The MSDS format adheres to the standards and regulatory requirements
of the United States and may not meet regulatory requirements
in other countries.
DuPont Page 1
Material Safety Data Sheet
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PYRALUX(R) FR ADHESIVE (VAPORS)
L0000055 Revised 13-JUN-2003
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CHEMICAL PRODUCT/COMPANY IDENTIFICATION
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Material Identification
PYRALUX is a registered trademark of DuPont.
Product Use
In keeping with DuPont鈥檚 continuing commitment to safety and
the environment, we are providing this MSDS as a service to
our customers. This product is classified as non-hazardous
under OSHA鈥檚 Hazard Communication Standard (29 CFR
1910.1200). Pyralux(r) products do create off-gases in
normal use. These off-gases are regulated, but are present
at such low levels during normal use that no hazardous
exposure is anticipated.
Tradenames and Synonyms
Vapors from Pyralux (R) FR Sheet Adhesive
Vapors from Pyralux (R) FR Bond Ply
Vapors from Pyralux (R) FR Coverlay
Vapors from Pyralux (R) FR Clads
Tradenames and Synonyms (Remarks)
Pyralux (R) FR is the product name of a family of products
consisting of flexible Copper Clad Laminates, Coverlay, Bond
Ply, and Sheet Adhesive. This MSDS focuses on the vapors
that may evolve from the adhesive during processing of any
one of these products.
The Clads are made of copper foil laminated to polyimide
film with an adhesive. The Coverlay and Bond Ply are made
of polyimide film with an adhesive, and the Sheet Adhesive
is just adhesive.
Company Identification
MANUFACTURER/DISTRIBUTOR
DuPont
1007 Market Street
Wilmington, DE 19898
PHONE NUMBERS
Product Information : 1-800-441-7515 (outside the U.S.
302-774-1000)
Transport Emergency : CHEMTREC 1-800-424-9300(outside U.S.
703-527-3887)
Medical Emergency : 1-800-441-3637 (outside the U.S.
302-774-1000)
L0000055 DuPont Page 2
Material Safety Data Sheet
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COMPOSITION/INFORMATION ON INGREDIENTS
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Components
Material CAS Number %
The following vapors may be evolved during
lamination and baking (160-200 deg C)
BENZOPHENONE 119-61-9 0-10
*PHENOL 108-95-2 10-30
2-2鈥?-DIETHYL-1,1鈥?-BIPHENYL 13049-35-9 0-5
2,6-DICHLORO-BENZAMIDE 200854 0-5
ALIPHATIC HYDROCARBONS 0-5
*METHANOL 67-56-1 0-5
4-(DIMETHYLAMINO)-BENZOIC ACID ESTERS 1-5
PHTHALATE COMPOUNDS 30-60
UNKNOWN SI-CONTAINING COMPOUNDS 1-5
During drilling and routing operations which
produce dust, the following may be released:
*ANTIMONY TRIOXIDE 1309-64-4
* Disclosure as a toxic chemical is required under Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR part 372.
Components (Remarks)
The concentrations are based on GC/MS analyses of film
vapors in lamination and baking, the principle steps where
vapor evolution occurs. The quantity of vapors is estimated
to be 1-5 lbs per 100,000 sqft of adhesive. Vapor evolution
results are based on the percentage of weight loss measured
by Thermal Gravimetric Analysis (TGA). This weight loss
includes water vapor. The pounds of vapor are not all
"VOC鈥檚" as "defined" by the EPA for Clean Air Act purpose.
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HAZARDS IDENTIFICATION
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Potential Health Effects
As a part of the hazard assessment process, DuPont has
conducted industrial hygiene studies to monitor the
potential exposure to the off-gases from this product during
normal use. Conclusions from the results of these studies
indicate that exposure levels during press lamination using
adequate ventilation were well below regulated limits (e.g.
an order of magnitude below the exposure limit.) Tests run
for antimony trioxide and nuisance dust levels at a
drilling/routing station with vacuum exhaust also indicated
exposure levels well below regulated limits.
As a result of this test data, DuPont believes the potential
exposure to the vapors and dusts of this product to be
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Material Safety Data Sheet
(HAZARDS IDENTIFICATION - Continued)
minimal.
