Analysis

Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
67-63-0	Isopropyl alcohol	99.98	200-661-7
493-52-7	Methyl red	0.02	207-776-1

Section 3 - Hazards Identification

Appearance: colorless liquid. Flash Point: 12.8 deg C.
Warning! Flammable liquid and vapor. Causes eye and skin irritation. Prolonged or repeated contact causes defatting of the skin with irritation, dryness, and cracking. May cause respiratory and digestive tract irritation. May cause central nervous system depression. May form explosive peroxides. May cause kidney damage.
Target Organs: Kidneys, central nervous system.


Potential Health Effects
Eye: Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury.
Skin: May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May cause irritation with pain and stinging, especially if the skin is abraded.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Inhalation of vapor may cause respiratory tract irritation.
Chronic: Prolonged or repeated skin contact may cause defatting and dermatitis. May cause allergic skin reaction in some

Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Urine acetone test may be helpful in diagnosis.
Antidote: None reported

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. This chemical poses an explosion hazard. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective.
Flash Point: 12.8 deg C ( 55.04 deg F)
Autoignition Temperature: 432.2 deg C ( 809.96 deg F)
Explosion Limits, Lower:2.5 at 26.1癈
Upper: 12.1 at 65.6癈
NFPA Rating: (estimated) Health: ; Flammability: ; Instability:

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Isopropyl alcohol	200 ppm TWA; 400 ppm STEL	400 ppm TWA; 980 mg/m3 TWA 2000 ppm IDLH	400 ppm TWA; 980 mg/m3 TWA
Methyl red	none listed	none listed	none listed

OSHA Vacated PELs: Isopropyl alcohol: 400 ppm TWA; 980 mg/m3 TWA Methyl red: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear safety glasses and chemical goggles if splashing is possible.
Skin: Wear appropriate gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: A NIOSH/MSHA approved or European Standard EN 149 air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: colorless
Odor: Alcohol odor.
pH: Not available.
Vapor Pressure: 33 mm Hg
Vapor Density: 2.1 (air=1)
Evaporation Rate:1.5 (n-butyl acetate=1)
Viscosity: 2.1 cP at 25 deg C
Boiling Point: 82 deg C
Freezing/Melting Point:-90 deg C
Decomposition Temperature:Not available.
Solubility: Completely soluble in water.
Specific Gravity/Density:0.78 (water=1)
Molecular Formula:Mixture
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable. This material may be sensitive to peroxide formation.
Conditions to Avoid: This material may be sensitive to peroxide formation., incompatible materials, ignition sources.
Incompatibilities with Other Materials: Strong oxidizers, acetaldeyde, chlorine, ethylene oxide, acids and isocyanates, hydrogen + palladium, nitroform, oleum, phosgene, potassium t-butoxide, oxygen, trinitromethane, barium perchlorate, tetrafluoroborate, chromium trioxide, sodium dichromate + sulfuric acid, aluminum, and aluminum triisopropoxide. Isopropyl alcohol has been reported to be susceptible to autoxidation and should therefore be considered peroxidizable.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 67-63-0: NT8050000      
CAS# 493-52-7: DG8960000
LD50/LC50:
CAS# 67-63-0:
     Draize test, rabbit, eye: 100 mg Severe;
     Draize test, rabbit, eye: 10 mg Moderate;
     Draize test, rabbit, eye: 100 mg/24H Moderate;
     Draize test, rabbit, skin: 500 mg Mild;
     Inhalation, mouse: LC50 = 53000 mg/m3;
     Inhalation, rat: LC50 = 16000 ppm/8H;
     Inhalation, rat: LC50 = 72600 mg/m3;
     Oral, mouse: LD50 = 3600 mg/kg;
     Oral, mouse: LD50 = 3600 mg/kg;
     Oral, rabbit: LD50 = 6410 mg/kg;
     Oral, rat: LD50 = 5045 mg/kg;
     Oral, rat: LD50 = 5000 mg/kg;
     Skin, rabbit: LD50 = 12800
CAS# 493-52-7:
.

Carcinogenicity:
CAS# 67-63-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 493-52-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: Early epidemiological studies suggested an association between the strong acid manufacture of isopropyl alcohol and paranasal sinus cancer in workers. The risk of laryngeal cancer may also be increased in these workers. However, it has not been tested adequately in animals to assess its carcinogenicity.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: No data available. Isopropanol: Acute aquatic effects: Fathead minnow: LC50 =1000 mg/L/96 Hr. Golden orfe: LC50 = 8970 mg/L/48 Hr. goldfish: LC50 = GT5000 mg/L/24 Hr.
Environmental: Isopropanol has a low potential to affect aquatic organisms, secondary waste treatment microorganisms, and the germination and growth of some plants. It is readily biodegradable and is not expected to persist in an aquatic environment. It is not likely to bioconcentrate.
Physical: None
Other: None

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	ISOPROPANOL	ISOPROPANOL
Hazard Class:	3	3
UN Number:	UN1219	UN1219
Packing Group:	II	II
Additional Info:		FLASHPOINT 12 C

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 67-63-0 is listed on the TSCA inventory.
     CAS# 493-52-7 is listed on the TSCA inventory.
Health & Safety Reporting List
     CAS# 67-63-0: Effective 12/15/86, Sunset 12/15/96
Chemical Test Rules
     CAS# 67-63-0: 40 CFR 799.2325
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 67-63-0: immediate, delayed, fire.
Section 313
     This material contains Isopropyl alcohol (CAS# 67-63-0, 99.98%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 67-63-0 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 493-52-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:

Safety Phrases:

WGK (Water Danger/Protection)
     CAS# 67-63-0: 1
     CAS# 493-52-7: 2
Canada - DSL/NDSL
     CAS# 67-63-0 is listed on Canada's DSL List.
     CAS# 493-52-7 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 67-63-0 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 10/16/1997
Revision #5 Date: 10/30/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.