Analysis

Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
67-63-0	Isopropyl alcohol	20-25%	200-661-7
74-98-6	Propane	<50.0	200-827-9
75-28-5	Isobutane	<50.0	200-857-2

Section 3 - Hazards Identification

Appearance: Clear liquid. Flash Point: -87.2 deg C.
Warning! Extremely flammable. May cause cardiac sensitization. May cause severe eye irritation and possible injury. Prolonged or repeated contact causes defatting of the skin with irritation, dryness, and cracking. Aspiration hazard if swallowed. Can enter lungs and cause damage. May cause respiratory tract irritation. May form explosive peroxides. May cause central nervous system depression. May cause liver and kidney damage.
Target Organs: Kidneys, heart, central nervous system, liver.


Potential Health Effects
Eye: Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury.
Skin: May cause skin irritation. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis.
Ingestion: Aspiration hazard. May cause central nervous system depression, kidney damage, and liver damage. Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: May cause respiratory tract irritation. Prolonged exposure may result in dizziness and general weakness. Exposure produces central nervous system depression. As a simple asphyxiant, exposure can cause an anesthetic action, difficulty in breathing, headaches, and dizziness.
Chronic: Prolonged or repeated eye contact may cause conjunctivitis. Prolonged or repeated skin contact may cause defatting and dermatitis. May cause cardiac sensitization and severe heart abnormalities.

Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid if irritation develops or persists. Wash clothing before reuse. Flush skin with plenty of soap and water.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Causes cardiac sensitization to endogenous catelcholamines which may lead to cardiac arrhythmias. Do NOT use adrenergic agents such as epinephrine or pseudoepinephrine. Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: Treat symptomatically and supportively. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Flammable liquid and vapor. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Contents under pressure. Exposure of aerosol cans to temperatures above 120癋 may cause bursting. Flashpoint for the propellent only is -125癋.
Extinguishing Media: Use water spray to cool fire-exposed containers. Use dry chemical, carbon dioxide, or alcohol-resistant foam.
Flash Point: -87.2 deg C ( -124.96 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 4; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Isolate area and deny entry. Provide ventilation.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep away from heat, sparks and flame.
Storage: Keep away from heat, sparks, and flame. Contents are under pressure. Do not expose to heat or store above recommended temperatures. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Isopropyl alcohol	200 ppm TWA; 400 ppm STEL	400 ppm TWA; 980 mg/m3 TWA 2000 ppm IDLH	400 ppm TWA; 980 mg/m3 TWA
Propane	1000 ppm TWA (listed under Aliphatic hydrocarbon gases alkane C1-C4)	1000 ppm TWA; 1800 mg/m3 TWA 2100 ppm IDLH	1000 ppm TWA; 1800 mg/m3 TWA
Isobutane	1000 ppm TWA (listed under Aliphatic hydrocarbon gases alkane C1-C4)	800 ppm TWA; 1900 mg/m3 TWA	none listed

OSHA Vacated PELs: Isopropyl alcohol: 400 ppm TWA; 980 mg/m3 TWA Propane: 1000 ppm TWA; 1800 mg/m3 TWA Isobutane: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: Clear
Odor: alcohol-like
pH: Not available.
Vapor Pressure: PSIG @ 21.1 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:0.83
Molecular Formula:Mixture
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures. This material may be sensitive to peroxide formation. Contents under pressure. Exposure of aerosol cans to temperatures above 120癋 may cause bursting.
Conditions to Avoid: High temperatures, incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 67-63-0: NT8050000      
CAS# 74-98-6: TX2275000      
CAS# 75-28-5: TZ4300000
LD50/LC50:
CAS# 67-63-0:
     Draize test, rabbit, eye: 100 mg Severe;
     Draize test, rabbit, eye: 10 mg Moderate;
     Draize test, rabbit, eye: 100 mg/24H Moderate;
     Draize test, rabbit, skin: 500 mg Mild;
     Inhalation, mouse: LC50 = 53000 mg/m3;
     Inhalation, rat: LC50 = 16000 ppm/8H;
     Inhalation, rat: LC50 = 72600 mg/m3;
     Oral, mouse: LD50 = 3600 mg/kg;
     Oral, mouse: LD50 = 3600 mg/kg;
     Oral, rabbit: LD50 = 6410 mg/kg;
     Oral, rat: LD50 = 5045 mg/kg;
     Oral, rat: LD50 = 5000 mg/kg;
     Skin, rabbit: LD50 = 12800
CAS# 74-98-6:
.

CAS# 75-28-5:
     Inhalation, rat: LC50 = 57 pph/15M;
.

Carcinogenicity:
CAS# 67-63-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 74-98-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 75-28-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	AEROSOLS	AEROSOLS
Hazard Class:	2.1	2.2
UN Number:	UN1950	UN1950
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 67-63-0 is listed on the TSCA inventory.
     CAS# 74-98-6 is listed on the TSCA inventory.
     CAS# 75-28-5 is listed on the TSCA inventory.
Health & Safety Reporting List
     CAS# 67-63-0: Effective 12/15/86, Sunset 12/15/96
Chemical Test Rules
     CAS# 67-63-0: 40 CFR 799.2325
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 67-63-0: immediate, delayed, fire.
Section 313
     This material contains Isopropyl alcohol (CAS# 67-63-0, 20-25%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 67-63-0 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 74-98-6 can be found on the following state right to know lists: New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 75-28-5 can be found on the following state right to know lists: New Jersey, Pennsylvania, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     F+
Risk Phrases:
     R 12 Extremely flammable.

Safety Phrases:
     S 16 Keep away from sources of ignition - No smoking.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).
     S 53 Avoid exposure - obtain special instructions before use.
     S 9 Keep container in a well-ventilated place.

WGK (Water Danger/Protection)
     CAS# 67-63-0: 1
     CAS# 74-98-6: 0
     CAS# 75-28-5: 0
Canada - DSL/NDSL
     CAS# 67-63-0 is listed on Canada's DSL List.
     CAS# 74-98-6 is listed on Canada's DSL List.
     CAS# 75-28-5 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of A, B1, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 67-63-0 is listed on the Canadian Ingredient Disclosure List.
     CAS# 74-98-6 is not listed on the Canadian Ingredient Disclosure List.
     CAS# 75-28-5 is not listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 7/23/1999
Revision #9 Date: 12/04/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.