MATERIAL SAFETY DATA SHEET
OHP, INC. Rev. Date: 06/14/2006
P.O. BOX 230, MAINLAND, PA 19451 Revised Date: 01/29/2003
Supersedes: 02/13/2001
800-659-6745
TRANSPORTATION EMERGENCY EMERGENCY AND PRODUCT INFORMATION
CHEMTREC: . . . . . . . . . . . . . . . . . . . . . .(800)-424-9300 OHP, Inc.: . . . . . . . . . . . . . . . . . . . . . . . . .(800)-356-4647
PYLON?miticide
EPA Registration Number: 241-374-59807
I. CHEMICAL PRODUCT INFORMATION V. HEALTH DATA
Trade Name . . . . . . . . . . . . . . . . . . . .: PYLON?miticide TOXICOLOGICAL TEST DATA:
Data for the formulated product:
Chemical Name . . . . . . . . . . . . . . . . .: 4-bromo-2-(4chlorophenyl)-
1-(ethoxymethyl)-5-(trifluoromethyl)-1H-pyrrole-3-car- Rat (male), Oral LD50 (calculated) = 560 mg/kg
bonitrile Rat (female), Oral LD50 (calculated) = 567 mg/kg
Synonyms . . . . . . . . . . . . . . . . . . . . .: pyrrole; CL 303,630; chlorfe- Rabbit (combined), Dermal LD50 > 2000 mg/kg
. . . . . . . . . . . . . . . . . . . . . . napyr
Rat (male), Inhalation LC50 (4 hr) = 0.571 mg/L
Formula . . . . . . . . . . . . . . . . . . . . . . .: C(15) H(11) Br CI F(3) N(2) O
Rat (female), Inhalation LC50 (4 hr) = 2.43 mg/L
Chemical Family . . . . . . . . . . . . . . . .: Pyrrole
Rat (male), Inhalation LC50 (1 hr - calculated) = 2.284 mg/L
Mol Wt . . . . . . . . . . . . . . . . . . . . . . . .: 407.6
Rat (female), Inhalation LC50 (1 hr - calculated) = 9.72 mg/L
Rabbit, Eye Irritation ?Not-irritating
II. INGREDIENTS
Rabbit, Skin Irritation ?Not-irritating
COMPONENT CAS No. % PEL/TLV ?SOURCE
Guinea pig, Dermal Sensitizer ?Not a sensitizer
CL 303,630
Note: Inhalation data for mists were not used to classify this material
(chlorfenapyr) 122453-73-0 21.44 None established
for transportation because it is reasonably foreseeable that such
Propylene glycol 57-55-6 7.5 None established
concentrations (mists) would not be encountered by a human during
Inerts N/A 71.06 None established transport (49CFR 173.132 (b) (3).
SARA Title III Section 313 . . . . . . . .: Not listed OSHA, NTP, or IARC Carcinogen . .: Not listed.
Effects of Overexposure:
III. PHYSICAL DATA
See Product Label and Directions For Use for additional pre-
Boiling/Melting Point @ 760mm Hg : Similar to water cautionary statements.
pH . . . . . . . . . . . . . . . . . . . . . . . . . . .: 6.5 ?7.2 2% dispersion
Vapor Pressure mmHg @ 20癈 . . . .: N/D CAUTION! KEEP OUT OF REACH OF CHILDREN
Specific Gravity or Bulk Density . .: 1.1 g/mL @ 20?C Avoid contact with skin and eyes. Do not breathe sprays or mists.
Solubility in Water . . . . . . . . . . . . . .: Forms a suspension Existing medical conditions aggravated by this product: None known.
Appearance . . . . . . . . . . . . . . . . . . . .: Off-white to tan liquid
Odor . . . . . . . . . . . . . . . . . . . . . . . . . .: N/A FIRST AID PROCEDURES
Intensity . . . . . . . . . . . . . . . . . . . . . .: N/A If swallowed: Call a poison control center or doctor immediately for
treatment advice. Have person sip a glass of water if able to
IV. FIRE AND EXPLOSION DATA swallow. Do not induce vomiting unless told to by a poison
control center or doctor. Do not give anything to an uncon-
Flash Point (test method) . . . . . . . .: N/D
scious person.
Autoignition Temp . . . . . . . . . . . . . .: N/D
If on skin or clothing: Take off contaminated clothing. Rinse skin
Flammability Limits in Air (% by Vol) : immediately with plenty of water for 15-20 minutes. Call a poi-
Lower: N/D son control center or doctor for treatment advice.
Upper: N/D If inhaled: Move person to fresh air. If person is not breathing, call
911 or an ambulance, then give artificial respiration, preferably
NFPA 704 HAZARD CODES
mouth-to-mouth, if possible. Call a poison control center or
Health: N/R Flammable: N/R Instability: N/R Other: N/R
doctor for further treatment advice.
NFPA 30 Storage Classification: N/R
If in eyes: Immediately hold eyelids open and flush with a steady,
Extinguishing Medium . . . . . . . . . .: Use water fog, foam, CO(2), gentle stream of water for 15-20 minutes. Call a poison control
or dry chemical extinguishing media. center or doctor for treatment advice.
Special Fire Fighting Procedures . .: Firefighters should be Note to physician: Treat symptomatically. No specific antidote.
equipped with self-contained breathing apparatus and
Note: Have the product container or label with you when calling a
turnout gear. Control run-off water- if water enters
poison control center or doctor or going for treatment.
drainage system, notify authorities downstream.
Unusual Fire Explosion Hazards . .: None known.
