Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 1 of 15
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MICROSHIELD T Triclosan Skin Cleanser
SYNONYMS
Antiseptic Wash Solution for Sensitive Skin, Manufacturer's Code: 60341,
60342, 60333, 60345
PRODUCT USE
Hand and skin topical antibacterail solution for external use.
SUPPLIER
Company: Johnson & Johnson Medical Pty Ltd Company: Johnson & Johnson Medical Pty Ltd
Address: Address:
1-5 Khartoum Road PO Box 134
North Ryde North Ryde
NSW, 2113 NSW, 2113
AUS AUS
Telephone: +61 2 9878 9000
Telephone: 1800 257 210
Emergency Tel: 13 11 26
Emergency Tel: +64 3 474 7000 NZ
Fax: 1800 808 233
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the
Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
Causes burns.
Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
SAFETY
Avoid over exposure - obtain special instructions before use.
This material and its container must be disposed of in a safe way.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
Use appropriate container to avoid environment contamination.
Avoid release to the environment. Refer to special instructions/Safety data
sheets.
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 2 of 15
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
ethoxylated and sulfated alcohol 0-10
fatty acid diethanolamide 0-10
lanolin, ethoxylated 61790-81-6 0-10
2,4,4'-trichloro-2'-hydroxydiphenyl ether 3380-34-5 0-10
cellulose 9004-34-6 0-10
propylene glycol 57-55-6 10
sodium cumene sulfonate 28348-53-0 0-10
citric acid 77-92-9 0-10
ethanolamine 141-43-5 0-10
fragrance 0-10
dye 0-10
water 7732-18-5 >30^
Section 4 - FIRST AID MEASURES
SWALLOWED
For advice, contact a Poisons Information Centre or a doctor.
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious
- Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
- Seek medical advice.
EYE
If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
- If pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
No adverse effects anticipated from normal use.
If skin irritation occurs:
- Immediately remove all contaminated clothing, including footwear
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
Emesis is contraindicated as the product may foam. Gastric lavage may be
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 3 of 15
Section 4 - FIRST AID MEASURES
considered.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
- There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
FIRE FIGHTING
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves for fire only.
- Prevent, by any means available, spillage from entering drains or water
courses.
- Use fire fighting procedures suitable for surrounding area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
- Non combustible.
- Not considered to be a significant fire risk.
- Expansion or decomposition on heating may lead to violent rupture of
containers.
- Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result.
HAZCHEM
None
Personal Protective Equipment
Gloves, boots (chemical resistant).
Breathing apparatus.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Slippery when spilt.
Clean up all spills immediately.
Wipe up.
Place in clean drum then flush area with water.
MAJOR SPILLS
Slippery when spilt.
Minor hazard.
- Clear area of personnel.
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 4 of 15
Section 6 - ACCIDENTAL RELEASE MEASURES
- Alert Fire Brigade and tell them location and nature of hazard.
- Control personal contact by using protective equipment as required.
- Prevent spillage from entering drains or water ways.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labelled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite and place in
appropriate containers for disposal.
- Wash area and prevent runoff into drains or waterways.
- If contamination of drains or waterways occurs, advise emergency services.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
individuals could be exposed for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
cellulose 500 mg/m?br>
propylene glycol 750 ppm
citric acid 500 mg/m?br>
ethanolamine 30 ppm
water 500 mg/m?br>
irreversible or other serious effects or symptoms which could
impair an individual's ability to take protective action is:
cellulose 500 mg/m?br>
propylene glycol 75 ppm
citric acid 50 mg/m?br>
ethanolamine 30 ppm
water 500 mg/m?br>
other than mild, transient adverse effects
without perceiving a clearly defined odour is:
cellulose 30 mg/m?br>
propylene glycol 50 ppm
citric acid 30 mg/m?br>
ethanolamine 6 ppm
water 500 mg/m?br>
The threshold concentration below which most people.
will experience no appreciable risk of health effects:
cellulose 15 mg/m?br>
propylene glycol 50 ppm
citric acid 10 mg/m?br>
ethanolamine 3 ppm
water 500 mg/m?br>
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 5 of 15
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING BULK OR LARGE QUANTITIES
- Limit all unnecessary personal contact.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- When handling DO NOT eat, drink or smoke.
