MATERIAL SAFETY DATA SHEET

MSDS DATE:08/14/07



SECTION 1: PRODUCT AND COMPANY IDENTIFICATION



PRODUCT NAME: SODIUM BISULFITE SOLUTION

SYNONYMS: SODIUM BISULPHITE, AQUEOUS SOLUTION; SODIUM HYDROGEN SULFITE; SODIUM DISULFITE; SULFUROUS ACID,

MONOSODIUM SALT; SODIUM ACID SULFITE

PRODUCT CODES: 26084-05

MANUFACTURER:    ELECTRON MICROSCOPY SCIENCES

DIVISION:        1560 INDUSTRY ROAD/P.O. BOX 550

ADDRESS:         HATFIELD, PA 19440



EMERGENCY PHONE: 215-412-8400

CHEMTREC PHONE: 800-424 -4300



FAX PHONE:         215-412-8450



CHEMICAL NAME: SODIUM BISULFITE

CHEMICAL FAMILY: BISULFITE, SODIUM SALT



SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS



INGREDIENT:

SODIUM BISULFITE

WATER



CAS NO.                       % WT                  % VOL            SARA 313 REPORTABLE

7631-90-5                       35-44                  N/A

7732-18-5                       56-65                  N/A

                              ppm                   mg/m3

   OSHA PEL-TWA:                N/A                    5

   OSHA PEL STEL :              N/A                    N/A

   OSHA PEL CEILING:             N/A                   N/A





   ACGIH TLV-TWA:                 N/A                 5

   ACGIH TLV STEL:                N/A                 N/A

   ACGIH TLV CEILING:             N/A                 N/A





SECTION 3: HAZARDS IDENTIFICATION



EMERGENCY OVERVIEW: DANGER! GONTAINS MATERIAL. WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: MUCOUS

MEMBRANES, RESPIRATORY TRACT, SKIN, EYE, LENS OR CORNEA. INCOMPATIBLE WITH ACIDS AND OXIDIZERS

(ACIDIFICATION WILL LIBERATE SULFUR DIOXIDE GAS). THERMAL DECOMPOSITION PRODUCTS ARE CORROSIVE AND/OR

TOXIC AND INCLUDE OXIDES OF SULFUR.



ROUTES OF ENTRY: N/A



POTENTIAL HEALTH EFFECTS

   EYES: VAPORS FROM THIS PRODUCT ARE IRRITATING TO THE EYES. THIS PRODUCT CAUSES IRRITATION, REDNESS, AND

PAIN. MAY CAUSE BURNS IF LEFT UNTREATED



   SKIN: SODIUM BISULFITE MAY CAUSE SYMPTOMS OF SKIN IRRITATION SUCH AS REDDENING, SWELLING, RASH, SCALING

OR BLISTERING.



   INGESTION: MAY CAUSE ALLERGIC REACTION IN SOME ASTHMATICS. INGESTION OF LARGE AMOUNTS MAY CAUSE

NAUSEA, GASTROINTESTINAL UPSET AND ABDOMINAL PAIN. MAY CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION,

NAUSEA AND VOMITING, DIARRHEA, VIOLENT COLIC AND DEATH.



   INHALATION: PRODUCT IS IRRITATING TO THE NOSE, THROAT AND RESPIRATORY TRACT



ACUTE HEALTH HAZARDS: N/A



CHRONIC HEALTH HAZARDS: N/A



MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: BREATHING FUMES MAY AGGRAVATE ACUTE OR CHRONIC

ASTHMA AND CHRONIC PULMONARY DISEASE SUCH AS EMPHYSEMA AND BRONCHITIS. MAY CAUSE ALLERGIC REACTIONS IN

SULFIDE SENSITIVE INDIVIDUALS.





