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Section 1 - Chemical Product and Company Identification |
MSDS Name: Sulfuric acid solution, 0.02 N (N/50)
Catalog Numbers:
SA226-1, SA226-20, SA226-4
Synonyms:
Sulfuric acid 0.02N.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7732-18-5 |
Water |
99.906 | 231-791-2 |
| 7664-93-9 |
Sulfuric acid |
0.094 | 231-639-5 |
| 50-00-0 |
Formaldehyde |
.005% | 200-001-8 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless liquid.
Caution! May cause eye, skin, and respiratory
tract irritation.
Target Organs: Respiratory system, eyes, skin.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.
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Section 4 - First Aid Measures
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Eyes:
In case of contact, immediately flush eyes with plenty of water for a
t least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Provide ventilation.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Water
|
none listed
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none listed
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none listed
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| Sulfuric acid
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0.2 mg/m3 TWA (thoracic fraction)
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1 mg/m3 TWA 15 mg/m3 IDLH
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1 mg/m3 TWA
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| Formaldehyde
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0.3 ppm Ceiling
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0.016 ppm TWA 20 ppm IDLH
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0.75 ppm TWA; 0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer ha zard - see 29 CFR 1910.1048)
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OSHA Vacated PELs:
Water:
No OSHA Vacated PELs are listed for this chemical.
Sulfuric acid:
1 mg/m3 TWA
Formaldehyde:
3 ppm TWA (unless specified in 1910.1048)
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Glove protection is not normally required.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: colorless
Odor: none reported
pH: 4.4
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:1.0 (water=1)
Viscosity: Not available.
Boiling Point: 100 deg C
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:~1.0
Molecular Formula:Solution
Molecular Weight:Not available.
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
No information found..
Hazardous Decomposition Products:
Oxides of sulfur.
Hazardous Polymerization: Will not occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 7732-18-5:
ZC0110000
CAS# 7664-93-9:
WS5600000
CAS# 50-00-0:
LP8925000
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 =
>90 mL/kg;
.
CAS# 7664-93-9:
Draize test,
rabbit, eye: 250 ug Severe;
Inhalation, mouse: LC50 = 320
mg/m3/2H;
Inhalation, mouse: LC50 =
320 mg/m3;
Inhalation, rat: LC50 =
510 mg/m3/2H;
Inhalation, rat:
LC50 = 510 mg/m3;
Oral, rat: LD50 =
2140 mg/kg;
.
CAS# 50-00-0:
Draize test,
rabbit, eye: 750 ug/24H Severe;
Draize test, rabbit, eye: 750 ug
Severe;
Draize test, rabbit, eye:
10 mg Severe;
Draize test, rabbit,
eye: 37% Severe;
Draize test,
rabbit, skin: 2 mg/24H Severe;
Draize test, rabbit, skin: 50 mg/24H
Moderate;
Inhalation, mouse: LC50 =
454 mg/m3/4H;
Inhalation, mouse:
LC50 = 505 mg/m3/2H;
Inhalation,
rat: LC50 = 203 mg/m3;
Inhalation,
rat: LC50 = 578 mg/m3/2H;
Inhalation, rat: LC50 = 250
ppm/2H;
Oral, mouse: LD50 = 42
Carcinogenicity:
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7664-93-9:
- ACGIH:
A2 - Suspected Human Carcinogen (contained in strong inorganic acid mists)
- California:
carcinogen, initial date 3/14/03 (listed as Strong inorganic acid mists containing sulfuric acid).
- NTP:
Known carcinogen (listed as Strong inorganic acid mists containing s).
- IARC:
Group 1 carcinogen
CAS# 50-00-0:
- ACGIH:
A2 - Suspected Human Carcinogen
- California:
carcinogen, initial date 1/1/88 (gas)
- NTP:
Suspect carcinogen
- IARC:
Group 1 carcinogen
Epidemiology:
Workers exposed to industrial sulfuric acid mist showed a
statistical increase in laryngeal cancer. This suggests a
possible relationship between carcinogenesis and inhalation
of sulfuric acid mist.
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series:
CAS# 50-00-0: waste
number U122.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
NOT REGULATED FOR DOMESTIC TRANSPORT |
No information available. |
| Hazard Class: |
XCP |
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| UN Number: |
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| Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 7664-93-9 is listed on the TSCA inventory.
CAS# 50-00-0 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 7664-93-9: 1000 lb final RQ; 454 kg final RQ
CAS# 50-00-0: 100 lb final RQ; 45.4 kg final RQ
SARA Section 302 Extremely Hazardous Substances
CAS# 7664-93-9: 1000 lb TPQ
CAS# 50-00-0: 500 lb TPQ
SARA Codes
CAS # 7664-93-9: immediate, delayed, reactive.
CAS # 50-00-0: immediate, delayed.
Section 313
Sulfuric acid is not at a high
enough concentration to be reportable under Section 313.
Formaldehyde is not at a high
enough concentration to be reportable under Section 313.
No chemicals are reportable under Section 313.
Clean Air Act:
CAS# 50-00-0 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA.
CAS# 50-00-0 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
CAS# 50-00-0 is considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7664-93-9 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 50-00-0 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
WARNING: This product contains Sulfuric acid, listed as `Strong
inorganic acid mists contain', a chemical known to the state of
California to cause cancer.
WARNING: This product contains Formaldehyde, a chemical known to the
state of California to cause cancer.
California No Significant Risk Level:
CAS# 50-00-0: 40 鎔/day NSRL
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 7664-93-9: 2
CAS# 50-00-0: 2
Canada - DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7664-93-9 is listed on Canada's DSL List.
CAS# 50-00-0 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7664-93-9 is listed on the Canadian Ingredient Disclosure List.
CAS# 50-00-0 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 5/13/1998
Revision #11 Date: 7/25/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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