- Always wash hands with soap and water after handling.
- Avoid physical damage to containers.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
SUITABLE CONTAINER
Plastic container.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers.
STORAGE REQUIREMENTS
Keep cool. Store below 25 deg.C.
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA TWA STEL STEL Peak Peak
ppm mg/m? ppm mg/m? ppm mg/m?br>
_________________________ ________________ _____ _____ _____ _____ _____ _____
Australia Exposure Inspirable dust 10
Standards (Not specified)
Australia Exposure Inspirable dust 10
Standards (Not specified)
Australia Exposure Cellulose (paper 10
Standards fibre) (a)
Australia Exposure Propane-1,2-diol: 10
Standards particulates
only
Australia Exposure Propane-1,2-diol 150 474
Standards total: (vapour &
particulates)
Australia Exposure Inspirable dust 10
Standards (Not specified)
Australia Exposure Inspirable dust 10
Standards (Not specified)
Australia Exposure Ethanolamine 3 7.5 6 15
Standards
No data available: lanolin, ethoxylated as (CAS: 61790-81-6) / (CAS: 8039-09-6)
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 6 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Source Material TWA TWA STEL STEL Peak Peak
ppm mg/m? ppm mg/m? ppm mg/m?br>
_________________________ ________________ _____ _____ _____ _____ _____ _____
No data available: 2,4,4'-trichloro-2'-hydroxydiphenyl ether as (CAS: 3380-34-5)
No data available: cellulose as (CAS: 68442-85-3)
No data available: sodium cumene sulfonate as (CAS: 28348-53-0) / (CAS: 32073-22-6)
No data available: citric acid as (CAS: 77-92-9)
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Revised IDLH
Value (ppm) Value (mg/m3)
Ethanolamine 30
None assigned.
ODOUR SAFETY FACTOR (OSF)
OSF=0.77 (ETHANOL AMINE)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
activities
B 26-550 As "A" for 50-90% of
persons being distracted
C 1-26 As "A" for less than 50%
of persons being
distracted
D 0.18-1 10-50% of persons aware
of being tested perceive
by smell that the
Exposure Standard is
being reached
E <0.18 As "D" for less than 10%
of persons aware of
being tested
.
INGREDIENT DATA
LANOLIN, ETHOXYLATED:
These "dusts" have little adverse effect on the lungs and do not produce toxic
effects or organic disease. Although there is no dust which does not evoke some
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 7 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
cellular response at sufficiently high concentrations, the cellular response
caused by P.N.O.C.s has the following characteristics:
- the architecture of the air spaces remain intact,
- scar tissue (collagen) is not synthesised to any degree,
- tissue reaction is potentially reversible.
Extensive concentrations of P.N.O.C.s may:
- seriously reduce visibility,
- cause unpleasant deposits in the eyes, ears and nasal passages,
- contribute to skin or mucous membrane injury by chemical or mechanical action,
per se, or by the rigorous skin cleansing procedures necessary for their
removal. [ACGIH]
This limit does not apply:
- to brief exposures to higher concentrations
- nor does it apply to those substances that may cause physiological impairment
at lower concentrations but for which a TLV has as yet to be determined.
This exposure standard applies to particles which
- are insoluble or poorly soluble* in water or, preferably, in aqueous lung
fluid (if data is available) and
- have a low toxicity (i.e.. are not cytotoxic, genotoxic, or otherwise
chemically reactive with lung tissue, and do not emit ionizing radiation, cause
immune sensitization, or cause toxic effects other than by inflammation or by a
mechanism of lung overload).
