MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Product Name Vanish Marker Step 2 Neutralizer
Mixture
CAS #
Cleaner
Product use
Blue Steel Chemicals Inc.
Manufacturer
9659 - 49 Ave | Edmonton, Alberta, Canada | T6E 5Z5
Phone.780.430.6018 Fax.780.430.6077
www.bluesteelchemicals.com
613-996-6666
CANUTEC
LEGEND Health * 3
0
HMIS/NFPA
Flammability 0
Severe 4
3 0
Serious 3
Physical Hazard 0
Moderate 2
Slight 1 Personal Protection
B
Minimal 0
2. Hazards Identification
DANGER -- CORROSIVE
Emergency overview
Contains a potential mutagen.
Potential short term health effects
Eye, Skin contact, Inhalation, Ingestion.
Routes of exposure
Causes chemical burns. May cause blindness.
Eyes
May cause chemical burns.
Skin
May cause respiratory tract irritation.
Inhalation
Harmful if swallowed. May cause chemical burns to mouth, throat and stomach.
Ingestion
Eyes. Respiratory system. Skin.
Target organs
Prolonged or repeated exposure to dilutions can cause drying, defatting and dermatitis.
Chronic effects
The product causes burns of eyes, skin and mucous membranes.
Signs and symptoms
3. Composition / Information on Ingredients
Ingredient(s) CAS # Percent
Phosphoric acid 7664-38-2 10 - 30
Ethanol, 2-[2-[2-(tetradecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt 25446-80-4 1-5
Sodium dodecylbenzenesulfonate 25155-30-0 1-5
Ethanol 64-17-5 0.1 - 1
4. First Aid Measures
First aid procedures
Immediately flush with cool water. Remove contact lenses, if applicable, and continue
Eye contact
flushing for 15 minutes. Obtain medical attention immediately.
Immediately flush with water. W ash with soap and water. Obtain medical attention if
Skin contact
irritation persists.
If symptoms develop move victim to fresh air. If symptoms persist, obtain medical
Inhalation
attention.
Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water.
Ingestion
Obtain medical attention. Never give anything by mouth if victim is unconscious, or is
convulsing.
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Symptoms may be delayed.
Notes to physician
If you feel unwell, seek medical advice (show the label where possible). Ensure that
General advice
medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with
eyes and skin. Keep out of reach of children.
5. Fire Fighting Measures
Not flammable by W HMIS/OSHA criteria.
Flammable properties
Extinguishing media
Dry chemical. Carbon dioxide. Fog.
Suitable extinguishing media
Unsuitable extinguishing media Not available
Protection of firefighters
Not available
Specific hazards arising from
the chemical
Firefighters should wear full protective clothing including self contained breathing
Protective equipment for
apparatus.
firefighters
May include and are not limited to: Oxides of phosphorus. Oxides of carbon.
Hazardous combustion products
Explosion data
Not available
Sensitivity to mechanical
impact
Not available
Sensitivity to static discharge
6. Accidental Release Measures
Keep unnecessary personnel away. Do not touch or walk through spilled material. Do
Personal precautions
not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Keep people away from and upwind of spill/leak.
Stop leak if you can do so without risk. Prevent entry into waterways, sewers,
Methods for containment
basements or confined areas.
Before attempting clean up, refer to hazard data given above. Small spills may be
Methods for cleaning up
absorbed with non-reactive absorbent and placed in suitable, covered, labelled
containers. Prevent large spills from entering sewers or waterways. Contact emergency
services and supplier for advice. Never return spills in original containers for re-use.
7. Handling and Storage
Use good industrial hygiene practices in handling this material. Do not get this material
Handling
in your eyes, on your skin, or on your clothing.
Keep out of the reach of children.Store in a closed container away from incompatible
Storage
materials.
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8. Exposure Controls / Personal Protection
Exposure limits
Ingredient(s) Exposure Limits
Ethanol ACGIH-TLV
TW A: 1000 ppm
OSHA-PEL
TW A: 1000 ppm
Ethanol, 2-[2-[2-(tetradecyloxy)ethoxy]ethoxy]-, hydrogen ACGIH-TLV
sulfate, sodium salt Not established
OSHA-PEL
Not established
Phosphoric acid ACGIH-TLV
TW A: 1 mg/m3
STEL: 3 mg/m3
OSHA-PEL
TW A: 1 mg/m3
Sodium dodecylbenzenesulfonate ACGIH-TLV
Not established
OSHA-PEL
Not established
General ventilation normally adequate.
Engineering controls
Personal protective equipment
W ear chemical goggles.
Eye / face protection
Rubber gloves. Confirm with a reputable supplier first.
Hand protection
As required by employer code.
