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MSDS Material Safety Data Sheet
CAS

12035-39-1

File Name: 12035-39-1.asp

                                            MATERIAL SAFETY DATA SHEET



I PRODUCT IDENTIFICATION

Trade Name: Nickel Titanate Chemical Family: Metal titanate
Synonyms: Nickel titanium oxide, titanium nickel oxide Formula: NiTiO3
CAS #: 12035-39-1


II HAZARDOUS INGREDIENTS

Hazardous Components % OSHA/PEL ACGIH/TLV Sec. 302 Sec. 304 Sec. 313
1 mg/m3 1 mg/m3
Nickel Titanate 0-100 No Yes 1 lb Yes

HMIS Ratings (0-4): Health: 3 (chronic health hazard) Flammability: 0 Reactivity: 0
HMIS Protective Equipment: G: glasses, gloves, combination respirator.


III PHYSICAL DATA

Boiling Point: N/E or N/A Melting Point: N/E or N/A
Vapor Pressure: N/A Specific Gravity (H2O = 1): 5.097 g/cc
Vapor Density: N/A Solubility in H2O: Insoluble
Appearance and Odor: Yellow green powder, no odor. % Volatile: N/E or N/A


IV FIRE AND EXPLOSION HAZARD DATA

Flash Point: N/E or N/A Method Used: Non-flammable
Explosive Limits: Lower: N/A Upper: N/A

Extinguishing Media: Use suitable extinguishing agents for surrounding materials and type of fire.
Special Firefighting Procedures: Firefighters must wear full face, self-contained breathing apparatus with full protective clothing to
prevent contact with skin and eyes. Fumes from fire are hazardous. Isolate runoff to prevent environmental pollution.

Unusual Fire and Explosion Hazards: None recorded.


V HEALTH HAZARD INFORMATION

Effects of Exposure:

To the best of our knowledge the chemical, physical and toxicological properties of nickel titanate have not been thoroughly
investigated and recorded.

Nickel is a confirmed carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic and teratogenic data. Poison
by ingestion, intratracheal intraperitoneal, subcutaneous and intravenous routes. An experimental teratogen. Ingestion of soluble salts
causes nausea, vomiting and diarrhea. Hypersensitivity to nickel is common and can cause allergic contact dermatitis, pulmonary
asthma, conjunctivitis and inflammatory reactions around nickel containing medical implants and prosthesis.

Titanium is generally considered to be physiologically inert. There are no reported cases in the literature where titanium as
such has cause human intoxication. The dusts of titanium or most titanium compounds such as titanium oxide may be placed in the
nuisance category.
Acute Effects:

Inhalation: May cause irritation to the upper respiratory tract, mucous membranes, nasal cavities and pulmonary asthma attacks.
Ingestion: Large doses may cause intestinal disorders, convulsions and asphyxia.
Skin: May cause irritation.
Eye: May cause irritation.

Chronic Effects:

Inhalation: Prolonged or repeated inhalation may cause pneomitis.
Ingestion: May cause nickel toxicity.
Skin: May sensitize the skin (nickel itch). May cause allergic dermatitis, eczematous dermatitis and may be accompanied a week
later with superficial skin ulcers, which may discharge and become crusted.
Eye: May cause conjunctivitis.

Routes of Entry: Inhalation, ingestion, skin and eyes.

Target Organs: May affect the nasal cavities, lungs and skin.
Medical Conditions Generally Aggravated by Exposure: Pre-existing respiratory disorders, pulmonary functions, asthma and skin
disorders.
Carcinogenicity: NTP: Yes IARC: Yes OSHA: Yes

EMERGENCY AND FIRST AID PROCEDURES:

INHALATION: Remove victim to fresh air, keep warm and quiet, give oxygen if breathing is difficult and seek medical attention if
symptoms.
INGESTION: Give 1-2 glasses of milk or water and induce vomiting, seek medical attention if symptoms persist. Never induce
vomiting or give anything by mouth to an unconscious person.
SKIN: Remove contaminated clothing, brush material off skin, wash affected area with mild soap and water. Seek medical attention
if symptoms persist.
EYE: Flush eyes with lukewarm water, lifting upper and lower eyelids, for at least 15 minutes. Seek medical attention if symptoms
persist.


VI REACTIVITY DATA

Stability: Stable

Conditions to Avoid: None
Incompatibility (Material to Avoid): None recorded

Hazardous Decomposition Products: None recorded
Hazardous Polymerization: Will not occur.


VII SPILL OR LEAK PROCEDURES

Steps to Be Taken in Case Material is Released: Wear appropriate respiratory and protective equipment specified in Section VIII.
Isolate spill area and provide ventilation. Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a
closed container for proper disposal. Take care not to raise dust.

Waste Disposal Method: Dispose of in accordance with Federal, State and Local regulations.
VIII SPECIAL PROTECTION INFORMATION

Respiratory Protection: NIOSH approved dust-mist-vapor cartridge respirator.
Ventilation: Use local exhaust to maintain concentration at or below the PEL, TLV. General exhaust is recommended.

Protective Gloves: Rubber gloves Eye Protection: Safety glasses
Other Protective Clothing or Equipment: Protective gear suitable to prevent contamination.


IX SPECIAL PRECAUTIONS

Precautions to Be Taken in Handling and Storage: Store in a tightly sealed container in a cool, dry area. Wash thoroughly after
handling.

Work/Hygienic/Maintenance Practices: Implement engineering and work practice controls to reduce and maintain concentration of
exposure at low levels. Use good housekeeping and sanitation practices. Do not use tobacco or food in work area. Wash thoroughly
before eating and smoking. Do not blow dust clothing or skin compressed air.

Some of the chemicals listed herein are research or experimental substances which may be toxic, as defined by various
governmental regulations. In accordance with Environmental Protection Agency regulations and the Toxic Substance Control Act
(TSCA), these materials should only be handled by, or under the direct supervision of a 鈥渢echnically qualified individual鈥?, as defined
in 40 CFR 710.2(aa).


Issued by: S. Dierks
Dated: March 1995

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