2,4,4'-TRICHLORO-2'-HYDROXYDIPHENYL ETHER:
No data for 2,4,4'-trichloro-2'-hydroxydiphenyl ether.
CELLULOSE:
Cellulose is considered a nuisance dust which has little adverse effect on lung
and does not produce significant organic disease or toxic effects when
appropriate controls are applied.
PROPYLENE GLYCOL:
Saturated vapour concentration @ 20 deg C.= 65.8 ppm, 204.6 mg/m? i.e
higher concentrations can only occur as aerosols or at higher temperatures.
Odour Threshold: Practically odourless.
A small number of individuals show skin irritation or sensitisation from
repeated or prolonged exposure to propylene glycol. A workplace
environmental exposure limit (WEEL) has been established by AIHA and is
thought to be protective against systemic effects.
SODIUM CUMENE SULFONATE:
No data for sodium cumene sulfonate.
CITRIC ACID:
No data for citric acid.
ETHANOLAMINE:
Odour threshold: 3-4 ppm.
Continuous exposure at 5 ppm produced only slight systemic effects.
Intermittent exposure produces a lesser degree of toxicity in laboratory
animals. This decreased toxicity is related to the rate of elimination;
the longer retained, the greater the toxicity,. The TLV-TWA is thought to
be protective against the risk of irritation and neuropathic effects.
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 8 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTION
EYE
No special equipment for minor exposure i.e. when handling small quantities.
- OTHERWISE:
- Safety glasses with side shields.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens
or restrictions on use, should be created for each workplace or task. This
should include a review of lens absorption and adsorption for the class of
chemicals in use and an account of injury experience. Medical and first-aid
personnel should be trained in their removal and suitable equipment should be
readily available. In the event of chemical exposure, begin eye irrigation
immediately and remove contact lens as soon as practicable. Lens should be
removed at the first signs of eye redness or irritation - lens should be removed
in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
None under normal operating conditions.
OTHER
None under normal operating conditions.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.
Breathing Zone Maximum Half-face Full-Face
Level ppm Protection Factor Respirator Respirator
(volume)
1000 10 AK-AUS P -
1000 50 - AK-AUS P
5000 50 Airline * -
5000 100 - AK-2 P
10000 100 - AK-3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
None under normal operating conditions.
Provide adequate ventilation in warehouse or closed storage areas.
Avoid production of aerosols.
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 9 of 15
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Clear blue-aqua viscous liquid with citrus/floral fragrance; mixes with
water.
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not applicable Boiling Range (C): Not available
Melting Range (C): Not available Specific Gravity (water=1): 1.09
Solubility in water (g/L): Miscible pH (as supplied): 5.5
pH (1% solution): Not available Vapour Pressure (kPa): Not available
Volatile Component (%vol): Not available Evaporation Rate: Not available
Relative Vapour Density (air=1): Not available Flash Point (C): Not applicable
Lower Explosive Limit (%): Not applicable Upper Explosive Limit (%): Not applicable
Autoignition Temp (C): Not available Decomposition Temp (癈): Not available
State: Liquid Viscosity: Not available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Considered an unlikely route of entry in commercial/industrial environments.
The material may be discomforting to the gastro-intestinal tract if swallowed in
large quantity.
Ingestion may result in nausea, abdominal irritation, pain and vomiting and
diarrhoea.
EYE
The liquid may produce eye discomfort causing transient smarting, blinking.
SKIN
Excessive use or prolonged contact may lead to defatting, drying and irritation
of sensitive skin.
Not considered to cause discomfort through normal use.
INHALED
Not normally a hazard due to non-volatile nature of product.
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 10 of 15
Section 11 - TOXICOLOGICAL INFORMATION
Inhalation of aerosols (mists, fumes), generated by the material during the
course of normal handling, may be harmful.