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CARCINOGENICITY

   OSHA: NO    ACGIH:A4             NTP: NO       IARC: 3

   OTHER: N/A







SECTION 4: FIRST AID MEASURES



EYES: IMMEDIATELY FLUSH EYES WITH RUNNING WATER FOR A MINIMUM OF 20 MINUTES. HOLD EYELIDS OPEN DURING

FLUSHING. IF IRRITATION PERSISTS, REPEAT FLUSHING. OBTAIN MEDICAL ATTENTION IMMEDIATELY. DO NOT TRANSPORT

VICTIM UNTIL THE RECOMMENDED FLUSHING PERIOD IS COMPLETED UNLESS FLUSHING CAN BE CONTINUED DURING

TRANSPORT.



SKIN: FLUSH SKIN WITH RUNNING WATER FOR A MINIMUM OF 20 MINUTES. START FLUSHING WHILE REMOVING

CONTAMINATED CLOTHING. IF IRRITATION PERSISTS, REPEAT FLUSHING. OBTAIN MEDICAL ATTENTION IMMEDIATELY. DO NOT

TRANSPORT VICTIM UNLESS THE RECOMMENDED FLUSHING PERIOD IS COMPLETED OR FLUSHING CAN BE CONTINUED

DURING TRANSPORT.



INGESTION: DO NOT INDUCE VOMITING. IF VICTIM IS ALERT AND NOT CONVULSING, RINSE MOUTH AND GIVE ½ TO 1 GLASS OF

WATER TO DILUTE MATERIAL. IF SPONTANEOUS VOMITING OCCURS, HAVE VICTIM LEAN FORWARD WITH HEAD DOWN TO

AVOID BREATHING IN OF VOMITUS. RINSE MOUTH AND ADMINISTER MORE WATER. IMMEDIATELY CONTACT LOCAL POISON

CONTROL CENTER. IMMEDIATELY TRANSPORT VICTIM TO AN EMERGENCY FACILITY.



INHALATION: MOVE VICTIM TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION ONLY IF BREATHING HAS STOPPED. GIVE

CARDIOPULMONARY RESUSCITATION (CPR) IF THERE IS NO BREATHING AND NO PULSE. OBTAIN MEDICAL ATTENTION

IMMEDIATELY



NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: N/A









SECTION 5: FIRE-FIGHTING MEASURES



FLAMMABLE LIMITS IN AIR, UPPER: N/A

  (% BY VOLUME)         LOWER: N/A



FLASH POINT: N/A PRODUCT IS NON FLAMMABLE

 F:

 C:

METHOD USED: N/A



AUTOIGNITION TEMPERATURE: NOT COMBUSTIBLE

 F:

 C:



NFPA HAZARD CLASSIFICATION

   HEALTH: 2               FLAMMABILITY: 0                  REACTIVITY: 0

   OTHER: N/A



HMIS HAZARD CLASSIFICATION

   HEALTH: 2             FLAMMABILITY: 0               REACTIVITY: 0

   PROTECTION: C



EXTINGUISHING MEDIA: FOR SMALL FIRES USE DRY CHEMICAL, CARBON DIOXIDE OR WATER SPRAY. FOR LARGE FIRES, USE

DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL-RESISTANT FOAM OR FLOOD FIRE AREA WITH WATER. DO NOT GET SOLID

STREAM OF WATER ON SPILLED MATERIAL.



SPECIAL FIRE FIGHTING PROCEDURES: OXIDES OF SULFUR MAY BE PRESENT DURING A FIRE. USE SELF CONTAINED

BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING ARE RECOMMENDED. GAS TIGHT SUITS ARE REQUIRED IN

EXTREME 9> 1000 PPM) CONCENTRATIONS OF SULFUR DIOXIDE. EVACUATE RESIDENTS WHO ARE DOWNWIND OF FIRE.

PREVENT UNAUTHORIZED ENTRY TO FIRE AREA. DIKE AREA TO CONTAIN RUNOFF AND PREVENT CONTAMINATION OF WATER

SOURCES. NEUTRALIZE RUNOFF WITH LIME, SODA ASH OR OTHER SUITABLE NEUTRALIZING AGENTS ( SEE DEACTIVATING

CHEMICALS, SECTION 6) COOL CONTAINERS THAT ARE EXPOSED TO FLAME WITH STREAMS OF WATER UNTIL FIRE IS OUT.



