MATERIAL SAFETY DATA SHEET
(Essentially similar to OSHA form 174, Sept. 1985 - For Compliance with OSHA鈥檚 Hazard Communication Standard, 29CFR 1910.1200)
Section I - Product Identity: Lemon Peel鈩? (5790)
Date of Preparation: March 7 , 2007
Manufacturer鈥檚 Name:
Fiberlock Technologies, Inc. Information Telephone Number: (978) 623-9987
150 Dascomb Road Emergency Telephone Numbers:
Andover, MA 01810 Weekdays: (978) 623-9987
After hours, weekends & holidays: 鈥淐HEM-TEL鈥?
Emergency Contact Number: (800) 255-3924
Section II - Hazardous Ingredients/Identity Information
HAZARDOUS CAS. Acute Oral Acute Dermal Acute Inhalation OSHA ACGIH
COMPONENT % NO. LD50 LD50 LC50 PEL/TWA TLV/STEL
Dimethyl Glutarate 9 1119-40-0 8,191 mg/kg (Rat) 2,250 mg/kg (rabbit) 11 mg/l (rat) NONE ESTABLISHED NONE ESTABLISHED
1-Methyl-2-Pyrrolidone 57 872-50-4 4200 mg/kg (Rat) 8000 mg/kg (rabbit) No evidence of toxic effects NONE ESTABLISHED 100 PPM (EST)
Dimethyl Adipate 2 627-93-0 8,191 mg/kg (Rat) 2,250 mg/kg (rabbit) 11 mg/l (rat) NONE ESTABLISHED NONE ESTABLISHED
Dimethyl Succinate 4 106-65-0 8,191 mg/kg (Rat) 2,250 mg/kg (rabbit) 11 mg/l (rat) NONE ESTABLISHED NONE ESTABLISHED
D-Limonene 29 5989-27-5 NONE ESTABLISHED
*Based on either product or essentially similar product testing.
Section III - Physical/Chemical Characteristics (See reference note(s) No. 1, 2 on Reverse)
Not
Boiling Points of Major Constituent: 1.06 lbs./gal.
Specific Gravity (H2O=1) Wgt./gal.
Established
Not
Vapor Pressure (mm Hg) @ 100掳C Melting Point Water (Ice) N/A
Established
Vapor Density (AIR=1) Evaporation Rate
Heavier (Butyl Acetate=1)
X 0.7
Lighter
Appearance: Light colored liquid
Solubility in Water Partial Odor: Sweet Odor
Section IV - Fire and Explosion Hazard Data
DOT ID#:
Flammable Limits: DOT Proper Shipping Name:
Flash Point: Marking:
LEL: N/A UEL: N/A Not Regulated
140掳F SETA 鈥淜eep from Freezing鈥?
Fire and Explosion: When heated above flash point, releases vapors. When mixed with air and exposed to ignition source, vapors can
burn in open or explode if confined. Vapors may be heavier than air. May travel long distances along the ground before igniting and
flashing back to vapor source. Vapors may accumulate and travel to ignition sources distant from the handling site; Flash Fire can
result. Fine sprays/mist may be combustible at temperatures below normal flash point. Extinguishing Media: Use water fog, foam, dry
chemical or CO2. Do not use a direct stream of water. Product will float and can be reignited on surface of water.
Special Fire Fighting Procedures and Precautions: Caution, combustible. Do not enter confined fire space without full bunker gear
(helmet with face shield, bunker coats, gloves and rubber boots), including a positive pressure NIOSH approved self-contained
breathing apparatus. Cool fire exposed containers with water. Special Precautions: Keep liquid and vapor away from heat, sparks and
flame. Surfaces that are sufficiently hot may ignite even liquid product in the absence of sparks or flame. Extinguish pilot lights,
cigarettes and turn off other sources of ignition prior to use and until all vapors are gone. Vapors may accumulate and travel to ignition
sources distant from the handling site; flash fire can result. Containers, even those that have been emptied, can contain explosive
vapors. Do not cut, drill, grind, weld or perform similar operations on or near containers. Static electricity may accumulate and create a
fire hazard. Ground fixed equipment. Bond and ground transfer containers and equipment.
Section V - Reactivity Data
Hazardous Polymerization: Will not occur.
Stability: Stable
Incompatibility/Conditions and materials to avoid: Avoid heat, flame and contact with strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide and unidentified organic compounds may be formed during combustion.
Section VI - Health Hazard Data/Toxicity Data
The health effects noted below are consistent with requirements under the OSHA hazard communications standard (29 CFR 1910. 1200).
EFFECTS OF OVEREXPOSURE: Eye Contact: Liquid is severe irritant to the eyes. No permanent damage. Skin Contact: Liquid is irritating
to the skin. Prolonged or repeated liquid contact can result in defatting and drying of the skin which may result in skin irritation and severe
dermatitis, e.g. blisters, cracking, edema, redness. Inhalation: Vapors may cause irritation to nose, throat, and respiratory tract. Ingestion:
Very low toxicity by ingestion. Signs and Symptoms: Irritation as noted above. Early to moderate CNS (Central Nervous System) depression
may be evidenced by giddiness, headache, dizziness and nausea; in extreme cases, unconsciousness and death may occur. Aggravated
Medical Conditions: Preexisting eye, skin, and respiratory disorders may be aggravated by exposure to this product.
