MSDS Number: SLP018
Southern Lithoplate Inc.
Material Safety Data Sheet
830-n Thermal SC Developer
Section 1 - Chemical Product and Company Identification
MSDS Name: 830-n Thermal SC Developer
Company Identification:
Southern Lithoplate Inc.
105 Jeffrey Way
Youngsville, N.Carolina. 27596
For information in North America, call: 919-556-9400
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
CAS# Chemical Name Percent EINECS/ELINCS
7732-18-5 Water 40-70 231-791-2
1312-76-1 Potassium silicate 10-30
57-55-6 Propylene glycol 6-10 200-338-0
6834-92-0 Sodium silicate 3-7
1310-58-3 Potassium hydroxide 1-5 215-181-3
50-70-4 Glucitol 1-5 200-061-5
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: colorless or pale yellow liquid.
Warning! Eye contact may result in permanent eye damage. Irritant. Causes eye
and skin irritation. May cause respiratory tract irritation. Corrosive to aluminum.
Target Organs: Eyes, skin.
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MSDS Number: SLP018
Potential Health Effects
Eye: Causes eye irritation and inflammation. May cause chemical conjunctivitis.
Skin: May cause skin irritation, drying, defatting.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: May cause respiratory tract irritation.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Prolonged or
repeated eye contact may cause conjunctivitis.
Section 4 - First Aid Measures
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical aid.
Skin: In case of contact, flush skin with plenty of water. Remove contaminated
clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing
before reuse.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
aid.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
During a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion.
Extinguishing Media: Use foam, dry chemical, or carbon dioxide.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower: Not available.
Upper: Not available.
NFPA/HMIS Rating: (estimated) Health: 3; Flammability: 0; Instability: 0 PPE: C
Hazard Rating:0 =Minimal; 1 =Slight; 2 =Moderate; 3 = Serious; 4 = Severe
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in
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MSDS Number: SLP018
Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then
place in suitable container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the Protective
Equipment section. Provide ventilation. Observe local, state and federal regulations
regarding disposal.
Section 7 - Handling and Storage
Handling: Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before
reuse.
Storage: Store in a cool, dry place. Store in a tightly closed container.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate ventilation to keep
airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Water none listed none listed none listed
Potassium hydroxide 2 mg/m3 Ceiling none listed none listed
Propylene glycol none listed none listed none listed
Potassium silicate none listed none listed none listed
Sodium Silicate none listed none listed none listed
Glucitol none listed none listed none listed
OSHA Vacated PELs: Water: No OSHA Vacated PELs are listed for these chemicals.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate impervious protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149
approved respirator if exposure limits are exceeded or if irritation or other symptoms
are experienced.
Section 9 - Physical and Chemical Properties
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MSDS Number: SLP018
Physical State: Liquid
Appearance: colorless or pale yellow
Odor: odorless or slight musty odor
pH: 12.5 ?13.5 @ 20癈
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: ~212F.
Freezing/Melting Point: ~32F
Decomposition Temperature: Not available.
Solubility: Soluble in water.
Specific Gravity/Density: 1.1
Volatile Organic Compounds (VOC) 0.67lb / gallon
Section 10 - Stability and Reactivity
Chemical Stability: Stable at room temperature in closed containers under normal
storage and handling conditions.
Conditions to Avoid: Incompatible materials, excess heat, prolonged exposure to
air.
Incompatibilities with Other Materials: Metals, acids.
Hazardous Decomposition Products: Toxic fumes of Carbon monoxide, carbon
dioxide and sodium oxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
RTECS#:
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;
.
CAS# 1310-58-3:
Draize test, rabbit, skin: 50 mg/24H Severe;
Oral, rat: LD50 = 273 mg/kg;
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MSDS Number: SLP018
CAS# 1312-76-1:
Oral, rat: LD50 = >1500 mg/kg;
CAS# 6834-92-0:
Oral, rat: LD50 = >1500 mg/kg;
CAS# 50-70-4:
Oral, mouse: LD50 = 17800 mg/kg;
Oral, rat: LD50 = 15900 mg/kg;
CAS# 57-55-6:
Draize test, rabbit, eye: 100 mg Mild;
Draize test, rabbit, eye: 500 mg/24H Mild;
Oral, mouse: LD50 = 22 gm/kg;
Oral, rabbit: LD50 = 18500 mg/kg;
Skin, rabbit: LD50 = 20800 mg/kg;
Carcinogenicity:
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 1310-58-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 1312-76-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 6834-92-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 50-70-4: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 57-55-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: CAS# 57-55-6; An expert panel convened by the NTP's Center for
the Evaluation of Risks to Human Reproduction concluded 2/13/03 that
developmental and reproductive risks stemming from exposure.
Reproductive Effects: CAS# 57-55-6; It has generally not affected fertility or
reproduction, except at very high doses where effects could be attributed to
nutritional deficiency.
Mutagenicity: CAS# 57-55-6; DNA Inhibition: Subcutaneous, mouse = 8000
mg/kg.; Cytogenetic Analysis: Subcutaneous, mouse = 8000 mg/kg.; Cytogenetic
Analysis: Hamster, Fibroblast = 32 gm/L.No information found
Neurotoxicity: No information found
Other Studies:
Section 12 - Ecological Information
CAS# 57-55-6
Water flea Daphnia: EC50 > 10000 mg/L; 48 Hr; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 = 710 mg/L; 30 min; Microtox testFish:
Goldfish: LC50 > 5000 mg/L; 24 Hr; UnspecifiedFish: Guppy: LC50 > 1000 mg/L; 48
Hr; Unspecified If released to water, 1,2-propanediol is expected to degrade
relatively rapidly via biodegradation.
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MSDS Number: SLP018
CAS# 6834-92-0
Based on 100% solids of this material the 96hr median tolerance for fish (Gambusia
affnis) 2320ppm
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is
classified as a hazardous waste. US EPA guidelines for the classification
determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must
consult state and local hazardous waste regulations to ensure complete and accurate
classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
US DOT Canada TDG
Shipping Name: Potassium hydroxide solution Potassium hydroxide solution
Hazard Class: 8 8
UN Number: UN1814 UN1814
Packing Group: II II
Section 15 - Regulatory Information
US FEDERAL
TSCA
All ingredients are listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 1310-58-3: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
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MSDS Number: SLP018
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 1310-58-3: immediate, reactive.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 1310-58-3 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the
CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the
CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5; CAS# 50-70-4 is not present on state lists from CA, PA, MN,
MA, FL, or NJ.
CAS# 1310-58-3 can be found on the following state right to know lists:
California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
CAS# 57-55-6 can be found on the following state right to know lists:
Pennsylvania, Minnesota.
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 22 Harmful if swallowed.
R 35 Causes severe burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable gloves and eye/face protection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 1310-58-3: 1
Canada - DSL/NDSL
CAS# 7732-18-5, 57-55-6, 1310-58-3 are listed on Canada's DSL List.
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MSDS Number: SLP018
Canada - WHMIS
This product has a WHMIS classification of D1B, E.
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the MSDS contains all of the information
required by those regulations.
Canadian Ingredient Disclosure List
CAS# 1310-58-3 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
MSDS Revision Date 6/25/09
The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall Southern Lithoplate
Inc. be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect,
incidental, consequential or exemplary damages, howsoever arising, even if Southern Lithoplate Inc. has been
advised of the possibility of such damages.
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