FUELITE
ChemWatch Material Safety Data Sheet
CHEMWATCH 85661
Date of Issue: Mon 16-Sep-2002
IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA.
CONSIDERED A DANGEROUS SUBSTANCE ACCORDING TO DIRECTIVE 67/548/EEC, POINT 4;
AND TO 29 CFP 1910-1200 (USA).
SUPPLIER
Company Andrew Brands Ltd
Address 3 Porana Road, Glenfield, AUCKLAND
Telephone 0800 802 626 or 09 979 3777
Emergency Telephone 0800 243 622
Fax 0800 731 770
Website www.andrew.co.nz
CHEMWATCH HAZARD RATINGS
Flammability 3
Toxicity 2
Body Contact 2
Reactivity 0
Chronic 2
SCALE Min/Nil =0 Low =1 Moderate=2 High=3 Extreme=4
PERSONAL PROTECTION EQUIPMENT FOR INDUSTRIAL / COMMERICAL
ENVIROMENTS
Short Gloves
Overalls
Goggles or Full Face Respirator
Product Name Fuelite
Other Names Formerly Shellite
CAS RN No (s) None
UN Number 3295
Packing Group II
Dangerous Goods Class 3(3.1)
Subsidiary Risk None
Hazchem Code 3[W]E
Posions Schedule Number S5, NZS4
USE
Used as rubber solvent, cleaning solvent, lighter fluid and as fast evaporating, highly volatile solvent in
enamels, adhesives and lacquers. The use of a quantity of material in an unventilated or confined space may
result in increased exposure and an irritating atmosphere developing Before starting consider control of
exposure by mechanical ventilation.
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PHYSICAL DESCRIPTION / PROPERTIES
APPEARANCE
Clear highly flammable liquid with a typical hydrocarbon liquid odour; floats on water. Classed as an aliphatic
solvent; i.e has low aromatic content.
Boiling Point 47-128
Melting Point Not available
Vapour Pressure (kPa) 34.5 @ 15 deg C
Specific Gravity 0.708 @ 15 deg C
Flash Point (deg C) <-30
Lower Explosive Limit (%) 1.0
Upper Explosive Limit (%) 7.5
Solubity in Water (g/L) Immiscible
INGREDIENTS
NAME CAS RN %
Paraffins and naphthenes as Various >60
Liquid hydrocarbons
N-hexane 110-54-3 13
Aromatic hydrocarbons total, including <
5.0
Toluene 108-88-3 3.5
app
Ethylbenzene 100-41-4 1
Benzene 71-43-2 <
0.5
C8 and higher aromatics 1
HEALTH HAZARD
ACUTE HEALTH EFFECTS
SWALLOWED
The liquid is discomforting and may be harmful if swallowed. Ingestion may result in nausea, pain, vomiting.
Vomit entering the lungs by aspiration may cause potentially lethal chemical pneumonitis. Considered an
unlikely route of entry in commercial/industrial environments.
EYE
The liquid is highly discomforting to the eyes and is capable of causing a mild, temporary redness of the
conjunctiva (similar to wind-burn), temporary impairment of vision and/ or other transient eye damage/
ulceration. The vapour is discomforting to the eyes. The material may be irritating to the eye, with prolonged
contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.
SKIN
The liquid is discomforting to the skin and is capable of causing skin reactions which may lead to dermatitis.
Toxic effects may result from skin absorption. Exposure limits with "skin" notation indicate that vapour and
liquid may be absorbed through intact skin. Absorption by skin may readily exceed vapour inhalation
exposure. Symptoms for skin absorption are the same as for inhalation. Contact with eyes and mucous
membranes may also contribute to overall exposure and may also invalidate the exposure standard. The
material may accentuate any pre-existing skin condition. Open cuts, abraded or irritated skin should not be
exposed to this material.
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INHALED
The vapour is discomforting to the upper respiratory tract and may be toxic. Inhalation hazard is increased at
higher temperatures. Acute effects from inhalation of high concentrations of vapour are pulmonary irritation,
including coughing, with nausea; central nervous system depression - characterised by headache and
dizziness, increased reaction time, fatigue and loss of co-ordination. If exposure to highly concentrated
solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma and possible
death.