CHRONIC HEALTH EFFECTS
Primary route of exposure is usually by skin contact. Prolonged or continuous
skin contact with the liquid may cause defatting with drying, cracking,
irritation and dermatitis following. As with any chemical product, contact with
unprotected bare skin; inhalation of vapour, mist or dust in work place
atmosphere; or ingestion in any form, should be avoided by observing good
occupational work practice.
TOXICITY AND IRRITATION
Not available.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
LANOLIN, ETHOXYLATED:
TOXICITY IRRITATION
Oral (rat) LD50: >21300 mg/kg *
Skin (rabbit): non-irritating *
Eye (rabbit): non-irritating *
2,4,4'-TRICHLORO-2'-HYDROXYDIPHENYL ETHER:
TOXICITY IRRITATION
Oral (rat) LD50: 3700 mg/kg Skin (human):0.75 mg/3d-I- Mild
Inhalation (rat) LC50: > 140 mg/kg* Skin (rabbit): 10% - Mild
Dermal (rabbit) LD50: > 6000 mg/kg* Eye: SEVERE **
[Van Waters & Rogers]* [Thompson Research] **
CELLULOSE:
TOXICITY IRRITATION
Oral (rat) LD50: > 5000 mg/kg Nil Reported
Dermal (rabbit) LD50: > 2000 mg/kg
PROPYLENE GLYCOL:
TOXICITY IRRITATION
Oral (rat) LD50: 20000 mg/kg Skin(human):500 mg/7days Mild
Dermal (rabbit) LD50: 20800 mg/kg Skin(human):104 mg/3d Intermit Moderate
Eye (rabbit): 100 mg - Mild
Eye (rabbit): 500 mg/24h - Mild
SODIUM CUMENE SULFONATE:
None assigned. Refer to individual constituents.
CITRIC ACID:
TOXICITY IRRITATION
Oral (rat) LD50: 3000 mg/kg Skin (rabbit): 500 mg/24h - Mild
Eye (rabbit): 0.75 mg/24h-SEVERE
ETHANOLAMINE:
TOXICITY IRRITATION
Oral (rat) LD50: 2050 mg/kg Skin (rabbit):505 mg open-Moderate
Oral (rat) LD50: 1510 mg/kg * Eye (rabbit): 0.76 mg - SEVERE
Dermal (rabbit) LD50: 1000 mg/kg
* Bayer
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 11 of 15
Section 12 - ECOLOGICAL INFORMATION
Refer to data for ingredients, which follows:
LANOLIN, ETHOXYLATED:
Alcohol ethoxylates are generally biodegradable and do not persist for any
substantial period in the environment. Contamination of natural waters, however,
should be avoided.
A EU Risk Assessment Report (RAR) concluded that octyl- and nonyl- phenol
ethoxylates are not readily biodegradable but are inherently biodegradable
As a group, these materials are generally toxic to fish with LC50s ranging,
typically, between 1-6 mg/l.
Of special concern are the following families which are classified as
"Environmentally Hazardous Substances" by either or both the ADR (Accord
Europeen Relatif au Transport International des Merchandises Dangerous par
Route) and the IMDG Code (International Maritime Dangerous Goods Code).
alcohols C 6-17 (secondary) with 3-6 moles of ethoxylation.
alcohols C12-15 with 1-3 moles of ethoxylation (1-6 moles of ethoxylation IMDG)
alcohols C13-15 with 1-6 moles of ethoxylation.
New aquatic data suggests that
alcohols C 8-9 branched with 3-10 moles of ethoxylation
alcohols C 8-9 branched with > 10 moles of ethoxylation should also be
classified as 'harmful to the environment"
These alcohols may also be found linked to aromatic structures (in nonylphenol
ethoxylates for example). The current consensus determines that such entities
become Environmental Toxins by association.
