MATERIAL SAFETY DATA SHEET
(Complies with OSHA CFR 1910.1200, ANSI Z 400.1-1993)
SECTION 1: Chemical Product & Company Identification
Product Name(s): Lilly Miller Systemic Rose, Shrub & Flower Care 8-12-4
EPA Number: 192-211-33116
Registrant Name & Address: Lilly Miller Brands, PO Box 2289, Clackamas, Oregon 97015
Telephone Contact Number & Hours of Operation: 866-866-0301, 8 ?5 pm Pacific time
SECTION 2: Composition/Information on Ingredients
% by OSHA ACGIH
Hazardous Ingredients*: weight CAS No. OSHA PEL Ceiling TLV
O,S-Dimethyl acetylphophoroamidothioate (Acephate) 1.5 30560-19-1
Propylene Glycol <4 57-55-6
3 mg/m3
Diatomaceous Earth <43 60676-86-0
Ammonium Phosphate <10 7722-76-1
Diammonium Phosphate <10 7783-28-0
Ammonium Sulfate <10 7783-20-2
Potassium Sulfate <16 7778-80-5
10 mg/m3 5 mg/m3
Iron Oxide <3 1309-37-1
Magnesium Oxide <3 1309-48-4
Magnesium Sulfate <1 7487-88-9
Sodium Borate <1 1303-96-4
5 mg/m3 0.2 mg/m3
Manganese Oxide <1 1317-35-7
3
0.2 mg/m3
Manganese Sulfate <1 7785-87-7 5 mg/m
10 mg/m3
Zinc Oxide <1 1314-13-2
Zinc Sulfate <1 7733-02-0
Gypsum <5 13397-24-5
10 mg/m3
Limestone <1 1317-65-3
0.05 mg/m3
Silica <0.1 14808-60-7 **
* all ingredients in quantities > 1.0 % (0.1 % for carcinogens or teratogens) that are potentially hazardous per OSHA definitions
** 10 mg/m3?%SiO2+2)
5 mg/m3 as respirable dust
SECTION 3: Hazards Identification
EMERGENCY OVERVIEW
Physical description: tan or gray granular solid
Odor: sulfur-like
Potential Health Effects: This material may be irritating to the eyes, to the respiratory tract and slightly irritating to the skin. May be
harmful if absorbed through skin. Harmful if ingested. Causes reversible cholinesterase inhibition. Repeated overexposure may cause more
severe cholinesterase inhibition with more pronounced signs and symptoms. Prolonged contact may cause nervous system damage.
Contains probable or suspected human carcinogens. May aggravate pre-existing kidney disorders. Chronic exposure to dust may lead to
silicosis. Personnel responding to a spill of this material MUST wear protective clothing to avoid skin contact or inhalation of particles
to prevent toxic effects.
SECTION 4: First Aid Measures
Skin Contact: Remove contaminated clothing. Wash affected area with soap and water. If irritation appears, get medical attention.
Ingestion: If swallowed, contact physician or poison control center immediately. Never give liquids to an unconscious person.
Eye Contact: Immediately flush eyes with water for at least 15 minutes. Seek medical attention if irritation persists.
Inhalation: Remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Get medical attention.
NOTES TO PHYSICIAN: If symptoms of cholinesterase inhibition are present, atropine sulfate by injection is antidotal. 2-PAM is
also antidotal and may be administered in conjunction with atropine. If ingested, monitor for acidosis and central nervous system changes.
Persons with previous kidney dysfunction may require special treatment.
SECTION 5: Fire Fighting Measures
Flash point: N/A
Explosive limits (%): N/A
Extinguishing media: Water, dry chemical or foam.
Unusual fire/explosion hazards: May explode if mixed with oxidizers. Ammonia gas may be released in a fire.
Protective Equipment: Use NIOSH/MSHA approved SCBA.
Thermal decomposition: Oxides of sulfur and nitrogen, phosphorus-containing compounds, ammonia, and other unknown hazardous
materials may be formed in a fire situation. Incomplete combustion may lead to formation of carbon monoxide and/or other asphyxiants.