CHRONIC HEALTH EFFECTS
Principal routes of exposure are usually by inhalation of vapour and skin contact/absorption. Chronic solvent
inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS].
Chronic inhalation exposures may show indications of peripheral neuropathy, a progressive nerve disorder of
extremities. Prolonged or continuous skin contact with the liquid may cause defatting with drying, cracking,
irritation and dermatitis following. n-hexane is indicated in cases of peripheral neuropathy and chronic
inhalation exposure may be expected to show nervous system impairment.
FIRST AID
SWALLOWED
If poisoning occurs, contact a doctor or Poisons Information Centre.
If swallowed, DO NOT induce vomiting. Give a glass of water.
EYE
If this product comes in contact with the eyes:
Immediately hold eyelids apart and flush the eye continuously with running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by
occasionally lifting the upper and lower lids.
Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15
minutes.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
INHALED
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to
initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask
device, or pocket mask as trained. Perform CPR if necessary.
Transport to hospital, or doctor.
ADVISE TO THE DOCTOR
For acute or short term repeated exposures to petroleum distillates or related hydrocarbons:
Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.
Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal
retraction, obtundation) and given oxygen.
Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.
Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of
myocardial injury has been reported; intravenous lines and cardiac monitors should be established in
obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves
clearance. A chest x-ray should be taken immediately after stabilisation of breathing and circulation to
document aspiration and detect the presence of pneumothorax. Epinephrine (adrenalin) is not
recommended for treatment of bronchospasm because of potential myocardial sensitisation to
catecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents,
with aminophylline a second choice. Lavage is indicated in patients who require decontamination; ensure
use of cuffed endotracheal tube in adult patients.
[Ellenhorn and Barceloux: Medical Toxicology]
Page 3 of 10
PRECAUTIONS FOR USE
EXPOSURE STANDARDS
CEL TWA: 200 ppm, 800 mg/m続 [SHELL]
REPRODUCTIVE HEALTH GUIDELINES
Established occupational exposure limits frequently do not take into consideration reproductive end points
that are clearly below the thresholds for other toxic effects. Occupational reproductive guidelines (ORGs)
have been suggested as an additional standard. These have been established after a literature search for
reproductive no-observed-adverse effect-level (NOAEL) and the lowest-observed-adverse-effect-level
(LOAEL). In addition the US EPA's procedures for risk assessment for hazard identification and dose-
response assessment as applied by NIOSH were used in the creation of such limits.
: :
ORG UF Endpoint CR TLV Adequate.
n-hexane 176 mg/m3 NA NA NA Yes
toluene 9.6 mg/m3 10 D NA -
benzene 0.05 mg/m3 1000 D 1.4 -
: :
These exposure guidelines have been derived from a screening level of risk assessment and should not be
construed as unequivocally safe limits. ORGS represent an 8-hour time-weighted average unless specified
otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive American Industrial Hygiene
Association Journal 57: 641-649 (1996)
INGREDIENT DATA
LIQUID HYDROCARBONS:
No exposure limits set by NOHSC or ACGIH
N-HEXANE:
TLV TWA: 500 ppm [ACGIH]
TLV STEL: 1000 ppm [ACGIH]
TLV TWA: 50 ppm Skin;BEI [ACGIH]
PEL TWA: 500 ppm, 1800 mg/m続 [OSHA Z1]
TLV TWA: 50 ppm, 176 mg/m続 SKIN
ES TWA: 20 ppm, 72 mg/m続
OES TWA: 20 ppm, 72 mg/m続
MAK value: 50 ppm, 180 mg/m続
MAK Category II Peak Limitation: For substances with systemic effects and with a half-life in humans of less
than two hours.
Allows excursions of 2 times the MAK value, for 30 minutes (on average), four times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo when MAK and BAT
values are observed.
MAK values, and categories and groups are those recommended within the Federal Republic of Germany
Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed through intact skin.
Absorption by skin may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the
same as for inhalation. Contact with eyes and mucous membranes may also contribute to overall exposure
and may also invalidate the exposure standard.
Odour Threshold Value: 65 ppm
IDLH Level: 1100 ppm (lower explosive limit)
NOTE: Detector tubes for n-hexane, measuring in excess of 100 ppm, are available commercially.
