MATERIAL SAFETY DATA SHEET
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING
OF PRODUCT
JEFFCOOL?P150
PRODUCT CODE AND NAME JCLP150
:
DATE ISSUED : 7/31/2002
8/1/2002
DATE PRINTED :
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MATERIAL IDENTITY
PRODUCT CODE AND NAME
JEFFCOOL?P150
JCLP150
JCLP150 A
2
Chemical Name and/or Family or Description:
Industrial coolant and/or heat transfer fluid
COMPANY INFORMATION
Huntsman Petrochemical Corporation
P.O. Box 27707
Houston, TX 77227-7707
TELEPHONE NUMBERS
Transportation Emergency
Company: (409) 727-0831
CHEMTREC: (800) 424-9300
Medical Emergency: (409) 722-9673 (24 Hour)
General MSDS Assistance: (713) 235-6432
Technical Information: (512) 459-6543
2. COMPOSITION AND INFORMATION ON INGREDIENTS
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION ARE AS FOLLOWS: CARCINOGENS ARE LISTED WHEN
PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN
PRESENT AT 1.0 % OR GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER. THIS IS NOT INTENDED
TO BE COMPLETE COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND
OTHER REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:
NONE X
OSHA IARC NTP OTHER
Composition:
Chemical Name CAS Number Exposure Limits Range in %
1,2- propanediol 57-55-6 95.00-99.99
Phosphoric acid, dipotassium salt 7758-11-4 1.00-2.99
THIS PRODUCT IS CONSIDERED NON-HAZARDOUS ACCORDING TO OSHA (1910.1200).
1
JEFFCOOL?P150
PRODUCT CODE AND NAME JCLP150
:
DATE ISSUED : 7/31/2002
DATE PRINTED : 8/1/2002
COMPANY : HUNTSMAN
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Appearance:
Clear liquid; may be colored by customer request
Odor:
Mild odor
WARNING STATEMENT
CAUTION ! ASPIRATION HAZARD IF SWALLOWED -
CAN ENTER LUNGS AND CAUSE DAMAGE
THIS PRODUCT NOT INTENDED FOR INTERNAL USE
Hazardous Material National Fire Protection
0
Health Flammability
1
Information System Association NFPA
1
Fire
0 0
(United States) (United States) Reactivity
Health
0
Reactivity
Personal protection Specific danger
POTENTIAL HEALTH EFFECTS
Primary Route of Exposure
Eye X Skin X Inhalation X Ingestion
Effects of Overexposure
Acute:
May cause minimal irritation, experienced as temporary discomfort.
Eyes:
Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may
Skin:
cause defatting of skin or irritation, seen as local redness with possible mild discomfort.
Other than the potential skin irritation effects noted above, acute (short term) adverse effects
are not expected from brief skin contact; see other effects, below, and Section 11 for
information regarding potential long term effects.
Vapors or mist, in excess of permissible concentrations, or in unusually high concentrations
Inhalation:
generated from spraying, heating the material or as from exposure in poorly ventilated areas
or confined spaces, may cause irritation of the nose and throat, headache, nausea, and
drowsiness.
If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhea
Ingestion:
may occur. Aspiration may occur during swallowing or vomiting resulting in lung damage.
Unknown
Sensitization Properties:
Chronic:
No adverse effects have been documented in humans as a result of chronic exposure. Section 11 may contain applicable
animal data.
Medical Conditions Aggravated by Exposure:
There is no evidence that this product aggravates an existing medical condition.
Other Remarks:
None
2
JEFFCOOL?P150
PRODUCT CODE AND NAME JCLP150
:
DATE ISSUED : 7/31/2002
DATE PRINTED : 8/1/2002
COMPANY : HUNTSMAN
4. FIRST AID MEASURES
Eyes:
Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation persists.
Skin:
Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists.
Ingestion:
If person is conscious and can swallow, give two glasses of water (16 oz.) but do not induce vomiting. If vomiting occurs, give
fluids again. Have medical personnel determine if evacuation of stomach or induction of vomiting is necessary. Do not give
anything by mouth to an unconscious or convulsing person.
Inhalation:
If irritation, headache, nausea, or drowsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult
or respiratory irritation persists.