Skin and body protection
W here exposure guideline levels may be exceeded, use an approved NIOSH respirator.
Respiratory protection
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. W hen using do not
eat or drink. W ash hands before breaks and immediately after handling the product.
9. Physical & Chemical Properties
Clear.
Appearance
light green
Color
Liquid
Form
Mint.
Odor
Not available
Odor threshold
Liquid
Physical state
1.15
pH
Not available
Melting point
Not available
Freezing point
Not available
Boiling point
Not available
Flash point
Not available
Evaporation rate
Not available
Flammability limits in air, lower, %
by volume
Not available
Flammability limits in air, upper, %
by volume
Not available
Vapor pressure
Not available
Vapor density
Not available
Specific gravity
Not available
Octanol/water coefficient
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Not available
Solubility (H2O)
Not available
Auto-ignition temperature
Not available
VOC (Weight %)
Not available
Viscosity
Not available
Percent volatile
10. Chemical Stability & Reactivity Information
Stable under recommended storage conditions.
Chemical stability
Do not mix with other chemicals. Reacts violently with alkaline material. This product
Conditions to avoid
may react with reducing agents.
Reducing agents. Caustics. Oxidizers.
Incompatible materials
Hazardous decomposition products May include and are not limited to: Oxides of carbon. Oxides of phosphorus.
Hazardous polymerization does not occur.
Possibility of hazardous reactions
11. Toxicological Information
Component analysis - LC50
Ingredient(s) LC50
Ethanol 31623 ppm rat
Ethanol, 2-[2-[2-(tetradecyloxy)ethoxy]ethoxy]-, hydrogen Not available
sulfate, sodium salt
Phosphoric acid Not available
Sodium dodecylbenzenesulfonate Not available
Component analysis - Oral LD50
Ingredient(s) LD50
Ethanol 3450 mg/kg mouse; 1501 mg/kg rat
Ethanol, 2-[2-[2-(tetradecyloxy)ethoxy]ethoxy]-, hydrogen Not available
sulfate, sodium salt
Phosphoric acid 1530 mg/kg rat
Sodium dodecylbenzenesulfonate 438 mg/kg rat
Effects of acute exposure
Causes chemical burns. May cause blindness.
Eye
May cause chemical burns.
Skin
May cause respiratory tract irritation.
Inhalation
Harmful if swallowed. May cause chemical burns to mouth, throat and stomach.
Ingestion
Non-hazardous by W HMIS/OSHA criteria.
Sensitization
Non-hazardous by W HMIS/OSHA criteria.
Chronic effects
Non-hazardous by W HMIS/OSHA criteria.
Carcinogenicity
ACGIH - Threshold Limits Values - Carcinogens
Ethanol 64-17-5 A4 - Not Classifiable as a Human Carcinogen
Mutagenic effects were observed in somatic and reproductive cells of live animals (rats
Mutagenicity
and mice) exposed to high oral doses of ethanol.
Non-hazardous by W HMIS/OSHA criteria.
Reproductive effects
Non-hazardous by W HMIS/OSHA criteria.
Teratogenicity
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12. Ecological Information
Components of this product have been identified as having potential environmental
Ecotoxicity
concerns.
Ecotoxicity - Freshwater Fish Species Data
Ethanol 64-17-5 96 Hr LC50 Oncorhynchus mykiss: 12900 mg/L [flow-through] (30 days old); 96 Hr LC50
Pimephales promelas: 14.2 mg/L
Phosphoric acid 7664-38-2 96 Hr LC50 Gambusia affinis: 3-3.5 mg/L
Sodium dodecylbenzenesulfonate 25155-30-0 96 Hr LC50 Oncorhynchus mykiss: 10.8 mg/L [static]
Ecotoxicity - M icrotox Data
Ethanol 64-17-5 5 Min EC50 Photobacterium phosphoreum: 35470 mg/L; 30 min EC50 Photobacterium
phosphoreum: 34634 mg/L
Ecotoxicity - Water Flea Data
Ethanol 64-17-5 48 Hr EC50 Daphnia magna: 9268 mg/L; 24 Hr EC50 Daphnia magna: 10800 mg/L
Phosphoric acid 7664-38-2 12 Hr EC50 Daphnia magna: 4.6 mg/L
Not available
Environmental effects
Not available
Aquatic toxicity
Not available
Persistence / degradability
Not available
Bioaccumulation / accumulation
Not available
Partition coefficient
Not available
Mobility in environmental media
Not available
Chemical fate information
13. Disposal Considerations
Not available
Waste codes
Dispose in accordance with all applicable regulations.