Occupational polyneuropathy may result from exposures as low as 500 ppm (as hexane), whilst nearly
continuous exposures of 250 ppm have caused neurotoxic effects in animals. Many literature reports have
failed to distinguish hexane from n-hexane and on the assumption that the commercial hexane contains 30%
Page 4 of 10
n-hexane, a worst case recommendation for TLV is assumed to reduce the risk of peripheral neuropathies
(due to the metabolites 2,5-heptanedione and 3,6-octanedione) and other adverse neuropathic effects.
Concurrent exposure to chemicals (including MEK) and drugs which induce hepatic liver oxidative
metabolism can reduce the time for neuropathy to appear.
TOLUENE:
TLV TWA: 50 ppm Skin;A4;BEI [ACGIH]
PEL: 8hr TWA 200 ppm ; Ceiling Conc: 300ppm ; Max excursion: 500 ppm for 10 minutes [OSHA Z2]
ES TWA: 50 ppm, 191 mg/m続; STEL 150 ppm, 574 mg/m続 SKIN
TLV TWA: 50 ppm, 188 mg/m続 SKIN A4
NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as causing Cancer in
humans
OES TWA: 50 ppm, 191 mg/m続; STEL: 150 ppm, 574 mg/m続 SKIN
MAK value: 50 ppm, 190 mg/m続
MAK Category II Peak Limitation: For substances with systemic effects and with a half-life in humans ranging
from two hours to shift-length.
Allows excursions of 5 times the MAK value, for 30 minutes (on average), twice per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo when MAK and BAT
values are observed.
MAK values, and categories and groups are those recommended within the Federal Republic of Germany
IDLH Level: 500 ppm
Odour Threshold Value: 0.16-6.7 (detection), 1.9-69 (recognition)
NOTE: Detector tubes measuring in excess of 5 ppm, are available.
Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed through intact skin.
Absorption by skin may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the
same as for inhalation. Contact with eyes and mucous membranes may also contribute to overall exposure
and may also invalidate the exposure standard.
High concentrations of toluene in the air produce depression of the central nervous system (CNS) in
humans. Intentional toluene exposure (glue-sniffing) at maternally-intoxicating concentration has also
produced birth defects. Foetotoxicity appears at levels associated with CNS narcosis and probably occurs
only in those with chronic toluene-induced kidney failure. Exposure at or below the recommended TLV-TWA
is thought to prevent transient headache and irritation, to provide a measure of safety for possible
disturbances to human reproduction, the prevention of reductions in cognitive responses reported amongst
humans inhaling greater than 40 ppm, and the significant risks of hepatotoxic, behavioural and nervous
system effects (including impaired reaction time and incoordination). Although toluene/ethanol interactions
are well recognised, the degree of protection afforded by the TLV-TWA among drinkers is not known.
ETHYLBENZENE:
TLV TWA: 100 ppm A3; BEI [ACGIH]
TLV STEL: 125 ppm A3; BEI [ACGIH]
PEL TWA: 100 ppm, 435 mg/m続 [OSHA Z1]
TLV TWA: 100 ppm; STEL: 125 ppm A3
CAUTION: This substance has been classified by the ACGIH as A3 Animal Carcinogen (at relatively high
doses)
ES TWA: 100 ppm, 435 mg/m続; STEL: 125 ppm, 545 mg/m続 (Under review)
OES TWA: 100 ppm, 441 mg/m続; STEL: 125 ppm, 552 mg/m続
MAK value: 100 ppm, 440 mg/m続
Designated H in List of MAK values: Danger of cutaneous absorption.
Absorption of such substances through the skin can pose an incomparably larger danger of toxicity than their
inhalation. To avoid health risks when handling such substances, meticulous cleaning of the skin, hair and
clothing is imperative.
MAK Category I Peak Limitation: For local irritants Allows excursions of twice the MAK value for 5 minutes at
a time, 8 times per shift.
MAK Group D: Classification as to the effect of the substance on the developing embryo/foetus is not yet
possible because although data may indicate a trend, they are not sufficient for a final evaluation.
MAK values, and categories and groups are those recommended within the Federal Republic of Germany
Odour Threshold Value: 0.46-0.60 ppm
IDLH Level: 800 ppm (lower explosion limit)
NOTE: Detector tubes for ethylbenzene, measuring in excess of 30 ppm, are commercially available.
