MATERIAL SAFETY DATA SHEET
DYPHENE 669C
:
DISTRIBUTOR WESTERN RESERVE CHEMICAL
NAME AND : 4837 DARROW RD.
ADDRESS : STOW, OHIO 44224
PHONE : 330-650-2244
FAX : 330-650-2255
_________________________________________________
I. PRODUCT IDENTIFICATION
HMIS HAZARD RATINGS
HEALTH HAZARD 1 FIRE HAZARD 1 REACTIVITY 1
Based on the National Paint & Coatings Association HMIS rating system.
SARA/TITLE III HAZARD CATEGORIES (See Section X)
Immediate (ACUTE) Health: NO Reactive Hazard: NO
Delayed (Chronic) Health: NO Sudden Release of Pressure: NO
Fire Hazard: NO
CHEMICAL NAME: Formaldehyde, polymer with 4-(1,1-dimethyl-ethyl)phenol
4,4'-1(methylethylidene)bis(phenol)
CHEMICAL FORMULA: (C15H16O2隆C10H14O隆CH2O)x
DOT INFORMATION: This material may be regulated by the DOT because
it could contain a Reportable Quantity (RQ) of a
hazardous substance. Please examine the quantity
per package for the following hazardous substance:
DOT HAZARDOUS SUBSTANCE: RQ100# (Formaldehyde)
_________________________________________________________________
II. HEALTH HAZARD INFORMATION
EMERGENCY AND FIRST AID PROCEDURES
EYES:
IMMEDIATELY flush eyes with a directed stream of water for at
least 15 minutes while forcibly holding eyelids apart to ensure
complete irrigation of all eye and lid tissue. IF IRRITATION
OCCURS, GET MEDICAL ATTENTION.
SKIN:
Wash thoroughly with soap and water.
INHALATION:
Remove to fresh air. If breathing is difficult, have trained
person administer oxygen. If respiration stops, give
mouth-to-mouth resuscitation. GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION:
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NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Have
patient drink several glasses of water, then induce vomiting by
having patient tickle back of throat with finger. Keep airway
clear. SEEK MEDICAL ATTENTION IMMEDIATELY.
NOTES TO PHYSICIAN:
Treatment is symptomatic and no antidotes are known. Effects
of overexposure are related to ingredients.
ROUTES OF EXPOSURE
INHALATION:
Dust or vapors may be irritating to the respiratory tract. See
Section VII for additional hazards.
SKIN:
Dust or vapors may be irritating to the skin. Repeated contact
with the skin may cause dermatitis in sensitive individuals.
EYE CONTACT:
Dust or vapors may be irritating to the eyes.
INGESTION:
No data available for this material.
EFFECTS OF OVEREXPOSURE
ACUTE:
Dust or vapor may be irritating to the eyes, skin, and
respiratory tract. Repeated contact with the skin may cause
dermatitis in sensitive individuals.
CHRONIC:
The chronic effects of repeated dust or vapor inhalation are
not known. See Section VII.
TOXICOLOGY DATA:
p-tert-Butylphenol
Acute oral LD50 (rat) 2951 mg/kg
Acute dermal LD50 (rabbit) 2288 mg/kg
Acute eye irritation: (rabbit, 24 hr.) 50 ug/severe
Acute dermal irritation: (rabbit, 24 hr.) 500 mg/mild
III. IMPORTANT COMPONENTS
______________________
CAS NUMBER / NAME
54579441 Formaldehyde, polymer with 4-(1,1-dimethylethyl)
phenol and 4,4'-(1-methylethylidene)bis-phenol
EXPOSURE LIMITS PERCENTAGE
PEL:Not Established VOL ND
TLV:Not Established WT 95-98
COMMON NAMES:
Listed On(List Legend Below):
19 23
-----------------------------------
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98544 Phenol, 4-(1,1-dimethylethyl)-
EXPOSURE LIMITS PERCENTAGE
PEL:Not Established VOL ND
TLV:Not Established WT 1-3
COMMON NAMES:
p-tert-BUTYLPHENOL
Listed On(List Legend Below):
19 23
-----------------------------------
50000 Formaldehyde
EXPOSURE LIMITS PERCENTAGE
PEL:0.75 ppm TWA VOL ND
0.5 ppm (action level) WT 0-0.09
STEL 2 ppm
TLV:0.3 ppm; 0.37 mg/m3 Ceiling, A2
COMMON NAMES:
Listed On(List Legend Below):
01 02 07 09 11 15 18 21
-----------------------------------
All components of this product that are required to be on the TSCA
Inventory are listed on the Inventory.