Disposal instructions
Not available
Waste from residues / unused
products
Not available
Contaminated packaging
14. Transport Information
Department of Transportation (DOT)
Basic shipping requirements:
Phosphoric acid solution
Proper shipping name
8
Hazard class
UN1805
UN number
III
Packing group
Additional information:
A7, IB3, N34, T4, TP1
Special provisions
154
Packaging exceptions
154
ERG number
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Transportation of Dangerous Goods (TDG)
Basic shipping requirements:
PHOSPHORIC ACID, LIQUID
Proper shipping name
8
Hazard class
UN1805
UN number
III
Packing group
15. Regulatory Information
This product has been classified in accordance with the hazard criteria of the Controlled
Canadian federal regulations
Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
Canada - WHM IS - Ingredient Disclosure List
Ethanol 64-17-5 0.1 %
Phosphoric acid 7664-38-2 1%
Sodium dodecylbenzenesulfonate 25155-30-0 1%
This product is a "Hazardous Chemical" as defined by the OSHA Hazard
US Federal regulations
Communication Standard, 29 CFR 1910.1200.
U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Phosphoric acid 7664-38-2 5000 Lb final RQ; 2270 kg final RQ
Sodium dodecylbenzenesulfonate 25155-30-0 1000 Lb final RQ; 454 kg final RQ
Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical
CERCLA (Superfund) reportable quantity
Phosphoric acid: 5000.0000
Sodium dodecylbenzene sulfonate: 1000.0000
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
No
Section 302 extremely
hazardous substance
Section 311 hazardous chemical Yes
Not available
Clean Air Act (CAA)
Not available
Clean Water Act (CWA)
Not available
Safe Drinking Water Act (SDWA)
Not available
Drug Enforcement Agency (DEA)
Not available
Food and Drug Administration
(FDA)
Controlled
WHMIS status
Class D - Division 2A, Class E - Corrosive Material
WHMIS classification
WHMIS labeling
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W ARNING: This product contains a chemical known to the State of California to cause
State regulations
birth defects or other reproductive harm.
U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances
Ethanol 64-17-5 Present (refers to solutions greater than or equal to 25% which are not beverage alcohols)
Phosphoric acid 7664-38-2 Present
Sodium dodecylbenzenesulfonate 25155-30-0 Present (exempt when in solution)
U.S. - California - Proposition 65 - Developmental Toxicity
Ethanol 64-17-5 developmental toxicity, initial date 10/1/87 (when in alcoholic beverages)
U.S. - Louisiana - Reportable Quantity List for Pollutants
Phosphoric acid 7664-38-2 5000 Lb final RQ; 2270 kg final RQ
Sodium dodecylbenzenesulfonate 25155-30-0 1000 Lb final RQ; 454 kg final RQ
U.S. - M assachusetts - Right To Know List
Ethanol 64-17-5 Teratogen
Phosphoric acid 7664-38-2 Present
Sodium dodecylbenzenesulfonate 25155-30-0 Present
U.S. - M innesota - Hazardous Substance List
Ethanol 64-17-5 Present
Phosphoric acid 7664-38-2 Present
U.S. - New Jersey - Right to Know Hazardous Substance List
Ethanol 64-17-5 sn 0844
Phosphoric acid 7664-38-2 sn 1516
Sodium dodecylbenzenesulfonate 25155-30-0 sn 1698
U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances
Phosphoric acid 7664-38-2 5000 Lb RQ (air); 100 lb RQ (land/water)
Sodium dodecylbenzenesulfonate 25155-30-0 1000 Lb RQ (air); 100 lb RQ (land/water)
U.S. - Pennsylvania - RTK (Right to Know) List
Ethanol 64-17-5 Present
Phosphoric acid 7664-38-2 Environmental hazard
Sodium dodecylbenzenesulfonate 25155-30-0 Environmental hazard
U.S. - Rhode Island - Hazardous Substance List
Ethanol 64-17-5 Toxic; Flammable
Phosphoric acid 7664-38-2 Toxic; Flammable
Inventory name
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
16. Other Information
Information contained herein was obtained from sources considered technically accurate
Disclaimer
and reliable. W hile every effort has been made to ensure full disclosure of product
hazards, in some cases data is not available and is so stated. Since conditions of actual
product use are beyond control of the supplier, it is assumed that users of this material
have been fully trained according to the requirements of all applicable legislation and
regulatory instruments. No warranty, expressed or implied, is made and supplier will not
be liable for any losses, injuries or consequential damages which may result from the
use of or reliance on any information contained in this document.
22-Jan-2008
Issue date
15-Jan-2008
Effective date
15-Jan-2011
Expiry date
Dell Tech Laboratories Ltd. (519) 858-5021
Prepared by
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