UNUSUAL FIRE AND EXPLOSION HAZARDS: THERMAL DECOMPOSITION PRODUCTS ARE TOXIC AND INCLUDE OXIDES OF

SULFUR. SODIUM SULFIDE MAY BE FORMED AFTER DRIED SOLUTION RESIDUES ARE HEATED. THIS IS AN EXPLOSIVE HAZARD

AND STRONGLY ALKALINE IN CONTACT WITH WATER.

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HAZARDOUS DECOMPOSITION PRODUCTS: N/A







SECTION 6: ACCIDENTAL RELEASE MEASURES



ACCIDENTAL RELEASE MEASURES: STEPS TO BE TAKEN IN CASE OF A SPILL OR LEAK: REMOVE ALL IGNITION SOURCES.

VENTILATE AREA. USE APPROPRIATE PERSONAL PROTECTION EQUIPMENT. PREVENT LIQUID FROM ENTERING SEWERS OR

WATERWAYS. DIKE WITH INERT MATERIAL (SAND, EARTH, ETC) STOP OR REDUCE LEAK IF SAFE TO DO SO. COLLECT INTO

CONTAINERS FOR RECLAMATION OR DISPOSAL ONLY IF CONTAINER IS SUITABLE TO WITHSTAND THE MATERIAL. CONSIDER

INSITU NEUTRALIZATION AND DISPOSAL. ENSURE ADEQUATE DECONTAMINATION OF TOOLS AND EQUIPMENT FOLLOWING

CLEAN UP. COMPLY WITH FEDERAL, PROVINCIAL/STATE AND LOCAL REGULATIONS ON REPORTING RELEASES.



DEACTIVATING CHEMICALS: ALKALI MATERIALS SUCH AS DILUTE SODIUM HYDROXIDE, LIME, LIMESTONE, SODIUM

CARBONATE (SODA ASH), SODIUM BICARBONATE, DILUTE AQUA AMMONIA. SULFUR DIOXIDE MAY BE RELEASED DURING

NEUTRALIZATION.







SECTION 7: HANDLING AND STORAGE



HANDLING AND STORAGE:

PRECAUTIONS: WEAR APPROPRIATE PERSONAL PROTECTION EQUIPMENT. KEEP IGNITION SOURCES AWAY FROM SODIUM

BISULFITE STORAGE, HANDLING AND TRANSPORTATION EQUIPMENT. KEEP CONTAINERS CLOSED WHEN NOT IN USE. HAVE

EMERGENCY EQUIPMENT ( FOR FIRES, SPILLS, LEAKS, ETC.) READILY AVAILABLE. ENSURE ALL CONTAINERS ARE LABELED.

DO NOT EXPOSE TO STRONG ACIDS AS THIS WILL LIBERATE SULFUR DIOXIDE GAS.

HANDLING PROCEDURES AND EQUIPMENT: RUBBER LINED CARBON STEEL OR CERTAIN STAINLESS STEEL MATERIALS ARE

SUITABLE FOR USE. CONTACT CHEMTRADE LOGISTICS FOR SPECIFIC RECOMMENDATIONS WHEN HANDLING SODIUM

BISULFITE.

STORAGE TEMPERATURE: STORE ABOVE FREEZING POINT. IDEAL STORAGE TEMPERATURES ARE BETWEEN 20 AND 27

DEGREES CENTIGRADE.

STORAGE REQUIREMENTS: STORE IN A CORROSION-PROOF AREA AWAY FROM INCOMPATIBLE SUBSTANCES. STORE IN

TIGHTLY CLOSED CONTAINER, PREFERABLY THE SUPPLIER CONTAINER. STORE IN A COOL, WELL VENTILATED LOCATION

AWAY FROM HEAT, SPARKS AND FLAMES. STORAGE TANKS SHOULD BE CONSTRUCTED FROM POLYETHYLENE,

POLYPROPYLENE, FIBERGLASS-REINFORCED PLASTIC (FRP), CROSS LINKED POLYETHYLENE (XLPE), OR 316 STAINLESS

STEEL TO AVOID CORROSION PROBLEMS. TANKS SHOULD BE VENTED INTO AN ALKALINE FUME RECOVERY SYSTEM OR

SCRUBBER. STORAGE TANKS SHOULD BE PROTECTED FROM WATER INGRESS, AND MAINTAINED STRUCTURALLY IN A SAFE

AND RELIABLE CONDITION.



