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Material Safety Data Sheet MSDS# 15-01524
Section 1. Chemical Product and Company Identification
ARQUAD?APA 18 PG MS
Product name
: Surfactant.
Material Uses In Case of Emergency
AKZO NOBEL SURFACE CHEMISTRY LLC CHEMTREC: 800-424-9300
Supplier/
525 West Van Buren CANUTEC: 613-996-6666
Manufacturer
Chicago, IL 60607-3823 Medical/Handling: 914-693-6946
www.surfactants.akzonobel.com Product/Technical: 800-906-9977
AKZO NOBEL CHEMICALS LTD.
1 City Centre Drive, Suite 318
Mississauga, Ontario L5B 1M2
Canada
Section 2. Hazards Identification
Solid. (Solid paste.)
Physical State
Off-white.
Color
Bland.
Odor
WARNING!
Emergency Overview
CAUSES SEVERE EYE IRRITATION.
CAUSES SKIN IRRITATION.
TOXIC TO FISH. TOXIC TO AQUATIC ORGANISIMS. DO NOT RELEASE TO WATER.
Avoid contact with eyes, skin and clothing. Wash thoroughly after handling.
1-propanaminium, n,n,n-trimethyl-3-[(1-oxooctadecyl)amino]-, methylsulfate: IARC, NTP, OSHA,
Possible Carcinogenic
ACGIH: Not listed.
Effects
propylene glycol: OSHA None.; ACGIH IARC NTP Not listed.
octadecanamide, n-[3-(dimethylamino)propyl]-: IARC, NTP, OSHA, ACGIH: Not listed.
Absorbed through skin. Dermal contact. Eye contact.
Routes of Entry
See Toxicological Information (section 11)
Section 3. Composition/ Information on Ingredients
Name CAS # % by Weight
1-propanaminium, n,n,n-trimethyl-3-[(1-oxooctadecyl)amino]-, 19277-88-4 60-70
methylsulfate
propylene glycol 57-55-6 30-40
octadecanamide, n-[3-(dimethylamino)propyl]- 7651-02-7 0.1-2
Section 4. First Aid Measures
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
Eye Contact
water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
Skin Contact
contaminated clothing and shoes. Cold water may be used. W ash clothing before reuse.
Thoroughly clean shoes before reuse. Get medical attention immediately.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
Inhalation
oxygen. Get medical attention.
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Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
Ingestion
mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get
medical attention if symptoms appear.
Repeated or prolonged exposure is not known to aggravate medical condition.
Medical Conditions
Aggravated by
Overexposure
Section 5. Fire Fighting Measures
May be combustible at high temperature.
Flammability of the
Product
Closed cup: 99癈 (210.2癋). (Pensky-Martens.)
Flash Points
These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), sulfur oxides (SO2, SO3
Products of Combustion
...).
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
and Instructions
Be sure to use an approved/certified respirator or equivalent.
Protective Clothing (Fire)
Section 6. Accidental Release Measures
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning
Small Spill and Leak
by spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by
Large Spill and Leak
spreading water on the contaminated surface and allow to evacuate through the sanitary system.
Other Special
Considerations
Section 7. Handling and Storage
Avoid contact with eyes, skin and clothing. Wash thoroughly after handling.
Handling
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage
Section 8. Exposure Controls/ Personal Protection
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne
Engineering Controls
levels below recommended exposure limits. If user operations generate dust, fume or mist, use
ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection
Splash goggles.
Eyes
Lab coat.
Body
Respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
Respiratory
when ventilation is inadequate.
Gloves.
Hands
Not applicable.
Feet
Protective Clothing
(Pictograms)
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Splash goggles. Full suit. Respirator. Boots. Gloves. A self-contained breathing apparatus should be
Personal Protection in
used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a
Case of a Large Spill
specialist BEFORE handling this product.
Ingredient Name Exposure Limits United States
1-propanaminium, Not available.
n,n,n-trimethyl-3-[(1-oxooctadecyl)amino]-,
methylsulfate
propylene glycol AIHA WEEL (United States, 2005). Notes: 2004 Revised Document
TWA: 10 mg/m 3 8 hour(s). Form: All forms
octadecanamide, Not available.
n-[3-(dimethylamino)propyl]-
Section 9. Physical and Chemical Properties
Solid. (Solid paste.)
