SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 07/SEP/2005
Date Updated: 15/MAR/2004
Version 1.1
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name CELLULOSE NITRATE, 12 WT. % N,
VISCOSITY 18-25 CPS (WITH 30% IPA) (NO
BULK SALES ALLOWED)
Product Number 435023
Company Sigma-Aldrich Pty. Ltd.
12 Anella Avenue
Castle Hill NSW 2154
Australia
Technical Phone # +61 2 9841 0555 (1800 800 097)
Fax +61 2 9841 0500 (1800 800 096)
Emergency Phone # +44 8701906777 (1800 448 465)
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
CELLULOSE NITRATE 9004-70-0 None None
Ingredient Name Percent CAS # EC no Annex I
Index Number
2-PROPANOL 30 67-63-0 200-661-7 603-117-00-0
Symbols: F-Xi
R-Phrases: 11-36-67
Highly flammable. Irritating to eyes. Vapors may cause drowsiness
and dizziness.
CELLULOSE NITRATE 70 None None None
Formula C24H36N8O38
Synonyms C 2018 * CA 80-15 * Celex * Celloidin *
Cellulose nitrate * Cellulose, nitrate (9CI) *
Cellulose tetranitrate * Collodion * Collodion
cotton * Collodion wool * Colloxylin * Corial EM
finish F * E 1440 * Flexible collodion * FM-Nts
* Guncotton * HX 3/5 * Kodak LR 115 * LR 115 *
Nitrocellulose E950 * Nitrocotton * Nitron *
Nitron (nitrocellulose) * Nixon N/C * NTs 62 *
NTs 218 * NTs 222 * NTs 539 * NTs 542 *
Parlodion * Pyralin * Pyroxylin * RF 10 * RS *
R.S.Nitrocellulose * Soluble gun cotton * Synpor
* Tsapolak 964 * Xyloidin
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Highly flammable. Irritating to eyes and skin.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
EXPLOSION DATA
Dust Potential: This material, like most materials in powder
form, is capable of creating a dust explosion.
EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
Unsuitable: Do not use water.
SPECIAL RISKS
Specific Hazard(s): Flammable liquid. Emits toxic fumes under
fire conditions. Dry material is an explosive.
Explosion Hazards: Vapor may travel considerable distance to
source of ignition and flash back. Container explosion may occur
under fire conditions. Dry material is an explosive.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
SPECIFIC METHOD(S) OF FIRE FIGHTING
Use water spray to cool fire-exposed containers.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition. Use nonsparking
tools.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Immediately soak spilled material with water and remove to
covered metal containers. Add water to containers. Do not allow
material to become dry.
7 - Handling and Storage
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HANDLING
Directions for Safe Handling: Do not get in eyes, on skin, on
clothing. Do not breathe vapor.
Protection against Fire and Explosion: Dry material is an
explosive.
STORAGE
Conditions of Storage: Keep container closed. Keep away from
heat, sparks, and open flame.
SPECIAL REQUIREMENTS: Do not allow material to become dry.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath. Use nonsparking tools. Mechanical
exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Rubber gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Liquid
Color: Very faintly yellow
Form: Clear liquid
Property Value At Temperature or Pressure
pH N/A
BP/BP Range 83 掳C 760 mmHg
MP/MP Range N/A
Flash Point 12 掳C Method: closed cup
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density 1.23 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
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STABILITY
Stable: Stable.
Materials to Avoid: Aluminum, Halogens, Acid anhydrides, Bases,
Acids, Oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Hydrogen cyanide, Carboxylic
acids, Aldehydes Carbon monoxide, Carbon dioxide, Nitrogen oxides
Methane.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: QW0970000
ACUTE TOXICITY
LD50
Oral
Rat
> 5000 mg/kg
LD50
Oral
Mouse
> 5000 mg/kg
SIGNS AND SYMPTOMS OF EXPOSURE
Prolonged exposure can cause: Nausea, headache, and vomiting. To
the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Narcotic effect.
ROUTE OF EXPOSURE
Skin Contact: Causes skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes eye irritation.
Inhalation: May be harmful if inhaled. Material may be
irritating to mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.
TARGET ORGAN INFORMATION
Kidneys. Liver. Cardiovascular system. G.I. System. Nerves.
CHRONIC EXPOSURE - CARCINOGEN
Result: This product is or contains a component that is not
classifiable as to its carcinogenicity based on its IARC, ACGIH,
NTP, or EPA classification.
12 - Ecological Information
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Observe all federal, state, and local
environmental regulations.
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14 - Transport Information
RID/ADR
UN#: 2556
Class: 4.1
PG: II
Proper Shipping Name: Nitrocellulose with alcohol
IMDG
UN#: 2556
Class: 4.1
PG: II
Proper Shipping Name: CELLULOSE NITRATE WITH ALCOHOL
Marine Pollutant: No
Severe Marine Pollutant: No
IATA
UN#: 2556
Class: 4.1
PG: II
Proper Shipping Name: Nitrocellulose with alcohol
Inhalation Packing Group I: No
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: F-Xi
Highly Flammable. Irritant.
R-PHRASES: 11-36/38
Highly flammable. Irritating to eyes and skin.
S-PHRASES: 16-26-36-48-
Keep away from sources of ignition - no smoking. In case of
contact with eyes, rinse immediately with plenty of water and
seek medical advice. Wear suitable protective clothing. Keep
wet with: 2-Propanol
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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