Material Safety Data Sheet
ELECTOR
Version 1.2 Revision Date 11/19/2009 Print Date 02/19/2010
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : ELECTOR
: 000004270359
Substance Number
Common Name : Spinosad Suspension
Chemical Name : 1H-as-Indaceno[3,2-d]oxacyclododecin-7,15-dione, 2-[(6-deoxy-2,3,4-tri-O-
methylalpha-
L-mannopyranosyl)oxy]-13-[[(2R,5S,6R)-5-(dimethylamino)
tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-
2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16btetradecahydro-
14-methyl-, (2R,3aS,5aR,5bS,9S,13S,14R,16aS,16bR)-
Alternate Chemical Name : 1H-as-Indaceno[3,2-d]oxacyclododecin-7,15-dione, 2-[(6-deoxy-2,3,4-tri-Omethyl-
alpha-L-mannopyranosyl)oxy]-13-[[(2R,5S,6R)-5-(dimethylamino)
tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-
2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16btetradecahydro-
4,14-dimethyl-, (2S,3aR,5aS,5bS,9S,13S,14R,16aS,16bS)-
: Elanco Animal Health
Company
Division of Eli Lilly and Company
2001 West Main St
Greenfield, IN 46140
: 1-800-428-4441
Telephone
: CHEMTREC: 1-800-424-9300 (Outside U.S. 1-703-527-3887)
Emergency telephone
Item Code : AH0492, HJ0011, HJ0008
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Lilly Lab Labeling Code
Health: 1
Fire: 0
Reactivity: 0
Primary Hazards: Liver, Kidney, Bone Marrow
Hazard Summary (Caution): May cause liver effects. May cause kidney effects. May cause bone marrow effects.
Emergency Overview
1/7
Material Safety Data Sheet
ELECTOR
Version 1.2 Revision Date 11/19/2009 Print Date 02/19/2010
Form : suspension
Colour : tan
Odour : Latex paint
Potential Health Effects
Eyes : May cause mild or transient irritation.
Aggravated Medical Condition : None known.
Primary Routes of Entry : Inhalation Skin contact
Additional Information : Animal studies have reported the following effects: Liver. Kidney. Bone marrow
changes. (spinosad)
Carcinogenicity
NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.
IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable,
possible or confirmed human carcinogen by IARC.
OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen
or potential carcinogen by OSHA.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Concentration [%]
Spinosad 168316-95-8 2.46
Spinosyn A 131929-60-7
Spinosyn D 131929-63-0
Propylene Glycol 57-55-6 10
Excipients NA 10.25
Water 7732-18-5 77.29
NA = Not applicable, Not assigned, or Not available.
SECTION 4. FIRST AID MEASURES
Inhalation : Remove to fresh air. If breathing is irregular or stopped, administer artificial
respiration. Call a physician immediately.
Skin contact : Wash off immediately with plenty of water for at least 15 minutes. Take off all
contaminated clothing immediately. Get medical attention if irritation develops and
persists. Wash contaminated clothing before re-use.
Eye contact : Immediately flush eye(s) with plenty of water. Obtain medical attention.
Ingestion : If conscious, give the victim plenty of water to drink. Never give anything by mouth
2/7
Material Safety Data Sheet
ELECTOR
Version 1.2 Revision Date 11/19/2009 Print Date 02/19/2010
to an unconscious person. Call a physician immediately.
SECTION 5. FIRE-FIGHTING MEASURES
Flash point : no data available Upper explosion limit : no data available
Lower explosion limit : no data available
Suitable extinguishing media : Water Carbon dioxide (CO2) Dry chemical
Unusual Fire and Explosion : Hazardous decomposition products formed under fire conditions.
Hazard.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Methods for cleaning up : Prevent further migration into the environment. Use absorbent/adsorbent material to
solidify liquids. Clean up promptly by sweeping or vacuum. Wear protective
equipment, including eye protection, to avoid exposure (see Section 8 for specific
handling precautions). Large spills due to traffic accidents, etc., should be reported
immediately to CHEMTREC and Elanco Animal Health for assistance.
SECTION 7. HANDLING AND STORAGE
Storage
Requirements for storage areas : Keep container tightly closed in a dry and well-ventilated place. Do not freeze. Store
and containers in original container.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure guidelines
Components Exposure Limit Values
Spinosad Supplier: TWA 0.3 mg/m3
Propylene Glycol AIHA: TWA 10 mg/m3
In a manufacturing setting, wear chemical-resistant gloves and body covering to minimize skin contact. If handled in a ventilated
enclosure, as in a laboratory setting, respirator and goggles or face shield may not be required. Safety glasses are always required.
Engineering measures
Laboratory fume hood or local exhaust ventilation.
3/7
Material Safety Data Sheet
ELECTOR
Version 1.2 Revision Date 11/19/2009 Print Date 02/19/2010
Personal protective equipment
Respiratory protection : Use an approved respirator.