Ethyl benzene produces irritation of the skin and mucous membranes and appears to produce acute and
chronic effects on the central nervous system. Animal experiments also suggest the effects of chronic
exposure include damage to the liver, kidneys and testes. In spite of structural similarities to benzene, the
material does not appear to cause damage to the haemopoietic system. The TLV-TWA is thought to be
Page 5 of 10
protective against skin and eye irritation. Exposure at this concentration probably will not result in systemic
effects.
Subjects exposed at 200 ppm experienced transient irritation of the eyes; at 1000 ppm there was eye
irritation with profuse lachrymation; at 200 ppm eye irritation and lachrymation were immediate and severe
accompanied by moderate nasal irritation, constriction in the chest and vertigo; at 5000 ppm exposure
produced intolerable irritation of the eyes and throat.
BENZENE:
TLV TWA: 0.5 ppm Skin; A1; BEI [ACGIH]
TLV STEL: 2.5 ppm Skin; A1; BEI [ACGIH]
PEL TWA: 1 ppm [OSHA Z1]
The final benzene standard in 1910.1028 applies to all occupational exposures to benzene except in some
circumstances the distribution and sale of fuels, sealed containers and pipelines, coke production, oil and
gas drilling and production, natural gas processing, and the percentage exclusion for liquid mixtures where
the following limit from OSHA Z2 applies
PEL: 8hr TWA 10 ppm ; Ceiling Conc: 25ppm ; Max excursion: 50 ppm for 10 minutes [OSHA Z2]
ES TWA: 5 ppm, 16 mg/m続
WARNING: This substance is classified by the NOHSC as Category 1 ESTABLISHED
HUMAN CARCINOGEN
PROPOSED CHANGE
ES TWA 1 ppm
TLV TWA: 0.5 ppm, 1.6 mg/m続; STEL: 2.5 ppm, 8 mg/m続 SKIN A1
WARNING: This substance has been classified by the ACGIH as A1 CONFIRMED HUMAN CARCINOGEN
MEL TWA: 3 ppm
Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed through intact skin.
Absorption by skin may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the
same as for inhalation. Contact with eyes and mucous membranes may also contribute to overall exposure
and may also invalidate the exposure standard. Designated H in List of MAK values: Danger of cutaneous
absorption. Absorption of such substances through the skin can pose an incomparably larger danger of
toxicity than their inhalation. To avoid health risks when handling such substances, meticulous cleaning of
the skin, hair and clothing is imperative.
MAK IIIA1: Substances shown to induce malignant tumours in humans Germ cell mutagens: Group 3
Substances which have been demonstrated to cause genetic damage in mammalian (including human) germ
cells without proof of transmission.
The term "germ cell mutagen" is applied to substances causing hereditary disorders in the progeny due to
mutational damage in the male and female germ cell (ovum or spermatozoan). This damage may be gene
mutations or structural or numerical chromosome alterations.
MAK values, and categories and groups are those recommended within the Federal Republic of Germany
PEL TWA: 1 ppm, 3 mg/m続; C: 5 ppm, 15 mg/m続 [OSHA]
REL TWA: 0.32 mg/m続 10 hour; CEILING: 3.2 mg/m続 15 mins [NIOSH]
IDLH Level: 500 ppm
TRK:
coking plants (tar separator, condensation, gas exhauster house): 2.5 ml/m続; 8 mg/m続
refuelling field in the mineral oil industry: 2.5 ml/m続; 8 mg/m続
repair and servicing of parts conducting benzene
in the chemical and mineral oil industries: 2.5 ml/m続; 8 mg/m続
gasoline supply rooms for engine test stands: 2.5 ml/m続; 8 mg/m続
others: 1 ml/m続; 3.2 mg/m続
It is anticipated that the threshold value in air is to be reduced to 3.2 mg/m続 (1 ml/m続). The technical
exposure limit, TRK (Technische Richtkonzentrationen), defines the airborne concentration of named
carcinogenic materials, which is the minimum possible given the state of current technologies. TRK values
are assigned only for materials for which there is no current MAK (German exposure standard).