SECTION 6: Accidental Release Measures
Spills: Sweep up material carefully to avoid excessive dust. Reuse material if possible. If original containers are not available and
material is not reusable, place in metal drum and seal. Dispose of in accordance with instructions in Section 13.
SECTION 7: Handling & Storage
Storage: Store in closed, upright containers in a cool, dry, well-ventilated area out of reach of children. Do not contaminate water, food
or feed by storage or disposal. Do not reuse container.
Handling: Avoid breathing vapor or dust. Avoid contact with skin or clothing. Remove pets before applying. Keep away from surface
waters.
SECTION 8: Exposure Controls & Personal Protective Equipment
Skin: Protective gloves required; applicators should wear long pants and long-sleeved shirt. Wash outside of gloves with soap and water
before removing. Wash hands before eating, drinking, chewing gum, using tobacco, applying cosmetics, or using the toilet. Remove
clothing immediately if pesticide gets inside of clothing. Wash thoroughly and put on clean clothing.
Eye Protection: Goggles or faceshield recommended
Respiratory: When applied in well ventilated area, respiratory protection should not be needed. Use air monitoring to determine required
level of protection. Use NIOSH approved respirator with organic vapor cartridges with N/R/P100 particulate filters, or mechanical
ventilation, if necessary.
SECTION 9: Physical & Chemical Parameters
Appearance: granular solid Solubility in water: N/A Odor: sulfur-like
Density at 20篶: N/A Boiling point: N/A Melting point: N/A
3
Specific gravity: 57-59 lbs/ft Vapor pressure: N/A pH: N/A
SECTION 10: Stability & Reactivity
Stability: Stable
Incompatibility: Avoid contamination with water, acids, alkalis, or oxidizers.
Conditions to avoid: excessive heat or moisture
Hazardous Decomposition Products: Ammonia, inorganic oxides, aldehydes or lactic, pyruvic or acetic acids may form
Hazardous polymerization: will not occur
SECTION 11: Toxicological Information
Note to Consumers: Information provided in this section is oriented to medical and public health professionals involved in the assessment
and treatment of excessive and/or accidental exposures.
Symptoms of overexposure may include: headache, blurred vision, nervousness, weakness, nausea, cramps, salivation, respiratory
difficulty, muscle twitches, convulsions, loss of reflexes. Prolonged contact may cause nervous system damage. May aggravate pre-existing
kidney disorders.
Oral Rat LD50 = >5,000 mg/kg Dermal Rat LD50 = >5,000 mg/kg Inhalation Rat LC50 = >2.02 mg/liter of air
Not a contact sensitizer, non-irritating to skin, minimally irritating to eyes.
Carcinogens: May contain crystalline silica, a suspected human carcinogen.
SECTION 12: Ecological Information
Ecotoxicity: Do not apply directly to water; do not contaminate water by drift, runoff, or cleaning of equipment or disposal of washwaters.
Environmental Fate: No data available.
SECTION 13: Disposal Considerations
This material (as packaged) is not considered a hazardous waste. Be aware that the waste owner has responsibility for final disposal.
Regulations may also apply to empty containers, liners or rinsate. Laws may change or be reinterpreted; state and local regulations may
be different from federal regulations. This information applies to materials as manufactured; contamination or processing may change
waste characteristics and requirements.
SECTION 14: Transport Information
DOT Hazard Description: N/A
SECTION 15: Regulatory Information
CERCLA RQ: None
SARA TPQ: None
Individual States: States such as Pennsylvania, New Jersey, California, Vermont, Massachusetts and Rhode Island may have
components of this product listed; consult specific state regulatory requirements for additional information.
SECTION 16: Other Information
For additional information, refer to the American Conference of Governmental Industrial Hygienists (ACGIH) documentation of TLV's
(Threshold Limit Values) for individual components and the DOT Emergency Response Guidebook.
This information is provided in good faith, but without express or implied warranty.
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