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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 09/23/2005 Reviewed on 09/23/2005
* 1 Identification of substance
?Product details
?Trade name: Epifanes Clear Gloss Varnish
?Application of the substance / the preparation
classic high gloss marine varnish
?Manufacturer/Supplier:
W.HEEREN & ZOON BV
Postbus 166
1430 AD Aalsmeer
?Information department: Environment protection department.
?Emergency information: See under Manufacturer/Supplier
* 2 Composition/Data on components
?Chemical characterization
?Description:
Solvent mixture with additives
Resin mixture
?Dangerous components:
64742-48-9 Naphtha (petroleum), hydrotreated heavy Xn; R 10-65-66 25-50%
?Additional information:
For the wording of the listed risk phrases refer to section 16.
* 3 Hazards identification
?Hazard description: Not applicable.
?Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid
version.
At long or repeated contact with skin it may cause dermatitis due to the
degreasing effect of the solvent.
R 10 Flammable.
R 66 Repeated exposure may cause skin dryness or cracking.
?Classification system:
The classification was made according to the latest editions of international
substances lists, and expanded upon from company and literature data.
?NFPA ratings (scale 0 - 4)
Health = 2
Fire = 2
Reactivity = 0
?HMIS-ratings (scale 0 - 4)
Health =2
Fire =2
Reactivity = 0
* 4 First aid measures
?After inhalation: Supply fresh air; consult doctor in case of complaints.
?After skin contact: Generally the product does not irritate the skin.
?After eye contact: Rinse opened eye for several minutes under running water.
(Contd. on page 2)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 09/23/2005 Reviewed on 09/23/2005
Trade name: Epifanes Clear Gloss Varnish
(Contd. of page 1)
?After swallowing: If symptoms persist consult doctor.
* 5 Fire fighting measures
?Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray
or alcohol resistant foam.
?For safety reasons unsuitable extinguishing agents: Water with full jet
?Special hazards caused by the material, its products of combustion or resulting
gases:
Formation of toxic gases is possible during heating or in case of fire.
Carbon monoxide (CO)
?Protective equipment: No special measures required.
* 6 Accidental release measures
?Person-related safety precautions:
Keep away from ignition sources
Ensure adequate ventilation
Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection:
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Ensure adequate ventilation.
?Additional information: See Section 7 for information on safe handling.
* 7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep receptacle tightly sealed.
* 8 Exposure controls and personal protection
?Additional information about design of technical systems:
No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical
values that have to be monitored at the workplace.
?Additional information:
The lists that were valid during the creation were used as basis.
(Contd. on page 3)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 09/23/2005 Reviewed on 09/23/2005
Trade name: Epifanes Clear Gloss Varnish
(Contd. of page 2)
?Personal protective equipment:
?General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
?Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In
case of intensive or longer exposure use respiratory protective device that is
independent of circulating air.
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the
substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for
the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times,
rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but
also on further marks of quality and varies from manufacturer to manufacturer.
As the product is a preparation of several substances, the resistance of the
glove material can not be calculated in advance and has therefore to be checked
prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
?Eye protection: Tightly sealed goggles
?Body protection: Light weight protective clothing
* 9 Physical and chemical properties
?General Information
Form: Fluid
Color: According to product specification
Odor: Characteristic
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 150癈 (302癋)
?Flash point: 38癈 (100癋) (DIN 51755)
?Ignition temperature: 240.0癈 (464癋)
?Auto igniting: Product is not selfigniting.
?Danger of explosion: Product is not explosive. However, formation
of explosive air/vapor mixtures are possible.
?Explosion limits:
Lower: 0.6 Vol %
Upper: 7.0 Vol %
?Vapor pressure at 20癈 (68癋): 1.0 hPa (1 mm Hg)
?Density at 20癈 (68癋): 0.91 g/cm?br>
?Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
(Contd. on page 4)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 09/23/2005 Reviewed on 09/23/2005
Trade name: Epifanes Clear Gloss Varnish
(Contd. of page 3)
?Viscosity:
Kinematic at 20癈 (68癋): 50 s (ISO 6 mm)
?Solvent content:
Organic solvents: 38.0 %
VOC content: 38.0 %
VOC content:
378.3 g/l / 3.16 lb/gl
?Solids content: 62.0 % (SC% 1h 150C)
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous products of decomposition: No dangerous decomposition products known.
