia. Mixtures with lithium or sodium are shock-sensitive. Ignites or contact with germanium, mono- or di-alkali metal acetylides, trialkyl boranes, copper acetylides. Violent reaction with carbonyl compounds, diethyl ether, phosphine, natural rubber, aluminum, mercury, titanium. Vigorous reaction with methanol and other alcohols, tetrahydrofuran, mixtures of ethanol and phosphorous. Incompatible with acetaldehyde, ethyne, acrylonitrile, ammonia, antimony, calcium nitride, cesium oxide, cesium carbide, cesium acetylide, trifluorochlorine carbide, copper hydride, dimethyl formamide, ethyl phosphine, fluorine, iron carbide, isobutyrophenone, lithium carbide, lithium disilicide, nickel carbonyl, nitrogen triiodide, olefins, oxygen difluoride, ozone, phosphorous, oxides of phosphorous, rubidium carbide, rubidium acetylide, sodium carbide, sodium acetylide, strontium phosphide, tin, uranium carbide, zirconium carbide. Reacts violently with reducing agents.
Hazardous Decomposition Products: Hydrogen bromide, bromine fumes.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 7732-18-5: ZC0110000      
CAS# 7726-95-6: EF9100000
LD50/LC50:
CAS# 7732-18-5:
     Oral, rat: LD50 = >90 mL/kg;
.

CAS# 7726-95-6:
     Inhalation, mouse: LC50 = 750 ppm/9M;
     Inhalation, mouse: LC50 = 2900 mg/m3;
     Inhalation, rat: LC50 = 2700 mg/m3;
     Inhalation, rat: LC50 = 2700 mg/m3;
     Oral, mouse: LD50 = 3100 mg/kg;
     Oral, rabbit: LD50 = 2500 mg/kg;
     Oral, rat: LD50 = 1700 mg/kg;
.

Carcinogenicity:
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7726-95-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: BROMINE SOLUTION BROMINE SOLUTION
Hazard Class: 8 8(6.1)
UN Number: UN1744 UN1744
Packing Group: I I

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7732-18-5 is listed on the TSCA inventory.
     CAS# 7726-95-6 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     CAS# 7726-95-6: 500 lb TPQ
SARA Codes
     CAS # 7726-95-6: immediate, fire.
Section 313
     This material contains Bromine (CAS# 7726-95-6, 3.0%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     CAS# 7726-95-6 is considered highly hazardous by OSHA.
STATE
     CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 7726-95-6 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:


Safety Phrases:


WGK (Water Danger/Protection)

     CAS# 7732-18-5: No information available.
     CAS# 7726-95-6: 3
Canada - DSL/NDSL
     CAS# 7732-18-5 is listed on Canada's DSL List.
     CAS# 7726-95-6 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of C, D1A, E.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 7726-95-6 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #5 Date: 3/15/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

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