OTHER PRECAUTIONS: ON EXPOSURE TO AIR, THE PRODUCT WILL LOSE SOME SULFUR DIOXIDE AND GRADUALLY OXIDIZE TO

SULFATE. BOTH ACIDIFICATION AND HEATING ACCELERATE THE RELEASE OF SULFUR DIOXIDE FUMES.







SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION



ENGINEERING CONTROLS: PROVIDE EXHAUST VENTILATION OR OTHER CONTROLS TO KEEP THE AIRBORNE

CONCENTRATIONS OF VAPORS BELOW THEIR RESPECTIVE OCCUPATIONAL EXPOSURE LIMITS. ENSURE THE EYEWASH

STATIONS AND SAFETY SHOWERS ARE PROXIMAL TO THE WORKSTATION LOCATION.



VENTILATION: N/A



RESPIRATORY PROTECTION: A NIOSH/MSHA APPROVED AIR-PURIFYING RESPIRATOR EQUIPPED WITH ACID GAS/FUME, DUST,

                                                  3

MIST CARTRIDGES FOR CONCENTRATIONS UP TO 50 MG/M OR 20 PPM AS SULFUR DIOXIDE. A POWERED AIR-PURIFYING

RESPIRATOR WITH ACID GAS CARTRIDGES FOR UP TO 50 PPM SULFURE DIOXIDE. A FULL-FACEPIECE AIR-SUPPLIED

RESPIRATOR IF CONCENTRATIONS ARE FOR UP TO AND HIGHER THAN 100 PPM SULFUR DIOXIDE.



EYE PROTECTION: TIGHT FITTING CHEMCIAL GOGGLES AND FACE SHIELD



SKIN PROTECTION: IMPERVIOUS (I.E., NEOPRENE, PVC, RUBBER) GLOVES, COVERALLS, BOOTS AND/OR OTHER ACID

RESISTANT PROTECTIVE CLOTHING.



OTHER PROTECTIVE CLOTHING OR EQUIPMENT: WHERE THERE IS A DANGER OF SPILLING OR SPLASHING, ACID RESISTANT

APRONS OR SUITS OR SUITS SHOULD BE WORN. TROUSER LEGS SHOULD BE WORN OUTSIDE (NOT TUCKED IN) RUBBER

BOOTS. SAFETY SHOWERS AND EYEWASH FOUNTAINS SHOULD BE INSTALLED IN STORAGE AND HANDLING AREAS.



WORK HYGIENIC PRACTICES: N/A



EXPOSURE GUIDELINES:N/A

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MATERIAL SAFETY DATA SHEET

MSDS DATE:08/14/07







SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES



APPEARANCE: CLEAR, COLORLESS TO LIGHT YELLOW



ODOR:PUNGENT ODOUR OF SULFUR DIOXIDE



PHYSICAL STATE: LIQUID



pH AS SUPPLIED: 3.8 TO 5.2

pH (Other): N/A

BOILING POINT:

             F: 220 DEG

             C: 104 DEG

MELTING POINT: N/A

             F: N/A

             C: N/A

FREEZING POINT: N/A

             F: 43 DEG

             C: 6 DEG

VAPOR PRESSURE (mmHg): 32 mmHg

     @

             F: N/A

             C: 20 DEG

VAPOR DENSITY (AIR = 1): 0.62

     @

             F: N/A

             C: N/A

     @

             F: N/A

             C: N/A

EVAPORATION RATE: N/A



BASIS (=1): N/A









SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (con’t)