EMERGENCY AND FIRST AID PROCEDURES: Eye Contact: Flush eyes with plenty of water for 15 minutes while holding eyelids open.
Get medical attention. Skin Contact: Remove contaminated clothing/shoes. Flush skin with water. Follow by washing with soap and
water. If irritation occurs, get medical attention. Do not reuse clothing until cleaned. Inhalation: Remove victim to fresh air and provide
oxygen if breathing is difficult. Ingestion: Do not induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent
aspiration of liquid into the lungs. Get medical attention.
Supplemental Health Information: Overexposure may cause blurring of vision.
Section VII: Precautions for Safe Handling and Use
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Caution Combustible. Large spills: Eliminate
potential sources of ignition. Wear appropriate respirator and other protective clothing. Shut off source of leak only if
safe to do so. Dike and contain. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with
an absorbent such as clay, sand, or other suitable material; place in non-leaking containers and seal tightly for proper
disposal. Flush area with water to remove trace residue; dispose of flush solution as above. Small Spills: Take up with
an absorbent material and place in non-leaking containers for proper disposal.
Section VIII: Control Measures
RESPIRATORY PROTECTION: Avoid prolonged or repeated breathing of vapors. If exposure may or does exceed
occupational exposure limits (Section II) use a NIOSH-approved respirator to prevent overexposure. In accord with
29CFR 1910, 134 use either an atmosphere supplying respirator or an air-purifying respirator for organic vapors. Use
approved chemical/mechanical filters designed to remove particulates in open and restricted ventilation areas. Use
MSHA/NIOSH-approved airline type respirator or hood in confined areas. OSHA has established transitional occupa-
tional exposure limits for this product and/or components of this product. Refer to 29 CFR 1910.1000 for these transi-
tional limits and requirements for meeting these limits.
PROTECTIVE CLOTHING: Avoid contact with eyes. Wear safety goggles or glasses as appropriate. Avoid prolonged or
repeated contact with skin. Wear chemical resistant gloves and other clothing as required to minimize contact. Test
data from published literature and/or glove and clothing manufacturers indicate the best protection is provided by
nitride material.
ADDITIONAL PROTECTIVE MEASURES: Air-dry contaminated clothing in a well ventilated area then launder before
reusing.
SUPPLEMENTAL INFORMATION
To comply with New Jersey DOH Right-To-Know labeling law (N.J.A.C. 8:59 - 5.1 & 5.2)
CAS. No.: CHEMICAL INGREDIENTS: HMIS HAZARD RATING
1119-40-0 Dimethyl Glutarate Health 2 Flammability 1 Physical Hazard 0 Personal Protection G
872-50-4 1-Methyl-2-Pyrrolidone
HAZARD INDEX: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe
627-93-0 Dimethyl Adipate
PERSONAL PROTECTION CODE
106-65-0 Dimethyl Succinate
5989-27-5 D-Limonene G=Safety Glasses, Gloves, Vapor Respirator
Environmental Data Sheet (supplement to MSDS)
PRODUCT COMPOSITION AND SARA TITLE III INFORMATION
CAS.
COMPONENT % NO. EHS RQ (LBS) EHS TPQ (LBS) SEC 313 313 CATEGORY 311/312 Categories EHS = Extremely Hazardous Substance
Mixture 100 RQ = Reportable Quantity
Dimethyl Glutarate <30 1119-40-0 ACUTE HEALTH HAZARD TPQ = Threshold Planning Quantity
1-Methyl-2-Pyrrolidone <60 872-50-4 SEC = Section
Dimethyl Adipate <10 627-93-0 ACUTE HEALTH HAZARD
Dimethyl Succinate <12 106-65-0 ACUTE HEALTH HAZARD
RCRA INFORMATION
Under EPA - RCRA (40 CFR 261.21, If this product becomes a waste material, it would be ignitable hazardous waste, hazardous waste number D001. Refer to latest EPA or state regulations regarding proper disposal.
In accordance with SARA Title III, Section 313, the EDS should always be copied and sent with the MSDS. This product is listed on the EPA/TSCA inventory of chemical substances.
STATE/OTHER REGULATORY INFORMATION AND SPECIAL NOTES:
This information is being systematically repeated to our MSDS. It has previously been provided to you in various ways, including the MSDS. The new MSDS format is intended to provide the user with the information
in a more convenient manner.
The information contained herein is based on the data available to us and is believed to be correct. However, the occupational exposure limits and/or the respiratory precautions have been revised. Fiberlock Technologies,
Inc. makes no warranty, expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Fiberlock Technologies, Inc. assumes no responsibility for injury from the use of
the product described herein.
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