Equipment used for lamination and curing must be adequately
exhausted. Consult the DuPont publication "Pyralux Safe
Handling". Additional information provided in "Handling &
Safety Considerations for the Pyralux PC Curing Process" may
also be helpful.
POTENTIAL HUMAN HEALTH EFFECTS OF OVEREXPOSURE:
Inhalation may cause irritation of the upper respiratory
passages, with sneezing, coughing and discomfort; or
temporary lung irritation effects with cough, discomfort,
difficulty breathing, or shortness of breath.
Inhalation, ingestion or skin contact may cause temporary
mild depression of the central nervous system with
dizziness, confusion, incoordination or drowsiness followed
by an asymptomatic period usually ranging from 12 to 24
hours.
Skin contact may cause redness of the skin and dermatitis
with itching or rash. Evidence from animal testing on some
vapor components suggests that skin permeation can occur in
amounts capable of producing the effects of systemic
toxicity.
Eye contact with high concentrations of vapors may cause eye
irritation with discomfort, tearing or blurring of vision.
Individuals with pre-existing diseases of the central
nervous system, liver or kidneys may have increased
susceptibility to the toxicity of excessive exposures.
Carcinogenicity Information
The following components are listed by IARC, NTP, OSHA or ACGIH as
carcinogens.
Material IARC NTP OSHA ACGIH
ANTIMONY TRIOXIDE 2B
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FIRST AID MEASURES
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First Aid
INHALATION
If inhaled, remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
Call a physician.
SKIN CONTACT
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Material Safety Data Sheet
(FIRST AID MEASURES - Continued)
Flush skin with water after contact. Wash contaminated clothing
before reuse.
EYE CONTACT
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.
INGESTION
Ingestion is not considered a potential route of exposure.
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FIRE FIGHTING MEASURES
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Flammable Properties
Flammable limits in Air, % by Volume
LEL : not determined
UEL : not determined
Extinguishing Media
Use media appropriate for surrounding material.
Fire Fighting Instructions
Evacuate personnel to a safe area. Keep personnel removed and
upwind of fire. Wear self-contained breathing apparatus. Runoff
from fire control may be a pollution hazard.
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ACCIDENTAL RELEASE MEASURES
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Safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.
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HANDLING AND STORAGE
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Handling (Personnel)
Do not breathe vapor or mist. Do not breathe dust. Do not get in
eyes. Do not store or consume food, drink or tobacco in areas
where they may become contaminated with this material.
Good industrial hygiene procedures include washing hands
after handling.
L0000055 DuPont Page 5
Material Safety Data Sheet
(HANDLING AND STORAGE - Continued)
Storage
Do not store or consume food, drink or tobacco in areas where they
may become contaminated with this material.
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EXPOSURE CONTROLS/PERSONAL PROTECTION
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Engineering Controls
Use only with adequate ventilation.
Personal Protective Equipment
Eye/Face : Safety Glasses.
Respirator : USE ADEQUATE VENTILATION WHEN CUTTING OR
HEATING.
# Exposure Guidelines
Applicable Exposure Limits
BENZOPHENONE
PEL (OSHA) : None Established
TLV (ACGIH) : None Established
AEL * (DuPont) : None Established
WEEL (AIHA) : 0.5 mg/m3, 8 Hr. TWA
PHENOL
PEL (OSHA) : 5 ppm, 19 mg/m3, 8 Hr. TWA, Skin
TLV (ACGIH) : 5 ppm, 19 mg/m3, 8 Hr. TWA, Skin, A4
AEL * (DuPont) : None Established
METHANOL
PEL (OSHA) : 200 ppm, 260 mg/m3, 8 Hr. TWA
TLV (ACGIH) : 200 ppm, 8 Hr. TWA, Skin
STEL 250 ppm
AEL * (DuPont) : 200 ppm, 8 & 12 Hr. TWA, Skin
ANTIMONY TRIOXIDE
PEL (OSHA) : 0.5 mg/m3, as Sb, 8 Hr. TWA
TLV (ACGIH) : 0.5 mg/m3, handling and use as Sb
Antimony Trioxide Production,A2
8 Hr TWA
AEL * (DuPont) : 0.2 mg/m3, 8 Hr. TWA, as Sb
* AEL is DuPont鈥檚 Acceptable Exposure Limit. Where governmentally
imposed occupational exposure limits which are lower than the AEL
are in effect, such limits shall take precedence.
