Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MOCAP 10G 1/8
Version 3 / GB Revision Date: 09.05.2006
102000001975 Print Date: 14.07.2008
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product information
Trade name MOCAP 10G
Product code (UVP) 05927978
Usage insecticide
Company Bayer CropScience Limited
230 Cambridge Science Park
Milton Road
Cambridge
Cambridgeshire CB4 0WB
Great Britain
Telephone +44(0)1223 226500
Telefax +44(0)1223 426240
Emergency telephone number 0800-220876 (UK 24 hr)
+44(0)1603-242424 (Overseas 24 hr)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Granule (GR)
Ethoprophos 10% GR
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Ethoprophos 13194-48-4 T+, N R25, R26/27, 10.00
236-152-1 R43, R50/53
1,2-Propanediol 57-55-6 > 1.00 - < 5.00
200-338-0
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Harmful if swallowed.
Toxic in contact with skin.
May cause sensitization by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice
This product contains an anticholinesterase compound. Do not use if under medical advice not
to work with such compounds. In the case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MOCAP 10G 2/8
Version 3 / GB Revision Date: 09.05.2006
102000001975 Print Date: 14.07.2008
Skin contact
Wash off with soap and water. Take off contaminated clothing and shoes immediately. If
symptoms persist, call a physician.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical
attention if irritation develops and persists.
Ingestion
Induce vomiting only, if: 1. patient is fully conscious, 2. medical aid is not readily available, 3. a
significant amount (more than a mouthful) has been ingested and 4. time since ingestion is less
than 1 hour. (Vomit should not get into the respiratory tract). Call a physician or poison control
center immediately. Rinse mouth. Keep patient warm and at rest.
Notes to Physician
Symptoms
symptoms of cholinesterase inhibition (gastrointestinal disturbances, dyspnoea, narrowing of
the respiratory passages, bradycardia, miosis, clonic spasms).
Risks
This product is a cholinesterase inhibiting organophosphorous pesticide.
Dangerous amounts can be absorbed through the skin.
Treatment
Monitoring of respiratory, cardiac and central nervous system.
Endotracheal intubation should be done and gastric lavage performed, followed by
administration of charcoal.
Artificial respiration and/or oxygen may be necessary.
Elimination by dialysis (forced alkaline diuresis).
Observe specific parameters: red blood cell and plasma cholinesterase.
Against convulsions: give diazepam. For adults 5-10 mg intravenously as necessary until fully
sedated; for children 2.5 mg i.v.
Treatment: a high dose of atropine (1 to 4 mg for adults) repeated as needed.
In association, if possible, with Contrathion (Pralidoxime) (1g intravenously for adults) repeated
after 10 to 12 h.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
foam
dry powder
carbon dioxide (CO2)
Specific hazards during fire fighting
The product itself does not burn.
In the event of fire the following can be released:
carbon monoxide (CO)
nitrogen oxides (NOx)
phosphorus oxides (e.g. phosphorus pentoxide)
Sulphur oxides
carbon dioxide (CO2)
Special protective equipment for fire-fighters
Use breathing apparatus.
Further information
Contain the spread of the fire-fighting media.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MOCAP 10G 3/8
Version 3 / GB Revision Date: 09.05.2006
102000001975 Print Date: 14.07.2008
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Use personal protective equipment.
Environmental Precautions
Do not discharge into the drains/surface water/groundwater.
If spillage enters drains leading to sewage works inform local water company immediately.
If spillage enters rivers or watercourses, inform the Environment Agency (emergency telephone
number 0800 807060).
Methods for Cleaning Up
Sweep up or vacuum up spillage and collect in suitable container for disposal.
Pick up and fill the product into a tightly closed container.
When picked up, treat material as prescribed in Ch. 13. "Disposal considerations".
Additional Advice
Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see section 8.
Check also for any local site procedures.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Smoking, eating and drinking should be prohibited in the application area.
Do not breathe dust.
Storage
Requirements for storage areas and containers
Keep out of the reach of children.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Suitable materials
rigid material with protection against moisture
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Refer to COSHH assessment (Control of Substances Hazardous to Health (Amendment)
Regulations 2004). Engineering controls should be used in preference to personal
protective equipment wherever practicable. Refer also to COSHH Essentials.
Components with workplace control parameters
Components CAS-No. Control parameters Update Basis
1,2-Propanediol 57-55-6 10 mg/m3 2005 EH40 WEL
(Particulate.) (TWA)
1,2-Propanediol 57-55-6 474 mg/m3 / 150 ppm 2005 EH40 WEL
(Vapor and particulates.) (TWA)
Engineering measures
Provide appropriate exhaust ventilation at places where dust is formed.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MOCAP 10G 4/8
Version 3 / GB Revision Date: 09.05.2006
102000001975 Print Date: 14.07.2008
Personal protective equipment
Respiratory Protection Wear respirator conforming to EN149FFP2 or EN140P2.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.
Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination
outside cannot be removed. Wash hands always before eating,
drinking, smoking or using the toilet.
Eye protection Wear goggles conforming to EN166 (Field of Use 5 or equivalent).
Skin and body protection Wear standard coverall and type 3 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
Hygiene measures
Wash hands immediately after work, if necessary take a shower.