Other Instructions:
Aspiration of this product during induced emesis may result in severe lung injury. If evacuation of stomach is necessary, use
method least likely to cause aspiration, such as gastric lavage after endotracheal intubation. Contact a Poison Center for
additional treatment information.
5. FIRE-FIGHTING MEASURES
Ignition Temperature - AIT (degrees C):
Not determined.
Flash Point (degrees C):
100 ( 212 F ) (PMCC)
Flammable Limits % (Lower-Upper):
Lower: Not Determined
Upper: Not Determined
Recommended Fire Extinguishing Agents And Special Procedures:
Use water spray, dry chemical, foam, or carbon dioxide to extinguish flames. Use water spray to cool fire-exposed containers.
Water or foam may cause frothing.
Unusual or Explosive Hazards:
None
Special Protective Equipment for Firefighters:
No special equipment or procedures required.
6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300)
Procedures in Case of Accidental Release, Breakage or Leakage:
Contain spill if possible, contain with absorbent materials such as clay or soil, and shovel up. Avoid skin and eye contact.
3
JEFFCOOL?P150
PRODUCT CODE AND NAME JCLP150
:
DATE ISSUED : 7/31/2002
DATE PRINTED : 8/1/2002
COMPANY : HUNTSMAN
7. HANDLING AND STORAGE
Precautions to be Taken in
Handling:
Minimum feasible handling temperatures should be maintained.
Storage:
Periods of exposure to high temperatures should be minimized. Water contamination should be avoided.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Protective Equipment (Type)
Eye/Face Protection:
Safety glasses, chemical type goggles, or face shield recommended to prevent eye contact.
Skin Protection:
Workers should wash exposed skin several times daily with soap and water. Soiled work clothing should be laundered or
dry-cleaned.
Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust is generated and the occupational
exposure limit of the product, or any component of the product, is exceeded, use appropriate NIOSH or MSHA approved air
purifying or air supplied respirator after determining the airborne concentration of the contaminant. Air supplied respirators
should always be worn when airborne concentration of the contaminant or oxygen content is unknown.
Ventilation:
Local exhaust ventilation recommended if generating vapor, dust, or mist. If exhaust ventilation is not available or inadequate,
use MSHA or NIOSH approved respirator as appropriate.
Exposure Limit for the Total Product:
None established for product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Clear liquid; may be colored by customer request
Odor:
Mild odor
Boiling Point (degrees C):
186.7 ( 368 F )
Melting/Freezing Point (degrees C):
< -60 ( < -76 F )
Specific Gravity (water=1):
1.055
pH:
9.9
Vapor Pressure:
4
JEFFCOOL?P150
PRODUCT CODE AND NAME JCLP150
:
DATE ISSUED : 7/31/2002
DATE PRINTED : 8/1/2002
COMPANY : HUNTSMAN
< 1 mmHg at 20 C ( 68 F )
Viscosity:
< 20 cSt at 40 C ( 104 F )
VOC Content:
Not Determined
Vapor Density (Air=1):
2.6
Solubility in Water (%):
>10
Other:
None
10. STABILITY AND REACTIVITY
This Material Reacts Violently With:
None of these X
Air Water Heat Strong Oxidizers Others
Comments:
None
Products Evolved When Subjected to Heat or Combustion:
Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and ketones.
Hazardous Polymerizations:
DO NOT OCCUR
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION (ANIMAL TOXICITY DATA)
Oral:
LD50 Believed to be > 5.00 g/kg (rat) practically non-toxic
Inhalation:
Believed to be practically non-toxic
Dermal:
LD50 Believed to be > 2.00 g/kg (rabbit) practically non-toxic
IRRITATION INDEX, ESTIMATION OF IRRITATION (SPECIES)
Skin:
(Draize) Believed to be < .50 /8.0 (rabbit) no appreciable effect
Eyes:
(Draize) Believed to be < 15.00 /110 (rabbit) no appreciable effect
Sensitization:
Not determined.
Other:
This product may contain residual (less than 5 ppm) concentrations of propylene oxide. There is evidence that propylene
oxide causes tumors in laboratory animals.