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Material Safety Data Sheet
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PHYSICAL AND CHEMICAL PROPERTIES
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Physical Data
% Volatiles : 2.0 WT% WATER + VAPORS LISTED ABOVE.
Odor : NONE
Form : SOLID SHEET
Color : OFF-WHITE
Physical Hazards
DUST MAY CONTAIN ANTIMONY OXIDE.
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STABILITY AND REACTIVITY
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Chemical Stability
Stable at normal temperatures and storage conditions.
Incompatibility with Other Materials
None reasonably foreseeable.
Decomposition
Decomposes with heat.
SEE COMPOSITION INFORMATION FOR VAPOR INFORMATION.
Polymerization
Polymerization can occur.
Conditions leading to polymerization are HEAT AND PRESSURE
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TOXICOLOGICAL INFORMATION
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Animal Data
PHENOL
Skin absorption LD50, rabbit: 1669 mg/kg
Oral LD50, rat : 414 mg/kg
Inhalation 8 hour, LC50, rat: > 234 ppm
BENZOPHENONE
Inhalation 4 hour, ALC, rat : > 330 ppm
Skin absorption LD50, rabbit : 3535 mg/kg
Oral LD50, mice : 2895 mg/kg
METHANOL
Oral LD50, rat : 9,100 mg/kg
Dermal LD50, rabbit : 15,840 mg/kg
Inhalation 1 hour, LC50, rat : > 145,000 ppm
L0000055 DuPont Page 7
Material Safety Data Sheet
(TOXICOLOGICAL INFORMATION - Continued)
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DISPOSAL CONSIDERATIONS
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Waste Disposal
Treatment, storage, transportation, and disposal must be in
accordance with applicable Federal, State/Provincial, and Local
regulations. Do not burn.
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REGULATORY INFORMATION
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U.S. Federal Regulations
TSCA Inventory Status : In compliance with TSCA Inventory
requirements for commercial purposes.
State Regulations (U.S.)
WARNING - SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM- antimony trioxide
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OTHER INFORMATION
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Additional Information
MEDICAL USE: CAUTION: Do not use in medical applications
involving permanent implantation in the human body. For other
medical applications see DuPont CAUTION Bulletin No. H-50102.
PRECAUTIONARY STATEMENTS FOR VAPOR CONDENSATE AND
VACUUM PUMP OIL:
WARNING! CAUSES EYE, SKIN AND RESPIRATORY IRRITATION.
Oil in vacuum pump will collect and concentrate less
volatile components. Condensate will contain higher
percentages of less volatile components. The less volatile
components may include acrylate monomers which may cause
delayed skin burns and may cause skin sensitization. Avoid
contact with eyes, skin and clothing. Avoid breathing mist
or vapor. Wash thoroughly with soap and water after
handling. Laminators and curing equipment used to process
PYRALUX(R) films should be designed with adequate
ventilation to exhaust these vapors from the workplace.
Vapors may condense on cold surfaces in exhaust ducts.
Check these surfaces for condensate build-up before
handling.
INFORMATION ON THE CLEAN AIR ACT OF 1990 TITLE VI,
SECTION 611: CONCERNING OZONE DEPLETING SUBSTANCES -
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Material Safety Data Sheet
(Continued)
DuPont Riston (R), Vacrel (R), VALU (TM), and Pyralux (R)
photopolymer resists and sold masks do NOT contain and
are NOT manufactured with either Class I or Class II Ozone
Depleting Substances.
For further information regarding the safe use of this
material, please refer to DuPont technical bulletin
"Handling and Safety Considerations for the PYRALUX(R) PC
Curing Process."
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The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.
DUPONT iTECHNOLOGIES
14 ALEXANDER DRIVE
RESEARCH TRIANGLE PARK, NC 27709
919-248-5345 OR 919-248-5027
# Indicates updated section.
This information is based upon technical information believed to be
reliable. It is subject to revision as additional knowledge and
experience is gained.
End of MSDS
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