SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 16/OCT/2005
Date Updated: 03/AUG/2005
Version 1.3
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name COPPER(II) NITRATE HEMIPENTAHYDRATE,
99.99+%
Product Number 467855
Company Sigma-Aldrich Pty. Ltd.
12 Anella Avenue
Castle Hill NSW 2154
Australia
Technical Phone # +61 2 9841 0555 (1800 800 097)
Fax +61 2 9841 0500 (1800 800 096)
Emergency Phone # +44 8701906777 (1800 448 465)
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
COPPER(II) NITRATE HYDRATE 19004-19-4 221-838-5 None
Formula Cu(NO3)2.xH2O
Molecular Weight 187.56 AMU
Synonyms Claycop * Copper dinitrate * Copper(II) nitrate
* Copper(2+) nitrate * Cupric dinitrate * Cupric
nitrate * Nitric acid, copper(2+) salt, hydrate
(2:5)
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Contact with combustible material may cause fire. Harmful if
swallowed. Causes burns.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
CONDITIONS OF FLAMMABILITY
May accelerate combustion.
EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
Contact with other material may cause fire. May accelerate
combustion.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Keep away from
combustible materials, heat, sparks, and open flame.
SPECIAL REQUIREMENTS: Heat- and moisture-sensitive.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Remove and wash contaminated
clothing promptly. Discard contaminated shoes.
EXPOSURE LIMITS - UNITED KINGDOM
Source Type Value
OEL LTEL 1 MG(CU)/M3
PERSONAL PROTECTIVE EQUIPMENT
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Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Solid
Property Value At Temperature or Pressure
pH N/A
BP/BP Range N/A
MP/MP Range 114 掳C
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density 2.32 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Conditions to Avoid: Moisture. Heat.
Materials to Avoid: Reducing agents, Organic materials, Finely
powdered metals.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Nitrogen oxides, Copper oxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: QU7400000
ACUTE TOXICITY
LD50
Oral
Rat
794 mg/kg
Remarks: Behavioral:Convulsions or effect on seizure threshold.
Behavioral:Somnolence (general depressed activity).
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LD50
Intraperitoneal
Rat
20 MG/KG
Remarks: Behavioral:Somnolence (general depressed activity).
Behavioral:Convulsions or effect on seizure threshold.
LD50
Intravenous
Rat
14700 UG/KG
Remarks: Behavioral:Somnolence (general depressed activity).
Behavioral:Convulsions or effect on seizure threshold.
LD50
Oral
Mouse
430 mg/kg
Remarks: Behavioral:Somnolence (general depressed activity).
Behavioral:Convulsions or effect on seizure threshold.
LD50
Intraperitoneal
Mouse
17100 UG/KG
Remarks: Behavioral:Somnolence (general depressed activity).
Behavioral:Convulsions or effect on seizure threshold.
LD50
Intravenous
Mouse
23300 UG/KG
Remarks: Behavioral:Somnolence (general depressed activity).
Behavioral:Convulsions or effect on seizure threshold.
IRRITATION DATA
Skin
Rabbit
500 mg
Remarks: Severe irritation effect
Eyes
Rabbit
100 mg
Remarks: Severe irritation effect
Eyes
Rabbit
100 mg
4S
Remarks: Rinsed
SIGNS AND SYMPTOMS OF EXPOSURE
Chronic copper poisoning is typified by hepatic cirrhosis, brain
damage and demyelination, kidney defects, and copper deposition
in the cornea as exemplified by humans with Wilson's disease. It
has also been reported that copper poisoning has lead to
hemolytic anemia and accelerates arteriosclerosis. Material is
extremely destructive to tissue of the mucous membranes and
upper respiratory tract, eyes, and skin. Inhalation may result
in spasm, inflammation and edema of the larynxand bronchi,
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chemical pneumonitis, and pulmonary edema. Symptoms of exposure
may include burning sensation, coughing, wheezing, laryngitis,
shortness of breath, headache, nausea, and vomiting. To the best
of our knowledge, the chemical, physical, and toxicological
properties have not been thoroughly investigated.
ROUTE OF EXPOSURE
Skin Contact: Causes burns.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes burns.
Inhalation: Material is extremely destructive to the tissue of
the mucous membranes and upper respiratory tract. May be harmful
if inhaled.
Ingestion: Harmful if swallowed.
TARGET ORGAN INFORMATION
Vascular system. Central nervous system. Liver. Kidneys. Blood.
12 - Ecological Information
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
UN#: 3085
Class: 5.1
PG: II
Kemmler Number: 58
Proper Shipping Name: Oxidizing solid, corrosive,
n.o.s.
IMDG
UN#: 3085
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: OXIDIZING SOLID, CORROSIVE,
N.0.S.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 3085
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: Oxidizing solid, corrosive,
n.o.s.
Inhalation Packing Group I: No
Technical Name: Required
15 - Regulatory Information
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CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: O-C
Oxidizing. Corrosive.
R-PHRASES: 8-22-34
Contact with combustible material may cause fire. Harmful if
swallowed. Causes burns.
S-PHRASES: 17-26-36/37/39-45
Keep away from combustible material. In case of contact with
eyes, rinse immediately with plenty of water and seek medical
advice. Wear suitable protective clothing, gloves, and eye/face
protection. In case of accident or if you feel unwell, seek
medical advice immediately (show the label where possible).
COUNTRY SPECIFIC INFORMATION
Germany
WGK: 2
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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