Observance of the TRK value is intended to reduce the risk of adverse effects on health but does NOT
completely eliminate it. Since no threshold doses can be determined for carcinogens, health considerations
require that the exposure limits be kept as far as possible below the TRK and that the TRK value be
gradually reduced. The limitation of exposure peaks is regulated as follows;
Short-term exposure limit: 5 x TRK
Short-term exposure duration: 15 min/average
Frequency per work shift: 5 times
Interval: 1 hour
Report No. 35 1999, Deutsche Forschungsgemeinschaft.
Odour Threshold Value: 34 ppm (detection), 97 ppm (recognition)
NOTE: Detector tubes for benzene, measuring in excess of 0.5 ppm, are commercially available.
Page 6 of 10
The relative quality of epidemiological data and quantitative health risk assessments related to documented
and theoretical leukaemic deaths constitute the basis of the TLV-recommendation. One study [Dow
Chemical] demonstrates a significant fourfold increase in myelogenous leukaemia for workers exposed to
average benzene concentrations of about 5 ppm for an average of 9 years and that 2 out of four individuals
in the study who died from leukaemia were characterised as having been exposed to average benzene
levels below 2 ppm. Based on such findings the estimated risk of leukaemia in workers exposed at daily
benzene concentrations of 10 ppm for 40 years is 155 times that of unexposed workers; at 1 ppm the risk
falls to 1.7 times whilst at 0.1 ppm the risk is about the same in the two groups. A revision of the TLV-TWA to
0.1.ppm was proposed in 1990 but this has been revised upwards as result of industry initiatives.
Typical toxicities displayed following inhalation:
At 25 ppm (8 hours): no effect
50-150 ppm : signs of intoxication within 5 hours
500-1500 ppm : signs of intoxication within 1 hour
7500 ppm : severe intoxication within 30-60 minutes
20000 ppm : fatal within 5-10 minutes
Some jurisdictions require that health surveillance be conducted on occupationally exposed workers. Some
surveillance should emphasise
(i) demography, occupational and medical history and health advice
(ii) baseline blood sample for haematological profile
(iii) records of personal exposure
ENGINEERING CONTROLS
Use in a well-ventilated area
If inhalation risk of overexposure exists, wear SAA approved organic-vapour respirator.
General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required
in special circumstances. If risk of overexposure exists, wear approved respirator. Supplied-air type
respirator may be required in special circumstances. Correct fit is essential to ensure adequate protection.
Provide adequate ventilation in warehouses and enclosed storage areas. Air contaminants generated in the
workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh
circulating air required to effectively remove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., evaporating from tank (in still air). 0.25-0.5 m/s (50-100 f/min)
aerosols, fumes from pouring operations, intermittent container filling, 0.5-1 m/s (100-200 f/min.)
low speed conveyer transfers, welding, spray drift, plating acid fumes,
pickling (released at low velocity into zone of active generation)
direct spray, spray painting in shallow booths, drum filling, 1-2.5 m/s (200-500 f/min.)
conveyer loading, crusher dusts, gas discharge
(active generation into zone of rapid air motion)
grinding, abrasive blasting, tumbling, high speed 2.5-10 m/s (500-2000 f/min.)
wheel generated dusts (released at high initial velocity into zone of
very high rapid air motion)
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or favourable to capture 1: Disturbing room air currents
2: Contaminants of low toxicity or of nuisance value only. 2: Contaminants of high toxicity
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood-local control only
Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction
pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases).
Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance
from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1-
2 m/s (200-400 f/min) for extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within the extraction apparatus,
make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction
systems are installed or used. In confined spaces where there is inadequate ventilation, wear full-face air
supplied breathing apparatus
Page 7 of 10
PERSONAL PROTECTION
EYES
Safety glasses with side shields.
Chemical goggles. Full face shield.
DO NOT wear contact lenses.
Contact lenses pose a special hazard; soft contact lenses may absorb irritants and all lenses concentrate
them.
HANDS / FEET
Neoprene gloves or PVC gloves.
Protective footwear.
Do NOT use this product to clean the skin.
OTHER
Overalls.
Eyewash unit.
Barrier cream.
Skin cleansing cream.
