Material Safety Data Sheet
Material Name: Sirius Clear ID: MSDS0001
* * * Section 1 - Chemical Product and Company Identification * * *
Manufacturer's Part Number: 01881, 01883, 01882
Chemical Name: Solvent Ink
Product Use: Inkjet Printing
Manufacturer Information
FujiFilm Dimatix Inc. Phone: 603-443-5300
109 Etna Road
Lebanon, NH 03766 Emergency # 603-443-5300
* * * Section 2 - Hazards Identification * * *
Emergency Overview
Combustible liquid. Can cause moderate irritation to the respiratory tract and eyes. Can cause slight irritation to
the skin mouth, throat and stomach. This product is harmful if swallowed. May cause dizziness, incoordination,
headache, nausea, and vomiting.
Potential Health Effects: Eyes
Symptoms can include irritation, redness, and tearing.
Potential Health Effects: Skin
This product may cause defatting and dermatitis. This product may be harmful if it is absorbed through the skin.
Potential Health Effects: Ingestion
Ingestion can cause abdominal discomfort, nausea, vomiting and diarrhea.
Potential Health Effects: Inhalation
Prolonged or repeated exposure may cause dizziness, weakness, fatigue, nausea, and headache.
HMIS Ratings: Health: 2 Fire: 2 Physical Hazard: 0 Pers. Prot.: Safety goggles, impervious gloves
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
* * * Section 3 - Composition / Information on Ingredients * * *
CAS # Component Percent
111-77-3 Diethylene glycol monomethyl ether 30-60
57-55-6 1,2-Propylene glycol 30-60
Component Related Regulatory Information
This product may be regulated, have exposure limits or other information identified as the following: Glycol ethers.
Component Information/Information on Non-Hazardous Components
This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention or advice.
First Aid: Skin
For skin contact, flush with large amounts of water. If irritation persists, get medical attention.
First Aid: Ingestion
If the material is swallowed, get immediate medical attention or advice -- Do not induce vomiting.
First Aid: Inhalation
If inhaled, immediately remove the affected person to fresh air. If the affected person is not breathing, apply
artificial respiration. If breathing is difficult, give oxygen.
____________________________________________________________
Revision: 1.0000
Sirius Clear MSDS0001
Print Date: 1/6 Issue Date: 06/29/07
Material Safety Data Sheet
Material Name: Sirius Clear ID: MSDS0001
* * * Section 5 - Fire Fighting Measures * * *
General Fire Hazards
See Section 9 for Flammability Properties.
Combustible liquid. Irritating fumes and gases may be released upon thermal processing or during combustion.
May form explosive mixture with air at temperatures at or above the flashpoint. Empty containers may retain
product residue including Flammable or Explosive vapors. Do not cut, drill, grind, or weld near full, partially full, or
empty product containers.
Hazardous Combustion Products
Carbon monoxide and carbon dioxide.
Extinguishing Media
Dry chemical, carbon dioxide. alcohol-resistant foam, or water spray. Water and foam may cause frothing if liquid
is burning. Do not direct a solid stream of water or foam into hot, burning pools; this may result in frothing and
increase fire intensity.
Fire Fighting Equipment/Instructions
Firefighters should wear full-face, self contained breathing apparatus and impervious protective clothing.
Firefighters should avoid inhaling any combustion products.
NFPA Ratings: Health: 2 Fire: 2 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
* * * Section 6 - Accidental Release Measures * * *
Containment Procedures
Eliminate all sources of ignition or flammables that may come into contact with a spill of this material. Stop the
flow of material, if this is without risk. Contain the discharged material. Block any potential routes to water
systems.
Clean-Up Procedures
Wear appropriate protective equipment and clothing during clean-up. Evacuate the area promptly. Ventilate the
contaminated area. Do not allow the spilled product to enter public drainage system or open water courses. Use
non-sparking tools when opening or closing containers. Eliminate ignition sources including sources of electrical,
static or frictional sparks. Put material in suitable, covered, labeled containers. Dispose of waste material
according to Local, State, Federal, and Provincial Environmental Regulations.
Evacuation Procedures
Persons not wearing appropriate protective equipment should be excluded from area of spill until clean-up has
been completed.
Special Procedures
Avoid inhalation of vapors or mists. Avoid skin contact with the spilled material. Wear appropriate personal
protective equipment.