5
JEFFCOOL?P150
PRODUCT CODE AND NAME JCLP150
:
DATE ISSUED : 7/31/2002
DATE PRINTED : 8/1/2002
COMPANY : HUNTSMAN
12. DISPOSAL CONSIDERATIONS:
Waste Disposal Methods:
This product has been evaluated for RCRA characteristics and does not meet the criteria of a hazardous waste if discarded in
its purchased form. Under RCRA, it is the responsibility of the user of the product to determine at the time of disposal, whether
the product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures, processes,
etc. may render the resulting materials hazardous. Recycle to process, if possible.
Remarks:
None
13. TRANSPORT INFORMATION
Transportation
DOT:
Proper Shipping Name:
Not regulated
Hazard Class:
Not regulated
Identification Number:
Not regulated
Packing Group:
Not regulated
Label Required:
Not regulated
IMDG
Proper Shipping Name:
Not evaluated
ICAO
Proper Shipping Name:
Not evaluated
TDG
Proper Shipping Name:
Not regulated
Hazard Class:
Not regulated
Identification Number:
Not regulated
Label Required:
Not regulated
6
JEFFCOOL?P150
PRODUCT CODE AND NAME JCLP150
:
DATE ISSUED : 7/31/2002
DATE PRINTED : 8/1/2002
COMPANY : HUNTSMAN
14. REGULATORY INFORMATION
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances
Chemical Name CAS Number Range in % TPQ RQ
None.
Section 311 Hazardous Categorization:
N/A X
Acute Chronic Fire Pressure Reactive
Section 313 Toxic Chemical
Chemical Name CAS Number Concentration
None.
CERCLA 102(a)/DOT Hazardous Substances:
Chemical Name CAS Number Range in % RQ
None.
States Right-to-Know Regulations:
Chemical Name State Right-to-know
1,2- propanediol PA, RI
State list: CT (Connecticut), FL (Florida), IL (Illinois), MI (Michigan), LA (Louisiana), MA
(Massachusetts), NJ (New Jersey), PA (Pennsylvania), RI (Rhode Island)
California Prop. 65:
The following detectable components of this product are substances, or belong to classes of substances, known to the State of
California to cause cancer and/or reproductive toxicity.
Chemical Name CAS Number
Residual propylene oxide (typical) 75-56-9
INTERNATIONAL REGULATIONS:
TSCA Inventory Status:
This product, or its components, are listed on or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance
Inventory.
WHMIS Classification:
Not regulated
Canadian Inventory Status:
This product, or its components, are listed on or are exempt from the Canadian Domestic Substance List (DSL).
EINECS Inventory Status:
This product, or its components, are listed on or are exempt from the European Inventory of Existing Chemical Substances
(EINECS) or the European List of Notified Chemical Substances (ELINCS).
Australian Inventory Status:
This product, or its components, are listed on or are exempt from the Australian Inventory of Chemical Substances (AICS).
Japan Inventory Status:
Not determined
7
JEFFCOOL?P150
PRODUCT CODE AND NAME JCLP150
:
DATE ISSUED : 7/31/2002
DATE PRINTED : 8/1/2002
COMPANY : HUNTSMAN
15. ENVIRONMENTAL INFORMATION
Aquatic Toxicity:
Not determined.
Mobility:
Not determined.
Persistence and Biodegradability:
This product is estimated to have a moderate rate of biodegradation; greater than or equal to 30 % degradation over a test
period of 28 days or less.
Potential to Bioaccumulate:
This product is estimated to have a low potential to bioconcentrate.
Remarks:
None
16. OTHER INFORMATION 7/31/2002
None
THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE. IT IS PROVIDED INDEPENDENTLY OF ANY SALE
OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF HUNTSMAN'S PRODUCT SAFETY PROGRAM. IT
IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO EXPRESS WARRANTY,
OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE
PRODUCT OR THE INFORMATION CONTAINED HEREIN. DATA SHEETS ARE AVAILABLE FOR ALL HUNTSMAN PRODUCTS.
YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL HUNTSMAN PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE AND
YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE
INFORMATION CONTAINED HEREIN.
TO DETERMINE APPLICABILITY OR EFFECTS OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, USER
SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. HUNTSMAN DOES NOT UNDERTAKE
TO FURNISH ADVICE ON SUCH MATTERS.
The following sections have been revised: 11, 14
Supercedes: 10/29/1999
Date Issued: 7/31/2002.
Inquiries regarding MSDS should be directed to:
HUNTSMAN
Coordinator, Product Safety
P.O. Box 27707
Houston, TX 77227-7707
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