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MATERIAL SAFETY DATA SHEET
PYLON?miticide
EPA Registration Number: 241-374-59807
VI. REACTIVITY DATA
Stability . . . . . . . . . . . . . . . . . . . . . . .: Stable. Do not store below Hazardous Substance Superfund .: No
32癋. Avoid heat and sunlight. RQ(lbs) . . . . . . . . . . . . . . . . . . . . . . .: None
Conditions to Avoid . . . . . . . . . . . . .: Store in original container in
cool, dry well ventilated place away from ignition
Waste Disposal Method . . . . . . . . . .: Pesticide wastes are acutely
sources, heat or flame.
hazardous. Wastes resulting from this product may be
Chemical Incompatibility . . . . . . . . .: Oxidizing agents. disposed of on site or at an approved waste disposal
Hazardous Decomposition facility. Improper disposal of excess pesticide, spray
Products . . . . . . . . . . . . . . . . . .: Including oxides of carbon mix or rinsate is a violation of federal law. If these
and nitrogen; HCI; HF; HBr wastes cannot be disposed of according to label
instructions, contact the state agency responsible for
Hazardous Polymerization . . . . . . .: Does not occur.
pesticide regulation or the Hazardous Waste represen-
Conditions to Avoid . . . . . . . . . . . . .: Does not polymerize. tative at the nearest EPA Regional Office for guidance.
Corrosive to Metal . . . . . . . . . . . . . .: No Hazardous Waste 40CFR261 . . . . . .: No
Oxidizer . . . . . . . . . . . . . . . . . . . . . . .: No Hazardous Waste Number . . . . . . . .: None
Container Disposal . . . . . . . . . . . . .: Empty containers or liners
VII. PERSONAL PROTECTION may retain some product residues. DO NOT REUSE.
PESTICIDE APPLICATORS & WORKERS must refer to the Product Rinse the container or liner as needed for disposal.
Label and Directions for Use attached to the product for Agricultural Render it unusable by crushing or puncturing. Dispose
Use Requirements in accordance with the EPA Worker Protection of the container and any rinsate in a safe manner.
Standard 40 CFR part 170. Follow all applicable community, national or regional
regulations regarding waste management methods.
RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL
IX. SHIPPING DATA - PACKAGE
BLENDING, AND PACKAGING WORKERS:
D.O.T. Proper Shipping Name (49CFR172.101-102): None
Respiratory Protection . . . . . . . . . .: Supplied air respirators
should be worn if large quantities of mist are generated Hazardous Substance (49CFR CERCLA List):
or prolonged exposure possible. RQ(lbs): None
Eye Protection . . . . . . . . . . . . . . . . .: Chemical goggles when res- D.O.T. Hazard Classification (CFR 172.101-102): Primary: None
pirator does not provide eye protection. Secondary:
Protective Clothing . . . . . . . . . . . . .: Gloves and protective cloth- D.O.T. Labels Required (49CFR172.101-102): None
ing as necessary to prevent skin contact.
D.O.T. Placards Required (CFR172.504): None
Ventilation . . . . . . . . . . . . . . . . . . . . .: Whenever possible, engi-
Poison Constituent (49CFR172.203(K)): None
neering controls should be used to minimize the need
Bill of Lading Description: THIS PRODUCT IS NOT REGULATED
for personal protective equipment.
BY THE DEPARTMENT OF TRANSPORTATION.
CC NO. . . . . . . . . . . . . . . . . . . . . . . . .: Not applicable
VIII. ENVIRONMENTAL DATA
Environmental Toxicity Data UN/NA Code . . . . . . . . . . . . . . . . . . .: Not applicable
Based on standard laboratory tests on this formulation and the
active ingredient, chlorfenapyr, this product is very toxic to fish, X. ADDITIONAL INFORMATION
aquatic invertebrates, and honeybees, and toxic to algae. Complete Label and Directions for Use are attached to the product.
Agricultural Use Requirements
SARA 311 / 312 REPORTING
Use this product only in accordance with its labeling and with
the Worker Protection Standard, 40 CFR part 170. Refer to
FIRE: N PRESSURE: N REACTIVITY: N ACUTE: Y supplemental labeling under `Agricultural Use Requirements'
in the Directions for Use section for information about this
CHRONIC: N TPQ(lbs): N/R
standard.
Spill and Leak Procedures . . . . . . .: In case of large scale
spillage of this product, avoid contact, isolate area and
keep out animals and unprotected persons. Call
CHEMTREC (800) 424-9300 or OLYMPIC 800-356-4647.
For a small spill, wear personal protective equipment as
specified on the label.
For a Liquid Spill . . . . . . . . . . . . . . .: Dike and contain the spill
with inert material (sand, earth, etc.) and transfer the
liquid and solid diking materials to separate containers
for disposal.
For a Solid Spill . . . . . . . . . . . . . . . .: Sweep solid into a drum for
re-use or disposal. Remove personal protective equip-
ment and decontaminate it prior to re-use.
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MATERIAL SAFETY DATA SHEET
PYLON?miticide
EPA Registration Number: 241-374-59807
DISCLAIMER
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATE AND
INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD
FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR
YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT
PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT
YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PROD-
UCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO
WARRANTIES OF ANY KIND, EITHER EXPRESS OR IMPLIED,
INCLUDING WARRANTIES OR MERCHANTABILITY OR FITNESS
FOR A PARTICULAR PURPOSE, ARE MADE REGADING PROD-
UCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET
FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMA-
TION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL
PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE
DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE
CONSIDERED A PART OF OUR TERMS AND CONDITONS OF
SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE
THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION
FURNISHED BY OHP, INC. HEREUNDER ARE GIVEN GRATIS AND
OHP, INC. ASSUMES NO OBLIGATION OR LIABILTY FOR THE
DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR
RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED
AT YOUR RISK.
Pylon is a registered trademark of BASF Corp.
OHP 986200 / 986288 06/06
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