* * * Section 7 - Handling and Storage * * *
Handling Procedures
Avoid getting this material into contact with your skin and eyes. Do not breathe fumes from this material. Wash
thoroughly after handling. Use this product with adequate ventilation. Keep this product from heat, sparks, or open
flame. Empty containers retain product residue (liquid and/or vapor) and can be dangerous.
Storage Procedures
Keep this material in a cool, well-ventilated place. Keep the container tightly closed. Eliminate all sources of
ignition. Do not store around flammable or combustible materials.
____________________________________________________________
Revision: 1.0000
Sirius Clear MSDS0001
Print Date: 2/6 Issue Date: 06/29/07
Material Safety Data Sheet
Material Name: Sirius Clear ID: MSDS0001
* * * Section 8 - Exposure Controls / Personal Protection * * *
A: Componenet Exposure Limits
1,2-Propylene glycol (57-55-6)
50 ppm TWAEV (total aerosol and vapor); 155 mg/m3 TWAEV (total aerosol and vapor); 10 mg/m3 TWAEV
(aerosol only, for assessing the visibility in a work environment)
Engineering Controls
Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear safety glasses; chemical goggles (if splashing is possible).
Personal Protective Equipment: Skin
Use impervious gloves. Work clothing sufficient to prevent all skin contact should be worn, such as coveralls and
long sleeves.
Personal Protective Equipment: Respiratory
When respiratory protection is required, wear a NIOSH approved self-contained breathing apparatus with full
facepiece operated in a positive-pressure mode.
Personal Protective Equipment: General
Eye wash fountain and emergency showers are recommended. Use good industrial hygiene practices in handling
this material.
* * * Section 9 - Physical & Chemical Properties * * *
Appearance: Odor:
Clear Not available
Physical State: pH:
Liquid, semi-solid, or solid Not available
Vapor Pressure: Vapor Density:
Not available Not available
Boiling Point: Melting Point:
188C (370F) Not available
Solubility (H2O): Specific Gravity:
100% 1.04
VOC:
Evaporation Rate: 8.66
Not available
Bulk Density: Octanol/H2O Coeff.:
8.66 Not available
Flash Point: Flash Point Method:
61C (142F) - < 93C (200F) Not available
Upper Flammability Limit (UFL): Lower Flammability Limit (LFL):
12.6 1.4
Auto Ignition:
Burning Rate: 215C (419F)
Not available
* * * Section 10 - Chemical Stability & Reactivity Information * * *
Chemical Stability
Stable under normal conditions.
Chemical Stability: Conditions to Avoid
Avoid temperatures above the flashpoint and ignition sources.
Incompatibility
This product may react with strong acids or oxidizing agents.
Hazardous Decomposition
Carbon monoxide and carbon dioxide.
Possibility of Hazardous Reactions
Will not occur.
____________________________________________________________
Revision: 1.0000
Sirius Clear MSDS0001
Print Date: 3/6 Issue Date: 06/29/07
Material Safety Data Sheet
Material Name: Sirius Clear ID: MSDS0001
* * * Section 11 - Toxicological Information * * *
Acute Dose Effects
A: General Product Information
No information available for the product. Excessive inhalation of this material may cause central nervous system
depression. Symptoms include headache, dizziness, nausea and incoordination. This product may cause tearing
and redness to the eyes but not likely to cause permanent injury to eye tissue. Prolonged and/or repeated skin
contact with this product may cause irritation/dermatitis and defatting. Upon prolonged and repeated exposure,
this product may be harmful if absorbed through the skin.
B: Component Analysis - LD50/LC50
Diethylene glycol monomethyl ether (111-77-3)
Oral LD50 Rat: 4 mL/kg; Dermal LD50 Rabbit: 2500 礚/kg
1,2-Propylene glycol (57-55-6)
Oral LD50 Rat: 20000 mg/kg; Dermal LD50 Rabbit:20800 mg/kg
Carcinogenicity
A: General Product Information
No information available for the product.
B: Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP.
Teratogenicity
A component in this product has been fetotoxic, caused developmental abnormalities and maternal effects in
laboratory mice and rats.
* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
No data available for this product. Do not allow product to enter sewer or waterways.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Diethylene glycol monomethyl ether (111-77-3)
Test & Species Conditions
96 Hr LC50 Oncorhynchus mykiss 1000 mg/L
96 Hr LC50 Lepomis macrochirus 7500 mg/L Static
96 Hr LC50 Pimephales promelas 5741 mg/L
72 Hr EC50 Scenedesmus subspicatus >500 mg/L
17 Hr EC50 Pseudomonas putida >10000 mg/L
24 Hr EC50 water flea >500 mg/L
48 Hr EC50 Daphnia magna 1192 mg/L
1,2-Propylene glycol (57-55-6)
Test & Species Conditions
96 Hr LC50 Oncorhynchus mykiss 51600 mg/L Static
96 Hr LC50 Pimephales promelas 51400 mg/L Static
96 Hr EC50 Selenastrum capricornutum 19000 mg/L
30 min EC50 Photobacterium phosphoreum 710 mg/L
48 Hr EC50 water flea >10000 mg/L
____________________________________________________________
Revision: 1.0000
Sirius Clear MSDS0001
Print Date: 4/6 Issue Date: 06/29/07
Material Safety Data Sheet
Material Name: Sirius Clear ID: MSDS0001
* * * Section 13 - Disposal Considerations * * *
US EPA Waste Number & Descriptions
A: General Product Information
Wastes must be tested using methods described in 40 CFR Part 261 to determine if it meets applicable definitions
of hazardous wastes.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Recycling of this product is encouraged.
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.
* * * Section 14 - Transportation Information * * *
US DOT Information
Shipping Name: Combustible liquid, n.o.s. (Diethylene glycol monomethyl ether)
UN/NA #: NA1993 Hazard Class: Combustible liquid Packing Group: III
Required Label(s): Combustible liquid
TDG Information
Shipping Name: Not regulated as a dangerous good for transportation.
* * * Section 15 - Regulatory Information * * *
US Federal Regulations
A: General Product Information
No additional information available.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Diethylene glycol monomethyl ether (111-77-3)
SARA 313: 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3, R=alkyl C7 or less,
or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or less, or OR' consisting of carboxylic acid
ester, sulfate, phosphate, nitrate, or sulfonate, Chemical Category N230) (related to Glycol ethers)
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS CA MA MN NJ PA RI
Diethylene glycol monomethyl ether (箁elated to Glycol 111-77-3 No Yes No Yes Yes No
ethers) ?br>
1,2-Propylene glycol 57-55-6 No No Yes No Yes Yes
____________________________________________________________
Revision: 1.0000
Sirius Clear MSDS0001
Print Date: 5/6 Issue Date: 06/29/07
Material Safety Data Sheet
Material Name: Sirius Clear ID: MSDS0001
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
CAS # Minimum Concentration
Component
Diethylene glycol monomethyl ether 111-77-3 1%
1,2-Propylene glycol 57-55-6 1%
Additional Regulatory Information
A: General Product Information
All components are on the U.S. EPA TSCA Inventory List.
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulations and the MSDS contains information required by the Controlled Products Regulations.
B: Component Analysis - Inventory
Component CAS # TSCA CAN EEC
Diethylene glycol monomethyl ether 111-77-3 Yes DSL EINECS
1,2-Propylene glycol 57-55-6 Yes DSL EINECS
* * * Section 16 - Other Information * * *
Other Information
The information herein is presented in good faith and believed to be accurate as of the effective date given.
However, no warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities
comply with Federal, State or local laws.
Key/Legend
ACGIH = American Conference of Governmental Industrial Hygienists; CAS = Chemical Abstracts Service;
CERCLA = Comprehensive Environmental Response, Compensation, and Liability Act; CFR = Code of Federal
Regulations; CPR = Controlled Products Regulations; DOT = Department of Transportation; DSL = Domestic
Substances List; EINECS = European Inventory of Existing Commercial Chemical Substances; EPA =
Environmental Protection Agency; IARC = International Agency for Research on Cancer; IATA = International Air
Transport Association; mg/Kg = milligrams per Kilogram; mg/L = milligrams per Liter; mg/m3 = milligrams per
Cubic Meter; MSHA = Mine Safety and Health Administration; NA = Not Applicable or Not Available; NIOSH =
National Institute for Occupational Safety and Health; NJTSR = New Jersey Trade Secret Registry; NTP =
National Toxicology Program; OSHA = Occupational Safety and Health Administration; SARA = Superfund
Amendments and Reauthorization Act; TDG = Transport Dangerous Goods; TSCA = Toxic Substances Control
Act; WHMIS = Workplace Hazardous Materials Information System.
____________________________________________________________
Revision: 1.0000
Sirius Clear MSDS0001
Print Date: 6/6 Issue Date: 06/29/07
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