Eye protection : Safety glasses
Skin and body protection : When mixing and handling, use protective clothing, impervious gloves, and dust
respirator. Operators should wash thoroughly with soap and water after handling. If
accidental eye contact occurs, immediately rinse with plenty of water.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form : suspension Colour : tan
Physical state : liquid Odour : Latex paint
Safety data
pH : 7.3 - 8.7 Specific Gravity : 1.01 - 1.04
Flash point : no data available at
Lower explosion limit : no data available 20 癈
Upper explosion limit : no data available Water solubility : soluble
SECTION 10. STABILITY AND REACTIVITY
Materials to avoid : Strong oxidizing agents
Hazardous decomposition : Hazardous decomposition products formed under fire conditions.
products
Thermal decomposition : Stable under normal conditions.
Hazardous reactions : Hazardous polymerisation does not occur.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute oral toxicity
?Spinosad: LD50 (male rat) 4,444 mg/kg
LD50 (female rat) > 5,000 mg/kg
LDLo (dog) > 400 mg/kg
Acute inhalation toxicity
4/7
Material Safety Data Sheet
ELECTOR
Version 1.2 Revision Date 11/19/2009 Print Date 02/19/2010
?Spinosad: LC50 (rat) > 5,180 mg/m3 (4 h)
Acute dermal toxicity
?Spinosad: LD50 (rabbit) > 5,000 mg/kg
Skin irritation
?Spinosad: rabbit, No irritation
Eye irritation
?Spinosad: rabbit, slight irritation
Sensitisation
?Spinosad: guinea pig, Did not cause sensitization on laboratory animals.
Repeated dose toxicity
?Spinosad: In animals, has been shown to cause vacuolation of cells in liver, kidney, and bone
tissues and changes in blood and serum biochemistry. Dose levels producing these
effects were many times higher than any dose levels expected from exposure due to use.
Carcinogenicity
?Spinosad: Animal testing did not show any carcinogenic effects.
?Propylene Glycol: Animal testing did not show any carcinogenic effects.
Reproductive toxicity
?Spinosad: In laboratory animal studies, effects on reproduction have been seen only at doses that
produced significant toxicity to the parent animals.
Mutagenicity
?Spinosad: Result in genetic toxicity assays (in vitro and in vivo): Negative.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity to fish
?Spinosad LC50 / 96 h / Lepomis macrochirus: 5.94 mg/l
LC50 / 96 h / Oncorhynchus mykiss: 30 mg/l
Toxicity to algae
?Spinosad EC50 / Pseudokirchneriella subcapitata: >105.5 ppm
EC50 / Navicula sp.: 0.107 mg/l
Toxicity to daphnia
?Spinosad EC50 / 48 h/ Daphnia magna : 92.7 mg/l
SECTION 13. DISPOSAL CONSIDERATIONS
Waste disposal methods : In accordance with local and national regulations. Triple rinse containers. Offer for
5/7
Material Safety Data Sheet
ELECTOR
Version 1.2 Revision Date 11/19/2009 Print Date 02/19/2010
recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or
incinerator, or if allowed by state and local authorities, by burning. If burned, stay out
of smoke.
SECTION 14. TRANSPORT INFORMATION
UN Number : 3082
IMDG
Description of the goods : Environmentally hazardous substance, liquid, n.o.s.
(Spinosad)
Class :9
Packaging group : III
Labels :9
Marine pollutant : yes
Other information : Not dangerous goods in the meaning of DOT.
SECTION 15. REGULATORY INFORMATION
TSCA Status: Not On TSCA Inventory
131929-60-7 Spinosyn A
131929-63-0 Spinosyn D
Excipients
168316-95-8 Spinosad
DSL Status: This product contains the following components that are not on the Canadian DSL nor NDSL lists.
131929-60-7 Spinosyn A
131929-63-0 Spinosyn D
Excipients
168316-95-8 Spinosad
California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive
defects.
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic Chemicals
(40 CFR 372.65) - Supplier Notification Required
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De
Minimis) reporting levels established by SARA Title III, Section 313.
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302 Extremely
Hazardous Substance (40 CFR 355, Appendix A)
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
6/7
Material Safety Data Sheet
ELECTOR
Version 1.2 Revision Date 11/19/2009 Print Date 02/19/2010
SECTION 16. OTHER INFORMATION
Further information
As of the date of issuance, we are providing available information relevant to the handling of this material in the workplace.
All information contained herein is offered with the good faith belief that it is accurate. THIS MATERIAL SAFETY DATA
SHEET SHALL NOT BE DEEMED TO CREATE ANY WARRANTY OF ANY KIND (INCLUDING WARRANTY OF
MERCHANT ABILITY OR FITNESS FOR A PARTICULAR PURPOSE). In the event of an adverse incident associated
with this material, this safety data sheet is not intended to be a substitute for consultation with appropriately trained
personnel. Nor is this safety data sheet intended to be a substitute for product literature which may accompany the finished
product.
For additional information contact:
Elanco Animal Health
317-276-2000
1-800-428-4441
7/7
|