Physical State
Off-white.
Color
Bland.
Odor
Neutral.
pH
38 to 41癈 (100.4 to 105.8癋)
Melting/Freezing Point
Weighted average: 1.03 g/cm 3
Density
Soluble in cold water, methanol.
Solubility
See solubility in water, methanol.
Dispersion Properties
Viscosity = 0.581 P @ 25C. (propylene glycol)
Physical Chemical
Comments
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Reactive with OXIDIZING AGENTS, REDUCING AGENTS, acids, alkalis.
Incompatibility with
Various Substances
Will not occur.
Hazardous
Polymerization
Section 11. Toxicological Information
Toxicity to Animals
Ingredient Name or Product Test Result Route Species
name
1-propanaminium, LD50 >5000 mg/kg Oral Rat (based on similar
n,n,n-trimethyl-3-[(1-oxooctadecyl)am material data)
methylsulfate
propylene glycol LD50 18500 mg/kg Oral Rabbit
LD50 >2080 mg/kg Oral quail
LD50 18350 mg/kg Oral Guinea pig
LD50 20800 mg/kg Dermal Rabbit
LDLo 20000 mg/kg Oral Rabbit
octadecanamide, LD50 >2000 mg/kg Oral Rat based on data for:
n-[3-(dimethylamino)propyl]- (similar material)
octadecanamide, n-[3-(dimethylamino)propyl]-: NOEL = 500 ppm (two-year dietary) in rats based
Special Remarks on
on data for: (similar material).
Toxicity to Animals
NOEL = 3 mg/kg/day (two-year dietary) in dogs based on data for: (similar material).
CARCINOGENIC EFFECTS: Classified None. by OSHA, None. by NIOSH [propylene glycol].
Chronic Effects on
MUTAGENIC EFFECTS: Non-m utagenic for bacteria and/or yeast. [propylene glycol].
Humans
Non-mutagenic for bacteria and/or yeast. [octadecanamide, n-[3-(dimethylamino)propyl]-].
octadecanamide, n-[3-(dimethylamino)propyl]-: Mutagenic Effects based on data for: (similar
Special Remarks on
material)
Chronic Effects on
Humans
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Severely irritating to the skin. Practically non-toxic in contact with skin.
Acute Effects Skin
Severely irritating to the eyes.
Acute Effects Eyes
:
Special Remarks on
Eyes and Skin and Sensitization based on data for: (similar material)
Other Toxic Effects on
Humans
Section 12. Ecological Information
Ecotoxicity
Ingredient Name or Product name Species Period Result
propylene glycol Daphnia magna (EC50) 48 hour(s) >10000 mg/l
Pimephales promelas (LC50) 96 hour(s) 710 mg/l
Pimephales promelas (LC50) 96 hour(s) 55770 mg/l
Pimephales promelas (LC50) 96 hour(s) >62000 mg/l
octadecanamide, daphnia based on data for: 48 hour(s) 0.13 mg/l
n-[3-(dimethylamino)propyl]- (similar material) (EC50)
Algae. based on data for: 72 hour(s) 0.062 mg/l
(similar material) (EC50)
Biodegradability and 1-propanaminium, n,n,n-trimethyl-3-[(1-oxooctadecyl)amino]-, methylsulfate: 48% @ 28 day(s)
Ecotoxicity Remarks CBT based on data for: (similar material)
octadecanamide, n-[3-(dimethylamino)propyl]-: 55% @ 28 day(s) CBT based on data for:
(similar material); 72% @ 42 day(s) CBT based on data for: (similar material)
These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2...), sulfur oxides
Products of Degradation
(SO2, SO3...).
Section 13. Disposal Considerations
Waste must be disposed of in accordance with federal, state and local environmental control
Waste Information
regulations.
Consult your local or regional authorities.
Section 14. Transport Information
Regulatory UN Proper shipping name Class Packing Label Additional information
Information number Group
Not - - - -
DOT
Classification regulated.
