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LEONID CHEMICALS
CONTACT :
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MATERIAL SAFETY DATA SHEET Bangalore-560 022, Karnataka, INDIA
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CYCLOPROPYLAMINE
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SECTION 1- CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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MSDS Name:
CYCLOPROPYLAMINE
Catalog Numbers:
AC154880100, AC154880500, AC263700000, NC9012438, NC9022127, NC9035751,
NC9315427, NC9995526, XXAC15488-159K, XXAC15488-160K, XXAC15488-2KG
Synonyms:
Un Listed
Company Information:
LEONID CHEMICALS
62/A-2 1st Stage, Yeshwanthpur Industrial Suburb
Ashokpuram School Road
Bangalore-560 022, Karnataka, INDIA
Ph: +91-80-2337 8354, Fax: +91-80-2357 4827
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SECTION 2- COMPOSITION, INFORMATION ON INGREDIENTS
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CAS # : 765-30-0
Chemical Name : Cyclopropylamine
% : >97 %
EINECS# : 212-142-2
Hazard Symbols : Un Listed
Risk Phrases : Un Listed
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SECTION 3- HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW
Appearance: clear, colorless liquid. Flash Point: 1 deg C.
Danger! Causes eye and skin burns. Causes digestive and respiratory tract burns.
Flammable liquid and vapor. Harmful if swallowed. May cause allergic skin reaction.
Hygroscopic (absorbs moisture from the air). Corrosive to aluminum.
Target Organs:
Eyes, skin, mucous membranes.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow of tears).
Skin:
Causes skin burns. Amines have been known to cause skin irritation and sensitization.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
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Causes chemical burns to the respiratory tract. Inhalation of vapors may cause nausea,
vomiting, dizziness, and loss of consciousness.
Chronic:
Chronic exposure may cause effects similar to those of acute exposure.
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SECTION 4- FIRST AID MEASURES
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Eyes:
In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes.
Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid immediately. Wash
clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim is fully
conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
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SECTION 5- FIRE FIGHTING MEASURES
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General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating
and highly toxic gases may be generated by thermal decomposition or combustion. Use
water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors are
heavier than air and may travel to a source of ignition and flash back. Vapors can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point:
1 deg C ( 33.80 deg F)
Autoignition Temperature:
275 deg C ( 527.00 deg F)
Explosion Limits, Lower:
Not available.
Upper:
Not available.
NFPA Rating:
(estimated) (estimated) Health: 3; Flammability: 3; Instability: 1
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SECTION 6- ACCIDENTAL RELEASE MEASURES
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General Information:
Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable
container. Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide
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ventilation. A vapor suppressing foam may be used to reduce vapors.
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SECTION 7 - HANDLING and STORAGE
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse.
Ground and bond containers when transferring material. Use spark-proof tools and
explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Discard contaminated shoes. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Use only with adequate ventilation. Do not breathe vapor or mist.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Flammables-area.
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SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
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Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Ventilation fans and other electrical service must be non-sparking and have an explosion-
proof design.
Exposure Limits :
Chemical Name : Cyclopropylamine
ACGIH : none listed
NIOSH : none listed
OSHA - Final PELs : none listed
OSHA Vacated PELs:
Cyclopropylamine: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure
limits are exceeded or if irritation or other symptoms are experienced.
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SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
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Physical State : Liquid
Appearance : clear, colorless
Odor : amine-like - fish-like
pH : Not available.
Vapor Pressure : 148 mm Hg @ 25 deg C
Vapor Density : 2.0 (air=1)
Evaporation Rate : Not available.
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Viscosity : Not available.
Boiling Point : 49-50 deg C @ 760 mm Hg
Freezing/Melting Point : -50 deg C
Decomposition Temperature : Not available.
Solubility : Soluble.
Specific Gravity/Density : .8240 g/ml
Molecular Formula : C3H7N
Molecular Weight : 57.09
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SECTION 10 - STABILITY AND REACTIVITY
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Chemical Stability:
Stable under normal temperatures and pressures. Hygroscopic: absorbs moisture or water
from the air. Amines absorb carbon dioxide from the air to form carbamate salts.
Conditions to Avoid:
Ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Polymerization:
Will not occur.
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SECTION 11 - TOXICOLOGICAL INFORMATION
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RTECS#:
CAS# 765-30-0: Gz0685500
LD50/LC50:
CAS# 765-30-0:
Oral, rat: LD50 = 445 mg/kg;
Carcinogenicity:
CAS# 765-30-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available
Reproductive Effects:
No information available
Mutagenicity:
No information available
Neurotoxicity:
No information available
Other Studies:
Un Listed
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SECTION 12 - ECOLOGICAL INFORMATION
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No information available.
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SECTION 13 - DISPOSAL CONSIDERATIONS
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Chemical waste generators must determine whether a discarded chemical is classified as
a hazardous waste. US EPA guidelines for the classification determination are listed in 40
CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
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RCRA P-Series : None listed.
RCRA U-Series : None listed.
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SECTION 14 - TRANSPORT INFORMATION
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US DOT
Shipping Name : FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S.
Hazard Class : 3
UN Number : Un3286
Packing Group : II
Additional Info : Un Listed
Canada TDG
Shipping Name : FLAMMABLE LIQUID, TOXIC, CORROSIVE,
(CYCLOPROPYLAMINE)
Hazard Class : 3
UN Number : Un3286
Packing Group : II
Additional Info : FP 1 C
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SECTION 15 - REGULATORY INFORMATION
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US FEDERAL
TSCA
CAS# 765-30-0 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313 :
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No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the
CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 765-30-0 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are listed.
.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
FC
Risk Phrases:
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
WGK (Water Danger/Protection)
CAS# 765-30-0: 1
Canada - DSL/NDSL
CAS# 765-30-0 is listed on Canada's NDSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, E, D1B, D2B.
Canadian Ingredient Disclosure List:
Un Listed
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SECTION 16 - ADDITIONAL INFORMATION
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The information above is believed to be accurate and represents the best information
currently available to us. However, we make no warranty of merchantability or any other
warranty, express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine the
suitability of the information for their particular purposes. In no event shall Fisher be
liable for any claims, losses, or damages of any third party or for lost profits or any
special, indirect, incidental, consequential or exemplary damages, howsoever arising,
even if Fisher has been advised of the possibility of such damages.
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