This material is not listed as carcinogen - IARC, NTP, OSHA
LIST LEGEND
1 SARA EXTR HAZ SUB, SECTION 302 2 SARA TOXIC CHEM, SECTION 313
7 NTP "ANTPTD HUMAN CARCINOGENS" 9 IARC GROUP 2A OR 2B CARCINOGEN
11 CA PROP 65 - CARCINOGEN 15 PA SPECIAL & ENV HAZ SUBSTANCE
18 NY HAZARDOUS SUBSTANCES 19 PA REQUIREMENT- 3% OR GREATER
21 NJ SPECIAL HEALTH HAZ SUB 23 NJ REQUIREMENT- 1% OR GREATER
IV. FIRE AND EXPLOSION DATA
FLASH POINT: NA AUTOIGNITION TEMPERATURE: ND
FLAMMABLE LIMITS IN AIR, % BY VOLUME- UPPER: ND
LOWER: ND
EXTINGUISHING MEDIA:
Use water, dry chemical, Halon, alcohol foam, or carbon
dioxide.
SPECIAL FIRE FIGHTING PROCEDURES:
Do not inhale gases. In fire conditions wear NIOSH/MSHA
approved positive pressure self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARD:
Explosion hazard: Organic dust can be explosive when ideal
conditions of concentration, humidity and source are met.
V. SPECIAL PROTECTION
_________
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VENTILATION REQUIREMENTS:
General room ventilation plus local exhaust at points of
emission to maintain exposure below TLV(s).
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY:
A NIOSH/MSHA approved respirator, following manufacturer's
recommendations, should be used as a precautionary measure where
airborne contaminants may occur.
EYE:
Wear safety glasses with side shields or chemical safety
goggles (ANSI Z87.1).
GLOVES:
Wear impervious gloves such as neoprene or rubber.
OTHER CLOTHING AND EQUIPMENT:
Eye wash facility and emergency shower should be in close
proximity (ANSI Z358.1).
VI. PHYSICAL DATA
__________________________________
BOILING POINT @ 760 mm Hg: NA
FREEZING POINT: NA
VAPOR PRESSURE: NA
SPECIFIC GRAVITY (H2O=1): 1.08 - 1.10
SOLUBILITY IN H2O % BY WT: Insoluble
VAPOR DENSITY (Air=1): NA
APPEARANCE AND ODOR: Amber Flake or lump
pH: NA
VII. REACTIVITY DATA
____________
CONDITIONS CONTRIBUTING TO INSTABILITY:
Exposure to high temperature and/or moisture causes resin
agglomeration.
INCOMPATIBILITY:
None known
HAZARDOUS DECOMPOSITION PRODUCTS:
Combustion can produce carbon dioxide and carbon monoxide.
Traces of formaldehyde may be released in the resin curing
process. The air concentration will be dictated by curing
conditions, room ventilation and production rates. Airborne
monitoring should be conducted to accurately determine the level
of these substances in the air.
The symptoms of formaldehyde exposure including eye, nose,
throat and upper respiratory tract irritation, tearing and nose
stuffiness usually are initially experienced at air
concentrations in the range of 0.2-1.0 ppm and become more severe
above 1 ppm. For exceptionally sensitive individuals, symptoms
may appear at far lower concentrations.
In laboratory tests, formaldehyde has been shown to be
carcinogenic in rats. There is no conclusive evidence regarding
the carcinogenicity of formaldehyde in man. Formaldehyde is
listed by NTP as reasonably anticipated to be carcinogenic, and
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by IARC as a group 2A carcinogen, OSHA, in its formaldehyde
Standard (29 CFR 1910.1048) considers formaldehyde to be a
potential carcinogen.
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION:
Not known to undergo hazardous polymerization.