SOLUBILITY IN WATER: MISCIBLE IN ALL PROPORTIONS IN WATER



PERCENT SOLIDS BY WEIGHT: N/A



PERCENT VOLATILE: N/A

     BY WT/ BY VOL @

           F: N/A

           C: N/A

VOLATILE ORGANIC COMPOUNDS (VOC): N/A



      WITH WATER: N/A      LBS/GAL

   WITHOUT WATER: N/A      LBS/GAL



MOLECULAR WEIGHT: N/A

VISCOSITY: N/A

     @

            F: N/A

            C: N/A





SECTION 10: STABILITY AND REACTIVITY







STABILITY: UNDER NORMAL CONDITIONS: ON EXPOSURE TO AIR THE PRODUCT WILL LOSE SOME SULFUR DIOXIDE AND

GRADUALLY OXIDIZE TO SULFATE. UNDER FIRE CONDITIONS: DECOMPOSES TO FORM OXIDES OF SULFUR.



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MSDS DATE:08/14/07

CONDITIONS TO AVOID (STABILITY): HIGH TEMPERATURES, SPARKS, OPEN FLAMES AND ALL OTHER SOURCES OF IGNITION.

TEMPERATURES AT OR NEAR BOILING POINT CAUSES EVOLUTION OF SULFUR DIOXIDE.



INCOMPATIBILITY (MATERIAL TO AVOID): STRONG OXIDIZERS, MAY CAUSE STRONG EXOTHERMIC REACTION. LEWIS OR

MINERAL ACIDS ( ACIDIFICATION WILL LIBERATE SULFUR DIOXIDE GAS).



HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: THERMAL DECOMPOSITION PRODUCTS ARE TOXIC AND INCLUDE OXIDES

OF SULFUR.



HAZARDOUS POLYMERIZATION: WILL NOT OCCUR



CONDITIONS TO AVOID (POLYMERIZATION): N/A









SECTION 11: TOXICOLOGICAL INFORMATION



TOXICOLOGICAL INFORMATION:



SODIUM BISULFITE SOLUTION LD50: 2000 MG/KG (ORAL- RAT)



REPRODUCTIVE EFFECTS: N/A

MUTAGENICITY DATA: NEVIDENCE OF MUTAGENIC ACTIVITY IN BACTERIA, MICROORGANISMS, AND DNA.

TERATOGENICITY DATA: N/A

SYNERGISTIC MATERIALS: N/A





SECTION 12: ECOLOGICAL INFORMATION



ECOLOGICAL INFORMATION:



INGREDIENT NAME                SPECIES                   PEIROD        RESULT



SODIUM BISULFITE SOLUTION      MOSQUITO FISH. (LC50)     96 HOUR(S)    240 PPM



PRODUCTS OF:                             THESE PRODUCTS ARE SULFUR OXIDES (SO2, SO3). SOME METALLIC OXIDES

TOXICITY OF THE PRODUCTS

OF BIODEGRADATION:                       THE PRODUCTS OF DEGRADATION ARE TOXIC.









SECTION 13: DISPOSAL CONSIDERATIONS



WASTE DISPOSAL METHOD: COMPLY WITH FEDERAL, STATE, LOCAL REGULATIONS.



RCRA HAZARD CLASS: N/A







SECTION 13: DISPOSAL CONSIDERATIONS (con’t)

-DO NOT DISPOSE OF WASTE WITH NORMAL GARBAGE OR TO SEWER SYSTEMS

-RESPONSIBILITY FOR PROPER WASTE DISPOSAL IS WITH THE OWNER OF THE WASTE. WORK WITH THE APPROPRIATE

REGULATORY BODIES TO ENSURE COMPLIANCE WITH REGULATIONS.

-CONSIDER THE COLLECTION OF RESIDUAL SODIUM BISULFATE INTO CONTAINERS FOR RECLAMATION OR DISPOSAL ONLY IF

THE CONTAINER IS SUITABLE TO WITHSTAND THE MATERIAL.

-CONSIDER INSITU NEUTRALIZATION AND DISPOSAL.

-CLEAN-UP MATERIAL MAY BE A RCRA HAZARDOUS WASTE ON DISPOSAL.