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Oral LD50 >5000 mg/kg (rat)
Dermal LD50 >3000 mg/kg (rab)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: No irritating effect.
?Sensitization: No sensitizing effects known.
* 12 Ecological information
?General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water,
water course or sewage system.
* 13 Disposal considerations
?Product:
?Recommendation:
Must not be disposed of together with household garbage. Do not allow product
to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
* 14 Transport information
?DOT regulations:
?Hazard class: 3
(Contd. on page 5)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 09/23/2005 Reviewed on 09/23/2005
Trade name: Epifanes Clear Gloss Varnish
(Contd. of page 4)
?Identification number: UN1263
?Packing group: III
?Proper shipping name (technical name): PAINT
CONSUMER COMMODITY, ORM-D
?Label 3
?Remarks: CERCLA/DOT RQ: 617gal./4786 lbs.
?Land transport ADR/RID (cross-border):
?ADR/RID class: -
? Maritime transport IMDG:
? IMDG Class: -
? Marine pollutant: No
? Propper shipping name: CONSUMER COMMODITY, ORM-D
? Remarks: System Reference Code:5
? Air transport ICAO-TI and IATA-DGR:
? ICAO/IATA Class: 3
? UN/ID Number: 1263
? Label 3
? Packaging group: III
? Propper shipping name: PAINT
* 15 Regulations
?Sara
?Section 355 (extremely hazardous substances):
None of the ingredient is listed.
?Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
?TSCA (Toxic Substances Control Act):
64742-48-9 Naphtha (petroleum), hydrotreated heavy
80-46-6 p-(1,1-dimethylpropyl)phenol
68409-80-3 Isomeren van vetzure calciumzouten, C6-C19
Isomers from fatty acid salts
22464-99-9 Zirconiumoctoate, 12 % Zr
96-29-7 2-butanone oxime
57-55-6 propane-1,2-diol
108-83-8 2,6-dimethylheptan-4-one
136-52-7 cobalt bis(2-ethylhexanoate)
60-33-3 linoleic acid, pure
463-40-1 linolenic acid, crude
112-80-1 oleic acid, pure
131-56-6 2,4-dihydroxybenzophenone
112-34-5 2-(2-butoxyethoxy)ethanol
?Proposition 65
?Chemicals known to cause cancer:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
(Contd. on page 6)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 09/23/2005 Reviewed on 09/23/2005
Trade name: Epifanes Clear Gloss Varnish
(Contd. of page 5)
?Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
?Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
?Cancerogenity categories
?EPA (Environmental Protection Agency)
None of the ingredients is listed.
?IARC (International Agency for Research on Cancer)
136-52-7 cobalt bis(2-ethylhexanoate) 2B
?NTP (National Toxicology Program)
None of the ingredients is listed.
?TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
?MAK (German Maximum Workplace Concentration)
96-29-7 2-butanone oxime 2
112-80-1 oleic acid, pure 4
?NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
?OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
?Product related hazard informations:
Observe the general safety regulations when handling chemicals.
The product has been classified and marked in accordance with directives on
hazardous materials.
?Risk phrases:
10 Flammable.
66 Repeated exposure may cause skin dryness or cracking.
?Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe fumes/aerosol.
24 Avoid contact with skin.
46 If swallowed, seek medical advice immediately and show this container or
label.
51 Use only in well-ventilated areas.
?National regulations:
?Technical instructions (air):
Class Share in %
2,5
I
NK 25-50
?Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
* 16 Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 09/23/2005 Reviewed on 09/23/2005
Trade name: Epifanes Clear Gloss Varnish
(Contd. of page 6)
?Department issuing MSDS: Environment protection department.
?Contact: J.J. van Dijk
?* Data compared to the previous version altered.
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