-
Not - - - -
TDG
Classification regulated.
-
- -
Not - -
IMDG Class
regulated.
-
Not -
- - -
IATA-DGR
regulated.
Class
-
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Section 15. Regulatory Information
Irritating material
HCS Classification
TSCA: All intentionally present components are listed on the TSCA inventory.
U.S. Federal Regulations
DSL: All intentionally present components are listed on the DSL.
CERCLA: Hazardous substances.: No products were found.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: propylene glycol
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: propylene glycol:
Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard
SARA 313 Form R Reporting Requirements
No products were found.
SARA 313 Supplier Notification
No products were found.
Pennsylvania RTK: propylene glycol: (generic environmental hazard)
State Regulations
California prop. 65: No products were found.
Class D-2B: Material causing other toxic effects (TOXIC).
WHMIS (Canada)
CEPA DSL: 1-propanaminium, n,n,n-trimethyl-3-[(1-oxooctadecyl)amino]-, methylsulfate; propylene
glycol; octadecanamide, n-[3-(dimethylamino)propyl]-
Component EC Number EC Status EC Annex
1-propanaminium, 242-930-1 Not available. Not available.
European Union
n,n,n-trimethyl-3-[(1-oxooctadecyl)amin
methylsulfate
propylene glycol 200-338-0 Not available. Not available.
octadecanamide, 231-609-1 Not available. Not available.
n-[3-(dimethylamino)propyl]-
Australia (NICNAS): 1-propanaminium, n,n,n-trimethyl-3-[(1-oxooctadecyl)amino]-, methylsulfate;
Other International Lists
propylene glycol; octadecanamide, n-[3-(dimethylamino)propyl]-
China: 1-propanaminium, n,n,n-trimethyl-3-[(1-oxooctadecyl)amino]-, methylsulfate; propylene glycol;
octadecanamide, n-[3-(dimethylamino)propyl]-
Germany water class: propylene glycol
Japan (MITI): 1-propanaminium, n,n,n-trimethyl-3-[(1-oxooctadecyl)amino]-, methylsulfate; propylene
glycol; octadecanamide, n-[3-(dimethylamino)propyl]-
Japan (MOL): propylene glycol; octadecanamide, n-[3-(dimethylamino)propyl]-
Korea (TCCL): 1-propanaminium, n,n,n-trimethyl-3-[(1-oxooctadecyl)amino]-, methylsulfate; propylene
glycol; octadecanamide, n-[3-(dimethylamino)propyl]-
Philippines (RA6969): 1-propanaminium, n,n,n-trimethyl-3-[(1-oxooctadecyl)amino]-, methylsulfate;
propylene glycol; octadecanamide, n-[3-(dimethylamino)propyl]-
Section 16. Other Information
Hazardous Material 3 National Fire
Health
Fire Hazard
1
Protection
Information System 1
Fire Hazard
3 0
Health Reactivity
Association
(U.S.A.) 0
Reactivity
(U.S.A.) Specific Hazard
Personal Protection
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ARQUAD?APA 18 PG MS
Other Information Arquad?is a registered trademark of Akzo Nobel or affiliated companies and is registered in one or more
countries including the United States.
Validation Date 6/8/2006. Validated by Product Safety Specialist
No Previous Validation. 6/8/2007.
Previous Validation Date Print Date
Phone Number 312-544-7038
Notice to Reader
The information in the material safety data sheet should be provided to all who will use, handle, store, transport or otherwise be exposed
to this product. All information concerning this product and/or suggestions for handling and use contained herein are offered in good
faith and are believed to be reliable as of the date of publication. However, no warranty is made as to the accuracy of and/or sufficiency
of such information and/or suggestions or as to the product's merchantability or fitness for any particular purpose, or that any suggested
use will not infringe any patent. Nothing contained herein shall be construed as granting or extending any license under any patent.
Buyer must determine for himself, by preliminary tests or otherwise, the suitability of this product for his purposes, including mixing
with other products. The information contained herein supersedes all previously issued bulletins on the subject matter covered. If the
date on this document is more than three years old, call to make certain that this sheet is current.
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