RESPIRATOR
Respiratory protection is required when ANY "Worst Case" vapour-phase concentration is exceeded (see
Computer Prediction in "Exposure Standards").
Protection Half Face Full Face
Factor Respirator Respirator
10 x ES AX -AUS -
AX -PAPR-AUS -
50 x ES - AX -AUS
- AX -PAPR-AUS
100 x ES - AX -2
- AX -PAPR-2
^ - Full-face.
The local concentration of material, quantity and conditions of use determine the type of personal protective
equipment required. For further information, consult site specific CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
SAFE HANDLING
STORAGE AND TRANSPORT
SUITABLE CONTAINER
Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers
STORAGE REQUIREMENTS
Store in original containers in approved flame-proof area.
No smoking, naked lights, heat or ignition sources.
DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
Keep containers securely sealed.
Store away from incompatible materials in a cool, dry well ventilated area.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storing and handling recommendations.
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TRANSPORTATION
Class 3 - Flammable liquids shall not be loaded in the same vehicle or packed in the same vehicle or packed
in the same freight container with:
Class 1 - Explosives;
Class 2.1 - Flammable gases (where both flammable liquids and flammable gases are in bulk);
Class 2.3 - Poisonous gases;
Class 4.2 - Spontaneously combustible substances;
Class 5.1 - Oxidising agents;
Class 5.2 - Organic peroxides;
Class 7 - Radioactive substances.
SPILLS AND DISPOSAL
MINOR SPILLS
Remove all ignition sources.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact by using protective equipment.
Contain and absorb small quantities with vermiculite or other absorbent material.
Wipe up.
Collect residues in a flammable waste container.
MAJOR SPILLS
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
May be violently or explosively reactive.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
Consider evacuation (or protect in place).
No smoking, naked lights or ignition sources.
Increase ventilation.
Stop leak if safe to do so.
Water spray or fog may be used to disperse /absorb vapour.
Contain spill with sand, earth or vermiculite.
Use only spark-free shovels and explosion proof equipment.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite.
Collect solid residues and seal in labelled drums for disposal.
Wash area and prevent runoff into drains.
If contamination of drains or waterways occurs, advise emergency services.
EMERGENCY RESPONSE PLANNING GUIDLINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing life-threatening health effects is 1000 ppm
irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is 300 ppm other than mild, transient adverse effects without perceiving a clearly defined
odour is 50 ppm American Industrial Hygiene Association (AIHA)
DISPOSAL
Consult manufacturer for recycling options and recycle where possible .
Consult State Land Waste Management Authority for disposal.
Incinerate residue at an approved site.
Recycle containers if possible, or dispose of in an authorised landfill.
Page 9 of 10
FIRE FIGHTERS' REPORT
EXTINGUISHING MEDIA
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.
FIRE FIGHTING
Alert Fire Brigade and tell them location and nature of hazard.
May be violently or explosively reactive.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
Consider evacuation (or protect in place).
Fight fire from a safe distance, with adequate cover.
If safe, switch off electrical equipment until vapour fire hazard removed.
Use water delivered as a fine spray to control the fire and cool adjacent area.
Avoid spraying water onto liquid pools.
Do not approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
When any large container (including road and rail tankers) is involved in a fire, consider evacuation by 500
metres in all directions.
FIRE/EXPLOSION HAZARD
Liquid and vapour are highly flammable.
Severe fire hazard when exposed to heat, flame and/or oxidisers.
Vapour forms an explosive mixture with air.
Severe explosion hazard, in the form of vapour, when exposed to flame or spark.
Vapour may travel a considerable distance to source of ignition.
Heating may cause expansion / decomposition with violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO) May emit clouds of acrid smoke
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents as ignition may result
HAZCHEM
3[Y]E
CONTACT POINT
In the event of a chemical event of a chemical incident phone 0800 243 622 for immediate
assistance.
AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE: 13 11 26
POLICE, FIRE BRIGADE OR AMBULANCE: 000
NEW ZEALAND POISONS INFORMATION CENTRE
24 HOUR SERVICE: (03) 4747 000
NZ EMERGENCY SERVICES: 111
End of Report
Date of preparation Mon 16-Sep-2002
http://zenstoves.net
Print Date Thu 20-Feb-2003
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+613) 9572 4700
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