SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 28/NOV/2004
Date Updated: 12/MAR/2004
Version 1.2
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name CHLORAZOLE BLACK E
Product Number C1144
Company Sigma-Aldrich Pty, Ltd
Unit 2, 14 Anella Avenue
Castle Hill NSW 1765
Australia
Technical Phone # +61 2 9841 0555
Fax +61 2 9841 0500
Emergency Phone # +61 2 9841 0566
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
CHLORAZOLE BLACK 1937-37-7 217-710-3 611-025-00-7
Formula C34H25N9Na2O7S2
Molecular Weight 781.7 AMU
Synonyms Ahco Direct Black GX * Airedale Black ED * Aizen
Direct Deep Black EH * Aizen Direct Deep Black
GH * Aizen Direct Deep Black RH * Amanil Black
GL * Amanil Black WD * Apomine Black GX *
Atlantic Black BD * Atlantic Black C * Atlantic
Black E * Atlantic Black EA * Atlantic Black GAC
* Atlantic Black GG * Atlantic Black GXCW *
Atlantic Black GXOO * Atlantic Black SD * ATul
Direct Black E * Azine Deep Black EW * Azocard
Black EW * Azomine Black EWO * Belamine Black GX
* Bencidal Black E * Benzanil Black E * Benzo
Deep Black E * Benzo Leather Black E * Benzoform
Black BCN-CF * Black 2EMBL * Black 4EMBL *
Brasilamina Black GN * Brilliant Chrome Leather
Black H * Calcomine Black * Calcomine Black EXL
* Carbide Black E * CERN prima 38 (Czech) *
Chloramine Black C * Chloramine Black EC *
Chloramine Black ERT * Chloramine Black EX *
Chloramine Black EXR * Chloramine Black XO *
Chloramine Carbon Black S * Chloramine Carbon
Black SJ * Chloramine Carbon Black SN *
Chlorazol Black E * Chlorazol Black E
(biological stain) * Chlorazol Black EA *
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
May cause cancer. Possible risk of harm to the unborn child.
Carc. Cat.2 Repr. Cat.3
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear respirator, chemical safety goggles, rubber boots, and
heavy rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Ventilate
area and wash spill site after material pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Wash thoroughly after
handling.
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PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Color: Deep brown
Form: Fine crystals
Property Value At Temperature or Pressure
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density N/A
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Stable: Stable.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Nitrogen oxides, Sulfur oxides.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: QJ6160000
ACUTE TOXICITY
LD50
Oral
Rat
7600 mg/kg
Remarks: Behavioral:Convulsions or effect on seizure threshold.
Behavioral:Ataxia. Gastrointestinal:Hypermotility, diarrhea.
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IRRITATION DATA
Eyes
Rabbit
100 mg
Remarks: Moderate irritation effect
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: Material may be irritating to mucous membranes and
upper respiratory tract. May be harmful if inhaled.
Ingestion: May be harmful if swallowed.
TARGET ORGAN INFORMATION
Liver.
CONDITIONS AGGRAVATED BY EXPOSURE
The toxicological properties have not been thoroughly
investigated.
CHRONIC EXPOSURE - CARCINOGEN
Result: Carcinogen.
Rat
Route of Application: Oral
Exposure Time: 13W
Result: Tumorigenic:Carcinogenic by RTECS criteria. Liver:Tumors.
Mouse
Route of Application: Oral
Exposure Time: 60W
Result: Tumorigenic:Equivocal tumorigenic agent by RTECS
criteria. Kidney, Ureter, Bladder:Tumors.
Mouse
Route of Application: Implant
Result: Tumorigenic:Equivocal tumorigenic agent by RTECS
criteria. Kidney, Ureter, Bladder:Tumors.
Rat
Route of Application: Oral
Exposure Time: 13W
Result: Tumorigenic:Carcinogenic by RTECS criteria. Liver:Tumors.
CHRONIC EXPOSURE - MUTAGEN
Rat
500 MG/KG
Oral
36H
Micronucleus test
Rat
500 MG/KG
Oral
12H
Unscheduled DNA synthesis
Rat
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300 MG/KG
Cell Type: S. typhimurium
Body fluid assay
Mouse
2 GM/KG
Oral
DNA damage
CHRONIC EXPOSURE - TERATOGEN
Result: Possible risk of congenital malformation in the fetus.
CHRONIC EXPOSURE - REPRODUCTIVE HAZARD
Species: Mouse
Dose: 5 GM/KG
Route of Application: Oral
Exposure Time: (8-12D PREG)
Result: Effects on Newborn: Other postnatal measures or effects.
12 - Ecological Information
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
Non-hazardous for road transport.
IMDG
Non-hazardous for sea transport.
IATA
Non-hazardous for air transport.
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
ANNEX I INDEX NUMBER: 611-025-00-7
INDICATION OF DANGER: T
Toxic.
R-PHRASES: 45 63
May cause cancer. Possible risk of harm to the unborn child.
S-PHRASES: 53 45
Restricted to professional users. Attention - Avoid exposure -
obtain special instructions before use. In case of accident or
if you feel unwell, seek medical advice immediately (show the
label where possible).
SWITZERLAND
SWISS POISON CLASS: 1*
16 - Other Information
WARRANTY
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The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2004 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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