Protective measures
Cholinesterase activity of the worker should be supervised.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form pellets
Colour beige
Odour unpleasant
Safety data
pH 7.0 at 1 % (24 - 25 癈)
Flash Point not applicable
Bulk Density ca. 770 kg/m3
Explosivity Not explosive
10. STABILITY AND REACTIVITY
Conditions to Avoid Extremes of temperature and direct sunlight.
Materials to avoid strong oxidizing agents
bases
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MOCAP 10G 5/8
Version 3 / GB Revision Date: 09.05.2006
102000001975 Print Date: 14.07.2008
Hazardous Reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Stable under normal conditions.
11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50 (rat) 329 mg/kg
Acute Inhalation Toxicity LC50 (rat) 0.360 mg/l
Exposure time: 4 h
Tested in the form of respirable fine dust.
Acute Dermal Toxicity LD50 (rabbit) 133 mg/kg
Skin Irritation No skin irritation. (rabbit)
Eye Irritation Slight irritant effect - does not require labelling. (rabbit)
Sensitization sensitizing
The value mentioned relates to the active ingredient ethoprophos.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 1.71 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient.
Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 0.20 mg/l
Exposure time: 48 h
The value mentioned relates to the active ingredient.
Toxicity to algae IC50 (Scenedesmus subspicatus) 2.4 mg/l
Exposure time: 72 h
The value mentioned relates to the active ingredient.
13. DISPOSAL CONSIDERATIONS
Product
In accordance with current regulations may be taken to waste disposal site or incineration plant,
after consultation with site operator and/or with the responsible authority.
Advice may be obtained from the local waste regulation authority (part of the Environment
Agency in the UK).
Contaminated packaging
Empty remaining contents.
Do not use containers for other products.
Return large containers to supplier.
Follow advice on product label and/or leaflet.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MOCAP 10G 6/8
Version 3 / GB Revision Date: 09.05.2006
102000001975 Print Date: 14.07.2008
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
UN-No 2783
Labels 6.1
Packaging group II
Hazard no. 60
Description of the goods UN 2783 ORGANOPHOSPHORUS PESTICIDE, SOLID,
TOXIC
(ETHOPROPHOS MIXTURE)
IMDG
UN-No 2783
Class 6.1
Packaging group II
EmS F-A , S-A
Marine pollutant Marine pollutant
Description of the goods ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC
(ETHOPROPHOS MIXTURE )
IATA
UN-No 2783
Class 6.1
Packaging group II
Description of the goods ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC
(ETHOPROPHOS MIXTURE )
UK 'Carriage' Regulations
UN-No 2783
Labels 6.1
Packaging group II
Hazard no. 60
Emergency action code 2X
Description of the goods UN 2783 ORGANOPHOSPHORUS PESTICIDE, SOLID,
TOXIC
(ETHOPROPHOS MIXTURE)
15. REGULATORY INFORMATION
This product has been classified in accordance with The Chemicals (Hazard Information and
Packaging for Supply) Regulations 2002: CHIP 3 and any subsequent amendments.
Classification:
Hazard warning labelling compulsory
Hazardous components which must be listed on the label:
?Ethoprophos
Symbol(s)
T Toxic
N Dangerous for the environment
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MOCAP 10G 7/8
Version 3 / GB Revision Date: 09.05.2006
102000001975 Print Date: 14.07.2008
R-phrase(s)
R22 Harmful if swallowed.
R24 Toxic in contact with skin.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S35 This material and its container must be disposed of in a safe way.
S36/37 Wear suitable protective clothing and gloves.
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S57 Use appropriate container to avoid environmental contamination.
CLASSIFICATION ACCORDING TO SPECIFIC UK REGULATIONS:
The labelling information below is that which has been approved under 'The Control of Pesticides
Regulations 1986' and/or 'Part III of the Food and Environment Protection Act 1985' and/or 'Plant
Protection Product Regulations 1999' and any subsequent amendments and may differ from that
indicated by any toxicological and/or other testing otherwise indicated in this 'Safety Data Sheet'.
Symbol(s)
T Toxic
N Dangerous for the environment
R-phrase(s)
R22 Harmful if swallowed.
R23 Toxic by inhalation.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S24 Avoid contact with skin.
S35 This material and its container must be disposed of in a safe way.
S37 Wear suitable gloves.
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S57 Use appropriate container to avoid environmental contamination.
Exceptional labelling
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: II (Moderately hazardous)
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R25 Toxic if swallowed.
R26/27 Very toxic by inhalation and in contact with skin.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The above information is intended to give general health and safety guidance on the storage and
transport of the product.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MOCAP 10G 8/8
Version 3 / GB Revision Date: 09.05.2006
102000001975 Print Date: 14.07.2008
It is not intended to apply to the use of the product for which purposes the product label and any
appropriate technical usage literature available should be consulted and any relevant licenses,
consents or approvals complied with.
The requirements or recommendations of any relevant site or working procedure, system or policy in
force or arising from any risk assessment involving the substance or product should take precedence
over any of the guidance contained in this safety data sheet where there is a difference in the
information given.
The information provided in this safety data sheet is accurate at the date of publication and will be
updated as and when appropriate.
No liability will be accepted for any injury, loss or damage resulting from any failure to take account
of information or advice contained in this safety data sheet.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
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