2,4,4'-TRICHLORO-2'-HYDROXYDIPHENYL ETHER:
BOD 5: 0 mgO2/g
COD: 1116 mgO2/g
TOC: 50%
Fish Toxicity Zebra Fish LC50: 0.5 mg/l (96h)
Daphnia Tox: EC50 0.4 mg/l 48h OECD 202
Algea Tox: EC50 0.2 mg/l 72h OECD 201
Toxicity to bacteria: 20 mg/l (3h) OECD 209
OECD biological degradation; <10% Oxygen consumption OECD 301C, 302C
Organo-halogen content: 36.7% chloro
PROPYLENE GLYCOL:
log Kow (Prager 1995): -0.92
log Kow (Sangster 1997): -0.92
log Pow (Verschueren 1983): 4.7
BOD5: 0.955 (2.2
BOD20: 1.225
ThOD: 1.685
log Kow: -1.41- -0.3
Half-life (hr) air: 32
Henry's atm m?/mol: 1.20E-08
BOD 5 if unstated: 0.995,2.2%
ThOD: 1.685
BCF: <1
Bioacculmulation: not sig
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Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 12 of 15
Section 12 - ECOLOGICAL INFORMATION
processes Abiotic: photoxid
CITRIC ACID:
Algae IC50 (72hr.) (mg/l): 80
log Pow (Verschueren 1983): -1.72
DO NOT discharge into sewer or waterways.
Biodegradable in a waste treatment facility
log Kow: -1.72
BOD 5 if unstated: 0.42
ThOD: 0.686
Toxicity Fish: LC50>100mg/L
Effects on algae and plankton: inhib. algae 100mg/L
ETHANOLAMINE:
Fish LC50 (96hr.) (mg/l): 170
Algae IC50 (72hr.) (mg/l): 0.75-1.6
log Kow (Sangster 1997): -1.31
log Pow (Verschueren 1983): -1.31
BOD5: 0.93
COD: 1.27
ThOD: 2.49
log Kow: -1.31
Koc: 5
Half-life (hr) air: 11
Henry's atm m?/mol: 4.00E-08
BOD 5 if unstated: 0.8-1.1,0%
COD: 1.27-1.28
ThOD: 2.49
BCF: <1
Toxicity Fish: LC50(96)13480mg/L
Toxicity invertebrate: cell mult. inhib.65-6500mg/L
Bioacculmulation: not sig
Nitrif. inhib.: 50% inhib at 4100mg/L
Anaerobic effects: sig degrad
Degradation Biological: sig
processes Abiotic: RxnOH*,no hydrol
Biodegradability:
BOD5: 800 mg/g
>70%: BOD of the ThOD (OECD 301F)
>90%: DOC reduction (OECD 301A)
Ecotoxicity:
Fish LC50 (96 h): Oncorrhynchus 150 mg/l
Daphnia LC50 (24 h): 120-140 mg/l
Algae NOEC (192 h): 0.75-0.97 mg/l
Environmental Fate:
Movement and Partitioning:
Bioconcentration potential is low (BCF less than 100 or log Kow less than
3). The potential for mobility in the soil is high (Koc between 0 and 50).
Log soil organic carbon partition coefficient (log Koc) is estimated to be
0.70.
Degradation and Persistence:
The material is biodegradable, passing the OECD tests for ready
biodegradability.
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 13 of 15
Section 12 - ECOLOGICAL INFORMATION
Biodegradation reached in CO2 evolution test after 28 days: 97%*
(modified Sturm Test, OECD 301B)
Biodegradation reached in modified OECD Screening Test after 28 days: 94%*
(OECD 301E)
Biodegradation reached in manometric Respirometer Test after 28 days:>70%*
(OECD 301F)
Biodegradation under aerobic static laboratory conditions is high (BOD20
or BOD28/ThOD >40%)
BOD20 (Biochemical Oxygen Demand after 20 days): 1.5 p/p
ThOD (Theoretical Oxygen Demand)): 2.36 p/p (calc).