-PROVINCIAL/STATE OR LOCAL REGULATIONS OR RESTRICTIONS ARE COMPLEX AND MAY DIFFER FROM FEDERAL

REGULATIONS.

-THE INFORMATION APPLIES TO THE MATERIAL AS MANUFACTURED; PROCESSING, NEUTRALIZING, USE OR CONTAMINATION

MAY MAKE THE INFORMATION INAPPROPRIATE, INACCURATE OR INCOMPLETE.







SECTION 14: TRANSPORT INFORMATION



U.S. DEPARTMENT OF TRANSPORTATION

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MSDS DATE:08/14/07

   PROPER SHIPPING NAME: RQ, BISULFITES, AQUEOUS SOLUTIONS, N.O.S.

   HAZARD CLASS: 8

   ID NUMBER: UN 2693

   PACKING GROUP: III

   LABEL STATEMENT: N/A



WATER TRANSPORTATION

   PROPER SHIPPING NAME:                 SAME

   HAZARD CLASS:

   ID NUMBER:

   PACKING GROUP:

   LABEL STATEMENTS:





AIR TRANSPORTATION

    PROPER SHIPPING NAME:                SAME

    HAZARD CLASS:

    ID NUMBER:

    PACKING GROUP:

    LABEL STATEMENTS:





OTHER AGENCIES: N/A









SECTION 15: REGULATORY INFORMATION



U.S. FEDERAL REGULATIONS

    TSCA (TOXIC SUBSTANCE CONTROL ACT): TSCA INVENTORY STATUS: REPORTED/ INCLUDED



   CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): YES

       RQ= 5000 LB



   SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT):

PRODUCT HAZARD CATEGORIES



ACUTE (IMMEDIATE) HEALTH:                YES

CHRONIC (DELAYED) HEALTH:                NO

FIRE:                                    NO

REACTIVITY:                              NO

SUDDEN RELEASE OF PRESSURE:              NO



   311/312 HAZARD CATEGORIES:

   313 REPORTABLE INGREDIENTS: YES



STATE REGULATIONS:



RIGHT- TO- KNOW:           ILLINOIS, MASSACHUSETTS, NEW JERSEY, PENNSYLVANIA

CALIFORNIA PROP 65:        NO PRODUCTS WERE FOUND



INTERNATIONAL REGULATIONS:



CANADA

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS)

WHMIS CLASSIFICIATIONS:     CLASS D-2B MATERIAL CAUSING OTHER TOXIC EFFECTS 9TOXIC)

                            CLASS E � CORROSIVE

                            CEPA DSL: ALL COMPONENTS LISTED

WHMIS HEALTH EFFECTS INDEX: CORROSIVE MATERIAL

                            SENSITIZING MATERIAL



WHMIS INGREDIENT DISCLOSURE LIST:        CONFIRMED A; MEETS CRITERIA FOR DISCLOSURE AT 1% OR GREATER.





EINECS NUMBER: 231-548-0







SECTION 16: OTHER INFORMATION



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MATERIAL SAFETY DATA SHEET

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OTHER INFORMATION: N/A



PREPARATION INFORMATION: N/A



DISCLAIMER: IN COMPLIANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD, 2.9 C.F.R

1910. 1200, WE ARE PROVIDING YOU WITH A MSDS FOR THE HAZARDOUS MATERIAL YOU ARE

PURCHASING.

IT IS YOUR RESPONSIBILITY TO EDUCATE YOUR EMPLOYEES ON THE SAFE USE OF THE HAZARDOUS

MATERIAL.

ELECTRON MICROSCOPY SCIENCES MAKES NO PRESENTATION AS TO THE ACCURACY OF THE

INFORMATION IN THE MSDS. THE INFORMATION IS BELIEVED TO BE CORRECT; HOWEVER, YOU

(THE CUSTOMER), SHOULD PERFORM YOUR OWN INVESTIGATION AND INDEPENDENT

VERIFICATION. IF YOU RESELL THE PRODUCT, YOU ARE RESPONSIBLE TO FORWARD THE

INFORMATION IN THE MSDS TO YOUR CUSTOMER.









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