________________________
VIII. HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS:
Observe good housekeeping practices. Contain material and
prevent accumulations of dust.
Store in a cool, dry place to avoid effects of heat and
moisture on resin agglomeration. Storage temperatures above 75掳F
must be avoided.
IX. ENVIRONMENTAL PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Sweep or vacuum spills. To minimize dust, vacuum cleaning is
preferred.
WASTE DISPOSAL METHOD:
Dispose of according to federal, state and local government
regulations.
X. ADDITIONAL INFORMATION
OSHA Standard 29CFR 1910.1200 requires that information be
provided to employees regarding the hazards of chemicals by means
of a hazard communication program including labeling, material
safety data sheets, training and access to written records. We
request that you, and it is your legal duty to, make all
information in this Material Safety Data Sheet available to your
employees.
To aid our customers in complying with regulatory requirements,
SARA Title III hazard categories for this product are indicated
in Section I. If the word 鈥淵ES" appears next to any category,
this product may be reportable by you under the requirements of
40 CFR Part 370. Please consult those regulations for details.
State of California Safe Drinking Water and Toxic Enforcement Act
Of 1986 (Proposition 65) :
WARNING: This product contains a chemical known to the State Of
California to cause cancer.
WARNING LABEL INFORMATION
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________________________
SIGNAL WORD: CAUTION
STATEMENT OF HAZARDS:
DUST OR VAPORS MAY BE IRRITATING TO SKIN, EYES, AND RESPIRATORY
TRACT.
POSSIBLE DUST EXPLOSION IF LARGE QUANTITIES OF DUST ARE DISPERSED
IN THE AIR.
REPEATED SKIN CONTACT MAY CAUSE DERMATITIS.
RELEASES FORMALDEHYDE, WHICH MAY CAUSE CANCER. RISK OF CANCER
DEPENDS ON DURATION AND LEVEL OF EXPOSURE.
PRECAUTIONARY STATEMENTS:
Do not breathe dust or vapors.
Do not get in eyes, on skin or clothing.
Wear safety glasses with side shields; rubber or neoprene gloves.
Wash thoroughly after handling.
FIRST AID:
IN CASE OF CONTACT:
FOR EYES:
IMMEDIATELY flush eyes with a directed stream of water for at
least 15 minutes while forcibly holding eyelids apart to ensure
complete irrigation of all eye and lid tissue. IF IRRITATION
OCCURS, GET MEDICAL ATTENTION.
FOR SKIN:
Wash thoroughly with soap and water.
IF INHALED:
Remove to fresh air. If breathing is difficult, have trained
person administer oxygen. If respiration stops, give
mouth-to-mouth resuscitation. GET MEDICAL ATTENTION IMMEDIATELY.
IF SWALLOWED:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Have
patient drink several glasses of water, then induce vomiting by
having patient tickle back of throat with finger. Keep airway
clear. SEEK MEDICAL ATTENTION IMMEDIATELY.
IN CASE OF:
SPILL OR LEAK:
Use dry pick-up. To minimize dust, vacuum cleaning of spills is
preferred.
FIRE:
Use water, dry chemical, Halon, alcohol foam, carbon dioxide.
Do not inhale gases. Wear positive pressure self-contained
breathing apparatus approved by NIOSH/MSHA.
DISPOSAL:
Dispose of according to government regulations.
HANDLING AND STORAGE:
Use in well ventilated area.
Keep away from heat, sparks, and open flames.
Do not store in unlabeled or mislabeled containers.
Avoid possible dust build up in the manufacturing area.
For product integrity, store in a cool, dry place to avoid resin
agglomeration or advancement. Resin will advance at temperatures
in excess of 75掳F.
INFORMATION REQUIRED BY FEDERAL, STATE OR LOCAL REGULATIONS:
This product contains:
CAS# NAME
54579441 Formaldehyde, polymer with 4-(1,1-dimethylethyl)
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phenol and 4,4'-(1-methylethylidene)bis(phenol)
98544 Phenol, 4-(1,1-dimethylethyl)-
50000 Formaldehyde
HMIS RATING SYSTEM: HEALTH 1 FLAMMABILITY 1 REACTIVITY 1
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