IC50 (Inhibitory Concentration): >1000 mg/l
(OECD Activated Sludge Respiration Inhibition Test (OECD 209)
Ecotoxicology:
The material is practically non-toxic to aquatic organisms on an acute
basis (LC50/ EC50 >100 mg/l in most sensitive species).
Daphnia LC50 (-) 114 mg/l *
Fish LC50 (-): Oncorhyncus mykiss 150 mg/l, gold fish 170 mg/l,
bluegill 300-1000 mg/l, fathead minnow 635 mg/l,
mosquito fish 337.5, golden orfe 224-525 mg/l
* (Dow Chemical)
BOD5: 60%; BOD19: 75%; BOD20: 100% **
Toxicity to microorganisms:
IC50 700 mg/l
Daphnia LC50 (48 h): 33 mg/l; 93 mg/l **
Fish KC50 (96 h): fathead minnow 125 mg/l, 206 mg/l **
ThOD: 1.54 mg/mg (measured); 1.31 mg/mg (calculated) **
Octanol/ Water coefficient Kow (measured): -1.31 **
Monoethanolamine is toxic to aquatic life at relatively low concentrations
in water.
Editors note: there is clear contradiction between the conclusion reached
by Dow Chemical and other manufacturers relating to aquatic toxicity.
Under present EC Directives the material is not toxic to aquatic life.
** (Dow Chemical)
Section 13 - DISPOSAL CONSIDERATIONS
- Recycle wherever possible or consult manufacturer for recycling options.
- Consult State Land Waste Management Authority for disposal.
- Bury residue in an authorised landfill.
- Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM
None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN,IATA,IMDG
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 14 of 15
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
REGULATIONS
lanolin, ethoxylated (CAS: 61790-81-6) is found on the following regulatory
lists;
Australia Inventory of Chemical Substances (AICS)
2,4,4'-trichloro-2'-hydroxydiphenyl ether (CAS: 3380-34-5) is found on the
following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
cellulose (CAS: 9004-34-6) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
cellulose (CAS: 68442-85-3) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
propylene glycol (CAS: 57-55-6) is found on the following regulatory lists;
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume
List
OECD Representative List of High Production Volume (HPV) Chemicals
sodium cumene sulfonate (CAS: 28348-53-0) is found on the following regulatory
lists;
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume
List
OECD Representative List of High Production Volume (HPV) Chemicals
sodium cumene sulfonate (CAS: 32073-22-6) is found on the following regulatory
lists;
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume
List
OECD Representative List of High Production Volume (HPV) Chemicals
citric acid (CAS: 77-92-9) is found on the following regulatory lists;
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume
List
OECD Representative List of High Production Volume (HPV) Chemicals
ethanolamine (CAS: 141-43-5) is found on the following regulatory lists;
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Poisons Schedule
International Council of Chemical Associations (ICCA) - High Production Volume
continued...
Johnson & Johnson Medical MICROSHIELD* T Triclosan Skin Cleanser
Chemwatch Material Safety Data Sheet
Issue Date: 1-Mar-2006 CHEMWATCH 6518-07
CD 2006/1 Page 15 of 15
Section 15 - REGULATORY INFORMATION
List
OECD Representative List of High Production Volume (HPV) Chemicals
No data available for lanolin, ethoxylated as CAS: 8039-09-6.
Section 16 - OTHER INFORMATION
Denmark Advisory list for selfclassification of dangerous substances
Substance CAS Suggested codes
2,4,4'-trichloro-2'-hydroxydiphenyl 3380-34-5 N;R50/53
ether
Ingredients with multiple CAS Nos
Ingredient Name Cas Nos
lanolin, ethoxylated 61790-81-6, 8039-09-6
cellulose 9004-34-6, 68442-85-3
sodium cumene 28348-53-0, 32073-22-6
sulfonate
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CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 1-Mar-2006
Print Date: 2-Mar-2006
* Trademark of Johnson & Johnson
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